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Lab 5
Date: 17.10.16
Abstract
1. Introduction
One of the main branches of chemical thermodynamics
which deals with time and rate of chemical reaction is kinetics.
Chemical kinetics involves investigations of how different physical
and chemical conditions can influence the reaction rate or speed
and tries to determine the reaction mechanism. This experiment
consists of two parts. First part investigates the dependence of
rate of reaction on concentration and determination of reaction
order. Second part involves kinetic analysis of reaction at different
temperatures. The reaction that will be analysed in this work is
called Iodine Clock Reaction. First introduced by Hans Heinrich
Landolt in 1886, it remains as one of the most important reactions
to understand chemical kinetics. There are some variations of this
process and most famous involves reactions of bromate and
iodine, with subsequent reduction with persulfate.
2. Theory
The main aim of the experiment is to analyse the kinetics of
the following reaction:
There are various factors that can affect the rate of proceeding
reaction. The most significant deviation occurs due to change of
temperature, concentration, from nature of reactants and
presence of catalyst. Reacting particles should come in direct
contact and should have sufficient energy to collide. This factor is
affected by surface area of reacting substances. Changing the
concentration of reagent will increase probability of colliding
those increasing the rate of reaction. By increasing the
temperature of system one increases the kinetic energy of
particles. This results in increased velocity of molecules and
greater proportion of collisions. Also, adding catalyst can greatly
enhance the reaction rate. Depending on different types of
catalyst mechanism of actions can vary.
Br O3
Br O3
changeconcetration of =
changetime
3. Method
Part A.
Part B.
4. Materials
5. Results and Discussion
Part A.
log ( 1.84)
m= =0.880 1
log ( 2)
1.6 10
8.0 10
(3)n =2n
(2)n
r3
=2.21=
r1
log ( 2.21)
n= =1.14 1
log ( 2)
H
+
r4 (0.04)n n
=3.77= =2
r1 (0.02)n
log ( 3.77)
p= =1.92 2
log ( 2)
Rate of each reaction has been calculated and reaction orders are
known. Using data above rate constant of clock reaction can be
calculated:
I
Br O3
+
H
2
r
k 1= 1
Part B.
lnk vs 1/T
5
ln(rate constant)
2
0
0 0 0 0 0 0 0 0 0 0 0
1/Temperature
Rate constant,
Temperature, K Time, s Rate, M/s
k
278.15 425 7.84310-8 12.25
293.65 230 1.44910-7 22.64
313.15 58 5.74710-7 85.53
A=k exp [ ]
Ea
RT
=22.64 exp[ 41548
]
8.314 293.65
=556.8 106
20.37 6
A=e =702.4 10
References
Post lab Questions
[ ]
Ea
RT
=702.4 106
[ 41548
8.314 (273.15+85)]= 612.0
k= A exp