4.

3.5

2.5
450
300
2 600

1.5

0.5

0
0 5 10 15 20 25
 Pc = 111.3 atm
Tc = 405.5 K
R= 0.08206 atm L/mol K

a= 4.19694587
b= 0.03737122

T= 450 K
Pr P V
1 111.3 0.23350862
2 222.6 0.07726756
4 445.2 0.06065428
10 1113 0.05087528
20 2226 0.04617505

T= 300 K
Pr P V
1 111.3 0.05236534
2 222.6 0.05058869
4 445.2 0.04836396
10 1113 0.04512772
20 2226 0.0428243
 T= 600 K
Pr P V
1 111.3 0.39289672
2 222.6 0.17318039
4 445.2 0.08597708
10 1113 0.0583681
20 2226 0.04997495
 P= 2226 atm
T= 600 K

V= 0.0221186 L/mol gas ideal

V= 0.04997495 L/mol van der Waals

f(V) = -2.452E-007

Z= 2.25940842

Z
0.70380778
0.46577729
0.7312613
1.53340869
2.78348232

Z
Z
5
0.23674802
0.45743122 4
0.87462966 3 Z
2.04026145 2
3.8722434 1
0
0 5 10 15 20 25
 2
1
0
0 5 10 15 20 25

Z
0.88815917
0.78296278
0.77741887 Z
1.31943487
2.5
2.25940842

1.5 Z

0.5

0
0 5 10 15 20 25
 Z

20 25
20 25

20 25
 Tc = 405.5 K
Pc = 111.3 atm
R= 0.08206 atm L/mol K

a = 85.634871126
b = 0.0259027367

P = 2226 atm
T = 600 K
V = 0.0397009465 L
f(V) = -2.28636E-007
Z = 1.7949123988

T = 300 T=
Pr P V Z V
1 111.3 0.036844886 0.16657876 0.05376804
2 222.6 0.0359784726 0.32532326 0.07371508
4 445.2 0.0347098706 0.6277047 0.05087634
10 1113 0.0325313736 1.47077012 0.03980301
20 2226 0.030766253 2.78193513 0.0348354
 3

2.5

1.5

0.5

0
0 5 10 15 20 25

450 T = 600
Z V Z
0.16205982 0.02369718 0.05356844
0.44436255 0.02541514 0.11490393
0.61337632 0.08780905 0.79398389
1.19968443 0.05016798 1.13406784
2.09991586 0.03970095 1.7949124
 T = 300
T = 450
T = 600

15 20 25
 F= 70
Xf xyleno = 0.15 10.5
Xf estireno = 0.25 17.5
Xf tolueno = 0.4 28
Xf Benceno = 0.2 14
1 70

D1 = 26.25
B1 = 17.5
D2 = 8.75
B2 = 17.5
70

f1 = 1.1191E-013
f2 = -3.553E-014
f3 = -1.030E-012
f4 = 4.6185E-014
 0.07 0.18 0.15 0.24
0.04 0.24 0.1 0.65
0.54 0.42 0.54 0.1
0.35 0.16 0.21 0.01

-2.81048387 1.22177419 -1.80241935 6.060483871

94.3629032 -29.8306452 -36.6854839 41.137096774
-66.0443548 20.2459677 30.5282258 -36.20564516
-24.5080645 9.36290323 8.95967742 -9.991935484

26.25
17.5
8.75
17.5

26.25
17.5 43.75 D
8.75
17.5 26.25 B

XDX = 0.114
XDS = 0.12
XDT = 0.492
XDB = 0.274
1

XBX = 0.21
XBS = 0.46666667
XBT = 0.24666667
XBB = 0.07666667
1
 10.5
17.5
28
14

70 F
 P
800

f(x) ==
f(x) 3.96314780457257E-006x^4 + 0.0004131216x^3
0.0007449112x^3 + 0.0394480731x^2 + 0.0360442962x^2
+ 1.1980993852x + 1.6061958
+ 24.4593586919
RR== 0.999996306
0.9996198817700 + 2.0671479468x - 0.582064627
f(x) = 0.0861525706x^2
R = 0.9841859905

600

f(x) = 5.8907195869x + 64.4059714751

500
R = 0.7798188129

400

300

200
 400

300

200

100

0
-60 -40 -20 0 20 40 60 80

A=
B=
T P 1/Tabs log(P) Pestimada
-36.7 1 0.00422922 0 2.99951066
-19.6 5 0.003944 0.69897 9.28083633
-11.5 10 0.0038219 1 15.0510788
-2.6 20 0.00369617 1.30103 24.7622281
7.6 40 0.00356189 1.60205999 42.1440357
15.4 60 0.0034656 1.77815125 61.7057099
26.1 100 0.00334169 2 100.794503
42.2 200 0.00317108 2.30103 198.083546
60.6 400 0.00299625 2.60205999 395.833756
80.1 760 0.00283086 2.88081359 762.017875

A= 6.60788682
B= 1049.44111
C= 201.456626
T P Pestimada error^2 residuos
-36.7 1 1.73078236 0.53404286 -0.73078236
-19.6 5 6.87354644 3.51017626 -1.87354644
-11.5 10 12.1129898 4.46472588 -2.1129898
-2.6 20 21.4048004 1.9734641 -1.40480038
7.6 40 38.7255461 1.62423277 1.27445391
15.4 60 58.6888045 1.71923364 1.3111955
26.1 100 99.1075512 0.79646481 0.89244877
42.2 200 199.911356 0.00785768 0.08864354
60.6 400 401.099303 1.20846662 -1.09930279
80.1 760 759.63369 0.134183 0.36630998
15.9728476
 a0 = -0.58206463
a0 = 64.4059724 a1 = 2.06714836
a1 = 5.89071956 a2 = 0.08615257
T P Pestimada error^2 Pestimada error^2
-36.7 1 -151.783435 23342.7781 39.5916197 1489.31311
-19.6 5 -51.0521309 3141.84137 -8.00180282 169.046877
-11.5 10 -3.33730245 177.883637 -12.9605939 527.188873
-2.6 20 49.0901016 846.234011 -5.37425901 643.85302
7.6 40 109.175441 4785.24165 20.1044351 395.833504
15.4 60 155.123054 9048.39533 51.6839625 69.15648
26.1 100 218.153753 13960.3093 112.058497 145.40734
42.2 200 312.994338 12767.7204 240.075531 1606.04816
60.6 400 421.383578 457.257389 441.070361 1686.77457
80.1 760 536.252609 50062.895 717.752241 1784.87318
118590.556 8517.49512

3 + 0.0360442962x^2
80993852x + 1.6061958278x + 24.6787572055
+ 24.4593586919
27

4751 P
Linear (P)
Polynomial (P)
Polynomial (P)
Polynomial (P)
 Polynomial (P)
Polynomial (P)

40 60 80 100

7.75047622
log(P)
1719.80153 3.5
error^2
3
3.99804287 f(x) = - 2035.3310261357x + 8.7520099666
18.3255597 2.5 R = 0.9915015993
25.5133969 2
22.6788161
4.59688908 1.5
2.90944617 1
0.63123438
0.5
3.67279678
17.357593 0
4.07181839 0.00260.0028 0.003 0.00320.00340.00360.0038 0.004 0.00420
103.755593

residuos
2

1.5

0.5

0
-60 -40 -20 0 20 40 60 80 100
-0.5

-1

-1.5

-2

-2.5
 -1

-1.5

-2

-2.5
 a0 = 24.660293278
a0 = 24.45936698 a1 = 1.6059158217
a1 = 1.1982151168 a2 = 0.0362935314
a2 = 0.0394525774 a3 = 0.0004280918
a3 = 0.000744819 a4 = 3.73008E-006
Pestimada error^2 Pestimada error^2
-3.19389075 17.588719588 0.21242562 0.6202733964
10.5223115 30.495924305 4.45401566 0.2980988955
14.7647199 22.702555999 10.4062462 0.165035983
21.5976162 2.552377396 20.7229027 0.5225883557
36.1715404 14.657102977 39.1619343 0.7023541514
54.9887286 25.112841406 59.7720731 0.051950683
95.8508411 17.215519599 100.64044 0.4101630172
201.256997 1.5800426027 201.064186 1.1324924543
407.711021 59.45985089 400.836164 0.6991705676
756.343686 13.368631285 759.709377 0.0844617791
204.73356605 4.6865892831
 log(P)

310261357x + 8.7520099666
5993
log(P)
Linear (log(P))

0.00340.00360.0038 0.004 0.00420.0044

residuos

60 80 100
 A = 9.7134140697
B = 1663.5441363
T/(K) P/(Pa) Pestimada error^2 residuales
290.08 8634 9520.00084 784997.48221 886.00083646
302.39 15338 16296.4921 918707.14138 958.49211858
311.19 22484 23316.5047 693064.04578 832.50468214
318.69 30464 31150.8209 471722.93433 686.82088955
325.1 38953 39481.2774 279077.03345 528.27742091
330.54 47571 47929.9235 128826.04457 358.92345225
334.89 55511 55715.9551 42006.603107 204.95512462
338.94 63815 63875.6808 3682.1546122 60.680759819
342.95 72985 72899.4191 7324.0971255 -85.580939031
346.24 81275 81061.7004 45496.732486 -213.29963077
349.91 91346 91034.9825 96731.876686 -311.01748614
353.47 102040 101646.085 155168.63424 -393.91450118
356.19 110850 110415.464 188821.2435 -434.53566424
358.87 120140 119648.648 241426.54746 -491.35175532
362.29 132780 132332.571 200192.63398 -447.428915
365.23 144530 144088.407 195004.27126 -441.59287954
367.9 155800 155483.736 100022.64214 -316.26356436
370.53 167600 167409.436 36314.523776 -190.56370005
373.15 180060 180012.65 2242.0286416 -47.350064853
375.84 193530 193736.33 42571.912365 206.32962067
378.52 207940 208232.974 85833.735301 292.97394987
381.32 223440 224295.528 731928.09427 855.5279623
$5,451,162.41
 A= 10
A= 9.0623192805 B= 1000
B= 1230.506819285 C= 1
C= -49.911887979 D= 0.000005
Pestimada error^2 residuales Pestimada error^2
8685.5313255 2655.47750467 51.5313255 79E+016 4.5829951E+032
15438.406371 10081.43930836 100.406371 93E+016 3.0867915E+032
22529.528765 2072.868419393 45.5287647 29E+016 2.4064961E+032
30490.752522 715.697444795 26.7525222 39E+016 1.9863746E+032
38976.939767 573.112439456 23.9397669 51E+016 1.7095716E+032
47587.005008 256.1602861383 16.0050082 71E+016 1.5195671E+032
55516.218862 27.2365198646 5.21886193 54E+016 1.3913222E+032
63815.231445 0.0535666017 0.2314446 75E+016 1.2876513E+032
72976.580021 70.8960489644 -8.41997915 41E+016 1.1977400E+032
81246.498743 812.3216300009 -28.5012566 04E+016 1.1321813E+032
91328.025792 323.0721586802 -17.9742082 81E+016 1.0666901E+032
102025.14846 220.5681895005 -14.8515383 97E+016 1.0099604E+032
110842.57949 55.063996112 -7.42051185 210E+015 9.7063819E+031
120103.77608 1312.172536091 -36.2239222 941E+015 9.3497460E+031
132788.67074 75.1818004133 8.67074394 249E+015 8.9349589E+031
144507.17444 521.0061564806 -22.8255593 966E+015 8.6112032E+031
155831.88319 1016.537712863 31.8831886 296E+015 8.3411039E+031
167648.1625 2319.626498419 48.162501 752E+015 8.0955277E+031
180097.20995 1384.580487375 37.2099515 106E+015 7.8695701E+031
193609.18344 6270.017058407 79.1834393 960E+015 7.6555504E+031
207833.99868 11236.28060962 -106.001324 663E+015 7.4591308E+031
223539.34956 9870.334897481 99.3495591 675E+015 7.2705494E+031
$51,869.71 ###
Ca0 = 1.5
Cb0 = 1.5
K1 = 1.06
K2 = 2.63
K3 = 5

Cd0 = 0
Cx0 = 0
Cz0 = 0

Ca = 0.4206889687
Cb = 0.2428965021
Cc = 0.1535655082
Cd = 0.7053345031
Cx = 0.1777924666
Cy = 0.5517689949
Cz = 0.3739765283
f1 = -1.39703E-007
f2 = 9.537726E-009
f3= 1.188948E-007
a 350 K K1 = 0.7 a 330 K
a 350 K K2 = 4 a 330 K
a 350 K K3 = 5 a 330 K

a 350 K a 330 K
Ca = 0.42068897 0.42749156
Cb = 0.2428965 0.2445263
Cc = 0.15356551 0.10738168
Cd = 0.7053345 0.68142769
Cx = 0.17779247 0.18296526
Cy = 0.55176899 0.57404601
Cz = 0.37397653 0.39108075
rho p = 1800
rho = 994.6
Dp = 2.08E-04
mu = 8.93E-04
g = 9.80665

vt = 0.0157816184
Re = 3.6556384641
Cd = 8.8426582734

f(vt) = -7.01E-10

Cd = 6.5652006443
Cd = 8.8426582734
Cd = 0.44
Cd = -21883.812148
kg/m3 rho p = 1800 kg/m3
kg/m3 rho = 994.6 kg/m3
m Dp = 2.08E-04 m
kg/ms mu = 8.93E-04 kg/ms
m/s2 g = 294.1995 m/s2

m/s vt = 0.20602148 m/s

Re = 47.7226106
Cd = 1.5566185

f(vt) = -4.335E-007

Cd = 0.50290627
Cd = 1.5566185
Cd = 0.44
Cd = -1676.16423
 T = 60 F
P1 = 21600 lbf/ft2
P2 = 0 lbf/ft2
z1 = 0
z2 = 300 ft
L = 1000 ft
D = 0.6650833333 ft
epsilon = 0.00015 ft
gc = 32.174 lbm ft/lbf s2
g = 32.174 ft/s2
densidad = 62.35393696 lbm/ft3
viscosidad = 0.000760873 lbm/ft s

v= 11.613317491 ft/s
Re = 632971.34823
fF = 0.0038479505

fF = 2.527761E-005
fF = 0.0038479505

f(v) = -8.76119E-008