PP PEPERIKSAAN PERCUBAAN AR3 KIMIA KERTAS 2

No RUBRIC Sub- Total

Mark Mark
1(a) Able to state the meaning of empirical formula correctly

Chemical formula which shows the simplest whole number ratio of atoms of 1 1
each element in a compound
Formula kimia menunjukkan nisbah nombor atom teringkas bagi setiap
unsur dalam sebatian

r : molecule

(b) Able to name the substance X correctly

Anhydrous calcium chloride 1 1

Kalsium klorida kontang

(c) Able to calculate the empirical formula of lead oxide correctly.

1. Mass of lead and oxygen 1

2. No of mole of lead and oxygen 1
3. Simplest ratio and empirical formula 1 3
Element Pb O
Mass (g) 1.04 0.08
No. of mole = 0.005 = 0.005
Simplest ratio of 1 1
mole

Empirical formula: PbO (Simplest ratio of mole is shown)

(d) Able to write balance chemical equation for the production of hydrogen
gas correctly

1. Correct formula of reactant and product 1

2. Balance 1 2

Zn + 2HCl ZnCl2 + H2

(e) Able to state the change of oxidation number for lead correctly
1 1
+2 0

(f) Able to state how to ensure all the lead oxide has completely reacted
correctly

Repeat heating, cooling and weighing until a constant mass obtained 1 1

Ulangi pemanasan, penyejukan dan penimbangan sehingga jisim tetap
diperoleh.

(g) Able to explain why no changes when lead oxide is replaced with zinc
oxide correctly

Zinc is more reactive than hydrogen//Hydrogen is less reactive than zinc 1 1

Zink lebih reaktif daripada hidrogen//Hidrogen kurang reaktif daripada zink

a: zinc is higher than hydrogen in reactivity series.

r: more electropositive in ECS / zinc is a reactive metal

Total 10
No RUBRIC Sub- Total
Mark Mark
2 (a) (i) Able to choose an element that is monoatomic correctly

W 1 1

(ii) Able to state element forms an amphoteric oxide correctly

R 1 1

(b) Able to write the electron arrangement correctly

2.8.1 1 1

(c) Able to mark the correct value of pH of the solution correctly

pH value 1 1
4 7 11

(d) Able to show the position of element P in the Periodic Table correctly

1 1

(e) (i) Able to draw the electron arrangement correctly

1. Correct number of shells with electron and nucleus shown 1
2. Label correct charge of ion and correct ratio of ion 1 2

T P

(ii) Able to state one physical properties of the compound formed correctly

High melting and boiling points//conduct electricity in the molten state or in 1 1

aqueous state//cannot conduct electricity in solid state//soluble in
water//insoluble in organic solvent
Takat lebur dan didih yang tinggi//mengalirkan arus elektrik dalam keadaan
leburan atau akueus//larut dalam air//tidak larut dalam pelarut organic/tidak
mengalirkan arus elektrik dalam keadaan pepejal

(f) (i) Able to state element used to fill the hot air balloon and state the reason
correctly

Gas W 1
Light//inert//not reactive 1 2
Ringan//lengai//tidak reaktif

Total 10
No RUBRIC Sub- Total
Mark Mark
3 (a) (i) Able to name the process correctly

Haber process 1 1
Proses Haber

(ii) Able to write balance chemical equation for the reaction to manufacture
ammonia

1. Correct formula of reactant and product 1

2. Balance 1 2

N2 + 3H2 2NH3

(b) (i) Able to name the catalyst used

Iron 1 1
Ferum

(ii) Able to state the temperature and pressure correctly

o o
Temperature : 450 C 550 C 1
Suhu

Pressure : 200 500 atm 1 2

Tekanan

(c) (i) Able to write a chemical formula of salt R correctly

(NH4)2SO4 1 1

(ii) Able to calculate the percentage of nitrogen by mass correctly in salt R

and urea

Percentage of N by mass in (NH4)2SO4 1

Peratus N mengikut jisim dalam (NH4)2SO4
= x 100 %
= 21.21%

Percentage of N by mass in CO(NH2)2

1 2
Peratus N mengikut jisim dalam (NH4)2SO4
= x 100%
= 46.67%

(iii) Able to state the best fertilizer for the growth of the plants correctly.

Urea//CO(NH2)2 1 1

Total 10
No RUBRIC Sub- Total
Mark Mark
4 (a) Able to state the substance required for the fermentation process correctly

Yeast//zymase 1 1
Yis//zimase

(b) Able to state the homologous series of compound P correctly

Alcohol 1 1
Alkohol

(c) Able to state the name of the compound Q correctly

Ethanoic acid 1 1
Asid etanoik

(d) (i) Able to explain the answer correctly

High heat of combustion//less sooty//complete combustion//does not pollute the 1 1

environment
Mempunyai haba pembakaran yang tinggi / kurang berjelaga/ pembakaran
berlaku lengkap/ tidak mencemarkan alam sekitar

(ii) Able to write a balanced chemical equation when substance P is burnt

completely in excess oxygen ocrrectly

1. Correct formula of reactants and products 1

2. Balance 1 2

C2H5OH + 3O2 2CO2 + 3H2O

(e) (i) Able to state the reaction to produce compound R correctly

Esterification 1 1
Pengesteran

(ii) Able to compare the electrical conductivity between compound Q and

compound R and able to explain correctly

Compound Q can conduct electricity but compound R cannot conduct electricity 1

Compound Q has free moving ions//Compound R does not have free moving 1 2
ions
Bahan Q boleh mengkonduksi elektrik tetapi bahan R tidak boleh.
Bahan Q mengandungi ion-ion yang bergerak bebas//bahan R tiada ion-ion
bergerak bebas

(f) Able to draw the structural formula of the compound X with correct
functional group

1 1

Total 10
No RUBRIC Sub- Total
Mark Mark
5 (a) (i) Able to state the colour change of iron(II) sulphate

Green to brown 1 1
Hijau ke perang

(ii) Able to describe a chemical test to verify the product correctly

1. Add potassium hexacyanoferrate(II) solution 1

2. A dark blue precipitate is formed. 1 2
1. Tambah larutan kalium heksasianoferat(II)
2. Satu mendakan biru gelap terhasil.
Or
1. Add potassium thiocyanate solution.
2. Blood red colouration is formed.
1. Tambah larutan kalium tiosianat
2. Warna merah darah terhasil.
Or
1. Add sodium hydroxide solution / ammonium solution slowly until excess.
2. A brown precipitate is formed.
1. Tambah larutan natrium hidroksida dan larutan ammonium secara
perlahan-lahan sehingga berlebihan
2. Satu mendakan perang terhasil

(b) (i) Able to state the role of magnesium correctly

As reducing agent // To reduce iron(III) ion to iron(II) ion 1 1

Sebagai agen penurunan // Untuk menurunkan ion ferum(III) kepada ion
ferum(II)

(ii) Able to write the ionic equation for the reaction correctly
1. Correct formula of reactants and products 1
2. Balanced equation 1 2
3+ 2+ 2+
Mg + 2Fe Mg + 2Fe

(c) Able to suggest a method to reduce iron(II) to iron

Displacement of metal by using zinc / magnesium metal 1 1

(d) Able to draw a labeled diagram and mark the positive and negative
terminal correctly

1. Functional set-up apparatus 1

2. Label: carbon, bromine water, iron(II) sulphate solution, dilute sulphuric 1
acid
3. Negative terminal: carbon immersed in iron(II) sulphate solution 1 3
Positive terminal: carbon immersed in bromine water

Bromine water
Air bromin Iron(II) sulphate
Iron(II) sulphate solution
solution
Larutan ferum(II) sulfat
Larutan ferum(II) sulfat

Carbon electrode
+ - Elektrod karbon
Bromine water
Air bromin
Iron(II) sulphate solution
Porous
Porous
pospot Larutan ferum(II) sulfat
Pasu
Pasu berliang
berliang

Carbon electrode
Salt bridge + - Elektrod karbon
Salt bridge
Titian garam
Titian garam

Iron(II) sulphate
solution
Bromine water Larutan ferum(II)
Air bromin sulfat

Total 10
No RUBRIC Sub- Total
Mark Mark
6 (a) (i) Able to name solution P and solution Q correctly

1. Solution P: nitric acid 1

2. Solution Q: ethanoic acid 1 2
1. Larutan P: Asid nitrik
2. Larutan Q: Asid etanoik

r: chemical formula

(ii) Able to state the solution with higher pH value correctly

1 1
1. Q / Ethanoic acid / CH3COOH
Q / Asid etanoik / CH3COOH

(b) (i) Able to write the chemical equation correctly

CH3COOH + KOH CH3COOK + H2O 1 1

(ii) Able to calculate the mass of potassium ethanoate correctly

1. Number of moles of solution Q 1

2. Mass of potassium ethanoate with correct unit 1 2

Moles, Q = (0.5 x25)/1000

= 0.0125

Mass of potassium ethanote = 0.0125 x 98

= 1.225 g

(c) Able to describe a test to identify the cation in lead (II) nitrate solution

1. Add potassium iodide solution 1

2. A yellow precipitate is formed. 1 2
1. Tambahkan larutan kalium iodida
2. Mendakan kuning terhasil.

(d) Able to suggest solution to relieve the pain and give a reason

1. Solution Q / Ethanoic acid / CH3COOH 1

Larutan Q / Asid etanoik / CH3COOH 1 2

2. Solution Q can neutralize sting of jelly-fish//

Solution Q is a weak acid that is not corrosive //
Neutralisation between solution Q and sting of jelly-fish produce less
heat.
Larutan Q dapat meneutralkan sengatan ikan jeli//
Larutan Q adalah asid lemah yang kurang mengakis.
Peneutralan antara larutan Q dengan sengatan ikan jeli menghasilkan
haba yang kurang

Total 10
No RUBRIC Sub- Total
Mark Mark
7(a) (i) Able to draw the electron arrangement correctly

1. Nucleus is shown and correct number of shell. 1

Nukleus ditunjukkan dan bilangan petala yang betul.

2. Correct number of electron in each shells and correct number of proton and 1 2
neutron in nucleus.
Bilangan elektron dalam setiap petala dan bilangan proton dan neutron di
dalam nukleus.

3 proton
3 proton + 7 neutron
7 neutron

(ii) Able to describe the atom correctly

1. The nucleus at the centre of the atom 1

Nukleus terdapat di pusat atom

2. The atom has 3 protons 1

Atom mempunyai 3 proton

3. The atom has 7 neutron 1

Atom mempunyai 7 neutron

4. The atom has 3 electons // 2 shells occupied electron // 1 valence electrons // 1 4

electron arrangement of the atom is 2.1
Atom mempunyai 3 elektons // 2 petala yang berisi elektron // 1 elektron
valens // susunan elektron atom ialah 2.1
(b) (i) Able to explain how the compound formed between element A and B
correctly

1. Electron arrangement of atom A is 2.4. 1

Susunan elektron atom A ialah 2.4.

2. Electron arrangement of atom B is 2.6. 1

Susunan elektron atom B ialah 2.6.

3. Atom A contribute 4 electrons and atom Q contribute 2 electrons for sharing 1

Atom A menyumbang 4 elektrons dan atom Q menyumbang 2 elektron untuk
Perkongsian

4. To achieve stable octet electron arrangement 1

Untuk mencapai susunan elektron oktet yang stabil

5. 1 atom A share electron with 2 atoms B to form covalent bond 1

1 atom A berkongsi electron dengan 2 atom B untuk membentuk ikatan
Kovalen

6. Covalent compound, AB2 is formed. 1

Sebatian kovalen, AB2 terbentuk.

7. Nucleus, number of electrons correct 1

Nukleus, bilangan elektron betul

8. Number of shells correct 1 8

Bilangan petala yang betul

x
x x
Q
B x R
A x B
Q
x

(ii)
AB2 C2B
Melting point Lower Higher 1
Takat lebur Lebih rendah Lebih tinggi

Type of particles Molecules Ions 1+1

Jenis zarah Molekul Ion

Force of attraction Van der Waals Strong electrostatic 1+1

Daya tarikan Van der Waals Daya elektrostatik yang
kuat
Heat needed to Less More 1 6
overcome the force Kurang Banyak
Tenaga haba yang
diperlukan untuk
mengatasi daya

Total 20
No RUBRIC Sub- Total
Mark Mark
8(a) Able to compare the product of electrolysis at anode for three
experiments, explain the reason for the discharge of the ions and write the
half equation of the products.

Experiment I
1. Chlorine gas produced at anode.
Gas klorin terbentuk di anod. 1

2. Chloride ion is selectively discharged because the concentration of the 1

chloride ions is higher than hydroxide ions
Ion klorida dipilih untuk dinyahcas kerana kepekatan ion klorida lebih tinggi
daripada ion hidroksida
-
3. 2Cl Cl2 + 2e- 1

Experiment II
4. Oxygen gas produced at anode. 1
Gas oksigen terbentuk di anod

5. Hydoxide ions is selectively discharged because it is lower than chloride ions 1

in the electrochemical series.
Ion hidoksida dipilih untuk dinyahcas kerana kedudukannya lebih rendah
daripada ion klorida dalam siri elektrokimia.
1
-
6. 4OH O2 + 2H2O + 4e-

Experiment III
7. Copper(II) ions produced at anode 1
Ion kuprum (II) terbentuk di anod

8. Copper atoms undergoes ionization to produce copper(II) ions 1

Kuprum atom mengalami pengionan untuk membentuk ion kuprum(II)

9. Because anode is copper which is active electrode 1

Kerana anod adalah kuprum di mana kuprum adalah elektrod aktif
2+
10. Cu Cu + 2e- 1 10

(b) Able to state a method and electrolyte correctly and write the half
equation correctly

1. Method: electrolysis 1
kaedah: elektrolisis

2. Electrolyte: silver nitrate 1

Elektrolit: argentum nitrat
+
3: Anode: Ag Ag + e- 1
+
4: Cathode: Ag + e- Ag 1 4
(c) (i) Able to state metal X and solution Y correctly

1. Mg // Zn // [any suitable metal] 1

2. MgSO4 // ZnSO4 // [ any suitable solution] 1 2

(ii) Able to positive terminal and negative terminal correctly

3. Positive terminal: Cu 1
4. Negative terminal: X // Mg // Zn 1 2

(iii) Write the half equation correctly

2+
5. Positive terminal: Cu + 2e Cu 1
2+ 1 2
6. Negative terminal: Mg Mg + 2e-

Total 20
 No RUBRIC Sub- Total
Mark Mark
9. (a) (i) Able to state alcohol P and alcohol Q correctly

1. P: C3H7OH / propanol 1
2. Q: C2H5OH / ethanol 1

Able to draw the structural formula of alcohol P or alcohol Q

Alcohol P
1 3

Alcohol Q

(ii) Able to explain the different in the value of heat of combustion between
alcohol P and alcohol Q

1. The number of carbon (and hydrogen atoms) per molecule of alcohol P is 1

greater
Bilangan karbon (dan hydrogen atom) per molekul propanol adalah lebih
banyak berbanding dengan ethanol

2. More carbon dioxide and water are produced // More formation of bonds 1
during combustion of alcohol P
Lebih karbon dioksida dan air dihasilkan // Lebih pembentukan ikatan
semasa pembakaran alcohol P

3. More heat is released during combustion of alcohol P 1 3

Lebih banyak haba dibebaskan semasa pembakaran alkohol P

(b) Able to calculate the mass of alcohol P used and with correct unit.

1. Heat change 1
2. Mole of alcohol P 1
3. Relative molecular mass of alcohol P 1
4. Mass of alcohol P with correct unit 1 4

1. Heat change = 300 x 4.2 x 20

= 25200 J

2 .2
2. Moles of alcohol P =
2016

= 0.0125

3. Relative molecular mass = 3(12) + 7+ 16+1

= 60

4. Mass of alcohol P = 0.0125 x 60 g //

= 0.75 g

Notes: If calculation refer to set II, consider 1 and 2 only]

(c) Able to describe the produce of experiment
3
1. Measure 100 cm [20 200] of water and pour into a copper can 1
3
Sukat 100 cm [20 200] air dan tuang ke dalam tin kuprum

2. Record the initial temperature of water 1

Rekod suhu awal air

3. Weigh the mass of spirit lamp filled with alcohol P / Q 1

Timbang jisim pelita yang berisi alkohol P / Q

4. Light the wick of spirit lamp 1

Nyala sumbu pelita
o
5. Stir and heat water until temperature increases by 20 C [10 50] 1
o
Kacau air dan panas air sehingga suhu air meningkat sebanyak 20 C [ 10
50]

6. Put out the flame and weigh the mass of spirit lamp 1
Padam nyalaan dan timbang jisim pelita

7. Record the highest temperature of water 1

Rekod suhu tertinggi air

Able to calculate the heat of combustion

o
8. Initial temperature of water = T1 C 1
Suhu awal air
o
Highest temperature of water = T2 C
Suhu tertinggi air
Mass of spirit lamp with alcohol P / Q before burning = M g
Jisim pelita berisi alkohol P / Q sebelum pembakaran
Mass of spirit lamp with alcohol P / Q after burning = N g
Jisim pelita berisi alkohol P/ Q selepas pembakaran

9. Heat given out = 100 x 4.2 x (T b - Ta) 1

= xJ

10. Moles, P / Q = 1 10
molar ma

= y mol

-1
H=- // - J mol
mol

Total 20
 No RUBRIC Sub- Total
Mark Mark
10 (a) Able to write chemical equation for the reaction between zinc and
sulphuric acid correctly.

1. Balance equation 1

H2SO4 + Zn ZnSO4 + H2

Able to calculate the maximum volume of hydrogen gas produced and

correct unit.

2. Number of moles of sulphuric acid 1

3. Number of moles of zinc 1
4. mol ratio // mol H2 gas 1
5. Volume H2 gas with correct unit 1 5

1.0 50
2. Moles, H2SO4 = // = 0.05
1000
2 .6
3. Moles, Zn = // 0.04 [Limiting factor]
65

4. Mole ratio: 1 mol Zn produces 1 mol H2. //

0.04 mol Zn produce 0.04 mol H2.//
3
5. Volume of H2 gas = 0.04 x 24.0 dm //
3 3
= 0.96 dm // 960 cm

(b) (i) Able to compare the rate of reaction and explain using collision theory.

1. Rate of reaction in Experiment I is higher than Experiment II. 1

Kadar tindak balas Eksperimen I lebih tinggi daripada Eksperimen II.

2. Copper (II) sulphate acts as catalyst in Experiment I. 1

Kuprum (II) sulfat bertindak sebagai mangkin dalam Ekperimen II.

3. Copper (II) sulphate / Catalyst lower the activation energy of the reaction. 1
Kuprum (II) sulfat / mangkin merendahkan tenaga pengaktifan

4. More colliding particles are able to overcome / achieve the lower activation 1
energy.
Lebih banyak zarah-zarah dapat mengatasi tenaga pengaktifan yang lebih
rendah

5. The frequency of effective collision between zinc (atoms) and hydrogen 1 5

ions in Experiment I is higher.
Frekuensi perlanggaran berkesan di antara (atom-atom) zink dan ion-ion
hydrogen Eksperimen I lebih tinggi.

a: rate of effective collision

r: rate of reaction is faster / slower
(c) Able to describe an experiment to show how concentration can affect the
rate of reaction.

1. Fill a basin with water. 1

Isi air ke dalam sebuah basin .

2. Fill a burette with water and invert it. 1

Isi air ke dalam buret dan diterbalikkan

3. Record the initial reading. 1

Rekod bacaan awal buret.
3 -3
4. Pour [20 200 cm ] of 1.0 [0.1 2.0 mol dm ] / dilute [sulphuric acid] into a 1
conical flask.
3 -3
Tuang [20 200 cm ] asid sulfurik 1.0 [0.1 2.0 mol dm ] ke dalam
kelalang kon

5. Add [0.5 5.0g] of zinc. 1

Tambah [0.5 5.0 g] zink.

6. Record the burette reading at 30s / 60s / 1 minute interval. // 1

Record the time taken to collect [fixed volume] of gas . //
Record the volume of gas in [fixed time] //
Rekod bacaan buret pada selang 30 s / 60 s / 1 minit //
Rekod masa untuk mengumpul gas [dengan isipadu yang tetap]
Rekod isipadu gas dalam [masa yang tetap]
-3
7. Repeat steps 1 to 6 using different concentration 0.5 [0.1 2.0 mol dm ]. 1
Ulangi langkah 1 hingga 6 dengan dengan kepekatan yang berlainan 0.5
-3
[0.1 2.0 mol dm ].

8. Tabulation of data
Time /s) 0 30 60 90 120 150 180 1
Total volume of
3
gas /cm

Alternative 1:
-3
Concentration of acid / mol dm Time taken to collect [a fixed volume
-3
Kepekatan asid / mol dm of gas]/s
Masa untuk mengumpul [isipadu gas
yang tetap]/s
0.5
1.0

Alternative 2:
-3
Concentration of acid / mol dm Volume of gas collected in [a fixed
-3 3
Kepekatan asid / mol dm time] / cm
Isipadu gas terkumpul [pada masa
3
yang tetap] / cm
0.5
1.0
9. Interpreting data 1
3
Volume of gas / cm
-3
1.0 mol dm sulphuric
acid
-3
0.5 mol dm sulphuric
acid

or
If no graph, must show calculation
-3
1.0 mol dm sulphuric acid
volume of gas
Rate of reaction =
time taken
=a
-3
0.5 mol dm sulphuric acid
volume of gas
Rate of reaction =
time taken
=b

.a>b

Jika graf tidak ditunjukkan, maka mesti menunjuuk penghitungan

-3
Asid sulfurik 1.0 mol dm
Isipadu gas
Kadar tindak balas =
Masa
=a
-3
Asid sulfurik 0.5 mol dm
Isipadu gas
Kadar tindak balas =
Masa
=b
.a>b
-3 1 10
10. Rate of reation using 1.0 mol dm sulphuric acid is higher.//
When the concentration of sulphuric acid is higher, the higher the rate of
reaction.
-3
Kadar tindak balas dengan menggunakan asid sulpfurik 1.0 mol dm
adalah lebih tinggi. //
Apabilan kepekatan asid sulfurik bertambah, kadar tindak balas bertambah.

Total 20