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WARDS TOWARDS P TOWARDS TOWARDS
LSTEPTO L STEP FINAL STE LSTEP
Page # 1
Po s ta
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with solutio
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Po sta
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Questio
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P o s ta
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Questio
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Po s ta
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Que stio
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080037-70333
PART-A : CHEMISTRY Q.6 For the equation
Q.1 Consider separate solutions of 0.500 M 1
SO 2(g ) O 2( g ) SO 3(g )'
C 2 H5 OH(aq), 0.100 M Mg3 (PO4 ) 2(aq), 2
0.250 M KBr(aq) and 0.125 M Na3PO4(aq) if KP = KC(RT)x where the symbols have usual
at 25C. Which statement is true about these meaning then the value of x is
solutions, assuming all salts to be strong (assuming ideality)
electrolytes?
1 1
(1) 0.100 M Mg3(PO4)2(aq) has the highest (1) (2)
osmotic pressure. 2 2
(2) 0.125 M Na3PO4(aq) has the highest (3) 1 (4) 1
osmotic pressure. Ans. [1]
(3) 0.500 M C2H5OH(aq) has the highest
osmotic pressure. Q.7 Given below are the half - cell reactions:
(4) They all have the same osmotic pressure. Mn2+ + 2e Mn; Eo = 1.18 V
Ans. [4] 2 (Mn3+ + e Mn2+) ; Eo = +1.51 V
The Eo for 3Mn2+ Mn + 2Mn3+ will be
Q.2 Which one of the following bases is not present (1) 2.69 V; the reaction will occur
in DNA? (2) 0.33 V; the reaction will not occur
(1)Adenine (2) Cytosine (3) 0.33 V; the reaction will occur
(3) Thymine (4) Quinoline (4) 2.69 V; the reaction will not occur
Ans. [4] Ans. [4]
Q.3 Considering the basic strength of amines in Q.8 If Z is a compressibility factor, van der Waals
aqueous solution, which one has the smallest equation at low pressure can be written as
pkb value? a
(1) CH3NH2 (2) (CH3)3N (1) Z = 1
VRT
(3) C6H5NH2 (4) (CH3)2NH
Ans. [4] Pb
(2) Z = 1
RT
Q.4 The metal that cannot be obtained by Pb
electrolysis of an aqueous solution of its salts (3) Z = 1 +
RT
is:
(1) Ca (2) Cu RT
(4) Z = 1 +
(3) Cr (4)Ag Pb
Ans. [1] Ans. [1]
Page # 2
Q.10 Among the following oxoacids , the correct Q.14 For which of the followingmolecule significant
decreasing order of acid strength is : 0?
(1) HClO4 > HOCl > HClO2 > HClO3
Cl CN
(2) HClO4 > HClO3 > HClO2 > HOCl
(3) HClO2 > HClO4 > HClO3 > HOCl
(4) HOCl > HClO2 > HClO3 > HOCl4
(a) (b)
Ans. [2]
Cl CN
Q.11 The ratio of masses of oxygen and nitrogen in
a particular gaseous mixture is 1 : 4. The ratio OH SH
of number of their molecule is
(1) 7 : 32
(2) 1 : 8 (c) (d)
(3) 3 : 16
(4) 1 : 4 OH SH
Ans. [1] (1) (a) an (b)
(2) only (c)
Q.12 Which one of the following properties is not (3) (c) and (d)
shown by NO? (4) only (a)
(1) It is a neutral oxide Ans. [3]
(2) It combines with oxygen to form nitrogen
dioxide Q.15 CsCl crystallises in body centred cubic lattice.
(3) It's bond order is 2.5 If'a'isits edgelengththenwhichofthefollowing
(4) It is diamagnetic in gaseous state expression is correct?
Ans. [4]
3a
(1) rCs rCl
Q.13 Which series of reactions correctly represents 2
chemical relations related to iron and its
3a
compound ? (2) rCs rCl
2
(1) Fe O2 , FeO dil
heat
H 2SO 4
(3) rCs rCl 3 a
FeSO4 heat
Fe
(2) Fe Cl (4) rCs rCl = 3a
2 , FeCl3 heat
heat
FeCl2
,air
Ans. [2]
Zn
Fe
(3) Fe O2 , 600C
Fe3O4 CO
heat
, FeO
700C
Q.16 Which one is classified as a condensation
CO
, Fe polymer?
(4) Fe dil
H FeSO4 H2SO
2SO 4 ,O 2
4 (1) Neoprene
(2) Teflon
Fe2(SO4)3 heat
Fe (3)Acrylonitrile
Ans. [3] (4) Dacron
Ans. [4]
Page # 3
Q.17 For the estimation of nitrogen, 1.4g of an Q.21 In which of the following reactions H2O2 acts
organic compound was digested by Kjeldahl as a reducing agent?
method and the evolved ammonia was (a) H2O2 + 2H+ + 2e 2H2O
M (b) H2O2 2e O2 + 2H+
absorbed in 60 mL of sulphuric acid. The (c) H2O2 + 2e 2OH
10
(d) H2O2 + 2OH 2e O2 + 2H2O
M (1) (c), (d) (2) (a) , (c)
unreacted acid required 20 mL of sodium
10 (3) (b), (d) (4) (a), (b)
hydroxide for complete neutralization. The Ans. [3]
percentage of nitrogen in the compound is
(1) 10% (2) 3% Q.22 The correct statement for the molecule, CsI3
(3) 5% (4) 6% is :
Ans. [1] (1) it contains Cs+ and I3 ions.
(2) it contains Cs3+ and I ions.
Q.18 For complete combustion of ethanol (3) it contains Cs+ , I and lattice I2 molecule
C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l), (4) it is a covalent molecule
the amount of heat produced as measured in Ans. [1]
bomb calorimeter, is 1364.47 kJ mol1 at
25C. Assuming ideality the Enthalpy of Q.23 The major organic compound formed by the
combustion, CH, for the reaction will be reaction of 1,1,1trichloroethane with silver
(R = 8.314 kJ mol1) powder is :
(1) 1361.95 kJ mol1 (1) Ethene
(2) 1460.50 kJ mol1 (2) 2 Butyne
(3) 1350.50 kJ mol1 (3) 2 Butene
(4) 1366.95 kJ mol1 (4)Acetylene
Ans. [4] Ans. [2]
Q.19 The octahedral complex of a metal ion M3+ Q.24 The equivalent conductance of NaCl at
with four monodentate ligands L1, L2, L3 and concentration C and at infinite dilution are C
L4 absorb wavelengths in the region of red, and , respectively. The correct relationship
green, yellow and blue, respectively. The between C and is given as
increasing order of ligand strength of the four (where the constant B is positive)
ligands is : (1) C = (B) C
(1) L1 < L3 < L2 < L4 (2) C = (B) C
(2) L3 < L2 < L4 < L1
(3) L1 < L2 < L4 < L3 (3) C = + (B) C
(4) L4 < L3 < L2 < L1 (4) C = + (B) C
Ans. [1] Ans. [2]
Q.20 The most suitable reagent for the conversion Q.25 Resistance of 0.2 M solution of an electrolyte
of RCH2 OH R CHO is : is 50.The specificconductance of the solution
(1) K2Cr2O7 is 1.4 S m1. The resistance of 0.5 M solution
(2) CrO3 of the same electrolyte is 280 . The molar
(3) PCC (Pyridinium Chlorochromate) conductivityof 0.5 M solution of the electrolyte
(4) KMnO4 in S m2 mol1 is
Ans. [3] (1) 5 103 (2) 5 103
(3) 5 102 (4) 5 104
Ans. [4]
Page # 4
Q.26 Sodium phenoxide when heated with CO2 Q.28 The correct set four quantum numbers for the
under pressure at 125C yields a product valence electrons of rubidium atom (Z = 37)
which on acetylation produces C. is :
ONa 1 1
125 H+ (1) 5, 1, 0, + (2) 5, 1, 1, +
+ CO2 5 atm B Ac O C 2 2
2
Page # 5
PART-B : MATHEMATICS Q.35 Let PS be the median of the triangle with
vertices P(2, 2), Q(6, 1) and R (7, 3).
sin ( cos2 x ) The equation of the line passing through
Q.31 Lim is equal to
x 0 x2 (1, 1) and parallel to PS is
(1) 2x 9y 11 = 0
(1) (2) (2) 4x 7y 11 = 0
2 (3) 2x + 9y + 7 = 0
(3) 1 (4) (4) 4x + 7y + 3 = 0
Ans. [1] Ans. [3]
Q.32 Let the population of rabbits survivingat a time Q.36 The area of the region described by
t be governed by the differential equation A = {(x, y) : x2 + y2 1 and y2 1 x} is
dp( t ) 1 2 4
= p(t) 200. (1) (2)
dt 2 2 3 2 3
If p(0) = 100, then p(t) equals
4 2
t (3) (4)
(1) 400 300 e 2 2 3 2 3
Ans. [2]
t
(2) 400 300 e 2
Q.37 If A is an 3 3 non-singular matrix such that
t AA' = A'A and B = A1A', then BB' equals
(3) 300 200 e 2 (1) (B1)' (2) I + B
t (3) I (4) B1
(4) 600 500 e 2 Ans. [3]
Ans. [2]
Q.38 The image of the line
Q.33 The statement ~ (p ~ q) is x 1 y 3 z 4
(1) a fallacy in the plane
3 1 5
(2) equivalent to p q
2x y + z + 3 = 0 is the line
(3) equivalent to ~ p q
(4) a tautology x 3 y5 z 2
(1)
Ans. [2] 3 1 5
x 3 y5 z 2
Q.34 Let and be the roots of equation (2)
3 1 5
px2 + qx + r = 0, p 0. If p, q, r are in A.P.
x 3 y5 z2
1 1 (3)
and = 4, then the value of | | is 3 1 5
x 3 y5 z 2
2 13 61 (4)
(1) (2) 3 1 5
9 9 Ans. [2]
2 17 34
(3) (4)
9 9
Ans. [1]
Page # 6
Q.39 If x = 1 and x = 2 are extreme points of Q.43 If z is complex number such that | z | 2,
f(x) = log | x | + x2 + x, then
1
1 then the minimum value of z
(1) = 2, = 2
2
3 5
1 (1) is strictly greater than but less than
(2) = 6, = 2 2
2
5
1 (2) is equal to
(3) = 6, = 2
2 (3) lies in the interval (1, 2)
1 5
(4) = 2, = (4) is strictly greater than
2 2
Ans. [4] Ans. [3]
Page # 7
Q.47 A bird is sitting on the top of a vertical pole Q.51 If f and g are differentiable functions in [0, 1]
20 m high and its elevation from the point O satisfying f (0) = 2 = g (1), g(0) = 0 and
on the ground is 45. It flies off horizontally f (1) = 6, then for some c ] 0, 1 [
straight away from the point O. After one (1) f ' (c) = 2 g ' (c) (2) 2 f ' (c) = g ' (c)
second, the elevation of the bird from O is (3) 2 f ' (c) = 3 g ' (c) (4) f ' (c) = g ' (c)
reduced to 30. Then the speed (in m/s) of the Ans. [1]
bird is
(1) 20 3 1 Q.52 Three positive numbers form an increasing G.P.
If the middle term in this G.P. is doubled, the
(2) 40 2 1 new numbersare inA.P.Thenthecommon ratio
(3) 40 of the G.P. is
3 2
(1) 2 3 (2) 2 3
(4) 20 2
(3) 3 2 (4) 2 3
Ans. [1]
Ans. [1]
Q.48
If a b b c c a [a b c ]2 then is Q.53 If g is the inverse of a function f and
equal to 1
(1) 1 f ' (x) = , then g ' (x) is equal to
1 x5
(2) 2
(3) 3 (1) 1 + {g(x)}5 (2) 1 + x5
(4) 0 1
Ans. [1] (3) 5x4 (4)
1 {g ( x )}5
Ans. [1]
Q.49 Let A and B be two events such that
P AB 1
6
, PA B
1
4
and
Q.54 Let a, b, c and d be non-zero numbers. If the
point of intersection of the lines
4ax + 2ay + c = 0 and 5bx + 2by + d = 0 lies
1
P( A ) , where A stands for the in the fourth quadrant and is equidistant from
4
the two axes then
complement of the eventA. Then the eventsA (1) 3bc + 2ad = 0 (2) 2bc 3ad = 0
and B are (3) 2bc + 3ad = 0 (4) 3bc 2ad = 0
(1) independent and equally likely Ans. [4]
(2) mutuallyexclusive and independent
(3) equally likely but not independent Q.55 If , 0, and f (n) = n + n and
(4) independent but not equally likely
Ans. [4] 3 1 f (1) 1 f (2)
1 f (1) 1 f (2) 1 f (3)
Q.50 The locus of the foot of perpendicular drawn 1 f (2) 1 f (3) 1 f (4)
from the centre of the ellipse x2 + 3y2 = 6 on = K(1 )2 (1 )2 ( )2 ,
any tangent to it is then K is equal to
(1) (x2 + y2)2 = 6x2 2y2 (1) 1 (2)
(2) (x2 y2)2 = 6x2 + 2y2
(3) (x2 y2)2 = 6x2 2y2 1
(3) (4) 1
(4) (x2 + y2)2 = 6x2 + 2y2
Ans. [4] Ans. [4]
Page # 8
PART-C : PHYSICS
x x
2
Q.56 The integral 1 4 sin 4 sin dx Q.61 The pressure that has to be applied to the ends
0
2 2 of a steel wire of length 10 cm to keep its length
equals constant when its temperature is raised by
100C is :
(1) 4 3 4 (2) 4 (For steel Young's modulus is 2 1011 Nm2
3 and coefficient of thermal expansion is 1.1
2 105 K1)
(3) 44 3 (4) 4 3 4
3 (1) 2.2 109 Pa (2) 2.2 107 Pa
6
(3) 2.2 10 Pa (4) 2.2 108 Pa
Ans. [1]
Ans. [4]
Q.57 If (10) 9 + 2(11) 1 (10) 8 + 3(11) 2 (10) 7 +
............. + 10(11)9 = k (10)9, then k is equal Q.62 In the circuit shown here, the point 'C' is kept
to connected to point 'A' till the current flowing
through the circuit becomes constant.
121 Afterward, suddenly, point 'C' is disconnected
(1) 110 (2)
10 from point 'A' and connected to point 'B' at
441 time t = 0. Ratio of the voltage across resistance
(3) (4) 100 and the inductor at t = L/R will be equal to :
100
Ans. [4] A C R
Page # 9
Q.64 There is a circular tube in a vertical plane. Two Q.67 A green light is incident from the water to the
liquids which do not mix and of densities d1 air-water interface at the critical angle ().
and d2 arefilledin the tube.Eachliquid subtends Select the correct statement.
90 angleat centre.Radius joiningtheirinterface (1) The spectrum of visible light whose
d1 frequency is less than that of green light will
makes an angle with vertical. Ratio d is: come out to the air medium.
2 (2) The spectrum of visible light whose
frequency is more than that of green light will
come out to the air medium.
(3)Theentirespectrum ofvisiblelight will come
d2 out of the water at various angles to the normal.
(4)Theentirespectrum ofvisiblelight will come
out of the water at an angle of 90 to the normal.
d1 Ans. [1]
Note: The question is wrong because green light
1 cos 1 tan will not give any spectrum.Answer is given
(1) (2) assuming incident light to be white.
1 cos 1 tan
1 sin 1 sin Q.68 A block of mass m is placed on a surface with
(3) (4)
1 cos 1 sin
Ans. [2] x3
a vertical cross-section given by y = . If
6
Q.65 A bob of mass m attached to an inextensible the coefficient of friction is 0.5, the maximum
string of length is suspended from a vertical height above the ground at which the block can
support. The bob rotates in a horizontal circle be placed without slipping is:
with an angular speed rad/s about the 2 1
vertical.About the point of suspension: (1) m (2) m
3 3
(1) angular momentum changes in magnitude
but not in direction. 1 1
(3) m (4) m
(2) angular momentum changes in direction but 2 6
not in magnitude. Ans. [4]
(3)angularmomentumchangesbothindirection
and magnitude. Q.69 The coercivity of small magnet where the
(4) angular momentum is conserved. ferromagnet gets demagnetized is
Ans. [2] 3 103 Am1. The current required to be
passed in a solenoid of length 10 cm and
Q.66 A thin convex lens made from crown glass number of turns 100, so that the magnet gets
demagnetized when inside the solenoid, is:
3
has focal length f. When it is (1) 60 mA (2) 3 A
2
(3) 6 A (4) 30 mA
measured in two different liquids having Ans. [2]
4 5
refractive indices and , it has the focal
3 3
lengths f1 and f2 respectively. The correct
relation between the focal length is :
(1) f1 > f and f2 becomes negative
(2) f2 > f and f1 becomes negative
(3) f1 and f2 both become negative
(4) f1 = f2 < f
Ans. [1]
Page # 10
Q.70 A conductor lies along the z-axis at 1.5 z <
Q.73 Assume that an electric field E 30 x 2 i exists
1.5 m and carries a fixed current of 10.0 A in
in space. Then the potential difference VA
a z direction (see figure). For a field VO, is the potential at the origin and VA the
B = 3.0 104 e0.2x a y T, find the power potential at x = 2 m is :
(1) 120 J (2) 80 J
required to move the conductor at constant
(3) 80 J (4) 120 J
speed to x = 2.0 m, y = 0 m in 5 103 s.
Ans. [2]
Asuume parallel motion along the x-axis.
Note: The question is wrong because the unit of
z potential difference is volt.
1.5
I Q.74 Match List-I (Electromagnetic wave type) with
List-II (Its association/application) and select
y
B the correct option from the choices given below
2.0
x
the lists
1.5 List-I List-II
(a) Infrared waves (i) To treat muscular
strain
(1) 2.97 W (2) 14.85 W
(b) Radio waves (ii) For broadcasting
(3) 29.7 W (4) 1.57 W
(c) X-rays (iii) To detect fracture
Ans. [1]
of bones
(d) Ultraviolet rays (iv) Absorbed by the
Q.71 Two beams,Aand B, of plane polarized light
ozone layer of the
with mutually perpendicular planes of
atmosphere
polarization are seen through a polaroid. From
a b c d
the position when the beam A has maximum
(1) (i) (ii) (iv) (iii)
intensity (and beam B has zero intensity), a
(2) (iii) (ii) (i) (iv)
rotation of polaroid through 30 makes the two
(3) (i) (ii) (iii) (iv)
beams appear equally bright. If the initial
(4) (iv) (iii) (ii) (i)
intensities of the two beams are IA and IB
Ans. [3]
IA
respectively, then I equals:
B Q.75 The current voltage relation of diode is given
by I = (e1000/T 1) mA, where the applied
3 voltage V is in volts and the temperature T is in
(1) (2) 1
2 degree kelvin. If a student makes an error
1 measuring0.01 Vwhile measuringthe current
(3) (4) 3 of 5mA at 300K, what will be the error in the
3
Ans. [3] value of current in mA?
(1) 0.02 mA (2) 0.5 mA
Q.72 The forward biased diode connection is : (3) 0.05 mA (4) 0.2 mA
Ans. [4]
(1) 3V 3V
(2) 2V 4V
(3) 2V +2V
(4) +2V 2V
Ans. [4]
Page # 11
Q.76 One mole of diatomic ideal gas undergoes a Q.79 Four particles, each of mass M and equidistant
cyclic process ABC as shown in figure. The from each other, move along a circle of radius
process BC is adiabatic. The temperature at R under the action of their mutual gravitation
A, B and C are 400K, 800K and 600K attraction. The speed of each particle is
respectively. Choose the correct statements :
GM
B (1) 2 2
800K 2
P GM
600K (2) (1 2 2 )
A C 2
400K
V 1 GM
(3) (1 2 2 )
(1) The change in internal energyin the process 2 2
CA is 700 R
(2) The change in internal energyin the process GM
AB is 350 R (4)
R
(3) The change in internal energyin the process Ans. [3]
BC is 500 R
(4) Thechange in internal energyinwhole cyclic Q.80 From a tower of height H, a particle is thrown
process is 250 R vertically upwards with a speed u. The time
Ans. [3] taken by the particle, to hit the ground, is n
times that taken by it to reach the highest point
Q.77 A pipe of length 85 cm is closed from one end. of its path. The relation between H, u and n is
Find the number of possible natural oscillations (1) g H = (n 2)2u2
of air column in the pipe whose frequencies lie (2) 2g H = nu2(n 2)
below 1250 Hz. The velocity of sound in air is (3) g H = (n 2)u2
350 m/s. (4) 2 g H = n2u2
(1) 8 (2) 6 Ans. [2]
(3) 4 (4) 12
Ans. [2] Q.81 A student measured the length of a rod and
wrote it as 3.50 cm. Which instrument did he
Q.78 I a large building, there are 15 bulbs of 40W, 5 use to measure it ?
bulbs of 100W, 5 fans of 80W and 1 heater of (1)Avernier calliper where the 10 divisions in
1kW. The voltage of the electric mains is 220V. vernier scale matches with 9 division in main
The minimum capacity of the main fuse of the scale and main scale has 10 divisions in 1 cm.
buildingwill be (2)Ascrew gauge having 100 divisions in the
(1) 10 A (2) 12 A circular scale and pitch as 1mm.
(3) 14 A (4) 8A (3) A screw gauge having 50 division in the
Ans. [2] circular scale and pitch as 1mm
(4) Ameter scale.
Ans. [1]
Page # 12
Q.82 A parallel plate capacityis made of two circular
plates separated bya distance of 5mm and with 2 w g 2 w g
(1) R (2) R
a dielectric of dielectric constant 2.2 between 6T T
them. When the electric field in the dielectric is
2 3w g 2 w g
3 104 V/m, the charge density of the positive (3) R (4) R
plate will be close to T 3T
(1) 3 107 C/m2 (2) 3 104 C/m2
2 w g
(3) 6 104 C/m2 (4) 6 107 C/m2 Ans. None of these, Ans. is R 2
Ans. [4] 3T
2r
Page # 13
Q.88 Three rods of Copper, Brass and Steel are
welded together to form a Y-shaped structure.
Area of cross-section of each rod = 4 cm2.
End of copper rod is maintained at 100C
where as ends of brass and steel are kept at
0C. Length of the copper, brass and steel
rods are 46, 13 and 12 cms respectively. The
rods are thermallyinsulated from surroundings
except at ends. Thermal conductivities of
copper, brass and steel are 0.92, 0.26 and
0.12CGS units respectively. Rate of heat flow
through copper rod is
(1) 2.4 cal/s (2) 4.8 cal/s
(3) 6.0 cal/s (4) 1.2 cal/s
Ans. [2]
Note: The answer is wrong because the answer
is 4.8 erg/s.
1 aL2 bL3
(3)
2 2 3 (4) aL2 + bL3
Ans. [2]
Page # 14