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Topic 5 Energetics
Average
1 The average enthalpy change of breaking one mole of a bond in a gaseous
N bond
atom into its constituent gaseous atoms.
enthalpy:
Energy cycles for the formation of ionic compounds. If there is little
2 Born-Haber
E agreement between the theoretical and experimental values, this could
cycle
indicate a degree of covalent character.
4 The internal energy stored in the reactants. Only changes in enthalpy can be
R Enthalpy
measured.
A measure of the disorder of a system. Things causing entropy to increase:
5 A Entropy 1) increase of number of moles of gaseous molecules; 2) change of state
from solid to liquid or liquid to gas; 3) increase of temperature
7 Gibbs free
Q Must be for reaction to be spontaneous. G = H TS
energy
11 Standard
G 298 K and 1 atm.
conditions
Standard
13 I enthalpy of The energy required to vaporise one mole of a liquid.
vaporisation:
14 Enthalpy of The energy required to produce one mole of gaseous atoms from an
C
atomisation element in its standard state.
Bond
15 The energy change when one mole of a specific bond is broken or created
B dissociation
under standard conditions.
enthalpy
16 Enthalpy of The energy released when one mole of a compound is burned in excess
P
Combustion oxygen.
Standard
17 The energy change when one mole of a compound is formed under standard
L enthalpy of
conditions from its constituent elements in their standard states.
formation
Standard
18 The energy change when one mole of a substance is dissolved in an infinite
M enthalpy of
amount of water under standard conditions.
solution