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12/3/2016

KULIAH ESSO
IR :
bedanya nujol mull, KBr, neat
Bedanya amina primer, sekunder dan tersier
1H NMR :
Coupling constant
Alkena
Pada orto, meta dan para
13C NMR:
DEPT 45, 90 dan 135

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Coupling Constants

Distance between the peaks of multiplet


Measured in Hz
Not dependent on strength of the external
field
Multiplets with the same coupling
constants may come from adjacent groups
of protons that split each other.
=>
3

Values for
Coupling Constants

=>

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a c
H
C C
H
Complex Splitting
Hb

Signals may be split by adjacent


protons, different from each other, with
different coupling constants.
Example: Ha of styrene which is split by
an adjacent H trans to it (J = 17 Hz) and
an adjacent H cis to it (J = 11 Hz).
=>
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H
a
H
c Splitting Tree
C C
Hb

=>

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SINTESIS 6-
NITROVERATRALDEHIDA
Hasil dan Pembahasan
Spektra 1H-NMR
4, 5
4
5

2 9 proton
3
5 tipe proton

2
1 3

Analisis 1H-NMR (CD3OD) Senyawa 1a


Doan dan Tran (2011)
D F
-C=C- Doublet, J = 15,50 Hz
B C


E F
C A
A
j = 15,55 Hz j = 15,55 Hz
1,09


3,09
1,07

E
1,04

1,07

H2O
B F
2,11

7,7 7,6
CD3OD
7,4 7,3 7,2

C 8,0
2,04

F C
D
1,00

E B
D
6,9 6,8

12 11 10 9 8 7 6 5 4 3 2 1 0 8
Pergeseran Kimia (ppm)

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DEPT-135 DEPT Spectra

DEPT-90

DEPT-45

CH CH2 CH3
C normal C-13 spectrum

Quaternary carbons (C) do not show up in DEPT.

DEPT-90

DEPT-135

O
CH3

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Simulated DEPT Spectra of Ethyl Phenylacetate


O

O
DEPT-135

O
DEPT-90
O

DEPT-45

Normal C-13 spectrum

A C4H8O2

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C7H7Br P-

O-

M-

C4H8Cl2
B

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H-NMR C10H12O

10 8 6 4 2 0
PPM

C-NMR C10H12O

200 180 160 140 120 100 80 60 40 20 0


PPM

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MS C10H12O

1H-NMR C8H16O2
D F

A B
C

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13C-NMR C8H16O2

4
2 3 6

5
1

MS C8H16O2

43

71

57
27
101
15 87
144
129

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