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H I G H E R S C H O O L C E R T I F I C AT E
E X A M I N AT I O N
Chemistry
2020
Section I
75 marks
Part A 20 marks
Attempt Questions 120
Allow about 35 minutes for this part
(A) Hardness
(B) Turbidity
(C) Total dissolved solids
(D) Biochemical oxygen demand
2
C2H4 X polymer
(A) Cellulose
(B) Ethanol
(C) Glucose
(D) Styrene
4 Which pieces of glassware should be used when preparing a primary standard solution?
59
27
Co + 1
0
n 60
27
Co
(A) Cyclotron
(B) Scintillator
(C) Nuclear reactor
(D) Particle accelerator
7 Methyl orange, bromothymol blue and phenolphthalein indicators were mixed together
to form a solution.
red
red yellow
yellow
yello
Methyl orange
yellow
yellow
yellow blue
bl ue
Bromothymol blue
colourless
colourless pink
pink
Phenolphthalein
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
pH
(A) 0 14
(B) 3 4.5
(C) 3 7.5
(D) 4.5 6
(A) NH3
(B) NH4+
(C) H2O
(D) OH
10 Samples of a solution of barium nitrate were independently tested with chloride ions,
with sulfate ions and also for flame colour.
11 The pH of 0.1 mol L1 solutions of acetic, citric and hydrochloric acids was measured.
H F Cl H
H C C C C H
H H H H
(A) 2-chloro-2-fluorobutane
(B) 2-fluoro-3-chlorobutane
(C) 3-fluoro-2-chlorobutane
(D) 3-chloro-2-fluorobutane
(A) H+
(B) Cr3+
(C) Fe2+
(D) Cr2O72
(A) 0.59 V
(B) 0.92 V
(C) 1.90 V
(D) 2.13 V
15 In which row of the following table are the listed oxides correctly classified?
16 The graph shows the concentrations over time for the system:
T1 T2
Time
T1 T2
(A) H2 added CH3OH removed
(B) CO added CH3OH removed
(C) H2 added CO removed
(D) CO added CO and H2 removed
(A) 3.4 g
(B) 14 g
(C) 55 g
(D) 144 g
pH Degree of ionisation
(A) Increase Decrease
(B) Decrease Increase
(C) Increase Increase
(D) Decrease Decrease
(A) 2.65 g
(B) 5.30 g
(C) 10.6 g
(D) 53.0 g
20 All the lead ions present in a 50.0 mL solution were precipitated by reaction with excess
chloride ions. The mass of the dried precipitate was 0.595 g.
(A) 8.87 g L1
(B) 10.2 g L1
(C) 11.9 g L1
(D) 16.0 g L1
BLANK PAGE
Chemistry
Centre Number
Section I (continued)
Part B 55 marks
Attempt Questions 2133 Student Number
Allow about 1 hour and 40 minutes for this part
Answer the questions in the spaces provided. These spaces provide guidance for the expected
length of response.
Question 21 (4 marks)
(a) Write a balanced chemical equation, using structural formulae, for the formation 2
of ethyl butanoate.
(b) Common safety precautions in school laboratories include the use of safety 2
glasses, gloves and lab coats. Justify the use of another safety precaution
specifically required to safely make ethyl butanoate.
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2021 9
Question 22 (3 marks)
II
III
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 23 (3 marks)
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Question 24 (3 marks)
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2022 11
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12
Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 25 (3 marks)
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2023 13
Question 26 (8 marks)
Petroleum and sugar cane are both raw materials used for the production of ethanol.
(a) Construct separate flow diagrams for the production of ethanol from each raw 5
material.
14
Question 26 (continued)
(b) Compare the environmental sustainability of producing ethanol from these two 3
raw materials.
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End of Question 26
15
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 27 (3 marks)
Iodine-131 decays through both beta and gamma emission. Iodine-123 decays through
gamma emission only.
(a) Iodine-131 is used for diagnosis and therapy whereas Iodine-123 is used only 2
for diagnosis.
With reference to the information and the table, justify the different uses of these
two radioisotopes.
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(b) Write the equation representing the decay of Iodine-131 by beta emission. 1
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2024 17
Question 28 (3 marks)
A solution was made by mixing 75.00 mL of 0.120 mol L1 hydrochloric acid with 3
25.00 mL of 0.200 mol L1 sodium hydroxide.
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Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 29 (5 marks)
Draw a labelled diagram to show the layered structure of the atmosphere. In your 5
diagram include:
the names of TWO atmospheric pollutants, positioned in the layers where the
detrimental impact occurs
the names of the sources of the two pollutants identified.
2025 19
Question 30 (6 marks)
A chemist analysed aspirin tablets for quality control. The initial step of the analysis
was the standardisation of a NaOH solution. Three 25.00 mL samples of a
0.1034 mol L1 solution of standardised HCl were titrated with the NaOH solution.
The average volume required for neutralisation was 25.75 mL.
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(b) (i) Calculate the average mass (mg) of aspirin per tablet. 3
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Question 31 (5 marks)
(a) Using the data provided, construct a graph that shows the relationship between 3
carbon chain length and boiling point.
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(c) What is the intermolecular force responsible for the trend shown in the graph? 1
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22
Chemistry
Centre Number
Section I Part B (continued)
Student Number
Question 32 (3 marks)
2026 23
Question 32 (3 marks)
0.600
0.500
Absorbance
0.400
0.300
0.200
0.100
0.000
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45
A consumer wants to avoid eating fish with a mercury concentration greater than
0.5 mg/kg of fish.
Calculate the concentration of mercury in the fish sample and state whether the
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Question 33 (6 marks)
With reference to this statement, assess the need for chemists to collaborate when
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25
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26
Chemistry
Section II
25 marks
Attempt ONE question from Questions 3438
Allow about 45 minutes for this section
Pages
2027 27
(a) The following equipment was set up and the reaction allowed to proceed. Gases 3
were produced at both electrodes.
Graphite
P Q
rods
Pink due to
presence of
phenolphthalein
Na+(aq) Cl(aq)
N O
2 2
K =
2
NO
Calculate the equilibrium constant for this reaction and use this value to
describe the position of the equilibrium.
(iii) What could be changed that would result in a different value of K for this 1
equilibrium?
28
Question 34 (continued)
(d) (i) Outline how one of the steps involved in the Solvay process can be 3
chemically modelled in the school laboratory. Include a balanced
chemical equation in your answer.
(ii) Identify ONE risk factor and ONE difficulty associated with the 2
laboratory modelling of the step.
(e) Initially soap was the only product of the surfactant industry. Due to societal 7
pressures and chemical developments, production in this industry has evolved to
include a wide range of products.
Account for these changes over time with reference to the structure and uses of
surfactants.
End of Question 34
29
Ground surface
(ii) Suggest an alternative way the pipe can be chemically protected. Use 2
half-equations to support your answer.
30
Question 35 (continued)
(c) Corrosion in some wrecks can be represented in part by the following half-
equation.
Calculate the loss of iron, in grams, from the piece of steel if 0.76 g of
hydrogen sulfide was produced. Include a balanced equation in your
answer.
(d) A student set up the following two beakers to investigate factors affecting
electrolysis.
6V 12V
(ii) Draw diagrams to show how this investigation should be carried out to 4
accurately identify TWO factors affecting electrolysis. Indicate the
expected results on your diagrams.
(e) Critically evaluate the continued use of steel in ship building with reference to 7
the history of ocean-going vessels, the composition of steel and ways in which
its interaction with the environment can be controlled.
End of Question 35
31
(a) The diagram illustrates schematically the current model of muscle contraction. 3
X Y
ATP
Z
ADP + Pi
32
Question 36 (continued)
(c) (i) Why do fats have a greater energy density than carbohydrates? 1
(ii) Carbohydrates and fats have parts of their oxidative metabolic pathways 4
in common.
Use a flow diagram to outline the main stages of the aerobic metabolism
of fats and carbohydrates.
separate pathways
common pathway
stage where most of the ATP is produced
stage where most of the carbon dioxide is released.
(d) (i) Compare the forces and bonds that determine the level of structure in 3
proteins.
(e) Compare and contrast the aerobic and anaerobic metabolism of glucose within 7
the context of muscle function during different forms of exercise and the relative
amounts of energy released.
End of Question 36
33
[Mn(H2O)6]2+
[Mn(NH3)2(H2O)3OH]2+
[Mn(CO)4NO]
(b) (i) Why has copper sulfate pentahydrate (CuSO4.5H2O), with its strong blue 2
colour, not been used as a pigment?
34
Question 37 (continued)
Ionisation of Vanadium
16000
14000
Ionisation Energy (kJ mol1)
12000
10000
8000
6000
4000
2000
0
1 2 3 4 5 6 7
Ionisation Step
(d) (i) Describe an experiment that could be performed to relate the colour of 3
iron solutions to the electronic configuration of iron ions, if the supplied
salt is iron(II) chloride crystals.
(e) Evaluate the contribution of the Bohr model to the development of our 7
understanding of the structure of the atom.
End of Question 37
35
(a) Describe how the different characteristics of a soil sample would allow forensic 3
chemists to trace its origin.
(b) An athlete is required to give two urine samples. Sample A is tested for evidence
of substances on the banned substance list. If a banned substance is detected in
Sample A then Sample B is tested. If both samples are positive for a banned
substance then the athlete is asked to explain the findings at a court hearing.
76 91 32 8 76 91 32 8
A A B B
B
A B
76 91 32 8 76 91 32 8
36
Question 38 (continued)
(c) The diagram shows the separation of plant pigments by chromatography using
hexane as a solvent.
Xanthophyll pigment
Chlorophyll a
Chlorophyll b
Original concentrated
spot of plant pigment
(i) State which of the pigments is the least polar and justify your choice. 2
(ii) Explain how changing the solvent would affect the separation process. 3
37
Question 38 (continued)
CH2OH
O O
H H HOCH2 H
H
+
OH H H HO
HO OH OH CH2OH
H OH OH H
a-glucose b-fructose
(e) Analyse how modern techniques utilise the features of DNA and manipulate it to 7
successfully generate an individuals DNA profile.
End of paper
38
Board of Studies NSW 2012
2012 HIGHER SCHOOL CERTIFIC ATE EXAMINATION
Chemistry
DATA SHEET
Avogadro constant, NA .................................................................. 6.022 1023 mol1
Ionisation constant for water at 25C (298.15 K), Kw ................. 1.0 1014
Cu(s) 0.52 V
12
I2(s) + e I
0.54 V
12 I2(aq) + e
I 0.62 V
Fe 3+
+e
Fe 2+
0.77 V
+
Ag + e
Ag(s) 0.80 V
12
Br2(l) + e Br
1.08 V
12
Br2(aq) + e
Br
1.10 V
1
O (g) + 2H+ + 2e
2
2
H2O 1.23 V
12 Cl2(g) + e
Cl
1.36 V
12 Cr2O72 + 7H+ + 3e Cr3+ + 72 H2O 1.36 V
12 Cl2(aq) + e Cl
1.40 V
MnO4 + 8H+ + 5e Mn 2+
+ 4H2O 1.51 V
12 F2(g) + e F
2.89 V
Aylward and Findlay, SI Chemical Data (5th Edition) is the principal source of data for
2028 this examination paper. Some data may have been modified for examination purposes.
39
3 4 Atomic Number 79 5 6 7 8 9 10
Li Be Symbol Au B C N O F Ne
6.941 9.012 Standard Atomic Weight 197.0 10.81 12.01 14.01 16.00 19.00 20.18
Lithium Beryllium Name Gold Boron Carbon Nitrogen Oxygen Fluorine Neon
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.64 74.92 78.96 79.90 83.80
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.61 88.91 91.22 92.91 95.96 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
55 56 5771 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0
40
Caesium Barium Lanthanoids Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
87 88 89103 104 105 106 107 108 109 110 111 112
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn
Francium Radium Actinoids Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium
Lanthanoids
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
138.9 140.1 140.9 144.2 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0
Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium
Actinoids
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.0 231.0 238.0
Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium
Elements with atomic numbers 113 and above have been reported but not fully authenticated.
The International Union of Pure and Applied Chemistry Periodic Table of the Elements (February 2010 version) is the principal source of data. Some data may have been modified.