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Article history: In this study, we have investigated the possibility of the solid-state recycling of aluminium alloy machin-
Received 3 October 2013 ing swarf into c-channels using hot extrusion. Side milling swarf and lathe turning swarf generated from
Received in revised form 1 October 2014 a cast AlSi alloy ingot were cold compacted into columnar billets and successfully prole-extruded into
Accepted 15 October 2014
equilateral c-channels at 600 K, under extrusion ratios of 10 and 18. The c-channels obtained at an extru-
sion ratio of 18 showed straight extrusion without warping, except in the front-end region. In case of
Keywords:
the material recycled from the milling swarf at an extrusion ratio of 10, the optical microscopic study
Aluminium alloy
indicates the presence of coarse residual voids and cracks existing in regions where sufcient plastic
C-channel
Extrusion
strain was not introduced. In contrast, the material recycled from the same swarf at an extrusion ratio
Machining swarf of 18 did not contain any coarse voids, rather had a density comparable to that of the original ingot.
Mechanical property This could be attributed to the large strain of over 4.3 that was introduced in the sample recycled at the
Solid-state recycling extrusion ratio of 18, as predicted by nite element analysis. Uniaxial tensile tests showed that the dense
recycled material had a higher ductility than the original ingot, with a reduction of around 30% in the
ultimate tensile strength. The material recycled from the turning swarf exhibited insufcient bonding
among the individual pieces of the swarf, as compared to that recycled from the milling swarf under the
same conditions, thereby resulting in inferior mechanical properties.
2014 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
1. Introduction solid-state recycling method not only reduces the energy con-
sumption but also improves the recycling efciency dramatically
Currently, most aluminium scrap, including machining swarf, (up to more than 95% for aluminium [1]). In addition, the solid-state
i.e., small chips, is remelted in furnaces and recycled into ingots or recycling method offers the advantage of microstructural control
die-casting products. However, the conventional recycling method during the recycling process, which allows the metal scrap to be
is associated with the following disadvantages: (1) the metal yield recycled into materials with excellent mechanical properties. Thus
rate is very low, i.e., approximately 55% [1]. (2) Unavoidable reduc- far, several solid-state recycling processes have been intensively
tion in the purity of recycled ingots at the remelting stage results studied since 1980s, especially to recycle the machining swarf
in the degradation of their mechanical properties. (3) The remelt- discharged from factory machine tools.
ing process requires signicantly large amount of energy, which A great majority of studies on this topic have focussed on
is unfavourable in terms of energy conservation. These limitations recycling machining swarf into cylindrical bars [312] or rectan-
drive the development of alternative technologies for the recycling gular bars [1315], using hot/warm forward extrusion. In addition,
of aluminium scrap. recycling processes based on other SPD methods such as cyclic
Recently, solid-state recycling, which involves direct recycling extrusion compression (CEC) [16], equal channel angular pressing
of metal scrap into bulk material by using severe plastic (ECAP) [1719], high-pressure torsion (HPT) [20] or compressive
deformation (SPD), has emerged as a potential alternative to torsion [21], and combined use of forward extrusion and ECAP
the conventional remelting and recycling techniques [2]. The [22,23] have also been reported. Recently, another study [24] aimed
at producing a composite material including nano-particles from
machining chips via hot extrusion, and a new method was pro-
posed to produce clad plates from iron chips by using hot rolling
Corresponding author. Tel.: +81 166 55 8003; fax: +81 166 55 8003.
[25]. Almost all of the abovementioned methods require pre-
E-mail address: chiba@asahikawa-nct.ac.jp (R. Chiba).
1
Present address: Engineering Division, Oji Materia Co., Ltd., 20-6 Tokuda, Nay-
compaction of the machining swarf, the technical details of which
oro, Hokkaido 096-8555, Japan. have been reported elsewhere [26]. A brief review of the relevant
http://dx.doi.org/10.1016/j.jmapro.2014.10.002
1526-6125/ 2014 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
2 R. Chiba, M. Yoshimura / Journal of Manufacturing Processes 17 (2015) 18
Table 1
Chemical composition of the AC4CH aluminium alloy used in this study [27].
Element Cu Si Mg Zn Fe Mn Ti Sb Al
Mass% 0.01 6.9 0.37 0.02 0.13 0.01 0.13 0.001 Bal.
> 40 mm 30 mm
Tab
1 mm
Fig. 2. Dimensions (in mm) of orice on (a) die face and (b) cross sections along the
2.4. Finite element analysis of extrusion process
thickness direction.
0.891 and 0.887, respectively. This indicates that the billets contain
many voids. Furthermore, the macroscopic inspection of the sur-
faces of both the billets revealed that the size of an individual void
was larger in case of billet derived from the turning swarf.
Fig. 7. Appearances of the extrudates, as seen from (a) lateral view and (b), (c) bird
view.
Fig. 8. Optical micrographs of specimens extruded from milling-swarf billets at (a), (b) R = 10; (c) R = 18; and (d), (e) extruded from a turning-swarf billet at R = 18.
contrast, the specimen extruded at R = 10 with lubrication exhib- strain induced by extrusion. That is, the milling swarf, which is thin-
ited warping throughout the length of the specimen. The surfaces ner than the turning swarf, has a higher deformability and can gain
of the specimens recycled from the turning swarf (Fig. 1b) had the entry into tiny spaces to readily form a continuum body without
same characteristics as those of the recycled specimens obtained voids. On the other hand, the individual voids originally included
from the milling swarf. Note that the authors considered only the in the turning swarf billets are larger than those in the milling
specimens that were extruded with lubrication as a target for the swarf billets, despite their comparable densities. Therefore, even
following discussion. an extrusion at R = 18 is not sufcient to collapse the large voids.
Hence, the severe shear deformation of the material, including the
3.3. Macro- and micro-structures of the recycled materials residual voids near the surfaces, causes obvious cracks along the
swarf interfaces (Fig. 8d and e).
Fig. 8 shows the optical micrographs of the transverse section of Fig. 9 shows the microstructure of the extruded specimens at
the recycled specimens (extrudates). As can be seen from the opti- the centre of the transverse section of the back part (see Fig. 3). As
cal images shown in Fig. 8a and b, the material recycled from the evidenced from the gure, no boundaries between the chips were
milling swarf by hot extrusion at R = 10 exhibited relatively large found in the materials recycled from the milling swarf, whereas the
voids and cracks. This indicates that the bonding among the indi- boundaries were clearly observed in the material recycled from
vidual pieces of swarf is insufcient. On the other hand, the material the turning swarf. It can also be seen that the eutectic Si phases
recycled from the same swarf by extrusion at R = 18 had no observ- were rened, when compared with those in the original ingot and
able cracks located at the bonded interfaces of the swarf. Therefore, machining swarf. There was no large difference in the size of Si
the corresponding optical image revealed a highly dense surface, phases between the materials recycled at different extrusion ratios
although minute (<5 m) voids were slightly observed. Further- (R = 10 and 18) or between the materials recycled from the dif-
more, the optical image of the material recycled from the turning ferently shaped swarfs; the Si phases/particles of every recycled
swarf by extrusion at R = 18 (Fig. 8d and e) revealed a number of material ranged from 1 to 10 m in size. However, comparing
voids and long cracks along the swarf interfaces in the corner parts Fig. 9a and b, it appears that the Si particles are more isolated in
and adjacent to the surfaces. The cracks may be attributed to the the materials recycled at R = 18, when compared with the material
inability of the turning swarf billets to accommodate large shear recycled at R = 10.
6 R. Chiba, M. Yoshimura / Journal of Manufacturing Processes 17 (2015) 18
Table 2
Relative density of the materials recycled from milling swarf.
Billet Extrudates
R = 10 R = 18
Fig. 10. Mechanical properties of each separated part of the recycled material in the
form of c-channel.
Fig. 10 shows the tensile test results (0.2% proof stress, UTS,
and uniform elongation) of the separated parts of the respective
extruded specimens. The tensile test results indicate greater vari-
ability in the uniform elongation than in the proof stress and UTS,
similar to the case of solid-state recycled magnesium alloy [6].
Furthermore, major differences in the strength level and ductil-
ity between the side part and back part could be observed in all
the obtained c-channels. Both the strength level and ductility were
found to be higher in the side part. This could be attributed to the
difference in the strain introduced during extrusion processes, as
described in the forthcoming section. The 0.2% proof stress, UTS,
and fracture strain of the AC4CH ingot were 133.5 MPa, 191.1 MPa,
and 0.030, respectively (details not shown in Fig. 10) [27]. Thus,
all the recycled materials exhibited a decrease in the mechanical
strengths. However, the material recycled from the milling swarf
Fig. 9. Microstructure of the specimens extruded from milling-swarf billets at (a) by extrusion at R = 18 showed an increase in the ductility. The
R = 10 and (b) R = 18 (c) extruded from a turning-swarf billet at R = 18. observed improvement in ductility is due to the Si-phase rene-
ment, sufcient void reduction, and probably the partial dynamic
recrystallization. Since the aluminium alloy extruded sections gen-
erally undergo secondary processing, such as bending, to form
actual structural parts, their ductility is a very important factor from
the application perspective [30]. The material recycled by extrusion
at R = 10 had lower ductility. Some of the side parts cut out from
R. Chiba, M. Yoshimura / Journal of Manufacturing Processes 17 (2015) 18 7
Table 3
Vickers hardness of the materials recycled from milling swarf.
to produce c-channels of recycled materials with comparable [15] Guley V, Guzel A, Jager A, Ben Khalifa N, Tekkaya AE, Misiolek WZ. Effect of die
density and superior ductility to the original ingot. They could design on the welding quality during solid state recycling of AA6060 chips by
hot extrusion. Mater Sci Eng A 2013;574:16375.
be potentially used in certain branches of industry, for instance, [16] Peng T, Wang QD, Han YK, Zheng J, Guo W. Consolidation behavior
in applications such as the non-load-bearing components that of Mg10Gd2Y0.5Zr chips during solid-state recycling. J Alloys Compd
do not demand the full strength of as-cast aluminium. 2010;503:2539.
[17] Misiolek WZ, Haase M, Ben Khalifa N, Tekkaya AE, Kleiner M. High quality extru-
dates from aluminum chips by new billet compaction and deformation routes.
Acknowledgement CIRP Ann Manuf Technol 2012;61:23942.
[18] Luo P, McDonald DT, Zhu SM, Palanisamy S, Dargusch MS, Xia K. Analysis of
microstructure and strengthening in pure titanium recycled from machining
The authors would like to thank Mr. Toshiyuki Suzuki and Mr. chips by equal channel angular pressing using electron backscatter diffraction.
Toshiyuki Akimoto for preparing the extrusion dies. Mater Sci Eng A 2012;538:2528.
[19] Luo P, McDonald DT, Palanisamy S, Dargusch MS, Xia K. Ultrane-grained pure
Ti recycled by equal channel angular pressing with high strength and good
References ductility. J Mater Process Technol 2013;213:46976.
[20] Abd El Aal MI, Yoo Yoon E, Seop Kim H. Recycling of AlSi8Cu3 alloy chips via
[1] Lazzaro G, Atzori C. Recycling of aluminium trimmings by conform process. high pressure torsion. Mater Sci Eng A 2013;560:1218.
Light Metals 1992;3:137984. [21] Kanetake N, Kume Y, Ota S, Morimoto R. Upgrading in mechanical properties of
[2] Allwood JM, Cullen JM, Cooper DR, Milford RL, Patel ACH, Carruth MA, et al. Con- high performance aluminum alloys by compressive torsion process. Proc CIRP
serving our metal energy. WellMet2050. Cambridge: University of Cambridge; 2014;18:5761.
2010. [22] Ying T, Zheng MY, Hu XS, Wu K. Recycling of AZ91 Mg alloy through consol-
[3] Wu SY, Ji ZS, Rong SF, Hu ML. Microstructure and mechanical properties of idation of machined chips by extrusion and ECAP. Trans Nonferrous Met Soc
AZ31B magnesium alloy prepared by solid-state recycling process from chips. China 2010;20:s6047.
Trans Nonferrous Met Soc China 2010;20:7838. [23] Haase M, Ben Khalifa N, Tekkaya AE, Misiolek WZ. Improving mechani-
[4] Anilchandra AR, Surappa MK. Inuence of tool rake angle on the qual- cal properties of chip-based aluminum extrudates by integrated extrusion
ity of pure magnesium chip-consolidated product. J Mater Process Technol and equal channel angular pressing (iECAP). Mater Sci Eng A 2012;539:
2010;210:4238. 194204.
[5] Peng T, Wang Q, Han Y, Zheng J, Guo W. Microstructure and high tensile [24] Roshan MR, Mirzaei M, Jenabali Jahromi SA. Microstructural characteristics
strength of Mg10Gd2Y0.5Zr alloy by solid-state recycling. Mater Sci Eng and tensile properties of nano-composite Al 2014/4 wt.% Al2 O3 produced from
A 2010;528:71520. machining chips. J Alloys Compd 2013;569:1117.
[6] Zhao ZD, Chen Q, Yang L, Shu DY, Zhao ZX. Microstructure and mechanical prop- [25] Zhang S, Xiao H, Xie H, Gu L. The preparation and property research of
erties of MgZnYZr alloy prepared by solid state recycling. Trans Nonferrous the stainless steel/iron scrap clad plate. J Mater Process Technol 2014;214:
Met Soc China 2011;21:26571. 120510.
[7] Zhang T, Ji Z, Wu S. Effect of extrusion ratio on mechanical and corrosion [26] Pepelnjak T, Kuzman K, Kacmarcik I, Plancak M. Recycling of AlMgSi1 alu-
properties of AZ31B alloys prepared by a solid recycling process. Mater Des minium chips by cold compression. Metalurgija 2012;51:50912.
2011;32:27428. [27] Chiba R, Nakamura T, Kuroda M. Solid-state recycling of aluminium alloy
[8] Hu ML, Ji ZS, Chen XY, Wang QD, Ding WJ. Solid-state recycling of AZ91D swarf through cold prole extrusion and cold rolling. J Mater Process Technol
magnesium alloy chips. Trans Nonferrous Met Soc China 2012;22:s6873. 2011;211:187887.
[9] Anilchandra AR, Surappa MK. Microstructure and damping behaviour of con- [28] Hu M, Ji Z, Chen X, Zhang Z. Effect of chip size on mechanical property and
solidated magnesium chips. Mater Sci Eng A 2012;542:94103. microstructure of AZ91D magnesium alloy prepared by solid state recycling.
[10] Miao J, Ye B, Wang Q, Peng T. Mechanical properties and corrosion resistance of Mater Charact 2008;59:3859.
Mg10Gd2Y0.5Zr alloy by hot extrusion solid-state recycling. J Alloys Compd [29] Hu HE, Wang XY, Deng L. High temperature deformation behavior and opti-
2013;561:18492. mal hot processing parameters of AlSi eutectic alloy. Mater Sci Eng A
[11] Anilchandra AR, Surappa MK. Microstructure and tensile properties of consol- 2013;576:4551.
idated magnesium chips. Mater Sci Eng A 2013;560:75966. [30] Sakaki S, Utsumi N. Factors causing undesirable deformations during the bend-
[12] Mindivan H, Taskin N, Kayali ES. Recycling of pure magnesium chips by cold ing of extruded sections. Mater Trans 2006;47:13549.
press and hot extrusion processes. Acta Phys Pol A 2014;125:42931. [31] Chino Y, Mabuchi M, Iwasaki H, Yamamoto A, Tsubakino H. Tensile properties
[13] Guley V, Ben Khalifa N, Tekkaya AE. Direct recycling of 1050 aluminum alloy and blow forming of 5083 aluminum alloy recycled by solid-state recycling.
scrap material mixed with 6060 aluminum alloy chips by hot extrusion. Int J Mater Trans 2004;45:250915.
Mater Form 2010;3:8536. [32] Gronostajski JZ, Kaczmar JW, Marciniak H, Matuszak A. Direct recycling
[14] Li DH, Hu ML, Wang HB, Zhao WA. Low temperature mechanical property of of aluminium chips into extruded products. J Mater Process Technol
AZ91D magnesium alloy fabricated by solid recycling process from recycled 1997;64:14956.
scraps. Trans Nonferrous Met Soc China 2011;21:123440.