CHEMISTRY

1.The Group which shows +M effect

is,
1) -CN
2) -NO2
3) -OH
4) -CHO
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CN, NO2, CHO are electron with

drawing group, but OH is electron
donating group.

Answer is 3
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2. The nucleophilic attack by CN- to the

carbonyl group is an example for
1)+ E effect 2) - E effect
3) + M effect 4) - M effect
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-E effect involves complete transfer of pi bond present

in carboxyl group by attacking reagents CN-

SO ,it is 2) E EFFECT
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3.Which of the following has zero dipole

moment,
1.cis-but-2-ene
2. trans-but-2-ene
3. chloroform
4. 2-methylprop-1-ene
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Trans-2-butene has symmetric structure

SO the answer is 2) Trans-2-butene

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4.The product C in the reaction is :

CH3 COOH LiAlH4 PCl5
A B
Alc.KOH
C
1) Acetaldehyde 3) Acetylene
2) Ethylene 4) Acetyl chloride
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LiAlH4 Pcl5 alc

CH3COOH + 4[H] CH3CH2 OH CH3 CH2 Cl CH2 = CH2

-H2O -PoCl3 KOH

Answer is 2
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5.Reagent used to convert an acid to

alcohol is,
1) Na/C2H5OH 3) Zn in dilute HCl
2) Zn-Hg in conc HCl 4) LiAlH4
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Answer is 4
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6.In the reaction product C is :

CH3 - COOH NH3
A
Heat
B C
NaOBr

1) acetamide 3) ethanamine
2) methanamine 4) bromoethane
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NH3 Heat NaoBr

CH3COOH CH3COONH4 CH3CONH2 CH3CH2NH2

Answer is 3
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7. The process of seperation of racemic

mixture into (+) and (-) enantiomers is
called,
1.racemisation
2. resolution
3. enantiomerism
4. Walden inversion
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2. resolution
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8.Which of the following compounds

exhibits stereoisomerism?
1) 2-Methylbutene-1
2) 3-Methylbutyne-1
3) 3-Methylbutanoic acid
4) 2-Methylbutanoic acid
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H CH3
C C
H3C CH3

H H
H3C CH2 C COOH H3C C CH2 COOH
CH3 CH3

Answer is 4
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9.An organic molecule necessarily shows

optical activity if it

1) contains asymmetric carbon atoms

2) is non-planar
3) is non-superimposable on its mirror
image
4) is superimposable on its mirror
image
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3) is non-superimposable on its mirror

image
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10.Among cis-and trans-dichloroethene

1) cis form has more heat of combustion
2) trans form is less stable
3) boiling point of trans form is more
4)melting point of cis form is more
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1) cis form has more heat of combustion

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11.The amino acid which is not optically

active is,
1) Glycine
2) Alanine
3) Serine
4) Proline
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Glycine H

H2 N C COOH

Alanine H3 C CH COOH

NH2

Serine HO CH2 CH COOH

NH2

Proline COOH
N

H Answer is 1
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12.The compound obtained when

acetaldehyde reacts with aqueous
NaOH exhibits :
1) Optical isomerism
2) Geometric isomerism
3) Both optical and geometric isomerism
4) Neither optical nor geometric
isomerism
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OH

CH3 CH2 C CH2 CHO

H
acetaldol

Answer is 1
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13.In the sequence of reactions

H 3 O
CH 3 Br
A
KCN
B
LiAlH4
ether

the end product (C) is :
1) Acetaldehyde
2) Ethyl alcohol
3) Acetone
4) Methane
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KCN H3 O+
CH3 Br CH3 CN CH3 COOH

- H2 O LiAlH4

CH3 CH2 OH

Answer is 2
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14.Which one of the following order is

correct regarding the I effect of the
substituent's ?
1) NR2 < -OR > -F
2) -NR2 > -OR > -F
3) -NR2 < -OR < -F
4) -NR2 > -OR < -F
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As the electro negitivity of the

element increases I effect also
increases.Among N, F, and O,
flourine atom has high
electronegitivity.

So answer is 3
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15. Which of the following reagents react

with ethylamine to give ethyl alcohol?
1) Br2 / KOH
2) Acidified KMnO4
3) HNO3
4) HNO2
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CH3 CH2 NH H + OH NO CH3 CH2 OH + N2

Answer is 4
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16.cis-trans isomers can be

differentiated by:
1)Dipole moment
2)Melting point
3)Boiling point
4)All of these
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Isomerism means two organic compounds

having same molecular formula but
different physical and chemical
properties.

4)All of these
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17.How many chiral isomers can be

drawn from 2-bromo-3-chlorobutane
1)2
2)3
3)4
4)5
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If a molecule contains n number of chiral

carbon atoms then it posses 2 n
number of optical isomers.

3) 4
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18.Hoffmanns bromamide reaction

converts
1)Amine to alcohol
2)Cyanide to amide
3)Amide to lower amine
4)Aldehyde to ketone
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RCONH2 + Br2 + 4KOH R NH2 + 2KBr + K2CO3 + 2H2O

Answer is 3
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19.Which is used to increase the number

of carbons in the chain ?
1)Wurtz reaction
2)Frankland reaction
3)Alc. KCN
4)All the these
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4)All the these

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20.Which is used in the descent of series ?

1)Sodalime decarboxylation
2)Hoffmann bromamide reaction
3)Cannizzaro reaction
4)Both (1) & (2)
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4)Both (1) & (2)

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21.Sodium propionate on sodalime

decarboxylation gives
1)Methane
2)Ethane
3)Propane
4)Butane
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Cao
CH3 CH2 COONa + NaOH CH3 CH3 + Na2CO3

Answer is 2
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22.Ethyl bromide on treatment with

Na/dry ether gives

1)Ethane
2)Butane
3)Propane
4)Ethane
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CH3 CH2 Br + 2Na + Br CH2 CH3

CH3 CH2 CH2 CH3

Answer is 2
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23.Which of the following cannot be

prepared by wurtz reaction ?
1)Methane
2)Ethane
3)Hexane
4)Octane
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To perform Wurtz reaction two alkyl

halides are required.

1)Methane
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24.Which effect is a temporary effect and

operates only in the presence attacking
reagent?
1)Mesomeric effect
2)Inductive effect
3)Hyperconjugative effect
4)Electromeric effect
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4)Electromeric effect
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25. Ammonia is isoelectronic with

1)Methyl free-radical
2)Methyl carbanion
3)Methyl carbocation
4)All of these
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Ammonia is SP 3 hybridised and has

planar structure and it is similar to
carbanion.

2)Methyl carbanion
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26.Which statement is correct for

inductive effect?
1)It is a permanent effect
2)It is the property of single bond
3)It causes permanent polarization in the
molecules
4)All of these
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4)All of these
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27.Which of the following has +R

(resonance ) effect?
1)CN
2)CHO
3)-Cl
4)-NO2
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To exhibit +R effect, the atom or group

of atoms should have electron donating
nature. The Cl atom has both electron
donating and withdrawing nature on
benzene ring.
3)-Cl
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28.If a compound has n dissimilar dissymmetric

carbon atoms, then the possible number of
optical isomerism is,
1)n/2
2) 2n
3) 2n
4) 2n
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2) 2n
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29.Which one of the following acids

would u expect to be the strongest?
1)I CH2COOH
2)Cl -CH2COOH
3)Br -CH2COOH
4)F-CH2COOH
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As the high electronegative atom attached

to COOH group , O-H bond becomes
weak and donates proton easily and
becomes more acidic in nature.
F- atomis highly electronegative atom.

4)F-CH2COOH
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30.Which of the following alkyl groups has

the maximum + I-effect ?
1)CH3-
2)CH3CH2-
3)(CH3)2CH-
4)(CH3)3CH-
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+I effect increases as electron donating

group attached to carbon increases.

4)(CH3)3CH-
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31.Which organic species has only one

type of hybridized carbon ?
1)CH2=C=CH2

2)CH3- CH -CH3
3)CH3-CCH

4)CH2=CH- C H2
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4)CH2=CH- CH2
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32.which of the following species is

paramagnetic in nature ?
1) free radical
2) carbocation
3) both of these
4) none of these
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To show paramagnetic nature atom or

molecule should posses unpaired
electron. Free radicals are the reaction
intermediate having odd electron.

1) free radical
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33. which of the following does not show

electromeric effect ?
1) alkenes
2) ethers
3) aldehydes
4) ketones
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To show electromeric effect molecule

should have pi bonds. Ethers not have pi
bond.

2) ethers
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34. The ortho and para directing group is

1) COOH
2) -NO2
3) -OH
4)-CN
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Electron donating groups are acts as

ortho and para directing group on
benzene ring.

3) OH
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35.which one of the following series

contains electrophile only ?
1)H2O,SO3 ,H30+
2) NH3,H2O,AlCl3
3) AlCl3,SO3,NO2+
4)H20,Cl+,NH3
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Electrophiles are electron deficient

species.

3) AlCl3,SO3,NO2+
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36. The activating effect of OCH3 group

attached to the benzene ring can be
explained in terms of :
1) +R effect
2) R effect
3) + E effect
4) + I effect
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OCH 3 is the electron donating group.

1) +R effect
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37. The most stable

carbocation is
a) c)

b) d)
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37. The most stable

carbocation is
A)
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38.Inductive effect involves

1) displacement of sigma electrons
2) delocalization of pi electrons
3) delocalization of sigma electrons
4) displacement of pi electrons
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1) displacement of sigma electrons

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39.The basicity of aniline is less than that

of cyclohexylamine ,this is due to
1) +R effect of NH2 group
2) I effect of NH2 group
3) R effect of NH2 group
4) hyperconjugation effect
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NH2 NH2

Aniline Cyclohexylamine

Answer is 1
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40. Mesomeric effect involves

delocalization of
1) protons
2) sigma electrons
3) pi electrons
4) none of these
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3) pi electrons
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41. which of the following species does

not exert a resonance effect?
1) C6H5OH
2) C6H5Cl
3) C6H5NH
2
4) C6H5N H3
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4) C6H5 NH3
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42. In electrophillic aromatic substitution reaction ,the

nitro group is meta directing because it

1 ) decreases electron density at ortho and

para position
2) decreases electron density at meta position
3) increases electron density at meta position
4) increases electron density at ortho and para
positions
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O O- O- O-

N O N O N O N O
+

Answer is 1
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43. Homolytic fission of C-C bond in

ethane gives an intermediate in which
carbon is
1) Sp 3 hybridised
2) Sp 2 hybridised
3) Sp hybridised
4) Sp 2 d hybridised
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Homolytic fission gives free radicals and

are Sp 2 hybridised

1)Sp 2 hybridised
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44.Which of the following has meso isomer

also?
1)2-chlorobutane
2)2,3-dichlorobutane
3)2,3-dichloropentane
4)2-hydroxypentonic acid
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H H

H3C C C CH3

Cl Cl

Answer is 2
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45.A molecule of urea can

show
1)Chain isomerism
2)Position isomerism
3)Geometrical isomerism
4)Tautomerism
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4)Tautomerism

O OH

H2 N C NH2 HN C NH2
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