DALAL

TYPES OF WASTE : Kg/Hr C

LIQUID :1 H2S 12.43

CH3SH 18.73 26.09

HEAVY 175.17

TOTAL

70% C2H6O4S 122.62 19.51

15% C2H6S2 26.28 26.37

15% CS2 26.28 1.54

WATER 997.27

1203.60
110% 1323.96
70% 926.77

VAPOUR WASTE Kg/Hr C

VAPOUR Nitrogen 81.01

H2S 185.29

CH3SH 92.2

Air 1320.28

1678.78
110% 1846.66
70% 1292.66

\
Analysis
H2S
Carbon 0 %
Hydrogen 3.3 %
Nitrogen 0.00 %
Sulphur 96.97 %
Oxygen 0 %
100.27
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 13601 3248 Kcal/kg

NCV = 12871 3074 Kcal/kg

Analysis
CH3SH
Carbon 26.09 %
Hydrogen 4.35 %
Nitrogen 0.00 %
Sulphur 69.57 %
Oxygen 0 %
100.01
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 21725 5189 Kcal/kg

NCV = 20762 4959 Kcal/kg

Analysis
C2H6O4S
Carbon 19.51 %
Hydrogen 2.44 %
Nitrogen 0.00 %
Sulphur 26.02 %
Oxygen 52.03 %
100
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 3401 812 Kcal/kg

NCV = 2861 683 Kcal/kg

Analysis
C2H6S2
Carbon 26.37 %
Hydrogen 3.3 %
Nitrogen 0.00 %
Sulphur 70.33 %
Oxygen 0 %
100
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 20391 4870 Kcal/kg

NCV = 19660 4696 Kcal/kg

Analysis
CS2
Carbon 1.54 %
Hydrogen 0 %
Nitrogen 0.00 %
Sulphur 98.46 %
Oxygen 0 %
100
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 9558 2283 Kcal/kg

NCV = 9558 2283 Kcal/kg

LIQUID WASTE

1324 kg/hr
Mass to be fed in to the 1 =
H2S
Calorific Value (Given) 3248 kcal/kg

A/W Ratio ( 30% Extra) 4.39 5.91

Waste composition : % kg /hr

organics 1.03% 13.673
inorganics 0 0
moisture 0 0
Total 14

1324 kg/hr
Mass to be fed in to the 2 =
CH3SH
Calorific Value (Given) 5189 kcal/kg

A/W Ratio ( 30% Extra) 7.01 9.50

Waste composition : % kg /hr

organics 1.56% 20.603
inorganics 0 0
moisture 0 0
Total 21
 1324 kg/hr

Mass to be fed in to the 3 =

C2H6O4S
Calorific Value (Given) 812 kcal/kg

A/W Ratio ( 30% Extra) 1.10 1.48

Waste composition : % kg /hr

organics 10.19% 134.881
inorganics 0 0
moisture 0 0
Total 135

1324 kg/hr

Mass to be fed in to the 4 =

C2H6S2
Calorific Value (Given) 100 kcal/kg

A/W Ratio ( 30% Extra) 0.14 6.00

Waste composition : % kg /hr

organics 2.18% 28.903
inorganics 0 0
moisture 0 0
Total 29

1324 kg/hr

Mass to be fed in to the 5 =

CS2
Calorific Value (Given) 2283 kcal/kg

A/W Ratio ( 30% Extra) 3.08 4.20

Waste composition : % kg /hr

organics 2.18% 28.903
inorganics 0 0
moisture 0 0
Total 29

0 kg/hr
1324
TOTAL ORGAINIC
226.963

Waste composition : % kg /hr

organics 17.14% 226.96
inorganics 0 0
 moisture 82.86% 1097
Total 1324

Temperature T2 850 C

T1 30 C

Air Required for combustion of organics = 81 kg/hr

D.G. 79 kg/hr
Moist 2 kg/hr

Heat absorbed by waste =

1 by organics m*[0.6*(150-T1)+160+0.3(T2-150)]
6839.23 kcal/hr

2 by inorganics m*0.3*(T1-T2)
0.00 kcal/hr

3 by moisture m*{70+540+0.5(T2-100)}
0.00 kcal/hr

4 heat by Combustion air Air * 0.28 *(T2-T1)

18553.39 kcal/hr

5 heat by steam for = 0 kcal/hr

atomization

TOTAL HEAT REQUIRED = 1+2+3+4+5 25392.62 kcal/hr

25.39 x 10 kcal/hr

Heat released by wastes = 44416.68 kcal/hr

Total Heat absorbed = 27931.88 Kcal/Hr

Total Heat released = 39975.02 Kcal/hr

Net heat Available (Released - Absorbed) = 12043.13 kcal/hr

Fuel Used ( F.O. ) = CV = 9650 kcal/kg , A/F=

Fuel Used = -2.10 kg/hr

Combustion Air = 3145 kg/hr

D.G. 3082 kg/hr
Moist. 63 kg/hr

Mass out = 3424 D.G = 3360

Moist = 65

Thermal Capacity of Chamber = 0.8424 Mkcal/hr.

797899 kcal/hr
 1/9/2017

H N S O

3.3 96.97 13.7 1.03%

4.35 69.57 20.6 1.56%

192.7

2.44 26.02 52.03 134.9 10.19%

3.3 70.33 28.9 2.18%
98.46 28.9 2.18% 227.0

1097.0 82.86%

1324.0 1.00

H N S O

89.111
203.819

101.42 16.53%
1452.308 83.47%

1846.658

1
 H2S

100.27 100.27

2
CH3SH

100.01 100.01

3
C2H6O4S

100.00 100.00

4
C2H6S2

100.00 3174.00
 5
CS2

100.00 5058.57

1
H2S

1.35

2
CH3SH

1.35
 3
C2H6O4S

1.35

4
C2H6S2

44.40

5
CS2

1.36

TAL ORGAINIC TALLY

0.000
60+0.3(T2-150)]

13.04 17.00 1.30

185.00 kg/hr

kg/hr
kg/hr

873243 kcal/hr
OSTUKA

TYPES OF WASTE :

Liquid Organic Waste () :12000 ltr /Day

% Moisture 17.07 %
Organic 58.46 %
Ash 24.47 %
Calorific Value (Calculated ) 6348 kcal/kg
\
Analysis

Carbon 48.57 %
Hydrogen 11.42 %
Nitrogen 2.24 %
Sulphur 0 %
Oxygen 37.77 %
100
HCV= [35000*C+143000*(H-O/8)+9160*S]/100
LCV= HCV-9*H/100*2460

HCV = 26579 6348 Kcal/kg

NCV = 24050 5744 Kcal/kg

VERTICAL CHAMBER /ROTARY KILN :

LIQUID WASTE

Mass flow rate of feed = 0.60 M3/Day

600 kg/hr

Mass to be fed in to the RK = 600 kg/hr

Calorific Value (Given) 5744 kcal/kg

A/W Ratio ( 30% Extra) 7.76 10.00

Waste composition : % kg /hr

organics 58.46 351
inorganics 24.47 147
moisture 17.07 102
Total 600

Temperature T2 850 C

T1 30 C

Air Required for combustion of organics = 3508 kg/hr

D.G. 3437 kg/hr
Moist 70 kg/hr

Heat absorbed by waste =

 1 by organics m*[0.6*(150-T1)+160+0.3(T2-150)]
175450.15 kcal/hr

2 by inorganics m*0.3*(T1-T2)
36117.72 kcal/hr

3 by moisture m*{70+540+0.5(T2-100)}
100883.70 kcal/hr

4 heat by Combustion air Air * 0.28 *(T2-T1)

805344.96 kcal/hr

5 heat by steam for = 0 kcal/hr

atomization

TOTAL HEAT REQUIRED = 1+2+3+4+5 1117796.53 kcal/hr

1117.80 x 10 kcal/hr

Heat released by wastes = 2014781.90 kcal/hr

Total Heat absorbed = 1229576.19 Kcal/Hr

Total Heat released = 1813303.71 Kcal/hr

Net heat Available (Released - Absorbed) = 583727.53 kcal/hr

Fuel Used ( F.O. ) = CV = 9650 kcal/kg , A/F=

Fuel Used = -101.57 kg/hr

Combustion Air = 3145 kg/hr

D.G. 3082 kg/hr
Moist. 63 kg/hr

Mass out = 7291 D.G = 7055

Moist = 235

Thermal Capacity of Chamber = 1.7935 Mkcal/hr.

1716442 kcal/hr

Water Adddition for Cooling

Fuel used ( F.O. ) = CV = 9650 kcal/kg, A/F=

Fuel Required = -105.78 0 kg/hr

Cooling water Required = 593 kg/hr

D.G. 0 kg/hr
Moist 593 kg/hr

Mass out = 4553 kg/hr

D.G = 3788 kg/hr
Moist = 765 kg/hr

Thermal Capacity of Chamber = 1.1201 Mkcal/hr.

1183500 kcal/hr
 Total Amount of Ash to be removed = 147 kg/hr

S.C.C:

Mass to SCC :

1) LIQUID WASTE
Mass flowrate = 0 Kg/hr
0 Kg/hr

Waste composition : % Kg/hr

Organic 0 0
Moisture 0 0
Inorganics 0 0
0 0

Calorific Value = 0 Kcal/kg

A/W (48 % extra) 0.000 10.00

Air Required = 0 Kg/hr

D.G.= 0 kg/hr
Moist.= 0 kg/hr

2) Flue Gas from RK 4553 Kg/hr

D.G. = 3788 Kg/hr
Moist.= 765 Kg/hr

Temperature T1 850 C

T2 850 C
Heat and Mass Balance :

1) Heat absorbed by Liquid waste =

1 by organics m*[0.6*(150-T1)+160+0.3(T2-150)]
0.00 kcal/hr

2 by inorganics m*0.3*(T2-T1)
0 kcal/hr

3 by moisture m*{70+540+0.5(T2-100)}
0 kcal/hr

4 heat by Combustible Air * 0.28 *(T2-T1)

Air 0 kcal/hr

Total heat absorded by Liquid waste = 0 kcal/hr

Total heat released by Liquid waste = 0 kcal/hr

2) Heat absorbed by Flue gas from RK = 0 kcal/hr.

Total Heat released 0 Kcal/hr
Net heat available = R- A = 0 kcal/hr.

Fuel required ( F.O.) = 0.0 kg/hr

Air Required for Fuel = 0 Kg/Hr

D.G. = 0 kg/hr
Moist.= 0 kg/hr

MASS OUT FROM S.C.C at 850 deg C

Dry gas = 3788 Kg/hr

Moist = 765 Kg/hr
Total Mass flow 4553 kg/hr

Thermal Capacity of SCC = 1.1201 Mkcal/hr

1183500 kcal/hr.

Lets SCC = 1.183 Mkcal/hr

Flue gas = Total mass 4553 Kg/hr

D.G. = 3788 Kg/hr
Moist.= 765 Kg/hr

COOLING AIR REQUIREMENT:

Cooling Air Requirement to cool to 850 C

0 Kg/hr
0 Kg/hr

Mass out from After cooling to @ 850 C 4553 Kg/hr

Dry gas = 3788 Kg/hr
Moist = 765 Kg/hr
 1/9/2017

100.00 117.07

Density = 1000 Kg/m3

88.14

1.29
60+0.3(T2-150)]

13.04 17.00 1.30

185.00 kg/hr

kg/hr
kg/hr

1859149 kcal/hr

13.04 18.00

0 kg/hr

0
 2936 kg/day

0.00

60+0.3(T2-150)]

0
 0

0.0 Kg/Hr

1161116 kcal/hr.

0 m3/hr
 SPRAY DRYER

Total Gas = 4553 Kg/Hr

Dry gas 3788 kg/hr 850 219.87 1006.87
moisture 765 kg/hr ENTHALPY in kcal/kg
Temp Air Moist
inlet temp 850 C 75 17.73 626.80
outlet temp 250 C 100 23.77 640.23
200 48.14 692.90
Enthalpy @ t1 850 C 250 60.53 719.34
D.G 219.87 Kcal/hr 300 73.05 746.11
MOIST 1006.87 Kcal/hr 400 98.43 800.94
600 151.45 916.54
Enthalpy @ t2 250 C 700 178.61 960.00
D.G 60.525 Kcal/hr 800 206.02 991.25
MOIST 719.34 Kcal/hr 900 233.72 1022.49
1000 261.76 1086.95
Water Evaporated 1905 Kg/hr 1100 290.02 1153.17
Water Sprayed (10 % TDS salts) 212 Kg/Hr 1150 304.51 1187.16
1200 318.91 1221.19
VENTURI SCRUBBER
1420 HUMIDITY
Total = 5973 kg/hr 1577 158
Dry gas 3788 kg/hr Temp Humidity
moisture 2185 kg/hr kg moist/ kg gas
15 0.0106
inlet temp T1 250 C 70 0.2782
outlet temp T2 80 C 75 0.3851
80 0.5511
enthalpy @ t1 250 C 85 0.8352
D.G 60.525 Kcal/hr 90 1.4140
MOIST 719.34 Kcal/hr 95 3.1730
99 18.7300
enthalpy @ t2 80 C 30 0.0273
D.G 18.86 Kcal/hr 60 0.1530
MOIST 629.32 Kcal/hr 65 0.2051

Water Evaporated 645 kg/hr

503 Kg/Hr
@ venturi outlet

average mol. Wt. 23.13 kg

density of gas@ 0.799 kg/m

Avg.Temp. 0.0499 lb/ft

vol flow rate 8109.743 m/hr

286360.989 ft/hr

Velocity of gas @ throat 70 m/s

229.66 ft/s

c/s area of throat 0.0322 m

0.3464 ft

Diameter 0.2024 m
Length 0.6071 m

Pr. Drop 250 mm WC

9.843 inch WC

L 8.84 gal/1000ftgas

Water Circulated 2531.27 gal/hr

9.581 M/hr Extra 20 % = 11 M/hr
@venturi Outlet 6476 Kg/Hr
Dry gas 3788 kg/hr
moisture 2688 kg/hr

Moisture Holding Capacity @ 75 C 2088 kg/Kg of moist ,as the Humidity @ 80 C 0.5511
For the Dry Air kg moist/Kg DG

Amount of water being condensed = 600 kg/hr

No Condensation.

I D FAN

Inlet Temp 80 Deg C

D.G. 3788 kg/hr
Moist 2688 kg/hr
Total 6476 kg/hr

Mol Wt. 23.13 kg

Density 0.799 kg/m

Vol Flow 8110 m/hr

20% Extra 9732 m/hr

Power Required for this System

Assume Pr.drop = 850 mm of water column; Efficiency 0.65

Power = 47 HP OR 35 KW

Taking 20% loss = 57 HP 42 KW

RK SIZING :

Total mass = 4553 Kg/hr @ 850 deg C

Dry gas = 3788 Kg/hr
Moist = 765 Kg/hr

Avg Mole wt.= 26.30 kg

Gas Density.= 0.2854 kg/m3

Vol.flow rate.= 15955 m3/hr

Thermal capacity of MCC = = 1.7935 Mkcal/hr.

1793531.88 kcal/hr

FOR CIRCULAR CHAMBER

Assume: Thermal intensity of Combustion chamber = 100000 kcal/hrm3

Volume of chamber = Thermal capacity/Thermal intensity

= 17.94 m3 = * r2 * h

Dimension: Radius = 0.894 m

Diameter = 1.787 m 2850 mm

Length (L/ D) = 4 7.149 m Actual volume =

And the above dimensiones are can be corss checked for the sufficient
residence time (Minimum 2 sec) in the chamber

Residence time Rt = 4.04 (ok,as the Rt more than 2 sec.)

Fuel: ( F.O.) 3.5 % sulphur

Fuel Reqirement for startup ( to rise to 850 deg C) the MCC

Fuel is needed per m2 of chamber to raise to 850 deg C = 1.5

RK inside surface area = 45.16 m2

Therefore, fuel needed = 67.74 Litre

 17.924 m

lpm2
 SCC SIZING

Total Mass = 4553 Kg/hr @ 850 deg C

Dry gas = 3788 Kg/hr
Moist = 765 Kg/hr

Avg Mole wt.= 26.30 kg

Gas Density.= 0.2854 kg/m3

Vol.flow rate = 15955 m3/hr

4.4320 m3/s

Thermal capacity of SCC = 1.120 Mkcal/hr

1120136 Kcal/hr

Assume:Thermal intensity of Combustion chamber = 100000 kcal/hr m3

Volume of chamber = Thermal capacity / Thermal intensity

= 11.20 m3
Actaul Taken
Dimension: Radius = 0.764 m 1.15

Diameter = 1.528 m 2.3

Length (L/ D) = 4 6.112 m 9.20

Actual Volume = 11.203 m

And the above dimensiones are can be cross checked for the sufficient
residence time (Minimum 2 sec) in the chamber

Residence time, Rt = 2.53 ( ok,as the Rt more than 2 sec.)

Fuel: ( F.O. ) 3.5 % sulphur

Fuel Reqirement to rise up the SCC Chamber to 1000 deg C

Fuel is needed per m2 of chamber to raise to 1000 deg C =

SCC area = 33.01 m2

Therefore fuel needed = 57.77 Litre

han 2 sec.)

1.75 litre
Liquid Organinc Waste

Aqueous For Cooling

Fuel

Combustion and Cooling Air

TO DRAIN

Salt 147 Kg /hr

Evaporative Cyclone Scrubber I.D fan Chimney
 Liquid Organinc Waste

Fuel

Combustion and Cooling Air

Aqueous For Cooling

TO DRAIN
147 Kg /hr
Scrubber ID FAN Chimney
 Description
DMF

Methanol

IPA

P-Dioxane

M/c

Polyethelene glycol

Sulphate Ash

Residue on Ignition

Rest/Balance

1 12000
2 600
3 0.6
4 1000

5 600

Organic
Moisture
Salt
Ash

Extra Considred
 %w/w
4.06% to 8.0% C3H7NO 8% 48

0.04% to 2.0% CH3OH 2% 12

10.34% to 20.0% C3H8O 20% 120

4.43% to 8.0% C4H8O2 8% 48

13.44% to 20% 20% 120

30.50% 30.50% C2nH4n+2On+1 183

C1H6O2

21.48% 21.48% 128.88

7.20% 7.20% 43.2

Un-detectable

117% 703.08
LTR/DAY
LTR/20 HRS
Mtr^3
kg/mtr^3

411 0.5845707
120 0.1706776
128.88 0.1833077
43.2 0.0614439

1.1718 703.08
 C H N O
199.62 46.93 9.21 155.24 411.00
0.485693 0.114185 0.022409 0.377713
48.57% 11.42% 2.24% 37.77% 100.00%

58.46%
17.07%
18.33%
6.14%