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1) (13.47) If 100.0 mL of water is shaken with oxygen gas at 1.0 atm it will
dissolve 0.0039 g O2. Estimate the Henrys law constant for oxygen gas in
water.
2) (13.57) In an aqueous solution of sulfuric acid, the concentration is 1.89 mol%
of acid. The density of the solution is 1.0645 g mL-1. Calculate the following:
(a) the molal concentration of H2SO4, (b) the mass percent of the acid, and (c)
the molarity of the solution.
3) (13.62) Benzene and toluene help achieve good engine performance from
lead-free gasoline. At 40 C, the vapor pressure of benzene is 184 torr and
that of toluene is 58 torr. Suppose you wished to prepare a solution of these
liquids that will have a total vapor pressure of 96 torr at 40 C. What must be
the mole percent concentrations of each in the solution?
4) (13.70) What are the molecular mass and molecular formula of a
nondissociating molecular compound whose empirical formula is C4H2N if
3.84 g of the compound in 0.500 kg of benzene gives a freezing point
depression of 0.307 C?
5) (13.82) A 0.118 m solution of LiCl has a freezing point of -0.415 C. What is
the vant Hoff factor for this solute at this concentration?
Tugas II:
2) (16.45) Choose the stronger acid: (a) H3AsO4 or H3PO4; (b) H2CO3 or
HNO3; (c) H2SeO4 or HClO4. Give your reasons.
3) (16.55) Use Lewis structures to show how the following reaction involves
the transfer of a Lewis base from one Lewis acid to another. Identify the
two Lewis acids and the Lewis base.
3) (15.43) The heterogeneous reaction 2HCl(g) + I2(s) === 2HI(g) + Cl2(g) has
Kc = 1.610-34 at 25 C. Suppose 0.100 mol of HCl and solid I2 are placed
in a 1.00 L container. What will be the equilibrium concentrations of HI
and Cl2 in the container?
2) (17.64) Lactic acid, HC3H5O3, is responsible for the sour taste of old milk.
At 25 C, its Ka = 1.410-4. (a) What is the Kb of its conjugate base, the
lactate ion, C3H5O3-? (b) Is its conjugate base a stronger or a weaker base
than the acetate ion?
2) (18.35) At 25 C, the value of Ksp for AgCN is 6.010-17 and that for
Zn(CN)2 is 310-16. In terms of grams per 100 mL of solution, which salt is
more soluble in water?
5) (18.63) What pH would yield the maximum separation of Mn2+ from Sn2+
in a solution that is 0.010 M in Mn2+, 0.010 M in Sn2+, and saturated in
H2S? (Assume the green form of MnS in Table 18.2.)
6) (18.75) The overall formation constant for Ag(CN)2 equals 5.51018, and
the Ksp for AgCN equals 6.010-17. Calculate Kc for the following reaction:
AgCN(s) + CN-(aq) === Ag(CN)2-(aq)