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CHEMISTRY
PART-A
SECTION1
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
1. Which of the following volume (V) temperature (T) plots represents the behaviour of one mole of an
ideal gas at one atm pressure?
V(L) V(L)
(38.8 L (28.6L,
373 K) 373 K)
T(K) T(K)
V(L) V(L)
(30.6L, (14.2L,
373 K) 373 K)
T(K) T(K)
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3. Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds
CH3 Cl NO2
1 2 3 4
(A) 1 > 2 > 3 > 4 (B) 4 > 3 > 2 > 1 (C) 2 > 1 > 3 > 4 (D) 2 > 3 > 1 > 4
4. Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a
product B (molecular formula C3H6O), B forms a shining silver mirror on warming with ammonical silver
nitrate, B when treated with an aqueous solution of NH 2NHCONH2 and sodium acetate gives a product
C. Identify the structure of C
CH3C NHHCONH2
(A) CH3CH2CH = NNHCONH2 (B) |
CH3
CH3C NCONHNH2
(C) | (D) CH3CH2CH = NCONHNH2
CH3
H3C CH3
(A) C=C (B) CH3C CCH3
H H
(C) CH3CH2C = CH (D) CH2 = CHC = CH
7
6. If the nitrogen atom had electronic configuration 1s , it would have energy lower than that of the normal
2 2 3 7
ground state configuration 1s 2s 2p , because the electrons would be closer to the nucleus. Yet 1s is
not observed because it violates
(A) Heisenberg uncertainty principle (B) Hunds rule
(C) Paulis exclusion principle (D) Bohr postulate of stationary orbits
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7. Rutherfords experiment, which established the nucleus model of the atom, used a beam of
(A) -particles, which impinged on a metal foil and got absorbed.
(B) -rays, which impinged on a metal foil and ejected electrons.
(C) helium atoms, which impinged on a metal foil and got scattered
(D) helium nuclei, which impinged on a metal foil and got scattered.
9. A substance AX BY crystallises in a face centered cubic (PCC) lattice in which atoms A occupy each
corner of the cube and atoms B occupy the centres of each face of the cube. Identify the correct of each
face of the cube. Identify the correct composition of the substance A XBY
(A) AB3 (B) A4B3
(C) A3B (D) Composition cannot be specified.
10. Specify the coordination geometry around and hybridization of N and B atoms in a 1 : 1 complex of BF 3
and NH3.
3 3 3 3
(A) N : tetrahedral, sp ; B : tetrahedral, sp (B) N : pyramidal, sp ; B : pyramidal, sp
3 2 3 3
(C) N : pyramidal, sp ; B : planar, sp (D) N : pyramidal, sp ; B : tetrahedral, sp
11. One mole of a non-ideal gas undergoes a change of state (2.0 atm, 3.0 L, 95K) (4.0 atm, 5.0 L, 245
K) with a change in internal energy, U = 30.0L atom. The change in enthalpy (H) of the process in L
atm is
(A) 40.0 (B) 42.3
(C) 44.0 (D) not defined, because pressure is not constant
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14. Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox
titration. Some half cell reactions and their standard potentials are given below
MnO4 (aq) + 8H (aq) + 5e Mn (aq) + 4H2O(l) E = 1.51 V
- + - 2+
Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO 3)2.
- 2-
(A) MnO4 can be used in aqueous HCl (B) Cr2O7 can be used in aqueous HCl
2-
(B) MnO4 can be used in aqueous H2SO4 (D) Cr2O7 can be used in aqueous H2SO4
15. A gas X is passed through water to form a saturated solutions. The aqueous solution on treatment with
silver nitrate gives a white precipitate. The saturated aqueous solution also dissolve magnesium ribbon
with evolution of a colourless gas Y. Identify X and Y.
(A) X = CO2, Y = Cl2 (B) X = Cl2, Y =CO2
(C) X = Cl2, Y = H2 (D) X = H2, Y = CL2
16. An aqueous solution of a substance gives a white precipitate on treatment with dilute hydrochloride acid,
which dissolve on heating. When hydrogen sulphide is passed through the hot acidic solution, a black
precipitate is obtained. The substance is a
2+ 2+ + 2+
(A) Hg2 salt (B) Cu salt (C) Ag salt (D) Pb salt
17. Which of the following processes is used in the extractive metallurgy of magnesium?
(A) fused salt electrolysis (B) self reduction
(C) aqueous solution electrolysis (D) thermite reduction
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19. Identify the correct order of solubility of Na2S, CuS and ZnS in aqueous medium
(A) CuS > ZnS > Na2S (B) ZnS > Na2S > CuS
(C) Na2S > CuS > ZnS (D) Na2S > ZnS > CuS
21. Identify the correct order of acidic strengths of CO2, CuO, CaO, H2O
(A) CaO < CuO < H2O < CO2 (B) H2O < CuO < CaO < CO2
(C) CaO < H2O < CuO < CO2 (D) H2O < CO2 < CaO < CuO
23. Which of the following acids has the smallest dissociation constant?
(A) CH3CHFCOOH (B) FCH2CH2COOH (C) BrCH2CH2COOH (D) CH3CHBrCOOH
27. Identify the correct order of boiling points of the following compounds
CH3CH2CH2CH2OH, CH3CH2CH2CHO CH3CH2CH2COOH
1 2 3
(A) 1 > 2 > 3 (B) 3 > 1 > 2 (C) 1 > 3 > 2 (D) 3 > 2 > 1
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28. Identify the set of reagents/reaction conditions X and Y in the following set of transformations
CH3 CH2 CH2Br X
product Y
CH3 CH CH3
|
Br
(A) X = dilute aqueous NaOH, 20C, Y = HBr/acetic acid, 20C
(B) X = concentrated alcoholic NaOH, 80C; Y = HBr/acetic acid, 20C
(C) X = dilute aqueous NaOH, 20C; Y = Br2/CHCl3, 0C
(D) X = concentrated alcoholic NaOH, 80C; Y = Br2/CHCl3.0C
29. Identify a reagent from the following list which can easily distinguish between 1-butyne and 2-butyne
(A) bromine, CCl4 (B) H2, Lindlar catalyst
(C) dilute H2SO4, HgSO4 (D) ammonical Cu2Cl2 solution.
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PHYSICS
PART-A
SECTION2
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
1. In the figure, the potential barrier across a p-n junction when no battery is
connected across the rejunction.
(A) 1 and 3 both correspond to forward bias of junction
(B) 3 corresponds to forward bias of junction and 1 corresponds to reverse
bias of junction
(C) 1 corresponds to forward bias and 3 corresponds to reverse bias of
junction
(D) 3 and 1 both correspond to reverse bias of junction.
2. A nucleus disintegrates into two nuclear parts which have their velocities in the ratio 2 : 1. Ratio of their
nuclear sizes will be
1 1 1 1
(A) 2 3 : 1 (B) 1: 3 2 (C) 3 2 : 1 (D) 1: 2 3
3. The half life period of a radioactive element X is same as the mean life time of another radioactive
element Y. Initial they have the same number of atoms. Then:
(A) X and Y decay at same rate always (B) X will decay faster than Y
(C) Y will decay faster than X (D) X and Y have same decay rate initially
4. The diagram shows the energy levels for an electron in a emission atom. Which transition shown
represents the emission of a photon with the most energy?
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5. In Young's double slit experiment, carried out with light of wavelength = 5000 , the distance between
the slits is 0.2 mm and the screen is at 200 cm from the slits. The central maximum is at x =0. The third
maximum (taking the central maximum as zeroth maximum) will be at x equal to
(A) 1.67 cm (B) 1.5 cm (C) 0.5 cm (D) 5.0 cm
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9. A wire carrying current i is bent as shown and placed in the plane of paper in a uniform magnetic field
B . Force experienced by the wire can be expressed as:
10. A loop carrying current I lies in the xy-plane as shown in the figure. The unit
vector k is coming out of the plane of the paper. The magnetic moment of the
current loop is:
(A) a2Ik (B) 1 a2Ik
2
(C) 1 a2Ik (D) (2 1)a2Ik
2
11. In the figure shown, AB is a wire of length 100 cm whose resistance is 5 . If galvanometer reads zero,
the current flowing in the wire AB is
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13. Two identical capacitors have the same capacitance C. One of them is charged to potential V 1 and the
other to V2. The negative ends of the capacitors are connected together. When the positive ends are
also connected, the decrease in energy of the system is:
1 1 1 1
(A) C(V12 V22 ) (B) C(V12 V22 ) (C) C(V1 V2 )2 (D) C(V1 V2 )2
4 4 4 4
14. Three infinitely long charge sheets are placed as shown in figure. The electric field at point P is:
2 4 2 4
(A) k (B) k (C) k (D) k
0 0 0 0
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16. Youngs double slit experiment is carried out by using green, red and blue light, on colour at a time. The
fringe widths recorded are G, B and R, respectively. Then,
(A) G B R (B) B G R (C) R B G (D) R G B
17. A small coin is resting on the bottom of a beaker filled with a liquid. A ray
of light from the coin travels upto the surface of the liquid and moves along
its surface (see figure). How fast is the light travelling in the liquid
8 8
(A) 1.8 10 m/s (B) 2.4 10 m/s
8 8
(C) 3.0 10 m/s (D) 1.2 10 m/s
18. R is the range on a horizontal plane for a shot with the same velocity at two different angles of
projection. If h and h be the greatest heights attained corresponding to these angles of projection, what
2
is R equal to
(A) hh (B) 9 hh (C) 16 hh (D) 25 hh
19. Two blocks are connected by a spring as shown. The blocks are placed on a horizontal rough surface
with as the coefficient of friction between the blocks and the surface.
(A) M2g (B) (M1 M2)g (C) (M1 + M2)g (D) (2M1 M2 )g
2
20. A circular disc of radius R is removed from a bigger circular disc of radius 2R, such that the
circumference of the discs coincide. The centre of mass of the new disc is R from the centre of the
bigger disc. The value of is:
1 1 1 1
(A) (B) (C) (D)
3 2 6 4
21. A cubical block of side a is moving with velocity v on the horizontal
smooth plane as shown. It hits a ridge at point O. The angular speed
of the block after it hits O is:
3v 3v
(A) (B)
4a 2a
3v
(C) (D) zero
2a
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23. A large open tank has two holes in the wall. One is a square hole of side L at a depth y from the top and
the other is a circular hole of radius R at a depth 4y from the top. When the tank is completely filled with
water, the quantities of water flowing out per second from both holes are the same. Then R is equal to
L L
(A) (B) 2L (C) L (D)
2 2
24. A wave is represented by the equation y = 7 sin 7t 0.04x where x is in meters and t in second.
3
The speed of waves is:
49
(A) 175 m/s (B) 49 m/s (C) m/s (D) 0.28 m/s
25. A whistle producing sound waves of frequencies 9500 Hz and above is approaching a stationary person
-1 -1
with speed vms . The velocity of sound in air is 300 ms . If the person hear frequencies upto a
maximum of 10,000 Hz, the maximum value of v upto which he can hear the whistle is:
-1 -1 -1 -1
(A) 15 ms (B) 30 ms (C) 152 ms (D) (15/2) ms
26. A homogenous solid cylinder of length L(L<H/2) cross-sectional area A/5 is immersed
such that it floats with its axis vertical at the liquid-liquid interface with length L/4 in
the denser liquid as shown in the figure. The lower density liquid is open to
atmosphere having pressure P0. Then, density D of solid is given by:
5 4
(A) d (B) d
4 5
d
(C) 4d (D)
5
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27. A uniform solid cylinder rolling without slipping along a horizontal plane
suddenly encounters a pane inclined at angle as shown. The value of
which count bring the cylinder immediately to rest after impact, is:
(A) 90 (B) 60
(C) 120 (D) 30
28. Four similar particles of mass m are orbiting in a circle of radius r in the
same direction because of their gravitational attractive force. Velocity of a
particle is given by:
1
Gm 1 2 2 2 Gm
3
(A) r 4 (B) r
1
Gm 1 Gm 1 2 2
(1 2 2)
(C) r (D) 2 r 2
29. Effective focal length of the lens combination shown in the figure is -60 cm. The
radii of curvature of the curved surfaces are 12 cm each and the refractive index
of left and right lenses is 1.5. Refractive index of the liquid is:
30. A spherical surface of radius of curvature R separates air (refractive index 1.0) from glass (refractive
index 1.5). The centre of curvature is in the glass. A point object P placed in air is found to have a real
image Q in the glass. The line PQ cuts the surface at point O, and PO = OQ. The distance PO is equal
to
(A) 5R (B) 3R (C) 2R (D) 1.5R
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MATHEMATICS
PART-A
SECTION3
Single Correct Questions
Section 1 contains 30 Single Correct Questions out of which only one option is correct
x
1. The intercept on x-axis made by tangents to the curve, y = | t | dt,x R , which are parallel to the line y
0
= 2x, are equal to
(A) 4 (B) 2 (C) 3 (D) 1
10
x 1 x 1
2. The term independent of x in expansion of 2 / 3 is
x x 1 x x1/ 2
1/ 3
1 3
3. If P 1 3 3 is the adjoint of a 3 3 matrix A and |A| = 4, then is equal to
2 4 4
(A) 0 (B) 5 (C) 4 (D) 11
x 2 y 3 z4 x 1 y 4 z 5
4. If the lines and are coplanar, then k can have
1 1 k k 2 1
(A) exactly two values (B) exactly one value
(C) any value (D) exactly three values
5. Let A and B be two sets containing 2 elements and 4 elements respectively. The number of subsets of
A B having 3 or more elements is
(A) 220 (B) 256 (C) 211 (D) 219
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x 2
x 1 dx x 1
3
8. If
x2 x
Px Q log
x
c , then
1 3
(A) P = , Q = (B) P = 1, Q = 1
2 2
(C) P = Q = 1 (D) none of these
9. The x-coordinate of the incentre of the triangle that has the coordinates of mid-points of its sides as (0,
1), (1, 0) and one vertex is (0, 0) is
(A) 1 + 2 (B) 2 - 2 (C) 1 - 2 (D) 2 + 2
1 1 1
10. If x, y, z are in A.P. and tan x, tan y and tan z are also in A.P., then
(A) 2x = 3y = 6z (B) 6x =3y = 2z (C) 6x = 4y = 3z (D) x = y = z
2 2
11. The equation of the circle passing through the foci of the ellipse x /16 + y /9 = 1, and having centre at (0,
3) is
2 2 2 2
(A) x + y 6y 7 = 0 (B) x + y 6y + 5 = 0
2 2 2 2
(C) x + y 6y +7 = 0 (D) x + y 6y 5 = 0
14. If z is a complex number of unit modulus and argument , then arg (1 + z)/ (1 z)
(A) /2 (B) (C) - (D)
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15. The area (in square units) bounded by the curves y = x, 2y x + 3 = 0, x-axis, and lying in the first
quadrant is
(A) 18 (B) 27/4 (C) 36 (D) 9
16. All the students of a class performed poorly in Mathematics. The teacher decided to give grace marks of
10 to each of the students. Which of the following statistical measures will not change even after the
grace marks were given?
(A) median (B) mode (C) variance (D) mean
17. At present, a firm is manufacturing 2000 items. It is estimated that the rate of change of production P
w.r.t. additional number of workers x is given by dP/dx = 100 - 12x if the firm employs 25 more workers,
then the new level of production of items is
(A) 3000 (B) 4500 (C) 2500 (D) 3500
/3
dx
18. Statement-1: The value of the integral is equal to .
/ 6 1 tan x 6
b b
Statement-2: f(x)dx f(a b x)dx .
a a
(A) Statement-1 is true, Statement-2 is True, Statement-2 is a correct explanation for statement-1
(B) Statement-1 is true, Statement-2 is False
(C) Statement-1 is true, Statement-2 is True, Statement-2 is NOT a correct explanation for statement-1
(D) Statement-1 is False, Statement-2 is True.
3
19. The real number k for which the equation, 2x + 3x + k = 0 has two distinct real roots in [0, 1]
(A) does not exist (B) lies between 1 and 2
(C) lies between 2 and 3 (D) lies between -1 and 0
20. The circle through (1, -2) and touching the axis of x at (3, 0) also passes through the point
(A) (5, -2) (B) (2, -5) (C) (-2, 5) (D) (-5, 2)
21. Let Tn be the number of all possible triangles formed by joining vertices an n-sided regular polygon. If
Tn+1 Tn = 10, then the value of n is
(A) 5 (B) 10 (C) 8 (D) 7
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2 2 2
22. Given: A circle, 2x + 2y = 5 and a parabola, y = 45x.
Statement-1: An equation of a common tangent to these curve is y = x + 5.
Statement-2: If the line, y = mx + 5/m (m 0) is either common tangent, then m satisfies m 3m + 2
4 2
= 0.
(A) Statement-1 is true, Statement-2 is False
(B) Statement-1 is true, Statement-2 is True, Statement-2 is NOT a correct explanation for statemen-1
(C) Statement-1 is true, Statement-2 is True, Statement-2 is a correct explanation for statement-1
(D) Statement-1 is False, Statement-2 is True.
-1
23. If y = sec(tan x), then dy/dx at x = 1 is equal to
(A) 1 (B) 2 (C) 1/2 (D) 1/2
24. ABCD is a trapezium such that AB and CD are parallel and BC CD. If ADB = , BC = p and CD = q,
then AB is equal to
(B) [(p + q )2sin /(pcos + qcos)
2 2 2 2 2 2
(A) (p + q )/(p cos + q cos)
2 2 2 2
(C) (p + q cos)/(pcos + qcos) (D) [(p + q )sin/(pcos + qcos)
(1 cos2x)(3 cos x)
25. lim is equal to
x 0 x tan 4x
(A) 1/2 (B) -1/4 (C) 1 (D) 2
26. A multiple choice examination has 5 questions. Each question has three alternative answers of which
exactly one is correct. The probability that a student will get 4 or more correct answers just by guessing
is
5 5 5 5
(A) 10/3 (B) 11/3 (C) 13/3 (D) 17/3
28. A ray of light along x + 3y = 3 gets reflected upon reaching x-axis, the equation of the reflected rays is
(A) 3y = x - 1 (B) y = x + 3 (C) 3y = x - 3 (D) y = 3x - 3
29. If the vectors AB 3i 4k and AC 5i 2j 4k are the sides of a triangle ABC, then the length of the
median through A is
(A) 72 (B) 33 (C) 45 (D) 18
30. The sum of first 20 terms of the sequence 0.7, 0.77, 0.777, ......, is
-20 -20
(A) 7/81 (179 + 10 ) (B) 7/9 (99 - 10 )
-20 -20
(C) 7/9 (99 + 10 ) (D) 7/81 (179 - 10 )
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CHEMISTRY
1 2 3 4 5 6 7 8 9 10
C D C A B C D B A A
11 12 13 14 15 16 17 18 19 20
C D A A C D A B D C
21 22 23 24 25 26 27 28 29 30
A B C D A C D B D B
PHYSICS
1 2 3 4 5 6 7 8 9 10
B D C A B D A A A B
11 12 13 14 15 16 17 18 19 20
A A C C D D A C D A
21 22 23 24 25 26 27 28 29 30
A B A A A A C A D A
MATHEMATICS
1 2 3 4 5 6 7 8 9 10
D A D A D B C C B D
11 12 13 14 15 16 17 18 19 20
A A B B D C D D A A
21 22 23 24 25 26 27 28 29 30
A A D D D B C C B A
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