103

2601101-03 _______ _______

11/10/2014
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1. Write the names or the chemical formulas of the following compounds or ions: (8 pts)

(A) Rb2O2 Rubidium peroxide

(B) Mn(OH)2
(C) N2O3
(D) KHCO3
(E) palladium diacetate Pd(OAc)
(F) phosphorus sulfide
(G) Cadmium selenide CdSe
(H) silver chromate
Manganese(II) Hydroxide
Dinitrogen trioxide
Potassium bicarbonate
P4O10
Ag2CrO4

2. Complete the following table. (8 pts)

80
Symbol 56
Fe 2+ Br-
Number of protons 26 35
Number of neutrons 30 45
Number of electrons 24 36
Atomic number 26 35
Mass number 56 80
Net charge 2+ 1-

3. (A) Who was the first chemist to perform truly quantitative experiments? (2 pts)
Robert Boyle
(B) List three types of radioactivity characterized by Rutherford. Which is/are electrically
charged? Of these three types of radioactivity which is/are not particles? (3 pts)
(1) , (2)
(C) Who discovered the law of conservation of mass and was also called the father of
modern chemistry? (2 pts)
Antoine Lavoisier

4. (A) Adipic acid contains 49.32% C, 43.84% O, and 6.85% H by mass. What is the
empirical formula? (3 pts)
C3H5O2
(B) A substance, A2B, has the composition by mass of 60% A and 40% B. What is the
composition of AB2 by mass? (3 pts)
27% A, 73% B

1
 (C) A 2.00 g sample of an oxide of bromine is converted to 2.936 g of AgBr. Calculate the
empirical formula of the oxide. (molar mass for AgBr = 187.78) (3 pts)
BrO3

5. A compound is composed only of elements X and H, and with 91.33% of X by mass. Each
molecule has 2.67 times as many H atoms as X atoms. What is element X? (4 pts)
(A) C (B) Ne (C) Si (D) Cl (E) Cu

6. Balance the following equations: (12 pts)

(A) 2 MnO4 + Br + H2O 2 MnO2 + BrO3 + OH- (base)
(B) 6 Zn + As2O3 + 12H+ 2 AsH3 + 6 Zn2+ + 3H2O (acid)
(C) When 0.2 M sodium hydroxide and 0.2 M barium nitrate are mixed, a precipitate is
formed. What is the net ionic equation for the formation of this precipitate?
Ba2+(aq) + 2 OH-(aq) Ba(OH)(s)
(D) What is the net ionic equation for the reaction of Na(OH)(aq) with HNO3(aq)?
H+(aq) + OH-(aq) H2O(l)

7. Give the balanced net ionic equation for the reaction between aqueous lead nitrate and
aqueous potassium iodide. (3 pts)
Pb2+(aq) + I(aq) PbI2(s)

8. (A) When NH3(aq) is added to Cu2+(aq), a precipitate forms. What is its formula? (3 pts)
Cu(OH)2
(B) An aqueous solution of barium nitrate reacts with an aqueous solution of sodium
sulfate. Give the chemical formula for the solid precipitate and indicate its coefficient in
the balanced equation. (3 pts)
BaSO4, 1

9. When benzene (C6H6) reacts with bromine (Br2), bromobenzene (C6H5Br) is obtained:
C6H6 + Br2 C6H5Br + HBr
(A) What is the theoretical yield of bromobenzene in this reaction when 30.0 g of benzene
reacts with 65.0 g of bromine? (3 pts) 60.3 g
(B) If the actual yield of bromobenzene was 56.7 g, what was the percentage yield? (3 pts)
94 %

10. A sample is a mixture of KCl and KBr. When 0.1024 g of the sample is dissolved in water
and reacted with excess silver nitrate, 0.1889 g of solid is obtained. What is the
composition by mass percent of the mixture? (4 pts)
KCl : 77.4%, KBr : 22.6 %

11. Carminic acid contains only C, H, and O. It is 53.66% C and 4.09% H by mass. A titration
required 18.02 mL of 0.0406 M NaOH to neutralize 0.3602 g carminic acid. Assume only
one acidic H per molecule, what is the molecular formula of carminic acid? (5 pts)
C22H20O13

2
12. You have 130.0 mL of a 0.240 M solution of NaCl sitting in a beaker. After several days you
test the solution and find that it has a concentration of 0.410 M. How much water must have
evaporated? (Assume volumes are additive.) (5 pts)
53.9 mL

13. An element X forms both XCl2 and XCl4. Treatment of 10.00 g XCl2 with excess chlorine
forms 12.55 g XCl4. Calculate the atomic mass of X, and identify X. (Cl:35.45) (5 pts)
Atomic mass = 207 g / mole, X = Pb

14. (A) a qualitative graph of P versus molar mass of a 1 g sample of different gases at
constant volume and temperature. (5 pts)

(B) Plot a graph of volume versus temperature in degrees Celsius for an ideal gas at
constant volume and number of moles. (5 pts)

15. (A) A sample of helium was contaminated with argon gas. At 1 atm and 25C, the density
of the mixture is 0.200 g/L. What is the volume percent argon in the sample? (5 pts)
20 %
(B) When 0.72 g of a liquid is vaporized at 110C and 0.967 atm, the gas occupies 0.559 L.
The empirical formula of the gas is CH2. What is the molecular formula of the gas?
(5 pts)
C3H6