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(2) The capillary action, lifting fluids narrow tubes, occurs when there
are attractions between the liquid molecules and the inner surface of the
tube. The liquid meniscus is curved surface which is formed a narrow
tube. For water in a capillary tube glass, the meniscus is curved up at
the edges, so concave, while for the edges of mercury have a convex
meniscus shape. Taking consideration the text information and following
figure,
H2O Hg
* * * *
(a) (b) (c) (d)
a) Considering only the information given in the text, what are the
possible combinations between bases a, b, c and d? Justify.
b) In fact, only two item combinations occur in nature. Justify this fact in
terms of intermolecular interactions.
4. The disposable diaper absorbs urine. This avoids the urine contact
with baby's skin. Some diapers disposable, however, continue dried even
after absorb a large amount of urine. The secret of these diapers resides
in chemical properties: the polyacrylate sodium is a polyelectrolyte. The
dry sodium polyacrylate when mixed with water, forms a gel which can
entrap 800 times its weight in water. The inner layer of the diaper is also
made from a polymer, polypropylene, which is not wet, preventing the
rash in babies. Which kind of molecular interaction is involved in the
sodium polyacrylate chemical properties?
Information:
EJERCICIO DE EXAMEN
5. The vapor pressure of a substance is related with its molecular
properties. The geometric isomers cis-dibromo-eteno and trans-dibromo-
eteno are liquid at room temperature:
a) write the structural formulas of these compounds;
b) indicate, with justification, which is more volatile liquid to room
temperature.
Polypropylene
7. The vast majority of people, adults and/or children, like blowing soap
bubbles. A recipe to make the bubbles more resistant and bigger soap
bubbles is to add corn syrup (containing 80% glucose and 20% fructose)
to water with detergent. Based on the formula of glucose and fructose
and your knowledge of intermolecular forces, explain why the soap
bubble is more resistant in this case.
Based on this model, represent the hydrogen bonds that exist between
the molecules of ammonia, NH3.
.
10. Two glass substrates commonly used in the manufacture of windows
was cleaned and dried. At the ambient conditions, it was carefully
deposited a drop (0.05 ml) of mercury in one of the substrates and one
drop (0.05 ml) of water in the other substrate. Consider that the liquids
are pure.
a) Draw the deposited liquid drop format on each of the substrates.
b) Explain the reason for any differences in shapes of drops of the liquid
deposited on each of the glass substrates.
c) What is the influence of liquid volume in shape of droplets deposited
onto the substrates?
11. The intermolecular forces are responsible for various physical and
chemical properties of molecules, such as the melting point. Consider
the molecules F2, Cl2 and Br2.
a) What are the main intermolecular forces in those species?
b) Arrange these species in order of increasing melting temperature.
12. The y-axis of the figure represents the boiling point of the
compounds of the groups 14 and 16 of the periodic table. On the x-axis
presents their values of the molar masses. Taking into consideration the
following chart, respond to items below:
(a) Explain the observed behavior for the boiling points in the family of
carbon compounds
b) Explain why the water has point boiling higher than that of other
elements of oxygen group and why this discrepancy does not occur with
the family of elements of the carbon group.
13. The van der Waals constant for NH3 is greater than that for CO2
which in turn is greater than for O 2. Use your knowledge of
intermolecular forces to explain why this fact.