WCHO4 Jun 2015

1. H I

C = C
CH3 CH3
Priority group same side Z
Priority group opposite sides E
When naming we should give the lowest number to the functional group.so E -2
iodobut 2 ene
2. Add
3. pH = - log [H +]
= - log (0.4)
= 0.40
4. Carrier gas in gas chromatography
- Ar
- Ne
- CO2
5. P(g) + 3Q(g) 8 R(g)

Kp = P8 R
P1 p P3Q
= atm 8
3
atm x atm
4
= atm
6. a) N2O4 2 NO2(g)
(g)

Initial moles 5
Reacted & formed 1 2
@ equal 4 2
b) Kp = P2NO2 25% - N2O4
PN2O4 75 % - NO2
= (0.75 x 3)2 PNO2 = 0.75 x 3
= (0.25 x 3) PN2O4 = 0.25 x 3
= 6.75
7. CO(g) + Cl 2(g) COCL2(g)

 As pressure decreases system tries to increase the pressure equilibrium
moves to the direction where less number of gas molecules ,hence left hand side.Kp
depends only O temperature. So Kp remains same.
8. a) Sr 2+
(g) + 2 F (g) Sr 2+
(aq) +2F
(aq)

Sr 2+
(g) Sr 2+
(aq) - 1443
2F
(g) 2F
(aq) - 483 x 2
- 2409
b) Rb + (g) + Cl
(g) - 685 RbCl(s)

Rb +(aq) + Cl (aq)
H sol = - 297 -340 + 685
= + 48 kJmol -1
9. Polar molecules will absorb microwaves CH3
CH3 S1 CH3
CH3
10. a) H Cl
CH3 C C COOH Will give effervescence with the sodium
carbonate solution
Acid + Carbonate Salt + water + CO2
b) To distinguish aldehydes and ketones we can use
Fehling s (or benedict s) sol O
c) Iodoform test give yellow precipitate with CH3 C group
11. a) acidity with water
CH3 COCL > CH3 COOH > HCOOCH2CH3 > CH3 CONH2
-1
b) Peak at 3348 For amides O
C N group
C) Fruit flavored food additives one esters HCOOCH2 CH3
12. a) HCN (aq) H+(aq) + CN
(aq) @ pH 8 forward reaction is
.
So addition of HCl reduce the pH and hence reduce the [CN -] to a
greater extent
b) O O-
C CH3 step1 CH3 C CN
CH3 C
H2 CH2 CH3 Intermediate
X
 c) The products forms are two optical isomers since the original compound is
planner and equal attack of the nucleophile from the both sides can be happen.
OH

CH3 C CN

CH2 CH3

This product contain one more carbon atom than the ketone.
Contain nitrile group.
Products are .. molecules
But products mixture does not rotate pale of plane polarized light because
racemic mixture is formed.