The impact resistance of

composite materials---a review

W.J. CANTWELL* andJ. MORTONt

(* Ecole Polytechnique Fdd#rale de Lausanne, Switzerlandl t Virginia Polytechnic

Institute and State University, USA)

In this paper the impact response of continuous fibre-reinforced composites

is reviewed. An attempt is made to draw together much of the work pub-
lished in the literature and to identify the fundamental parameters determin-
ing the impact resistance of continuous fibre-reinforced composite materials.
The effect of varying the properties of the fibre, matrix and interphase are
examined as well as the role of target geometry and loading rate on the
dynamic response of these materials.

Key words: composite materials; impact testing; impact resistance; residual

strength; failure mode; fibre properties; matrix properties; interphase;
laminate stacking sequence; geometry; loading rate

Fibre-reinforced composite materials such as carbon,
glass and Kevlar ~ fibre-reinforced plastics are finding
increasing use in a wide range of both low and high
technology engineering applications. Composites offer
a number of distinct advantages over more conven-
tional engineering materials such as aluminium and
steel. These include higher specific strengths and
stiffnesses, superior corrosion resistance as well as
improved fatigue properties. Coupled with these
improvements in general overall performance is the
fact that the cost of manufacturing components from
fibre-reinforced plastic is often less than with more
conventional metals. This is true not only at the low-
cost end of the market occupied by sheet moulding
compounds (SMC) but also in the aerospace sector
where complex load-bearing shapes can be produced in
a limited number of steps, saving time in both joining
and assembly.
Composite materials do, however, suffer some serious
limitations. Perhaps the most significant amongst these
is their response to localized impact loading such as
that imparted by a dropped tool or runway debris. In
recent years many research programmes have been
undertaken in an attempt to better understand the
impact response of these materials 1-9. The majority of
this work has been undertaken on continuous fibre,
high performance composites since these materials are
finding increasing use in the design of a large number of
civil and military aircraft, i.e., in circumstances where
the consequences of impact are likely to be most
serious.
The manner in which composite materials respond to
impact loading and dissipate the incident kinetic energy
of the projectile is very different to that of metals. For
0010-4361/91/050347-16(~) 1991 Butterworth-Heinemann Ltd
COMPOSITES. VOLUME 22. NUMBER 5. SEPTEMBER1991
low and intermediate incident energies, metals absorb
energy through elastic and plastic deformation 1.
Although the latter may cause some permanent struc-
tural deformation, its consequences on the load-
carrying capability of the component are usually
small 11. At high incident impact energies target perfo-
ration may occur and the passage of the impactor will
generally result in petalling, cracking and spalling 12.
Although such damage will degrade the load-bearing
ability of the structure, its effects can generally be
predicted using fracture mechanics principles t2. In
composites, however, the ability to undergo plastic
deformation is extremely limited with the result that
energy is frequently absorbed in creating large areas of
fracture with ensuing reductions in both strength and
stiffness 1.13. Furthermore, the prediction of the post-
impact load-bearing capability of a damaged composite
structure is more difficult than for metals since the
damage zone is generally complex in nature and
consequently very difficult to characterize 12. The
problem is further complicated by the lack of existing
standards or established testing techniques for impact
of composite materials. Much of the work published in
the literature has been conducted on purpose-built
machines using convenient specimen geometries. As a
result, direct comparisons between different material
systems is often very difficult and immediate conclu-
sions are sometimes hard to draw.
The objective of this article is to draw together the
pertinent findings of many of the articles published in
the field of impact of fibre-reinforced composites and
thereby present a global view of the state-of-the-art.
Initially, the paper will review briefly the techniques
most frequently employed for assessing the impact
347
response of composite materials. Following this, the
effect of varying fundamental parameters such as fibre
and matrix properties and stacking sequence on the Weig
dynamic response of these materials will be considered. Specimen
Since a substantial amount of the work published in the
literature relates to tests on carbon fibre composites,
the main focus of this report will be on this material. Notch ~I/-- ~pactor Inertiabar
However, work undertaken on other materials will be
used in order to supplement and substantiate ideas and
theories.
Straingauge--I [
IMPACT TEST TECHNIOUESFOR COMPOSITE
MATERIALS
Ideally, the impact test fixture should be designed to Specimen
simulate the loading conditions to which a composite
component is subject in operational service and then
reproduce the failure modes and mechanisms likely to
occur. In simple terms, the impact problem can be
divided into two separate conditions: low velocity
impact by a large mass (dropped tool) and high velocity
Specimen [ __
Notch
~ or

/I
Straingauges
impact by a small mass (runway debris, small arms fire,
etc.). The former is generally simulated using a falling
weight or a swinging pendulum and the latter using a
gas gun or some other ballistic launcher. However, as
stated previously, due to a lack of experimental stan-
dards a wide variety of testing techniques is presently
oe'P"tar
being employed in order to assess the dynamic
response of reinforced plastics 1-4, 14-17, making direct b e
comparison difficult.
In this section the more commonly used techniques will
be presented and discussed as well as the problems
associated with the ensuing data analysis.

Low velocity impact

Machines currently used for simulating the low velocity
impact response of composite materials include the
Charpy and Izod pendulums, the falling weight fixtures
such as the Gardner and drop dart tests as well as
hydraulic machines designed to perform both in-plane
and out-of-plane testing at velocities up to 10 m s-1.

1. Charpy pendulum
Many of the early impact studies on composite materi-
als were undertaken using the Charpy test method
originally developed for testing metals 11'1s'19. The
reason for this choice was the fact that the Charpy
pendulum is both simple to use and can be instru-
mented, and therefore, in principle, can yield informa-
tion on the processes of energy absorption and dissipa-
tion in composites. The test specimen is generally a
thick beam, sometimes incorporating a notch at its mid
point as shown in Fig. l(a). The specimen is supported
in a horizontal plane and impacted by the swinging
pendulum directly opposite the notch. The energy
dissipated during impact is usually recorded by a dial
on the test apparatus. Further information can be
obtained by instrumenting the impactor with a strain
gauge, thereby enabling the determination of the
variation of the impact force with time. The energy
absorbed during impact can also be determined by
integrating the force/time signal.
Fig. 1 (a) Charpy impact test; (b) Izod impact test; (c) tensile
Hopkinson-bar test; (d) gas gun
The test set-up suffers a number of disadvantages such
as the fact that the load/time curves often contain high
frequency harmonic oscillations resulting from the
natural response of the impactor, etc. These effects can
generally be filtered once the harmonic frequencies of
the various components have been determined 2. As
stated previously, the test specimen is a short, thick
beam and is not therefore typical of engineering
components. Further, the test is destructive, inducing
failure modes that are not necessarily observed under
low velocity impact loading on operational structures.
Bader and Ellis.21 showed that the Charpy energy of
carbon fibre-reinforced plastic (CFRP) varied with
specimen geometry and doubt, therefore, the applica-
bility of the technique. The Charpy test is only suitable
for ranking the impact performance of continuous fibre

348 COMPOSITES. SEPTEMBER 1991

composites and as a first step in determining the
dynamic toughness of these materials.
2. Izod test
The Izod impact test is shown schematically in Fig.
l(b). The test set-up and procedure are similar to those
outlined above. In the Izod test specimen is clamped in
the vertical plane as a cantilever beam and impacted by
a swinging pendulum at the unsupported end. The test
suffers similar problems to those reported above and
again is best suited as a tool for ranking the impact
resistance of composite materials.
3. Drop-weight impact tests
Here a weight is allowed to fall from a pre-determined
height to strike the test specimen or plate supported in
the horizontal plane. In general, the impact event does
not cause complete destruction of the test specimen hut
rebounds, enabling a residual energy to be determined
if necessary. The incident velocity of the impactor can
be determined from the equations of motion or by
using optical sensors located just above the target.
Frequently, the impactor is instrumented, enabling the
force/time characteristics to be determined, and may
also contain a displacement transducer in order to
permit the determination of energy dissipation during
the impact event. One of the advantages of this test
with respect to the Charpy and Izod tests is that a wider
range of (est geometries can be tested, thereby
enabling more complex components to be tested.
Although testing is generally undertaken using a
hemi-spherical impactor, it is possible to use other
impactor shapes such as blunt cylinders or sharp points.
Variations on the drop-weight theme include the
Gardner test where a hemi-spherical impactor strikes a
small diameter circular plate and the driven dart test
where a hemi-spherical probe is driven into the
specimen at a pre-determined rate 22.
4. Hydraulic test machines
In recent years a number of workers have used hydrau-
lic test machines for assessing the deformation and
failure characteristics of materials at high rates of
strain 23'24. Here, test geometries such as tensile dog-
bone specimens or double cantilever beam (DCB)type
specimens can be tested over a wide range of strain
rates The strain history of the specimen can be
measured using bonded strain gauges or an optical
transducer. If a strain gauge or any other displacement
measuring device is bonded to the specimen, the strain
rate sensitivity of the adhesive should be considered.
The advantage of this technique is that the test speci-
mens permit the evaluation of basic material properties
such as tensile strength, modulus and interlaminar
fracture toughness without the contact effects associ-
ated with falling weight impact. Extreme care has to be
taken in order to ensure that the mass of the load cell
and gripping system are as low as possible since inertial
effects resulting from these components may conceal
the true material response24. Caution should also be
exercised when applying fracture mechanics principles
to geometries such as the DCB since the specimen may
not be deforming in the same mode as a similar
statically-loaded specimen24.
Intermediate and high rate impact
1. Hopkinson-bar technique
The Hopkinson-bar technique is similar to the previous
test procedure in that it permits the determination of
the variation of basic material properties as a function
of strain rate. Several different types of Hopkinson-bar
are currently employed; these include the punch-
loaded Hopkinson-bar, the compression bar, the
tensile bar and the Hopkinson-bar shear test z~-27. The
set-up and experimental procedures associated with
these tests has been discussed in detail elsewhere25.
Here, a brief description of the tensile test will be
given. The test set-up for undertaking dynamic tensile
tests is shown in Fig. l(c) ~. Here, specimens waisted
through the thickness are bonded into slots in the
inertia bar and input bar as shown in the diagram. This
configuration is then placed within the weighbar. Strain
rates approaching 1000 s-1 can then be achieved using
gas-driven projectiles to accelerate the weighbar and,
in turn, load the input bar 25. The inertia of the inertia
bar then enables the test coupon to be loaded dynami-
cally. Strain gauges bonded to the input and inertia
bars enable the incident and reflected stress waves to
be analysed and permit the determination of a dynamic
stress/strain curve for the material. The Hopkinson-bar
tensile test is destructive.
Care has to be taken in order to ensure that the inter-
face between the specimen and loading bars is good,
otherwise a shear failure within the gripping section is
likely to occur. Further, in order to minimize stress
concentrations associated with the gripping area,
relatively long specimens (approximately 60 mm) are
required when testing composite materials .
28
2. Gas gun impact testing
Impact testing at ballistic rates of strain can be achieved
using a high pressure gas gun such as that shown in Fig.
l(d) ~9. Typically, a gas such as nitrogen is fed to a
chamber located at one end of the barrel. Here the gas
is restrained by a plastic diaphragm. When the gas has
reached a pre-determined value the diaphragm is burst
(by electrical heating or a mechanical puncturing
device), accelerating a projectile down the barrel to
strike a specimen or component supported vertically.
The velocity of the impactor can be determined just
prior to impact using optical sensors3 or by using a
simple break-wire technique 29. Generally, the test is
not completely destructive but frequently results in
large-scale damage and/or target perforation. Until
recently the technique suffered the disadvantage that
very little information could be obtained from the test
itself. However, instrumented gas guns have now been
developed, enabling force/displacement histories to be
measured and the impact event to be analysed in more
detail31,32. Gas guns can be used to test large structures
and are therefore useful for assessing the high velocity
impact response of composite materials.
COMPOSITES. SEPTEMBER 1991 349
 Conclusions
At present, no acceptable standard testing procedures
are available for impact testing of composite materials.
Consequently, a wide variety of testing procedures,
specimen geometries and data reduction techniques are
presently being employed. Pendulum techniques such
as the Charpy and Izod tests often require specimen
geometries that are not representative of component
dimensions and so are essentially suitable only for
ranking the impact response of composites. Drop-
weight rigs and gas guns offer more representative
approaches for assessing the impact response of these
materials. Greater use of instrumented impactors has
led to a deeper understanding of the processes of
energy absorption and dissipation in these materials.
More recently, hydraulic machines have been used to
examine the response of composite materials at high
rates of strain. Although somewhat more expensive
than other, more conventional techniques, such
machines are ideally suited for analysing the rate
dependency of basic material properties.
INFLUENCE OF CONSTITUENT PROPERTIES ON
THE IMPACT RESPONSE OF COMPOSITE
MATERIALS
In sirqple terms, a fibre-reinforced composite is
composed of three constituents: the fibres, the matrix
and a fine interphase region (sometimes referred to as
the interface) responsible for assuring the bond
between the matrix and fibre. The manner in which the
material deforms and fractures depends upon both the
chemical and mechanical properties of these three
constituents. Detailed analyses using both optical and
scanning electron microscopes have identified a
number of failure mechanisms in fibre-reinforced
composite materials29'3336. These include delamina-
tion, intralaminar matrix cracking, longitudinal matrix
splitting, fibre/matrix debonding, fibre pull-out and
fibre fracture. The relative energy absorbing capability
of these fracture modes depends upon the basic proper-
ties of the constituents as well as the loading mode.
Typical values measured for a number of continuous
Table 1. Typical values of the energy absorbing capability of various continuous fibre composites for
different failure modes
Failure mode Material
Splitting Type II CF/epoxy
AS4/PEEK
Delamination T300/epoxy
IM6/PEEK
Transverse Treated CF/epoxy
fibre fractu re Untreated CF/epoxy
AS4/PEEK
Fibre pull-out CFIpolyester
CF/bismaleimide
Debonding CF/epoxy
350 COMPOSITES. SEPTEMBER 1991
fibre composites are given in Table 1. Generally
speaking, failure modes that involve fracture of the
matrix or interphase region result in low fracture
energies whereas failures involving fibre fracture result
in significantly greater energy dissipation.
The following sections will investigate the role of the
material constituents independently and examine the
influence of varying their properties on the overall
impact resistance of the composite.
Fibre
The role of the fibres in a composite structure is
extremely important since they are responsible for
bearing a significant percentage of the applied load. At
present, many types of fibre are available. In aeronau-
tical applications these include carbon, glass, and
KevlaP~ fibres. Within each of these categories fibres
exhibiting a wide range of mechanical properties are
available. Unfortunately, it is often difficult to separate
the effects of mechanical properties (such as strength
and stiffness) from those arising from geometrical
factors (such as fibre shape and diameter) and interfa-
cial properties (such as the strength of the chemical
bond between fibre and matrix).
Early studies36, in which the relative performance of a
number of continuous fibre composites was examined,
suggested that the Cliarpy impact resistance of S-glass
and Kevlar~ fibre-reinforced composites was over five
times greater than that of a Modmor II carbon fibre-
reinforced composite. Beaumont et al. is examined the
Charpy load/time traces of a number of materials and
showed that the curve corresponding to an HMS
carbon composite was extremely brittle, failing cata-
strophically at maximum load. The E-glass and Kevlar~
49 composites failed in a more progressive manner
indicative of energy dissipation through delamination,
splitting and other failure processes. The authors
quantified the Charpy load/time traces by defining a
ductility index (DI), this being the ratio of the energies
associated with the crack propagation phase (the area
after maximum load) and the initiation phase (the area
Typical fracture energy Reference
(kJ m-2)
0.1-1 11
3.8 60
0.1 102
2.2 62
20 72
60 72
128 60
26 104
800 105
6 106
 up to maximum load). The resulting ductility indices
for the Kevlar-49, E-glass and HMS carbon/epoxy
composites were 23, 0.4 and 0.0 respectively, indicating
clearly the superior energy absorbing capability of the
Kevlar fibre.
Hancox 37 and Bader and Ellis 21 compared the low
velocity impact response of composites containing type
I and II carbon fibres. In both cases it was shown that
the materials containing type II fibres (higher failure
strength) offered superior impact resistance. Similar
results have been observed following low velocity
impact tests on E- and S-glass fibre composites 15.
In an attempt to better understand the fundamental
parameters controlling the processes of energy absorp-
tion and dissipation in composite materials, Chamis et
al. 3s undertook Izod impact tests on a wide range of
systems. They concluded that flexure and interlaminar
shear deformations are dominant energy-absorbing
mechanisms in composites and that the area under the
material's linear stress/strain diagram represents a
useful approach for predicting the impact resistance of
a composite. Essentially, composites with large areas
under the stress/strain curve are more effective energy
absorbers. Fig. 2 presents the experimental data
obtained by Chamis and Sinclair39 plotted as a function
of the energy absorbing capability of the fibre as
determined by the energy under the static tensile
stress/strain curve. An examination of the data suggests
a possible relationship between these two parameters,
with materials containing fibres with a greater strain
energy absorbing capacity offering improved lzod
energies. It appears, therefore, that this technique
forms a useful guide for assessing and evaluating the
impact resistance of composite materials. This tech-
nique also explains the results of Hancox 37 and Bader
and Ellis 2~, reported above, who found that composites
based on type II carbon fibres outperformed type I
carbon fibre composites. The former has an elastic
energy absorbing capability some four times greater
than the latter.
Although the above approach is valuable for evaluating
the impact resistance of a composite, a complete
analysis should take into consideration energy dissipa-
tion in failure processes such as fibre/matrix debonding
40,
35
I tion in fibre failure strain, resulting in a loss of strain
E 30 ~-
25 ~-
E ments in the high velocity impact response of compos-
2O
Q.
.E 15--
10
0 I t{, , I, , , I , ii { ,,,
0.0 0.2 0.4 0.6 0.8
Normalized strain energy
Fig. 2 Variation of Charpy impact energy with normalized
strain energy absorbing capacity of fibres (data taken from
Ref 39)
and fibre pull-out. Beaumont 4 gives expressions for
work associated with micro-mechanical fracture
processes such as debonding and fibre pull-out. The
wot'k for debonding is given as:
Wd = ad2o2fld24Ef (1)
where d = fibre diameter, of = failure strength of the
fibre, ld = length of the debonded zone and Ef = fibre
modulus. The work to pull-out is given as:
Wp = ~d~Fg2 4 (2)
where lc = critical transfer length (-- otd/2x) and x =
constant frictional shear stress.
Beaumont concluded that post-debond fibre sliding is
the primary energy absorbing mechanism in glass fibre
composites, whereas fibre pull-out is responsible for
much of the toughness in a carbon fibre composite. An
examination of Equation (2) indicates a strong depen-
dency of work to pull-out on fibre diameter. In theory,
increasing the diameter of the reinforcing fibre should
result in a composite with an improved resistance to
pull-out and perhaps improved toughness 1L34. Morris
and Smith41 reported results that appear to support a
fibre diameter dependence in continuous fibre-
reinforced composites. Their conclusions are based,
however, on differences between glass and boron fibre
composites with different fibre volume fractions and
are not, therefore, conclusive.
In recent years, fibre manufacturers have been improv-
ing the strain to failure of carbon fibres by reducing
their diameter. Typically, the first generation of carbon
fibres such as T300 and AS4 had diameters of 7--8 ~tm.
More recent fibres such as IM6 have diameters of
approximately 5 tim. By improving the strain to failure
of the fibres in this way the manufacturers have also
improved the strain energy absorbing ability of com-
posites and thereby improved their impact resistance.
Davies et al. 42 showed that the interlaminar fracture
toughness of IMr/polyetheretherketone (PEEK)
(superior strain energy absorbing capability) is superior
to that AS4/PEEK. Curson et al. 4 drew similar conclu-
#ons following low velocity impact tests on these
materials.
Under conditions of low velocity impact loading, it
appears, therefore, that the improved toughness gained
by increasing the fibre diameter is offset by the reduc-
energy absorbing capability. It may be, however, that
increasing the fibre diameter might lead to improve-
ite materials. Under such loading conditions, the target
response is more localized with energy being dissipated
over an area immediate to the point of impact. Conse-
quently, the overall energy absorbing ability of the
structure is less important and local mechanisms such as
fibre pull-out and fracture become dominant.
1, I I As well as influencing the impact resistance of a com-
1.0 1.2 posite, the properties of the fibre also have a significant
effect upon the residual load-bearing capability of the
material. Composite systems that offer excellent impact
resistance do not necessarily exhibit superior post-
impact residual properties. For example, polyethylene
COMPOSITES. SEPTEMBER 1991 351
fibre composites are capable of absorbing large
amounts of energy before failure but still offer rela-
tively poor compressive properties due to the low
stiffness of the fibres themselves. In most circumstances
a compromise is required. The following section
considers briefly the effect of fibre properties on the
post-impact strength of composite materials.
1. Effect of fibre properties on post-impact
residual strength
In recent years a concerted effort has been made by the
manufacturers of high performance fibres to improve
both the short- and long-term mechanical properties of
advanced composites. Much of this improvement has
been achieved by increasing the strain to failure of the
reinforcing fibres. In the previous section, the energy
absorbing capacity of the fibres was identified as an
important parameter in determining the level of
damage incurred in a composite laminate. Often,
materials that satisfy this condition also offer excellent
residual properties. Cantwell et al. 43 showed that this
was the case for low and high strain carbon fibre
composites. An AS4 carbon fibre composite with a
superior strain energy absorbing capacity than that of
an XAS carbon fibre composite offered superior
residual properties, Fig. 3. This is not always the case,
however. For example, if the stiffness of the fibre is
very low and its strain to failure high, a composite
containing these fibres will be capable of absorbing
large amounts of energy but will exhibit poor residual
compressive properties. In order to overcome this,
hybrid composites are frequently used, combining the
energy absorbing capability of low modulus fibres with
stiffer fibres capable of resisting compressive loads**.
As stated previously, many of the latest generation of
composites are based on fibres with smaller diameters.
Since the compressive strength of a composite depends
upon the stability of the fibres, it would be expected
that smaller diameter fibres would result in a material
with poorer compressive properties. This indeed
appears to be the case 45. However, reducing the fibre
diameter increases the energy absorbing capability of
the composite, resulting in lower levels of damage for a
1200
~- 1000
e-
? ~.~ ~ " ' - o ..... o.. Tension
~ 600
~, 400
n.-
200 Compression/I'I"
I I I I
0 2 4 6
Impact energy (J)
Fig. 3 Variation of tensile and compressive residual strength
w i t h impact e n e r g y for l o w and high strain fibres (Ref 43): e,
high strain fibres; o, l o w strain fibres
352 COMPOSITES. SEPTEMBER 1991
given incident energy. The reductions in plain compres-
sive properties of the composite appear to be offset by
the reduction in damage area.
2, Conclusions
The properties of the fibres in a continuous fibre
composite have a significant effect on the impact
resistance and subsequent load-bearing capacity of
components made from such materials. For low
velocity impact loading, the ability of the fibres to store
energy elastically appears to be the fundamental
parameter in determining impact resistance. Kevlar
fibres, which have large areas under their stress/strain
curves, offer excellent impact resistance. The role of
the fibre diameter is not completely clear. A simple
pull-out model suggests that composites with larger
diameter fibres should be inherently tougher.
However, current trends are towards smaller diameter
fibres offering higher strains to failure. Any reduction
in toughness is thereby hidden by the increased energy
absorbing capacity of the fibres.
Matrix
The polymeric matrix in a fibre-reinforced composite
serves to protect, align and stabilize the fibres as well as
assure stress transfer from one fibre to another. In
general, both the stiffness and strength of the matrix
are considerably below those of the reinforcing fibre.
The latter is therefore responsible for carrying most of
the applied load in a composite component. The role of
the matrix is nevertheless critical. For example,
damage to the matrix such as impact-induced delamina-
tion can reduce the load-bearing capabifity of the
composite by up to 50% 46. As a result of this relatively
poor behaviour, much work has been undertaken in
recent years in an attempt to identify the fundamental
matrix properties that influence the impact resistance
of composite materials. Since the first generation of
matrix systems for advanced composites lacked tough-
ness, a number of techniques have been developed to
impro~,e the toughness of these materials. These
include:
the use of plasticizing modifiers11;
the addition of rubber particles such as carboxyl-
terminated butadiene-acrylonitrile (CTBN)47--49.;
the addition of thermoplastic particles such as
polyethersulphone (PES)and polyetherimide
(pE0~52;
a reduction in the cross-linking density of thermosets
such as epoxy resins53'54;
the use of thermoplastic matrices such as PEEK; and
the inclusion of thin, tough layers at ply
interfaces 5,5s-57.
Early work by Bradshaw et al. 11 showed that adding a
8 10 plastidzer to Epikote 828 epoxy resin increased the
Mode I fracture toughness by over two orders of
magnitude. When used as a matrix system in a carbon
fibre composite, increases in toughness did result;
however, in this case the Izod impact energy was
improved by only 25%. This disappointing transfer of
toughness was explained by the fact that the Izod test
induces crack propagation across fibres rather than
between them. Improvements in the interlaminar
toughness and resistance to splitting are hidden,
therefore, by the higher energy fracture energy associ-
ated with transverse fibre failure.
Husman et al. 17conducted high velocity impact tests on
a limited number of Modmor II carbon fibre compos-
ites. Their data suggested that the impact resistance of
these materials did not depend upon the properties of
the polymeric matrix.
In a more detailed analysis by Williams and Rhodes 49,
the impact resistance of 24 modified and unmodified
carbon fibre/epoxy composites was examined. Their
experimental analysis showed that both the level of
damage incurred as well as the residual compressive
properties of the laminates varied enormously. It was
found that the brittle laminates tended to fail by
extensive delamination whereas the tougher systems
failed in transverse shear near the impact location. The
authors concluded that the tensile performance of the
neat matrix has a significant influence on the impact
behaviour of a composite structure. For improved
impact resistance, the strength of the matrix should
exceed 69 MPa and its strain to failure should be
greater than 4%. Finally, in order to ensure adequate
compressive strength, the shear modulus should be
greater than 3.1 GPa.
Hirschbuehlers7 examined a large number of plain and
interleaved composite systems under a variety of
different loading conditions in an attempt to relate
matrix properties and post-impact compressive
strength. It was found that the residual compressive
properties of the composites increased with the flexural
strain to failure of the pure resin, Fig. 4.
Hunston47 analysed data from three sources in an
attempt to identify a link between matrix properties
and composite fracture toughness. He identified a
definite correlation between the resin Mode I fracture
toughness and composite interlaminar fracture energy
as measured by the DCB specimen, Fig. 5. With brittle
polymers, the resin toughness is fully transferred to the
composite, whereas with tougher polymers the resin
toughness is only partly transferred to the composite.
In the latter it is proposed that the presence of the
fibres restricts the crack-tip plastic zone size, thereby
reducing the positive effect of the tougher matrices.
Masters3s'~ extended this approach by conducting
Mode I, Mode II and compression after impact (CAI)
tests on a number of epoxy and bismaleimide-based
carbon fibre composites. He showed that no correlation
existed between the Mode I interlaminar toughness and
the CAI properties, Fig. 6, whereas a very good agree-
ment was found between the Mode II resistance and
residual compressive strength, Fig. 7. Similar observa-
tions have been made by other workers58 . It is
clear
that the matrix in a flexurally loaded composite will be
subjected to a large Mode II component and that the
forward shear properties of the matrix will be impor-
tant in determining the level of damage incurred. It is
somewhat less clear why the residual compressive
properties of the composite should be Mode II con-
trolled since the failure process is undoubtedly complex
containing a significant Mode I component. Master's
results are impressive nevertheless.
Materials that satisfy the above condition and therefore
3
I
E
o
2
E 1 J -~ Thermoset
-- / o + o Experimental
0 O0
'- O J 0 Toughened
~ thermoset
'~ + Thermoplastic
E
O 0 I 1 I L I L
o 0 1 2 3 4 5 6
Resin fracture energy (kJ m -2 )
Fig. 5 Variation of composite Mode I interlaminar fracture
energy with resin fracture energy (Ref 47)

500 ~-
0 t
a. 350 I E 450 7
,'- 300 .." 400 ~- AS4/907
AS4/1808-fi(m E
250 ~ 350
== C6000/1827-film A ]M6/1808-film A
00
_= 300 AS4/1808-filrn A
[M6/1808
250
E 2I
150 AS4/1808
C60O0/1827
AS4/1808-fitm C

A$4/3502-fi{m A
~ l I '~ 150
$ AS4/3502
~: 50 - 100
"o
o 50
0 , , I , , , I I ~ , I. ,. , , I , , , I , L ,
0.0 2.0 4.0 6.0 8.0 10.0 12.0 0 I 1 I I I

Neat resin flexural strain to failure (%) 0 100 200 300 400 500
Residual compression strength after impact (MPa)
Fig. 4 Variation of residual compressive strength of impact-
damaged composites with neat resin flexural failure strain Fig. 6 Variation of residual compression strength after impact
(Ref 57) with Mode I strain energy release rate (Ref 56)

COMPOSITES. SEPTEMBER 1991 353

 4000 tive to compressive loading since impact-generated
AS4/1808:film E delaminations tend to reduce the stability of the
E 3500 load-beating plies resulting in premature failure
IM6/1808-film A eAS4/1808-fiim A
AS4/3502.film A through buckling. In the previous section it was shown
~ 3ooo AS4/1808-film C that composites with high Mode II interlaminar
_~ 2500 IM6/3100-film E
C6000/18274ilm E fracture toughnesses offer superior CAI propertiess5,56.
It appears that the majority if not all of this improve-
IM6(3100-21-film E AS4/907
2000 ment in CAI behaviour results from the lower levels of
damage incurred during impact.
c 1500 A54/1808
....... AS4/1808
l M o / I ~ u ~ C6000/1827 The residual tensile properties of toughened compos-
AS4/3502
1000
I M 6 / 3 1 0 0 e I M 6 / 3 1 0 0 - 2 1
ites do not appear to be significantly better than those
of standard epoxy systems, Fig. 8. This results from the
fact that composites with tougher matrices tend to be
0 t I i I I more notch-sensitive due to reduced splitting and
0 100 200 300 400 500 delamination around stress concentrations such as
Resin compression strength after impact (MPa) notches or damage6s.
Fig. 7 Variation of residual compression strength after impact
w i t h M o d e II strain e n e r g y release rate (Ref 56)
Toughening composites using elastomeric particles
reduces the level of delamination and therefore
offer superior impact properties include thermoplastic- enhances residual compressive properties, Fig. 9.
based composites and interleaved laminates. In recent However, the presence of such inclusions often reduces
years considerable interest has been generated by the glass transition temperature of the matrix material
carbon fibre-reinforced PEEK (APC2), a semi- which in turn reduces the hot-wet properties of the
crystalline thermoplastic compositea'~'59-62. Interlami- composite. In many situations a compromise is there-
nar fracture testing and impact loading have shown that fore necessary.
this material offers excellent static and dynamic tough-
ness and is capable of absorbing a considerable amount
1400
of energy whilst incurring only small amounts of <.
damage4,63,64. Scanning electron micrographs of the O - -- -- Tough epoxy
1200' Brittle epoxy
fracture surfaces indicate extensive drawing and plastic
flow65. Another advantage of this material is that its 1000
thermoplastic matrix allows rapid repair using fusion
techniques such as the hot press technique66. Here, 80o
\

impact damage can be reduced or removed by simply

"0 ..... 0
heating the component to a temperature above the ~ 600
melting point of the matrix, reforming and cooling. The
high velocity impact response of carbon fibre/PEEK has g 4o0
received very little attention. Initial testing has sug- n-

gested that its high velocity impact response is perhaps 200

relatively poor. Dan-Jumbo et al. 59 showed that beyond
a certain velocity threshold, APC2 experienced a ,IL J ,I, f ~
0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
sudden drop in flexural strength. Similar observations
Impact energy (J)
have been observed by Morton and Godwin63 following
ballistic impact tests on this material. This will be Fig. 8 Variation of residual tensile strength with impact energy
discussed in more detail in the section on rate effects. for tough and brittle epoxy-based composites (Ref 75)
These observations suggest, therefore, that care should
be exercised when attempting to relate static properties
such as interlaminar toughness and strength to charac-
1000
terize tlynamic properties such as impact resistance.
~ 900, Toughened epoxy
Polymer interleafing involves the use of high toughness o Brittle epoxy
800,
films or layers at ply interfaces in relatively brittle - -
e-

materials. The inclusion of such layers increases the 700

laminate's interlaminar fracture toughness56 as well as 600
reducing the level of damage incurred for a given ~ s~
incident energy67. The load-bearing properties of
damaged intedeafed composites are significantly ~ 400
superior to those of conventional epoxy composites67.
Interlayer technology is still in its infancy; however, 72 200
early results are very favourable and the technique 8
100
offers enormous potential.
0
2a 4I 6f 8~ 110 112 14
1. Effect of matrix properties on post-impact Impact energy (J)
residual strength
Fig. 9 Residual compressive strength of toughened and brittle
Impact-damaged composites are probably most sensi- epoxy-based composites as a function of impact e n e r g y (Ref 75)

354 COMPOSITES. SEPTEMBER 1991

2. Conclusions
It is clear that matrix properties play a significant role
in determining the impact resistance and subsequent
load-beating capability of a fibre-reinforced plastic. At
present, a significant effort is being made to improve
the post-impact compressive properties of composites.
It appears that materials with high Mode II interlami-
nar fracture toughnesses offer superior compression
strengths after impact. Care should be exercised,
however, when correlating data obtained under static
loading conditions with results from dynamic tests.
Interphase
The strength of the bond between the matrix resin and
the fibre reinforcement is a controlling factor in deter-
mining the mechanical performance of most polymer
composites. In general, the surface of the fibres is
treated by an oxidative process in order to improve the
level of adhesion between matrix and fibre. Initially,
this interracial zone was considered as being a two-
dimensional surface with effectively zero thickness.
However, more recent studies have shown that this
region is in fact three-dimensional, having its own
distinct properties 69.
Studies have shown that varying the level of surface
treatment applied to a carbon fibre composite can
change the mode of failure as well as many fundamen-
tal mechanical properties H'69-7z. Composites with low
levels of fibre surface treatment fail at relatively low
stresses when loaded transversely to the fibres, leaving
smooth fibres on the fracture surface. Increasing the
level of treatment applied to the fibres increases the
transverse failure stress and failure occurs within the
matrix, i.e., the interphase region is no longer the
weakest link in the composite.
Rogers e t al. 71 showed that improving the fibre/matrix
bond strength in a carbon fibre-reinforced epoxy
resulted in a fourfold increase in the incident impact
energy required to initiate damage. At higher energies
the load-bearing properties of composites with surface-
treated fibres drops dramatically until the perforation
limit is reached72. Bless and Hartman 73 showed that the
perforation threshold energy in a surface-treated
composite is significantly lower than that of a similar
untreated laminate.
This behaviour has been explained by Dorey~'2, who
showed that the transverse fracture energy of a com-
posite, a fundamental parameter for determining
resistance to penetration and perforation, depends
strongly upon the fibre/matrix bond strength. Carbon
fibre-reinforced epoxies with untreated fibres offer
transverse fracture energies as high as 60 kJ m-2 (Ref
72). Transverse failure in composites with high levels of
fibre surface treatment absorbs considerably less
energy, with quoted ~2 transverse fracture energies
being as low as 20 kJ m-2. At energies levels above that
required to achieve perforation, damage in a surface-
treated composite tends to be localized around the
point of impact, often taking the form of a clean hole 71.
The post-perforation residual properties of treated
composites are generally superior to those of untreated
composites as shown in Fig. 10.
1000
~ Surface-treated fibres
(3.
800 0 Untreated fibres
" --- Penetration
600 ..- - O - -
-=E I/J
'\l /
/
0 2 4 6 8 10 12 14
Incident energy (J)
Fig. 10 Residual flexural strength vs. impact energy for ballisti-
cally impacted surface-treated and untreated carbon fibre
composites (Ref 72)
McGarry et al. TM attempted to enhance the impact
resistance of T300/MY-720 carbon fibre/epoxy by
coating the surfaces of the fibres with a thin layer of
CTBN rubber. Gardner impact tests showed that
treating the fibres in this way improved the threshold
energy for first damage significantly. Further, above
this threshold the level of damage for a given impact
energy was less in the modified composite.
1. Effect of interphase properties on post-impact
residual strength
Dorey 75 has shown that increasing the strength of the
fibre/matrix bond increases the interlaminar shear
strength (]LSS) of the composite until a plateau is
reached beyond which point no significant increase is
possible, Fig. 11. Over this range of treatment levels
the notched tensile strength falls dramatically. Increas-
ing the ILSS in this way suppresses the formation of
delaminated zones in the region of stress concentra-
tions, rendering the material more notch-sensitive.
Consequently, even though surface treatment of the
fibres reduces the level of damage for a given energy,
the increased notch-sensitivity of the laminate results in
poorer residual tensile properties, Fig. 1 2 7 5 . Con-
versely, treating the fibres improves the post-impact
compressive properties as shown in the lower part of
Fig. 12. Clearly, the level of surface treatment applied
to the fibres in a multidirectional composite will depend
upon the operational conditions the component will
encounter. In general, a compromise is sought in which
the fibres are given intermediate levels of treatment.
2. Conclusions
The level of treatment applied to the surface of the
fibres in a composite material has a significant effect
upon both its impact resistance as well as its residual
load-carrying capability. In general, impact on compos-
ites with low levels of fibre surface treatment generates
large areas of splitting and delamination with severe
effects on the compressive properties of the material.
Localized impact loading on highly treated fibre
composites results in a smaller, more localized damage
zone, a lower perforation threshold and improved
COMPOSITES. SEPTEMBER 1991 355
'[ Fibre stacking sequence
Composite materials offer a unique advantage in that
properties such as strength and stiffness can be tailored
to meet specific design requirements through a careful
selection of the fibre stacking sequence. Considerable
work has shown that the impact resistance of composite
materials also depends upon the specific order in which
the plies are stacked6'~'76-s. For example, unidirec-
T/T100 tional composites having all their fibres aligned in one
direction fail by splitting at very low energies and are
1.0 therefore highly unsuitable for applications where
impact loading might occur 11. Following impact tests
on a series of (0, +/-45 ) laminates, Dorey 1~as well as
Morton and Godwin 63 showed that composites having
+ / - 4 5 surface plies offered a superior impact resis-
tance and improved residual strengths. It was sug-
gestedsl that + / - 4 5 plies increased the flexibility of the
On/OnlO0
composite, thereby improving its ability to absorb
energy elastically. Further, placing such plies on the
surface of a composite serves to protect the load-
bearing 0 plies against damage induced by the imping,
ing projectilesl. These ideas were supported by Ste-
0.5 vanovic et al. s, who conducted instrumented Charpy
tests on a series of multidirectional T300 carbon fibre
composites. They showed that (+/-45 ) composites
were capable of absorbing considerably more energy
than (0,90), (0,+/--45 ) and (00,900,+/-45 ) lami-
nates.
A somewhat different approach was adopted by Nolet
and Sandusky in the design of a composite leading edge
for the A10 Thunderbolt 8z. They proposed that the
leading edge be very stiff in order to 'split off' the
0 I I I I
impinging bird with little or no loss in strength or
0 100 200 700
stiffness. They suggested that in order to achieve this
Surface treatment (%) requirement, a high percentage of carbon fibres should
be oriented in the spanwise direction of the aircraft's
Fig. 11 Variation of interlaminar shear strength and notched
strength of carbon fibre composites as a function of fibre leading edge.
surface treatment (Ref 75) The authors s3 showed that damage initiation in a series
1.0 of (+/-45 ) laminates subjected to low velocity impact
Treatment level
depended upon the thickness and therefore the stiffness
0% of the composite. Initial failure in thin, flexible targets
0~ o . . . . . 5%
occurs in the lowermost ply as a result of the tensile
A ~ _ Tension " - - - - 100%
n
tO
component of the flexural stress field. Damage in
t3
v
.c 0.6 thicker, stiffer targets initiates at the top surface due to
~,+\ \ ............ o 1.6
\~,\ ".. . . . . . . ... Lower [ Upper
-~ 0.4 '~,,. ~. '1,4 surf~rface
"0
X~O~ ~'II~
~+
..... ~ ~
"~_=t .- - . _--. .. .. .. . + 1,2
0.2
/ 1.0
Compression
0.0 I I I I O3 o.8
0 2 4 6 8 10
Impact energy (J) 0.6
E
Fig. 12 Residual strength of treated and untreated carbon fibre 0.4
composites vs. impact energy (Ref 75)
0,2
compressive properties. However, the increased notch
sensitivity associated with fibre surface treatment 0.0 ,,l..,n , , , l . . , l , , , J , , , l . , , l , , , f . , , l , , ,

results in a reduction in the post-impact tensile strength 0 1 2 3 4 5 6 7 8 9 10

of the material. The level of treatment applied to the Target thickness (mm)
surface of the fibres will depend, therefore, upon the Fig. 13 Low velocity impact energy to initiate damage vs.
desired application. target thickness for (+/-45 ) CFRP composites (Ref 29)

356 C O M P O S I T E S . S E P T E M B E R 1991
the contact stress field. This is shown in Fig. 13. This
curve clarifies Dorey's sl claim that increasing the
flexural stiffness of a target, for example, by placing
fibres on the surface of a laminate, can enhance its
impact resistance. This is true for the range of stiff-
nesses where initial failure occurs at the top surface of
the component. In more flexible targets, however,
reducing the flexural stiffness may precipitate failure at
a lower incident energy.
A detailed study by Hong and Liu 6 identified funda-
mental aspects in the development of damage in glass
fibre-reinforced plastic (GFRP) subjected to high
velocity impact loading. They showed that increasing
the angle q in a (~,q,0~) laminate resulted in greater
delamination-type damage for a given incident energy,
Fig. 14. Increasing q in this way also had the effect of
reducing the first damage threshold energy. The
authors als0 showed that for a given energy, increasing
the thickness of the GFRP target resulted in an increase
in delaminated area. This increase in damage area may
result from the reduction in the target's energy absorb-
ing capability as proposed by DoreySL Lius4 extended
this work by developing a simple model for predicting
the likely delamination sites in a number of different
composites. It was suggested that delamination in
multi-angle composites is more likely to occur at
interfaces where the mismatch in bending stiffness is
greatest, for example, between +/--45 plies. Liu
showed experimentally that the level of delamination in
a glass/epoxy composite increased as angle q in a (0,q)
laminate increased, i.e., as the bending stiffness
mismatch increased This evidence suggests that if
delamination needs to be suppressed, laminates with
sudden large changes in fibre direction should be
avoided.
Other techniques to reduce impact-induced delamina-
tion include the use of woven fabrics46"85,
hybridization 16'a6-88 (for example, carbon fibres with
Kevlar fibres) and three-dimensional stitchings9'9. The
first of these techniques involves replacing the unidirec-
tional +/-45 plies in a multidirectional composite by a
+/-45 woven fabric. The three-dimensional nature of
the fabric helps suppress the formation of delaminated
zones at this critical interface.
A
cq
4I
35
30
25
o
=
[3
[ 05/90s/05
[ 0s/605/05
[ 05/455]0s
[ 05/30s/05
[ 05/15~/0~
]
]
]
]
]
oo
++0~]
20
15
+(
r~ 10 O surface of the composite. This may not be an ideal
+ lid
C3
0 5 10 15 20 25 30
Impact energy (J)
Fig. 14 D e l a m i n a t e d area vs. i m p a c t energy for i m p a c t e d
(0s*,05",05") GFRP l a m i n a t e s (Ref 6)
The impact resistance of carbon fibre composites can
be enhanced considerably by incorporating plies of
lower modulus fibres 16,s6-s8. In order to assure compat-
ibility, the matrix resin is usually the same in the two or
more constituent materials. Hancox and Wellsa7
showed that the Izod impact energy of an HT-S carbon
fibre composite could be increased by 500% through
hybridization with E-glass fibres. As well as reducing
the basic price of the composite, the addition of the
glass fibres was found to change the mode of fracture
from a clean break to a delamination-type non-
catastrophic failure Similar conclusions were drawn by
Helfinstine 16following Charpy impact tests on Kevlar-
T300 carbon fibre hybrids. However, the absolute
magnitude of the increases was less impressive than
that reported by the previous workers for GFRP.
Dorey e t al. ~ assessed the high velocity impact
response of a number carbon-Kevlar hybrid laminates.
They showed that the addition of the lower modulus
Kevlar fibres increased the threshold energy for the
onset of damage by up to four times.
At present many workers are assessing the feasibility of
using weaving and braiding techniques in order to
improve the damage tolerance of fibre-reinforced
polymer composites s9-93. Su 93 conducted Mode I
delamination tests on both stitched and non-stitched
AS4 carbon fibre/J1 (a semi-crystalline thermoplastic).
His results showed that stitching with Kevlar fibre
resulted in a 100% increase in interlaminar fracture
toughness. Instrumented drop-weight impact tests on a
number of 2- and 3-D composites indicated that the
latter offered a superior impact resistance, the presence
of the third dimension reinforcement served to inhibit
the propagation of delaminated zones. Fabricating 3-D
structures is clearly more expensive and time consum-
ing than constructing with conventional 2-D prepregs.
In order to reduce these costs, it has been proposed
that a selective procedure be adopted, that is, 3-D
reinforcement be used at critical ply interfaces or at
component edges 93.
1. Effect of fibre stacking sequence on
post-impact residua/ strength
In this section the role that the fibre stacking sequence
plays in determining the residual properties of impact-
O
damaged composites is discussed As outlined above,
much of the work published in the literature concerns
the residual compressive properties of damaged
composites since this is considered to be the most
critical form of loading condition Certain conflicts may
exist, however, when considering the optimum fibre
stackin.8 sequence for residual compressive strength.
DoreyTM suggested that for improved impact resistance
the +/--45 fibres should be located on the outermost
stacking sequence for stability in compression Here,
stiffer laminates, for example, those with surface 0
fibres, are better suited to in-plane compressive
63
35 40 45 50 loading. Nevertheless, Morton and Godwin have
shown that an APC2 ( ~ , +/-45)2s laminate offers
inferior properties to those of a (+/-45,~,+/--45,0)s
plate, Fig. 15.
COMPOSITES, SEPTEMBER 1991 357
 1400 they split and fail at low energies. The mismatch in
i
bending stiffness between two plies appears to have a
45 outside
1200 I
significant effect upon the level of damage incurred at
/ ~ 0 outside
that interface. Damage appears to be greatest where
ply orientation changes of 90 occur. This suggests that
I000 r
for containment of damage laminates with abrupt
== changes in fibre direction should be avoided. Other
800 " ways to suppress damage include the use of woven
L fabrics, the use of hybrid composites or stitching at
i
6OO desired locations.
E
oo Jk
/k
4O0 A Geometry
r~ Geometry is a fundamental parameter in determining
200 i the impact response of a composite compo-
nenta,rt A5,63,75,83.Low velocity impact tests on CFRP
0 have shown that the mode of failure in a simple beam
0 5 10 15
may vary depending upon its span-to-depth ratio. Short
Incident impact energy (J) thick specimens tend to fail in an interlaminar mode
Fig. 15 Effect of placing 45 plies on the outer surface of a whereas as long thin beams failed in a flexure 11.
16-ply carbon fibre/PEEK laminate (Ref 63! Broutman and Rotem 15 showed that increasing the size
1000
of a GFRP beam increased its energy absorbing capabil-
ity under low velocity impact conditions. However,
(3 Non-woven
Mixed-woven doubling the size of the beam did not result in an
.~ 8o0 equivalent increase in energy absorption. Similar tests
Q-
o n CFRP 83 have shown that both the low velocity first
e- damage threshold energy and perforation limit of a
g, coo CFRP (0,-I-/---45 ) beam increased linearly with increas-
ing beam length. These results indicated that the
e--
A target's ability to absorb energy in elastic deformations
.o_ 400 W
determines its low velocity impact resistance. However,
e~
increasing the volume of the target does not necessarily
E
~
o
200
increase its impact resistance, for example, small beams
may be capable of absorbing greater energy than a
large circular plate s3. Further, the process of failure in
a large component often differs from that in a simple
0 1 2 3 4 5 6
laboratory specimen. Clearly, care needs to be taken
Impact energy (J}
when using small, simple specimens to characterize the
Fig. 16 Effect of replacing the + / - 4 5 plies in a 16-ply (0,+/- impact response of larger, more complex structures.
45) CFRP composite with a woven fabric (Ref 46)
High velocity impact tests on CFRP indicated that the
areal geometry of the target is less important at high
In the previous section it was stated that the use of rates of strain 93. Ultrasonic C-scans of impacted
woven +/--45" fabrics in (0", +/--45 ) laminates serves to specimens showed that the level of damage in a small,
reduce the overall level of delamination under impact 50 mm long beam was the same as that in a 150 mm
loading. The subsequent residual strengths of the coupon, Fig. 17. This suggests that high velocity impact
mixed-woven composites were superior to those of the loading by a light projectile induces a localized form of
standard material manufactured from unidirectional target response in which much of the incident energy of
plies, Fig. 16. the projectile is dissipated over a small zone immediate
to the point of impact. Tests on large plates have
Similar improvements in residual strength have been substantiated this claim 93 and it appears that under
noted following impact on stitched carbon fibre com- certain conditions small simple coupons can be used to
posites 92. Compression after impact tests on a number characterize the high velocity/low mass impact response
of AS4/3501--6 laminates92 showed that stitched lami- of composite structures.
nates offered residual strengths up to 100% greater
than their unstitched counterparts. One of the disad- Few workers have undertaken tests on full-size engi-
vantages of this process is that the undamaged com- neering components primarily as a result of the high
pressive strength of the material is reduced by up to costs involved. Gause et al. 94 showed that the curvature
20% 92. of the test component or structure influences the level
of damage incurred during impact loading. It appears
that negative curvatures inhibit delamination growth.
2. Conclusions Madan and Sutton 95 conducted low velocity impact
The impact resistance of a multidirectional laminate is tests on a number of stiffened panels designed for use
strongly dependent upon the specific orientation of the in advanced wing structures. Their results indicated
plies. Unidirectional laminates should be avoided since that the impact resistance of the structure was poor if

358 COMPOSITES. SEPTEMBER 1991

 Impact energy = 1.8 J Impact energy = 7.0 J
the material's behaviour as well as the structural
response of the target. The latter has already been
discussed in some detail above. In summary, it appears
that the low velocity impact resistance of a composite is
strongly dependent upon its ability to absorb energy
elastically. Consequently, the strain energy absorbing
Length = 50 mm Length = 50 mm capability of the fibres as well as the geometrical
configuration of the target are of great importance. At
very high rates of strain the structure responds in a
local mode and the strain energy absorbing of the fibres

n D Length = 75 mm Length = 75 mm
and structure is less important. Here, the magnitude of
the energy dissipated in mechanisms such as delamina-
tion, debonding and pull-out may become important.
In recent years more and more attention has been given
to determining the rate dependence of the ultimate
properties of composites and their
constituentsz~'24`26'28,~-gs. Harding and
co-workers25'27'2s'96 have examined the strain rate
sensitivity of Kevlar, GFRP and C'FRP. They have shown
that carbon fibre composites are rate-insensitive when
Length = 100 mm Length = 100 mm tested in fibre-dominated modes, whereas GFm' and
Kevlar composites exhibit a distinct rate-dependent

U U
behaviour with modulus and tensile strength increasing
with rate. Other workers have assessed the rate depen-
dence of matrix-dominated modes of failure such as
interlaminar fracture23'99. Such tests are particularly
useful since delamination (a matrix-dominated mode of
Length = 150 mm Length = 150 mm failure) is particularly detrimental to the compressive
Fig, 17 Effect of beam l e n g t h o n d a m a g e d e v e l o p m e n t in a strength of a laminated composite ~'11. DCB tests on
16-ply (0,+1-45 ) CFRP composite subjected t o h i g h v e l o c i t y carbon fibre/epoxy composites t2 have shown that the
i m p a c t l o a d i n g (Ref 29) Mode I interlaminar toughness does not vary with
strain rate, Fig. 18. Similar tests on carbon fibre/PEEK
(APC2), a thermoplastic matrix composite, have
the flanges were either too stiff or too flexible. This is
identified a distinct rate dependence :3, Fig. 18. Over a
clearly related to the structural stiffness effects shown
wide range of strain rates the Mode I fracture tough-
previously in Fig. 13. For optimum impact resistance a
ness remains invariant of strain rate. However, beyond
compromise is again required.
a certain threshold, the toughness drops dramatically to
approximately 20% of its original value. This gives
2. Conclusions cause for concern, suggesting that the impact resistance
of this material may be poor at high rates of strain.
In order to design components and structures for
Indeed, high velocity impact tests on APC2 have
impact resistance, geometrical effects need to be fully
suggested that beyond a certain threshold velocity a
understood. In the case of low velocity impact loading,
change in failure mode o c c u r s 63 and the material
the size of the specimen or component is a critical
parameter in determining its dynamic response. Here experiences a sudden drop in mechanical perfor-
mance59.
again the response of the target as well as the amount
of damage incurred is related to the target's ability to
store energy elastically. As a result of the lower level of 5O00
transverse constraint, beams tend to be capable of CF/PEEK D Unstable
absorbing more energy than larger structures such as 4000 Stable
circular plates. Care has to be taken, therefore, when
using simple beam-like specimens to evaluate the CF/epoxy
E"
dynamic response of more complex structures. I
E
3000 ,
ca
D= o
ta Q o
mo o o []
o o oo o o o oo oo
High velocity impact loading by a light projectile o o o o o o o o

induces a very localized form of target response,

resulting in much of the incident energy being dissi-
pated in a very small volume. Here, the areal geometry 1000
of the target is less important and simple coupons can
+,, %
often be used to characterize the response of the

full-scale structure.
10-6 10-s 10-4 10-3 10-2 10-1 10 o
(s -~ )
Rate
Fig. 18 Variation o f Gic w i t h s t r a i n rate f o r c a r b o n fibre/PEEK
The rate at which the structure is loaded affects both and a carbon fibre/epoxy composite (Refs 24 a n d 102)

COMPOSITES. SEPTEMBER 1991 359

These results suggest that care should be taken when
using data obtained from static tests in order to charac-
terize the dynamic response of composite materials.
Brittle thermosets such as epoxy resins do not appear
to exhibit a significant rate-dependent behaviour
whereas tougher systems such as the latest generation
of thermoplastic-based composites do 12. Clearly,
simple static tests would fail to identify such strain rate
sensitivity and may rank the materials incorrectly.
SUMMAR Y AND CONCLUSIONS
Concerns expressed regarding the impact resistance of
fibre-reinforced composites are without doubt well-
founded. Low energy impacts are capable of generating
large areas of delamination, resulting in significant
reductions in residual strength. In recent years a
concerted effort has been made by the materials
manufacturers to improve the impact resistance and
damage tolerance characteristics of continuous fibre
composites. In this review some of the fundamental
parameters governing the impact response and subse-
quent load-bearing properties of components manufac-
tured from these materials have been identified. The
following conclusions may be drawn from the present
review.
1) The strain energy absorbing capacity of the fibres is
one of the most important parameters in determin-
ing the impact resistance of a composite structure.
Fibres that have a large area under the stress/strain
curve tend to be better suited to energy absorbing
applications.
2) The Mode II (forward shear) properties of the
matrix appear to determine the level of damage
incurred during impact and therefore the residual
compressive properties of the composite. For good
compression strength after impact the Mode II
interlaminar fracture toughness should be high.
3) The strength of the fibre/matrix interphase region
can be adapted to the required application. For
example, if a projectile has to be stopped and
residual properties are not important, then the
interphase region should be weak to encourage
failure through gross splitting and delamination. If
damage containment is required, then the level of
treatment applied to the surface of the fibres should
be greater.
4) The fibre stacking sequence determines both the
elastic energy absorbing capability of the composite
as well as the failure mode. For damage contain-
ment, laminates with abrupt changes in fibre
orientation (for example, one with +/-45 inter-
faces) should be avoided.
5) Geometrical effects are significant under conditions
of low velocity impact loading. Varying the
geometry changes the target's ability to store energy
and therefore its impact resistance. Large targets
are not necessarily better energy absorbers than
small coupons. Care should be taken, therefore,
when interpreting data from tests on laboratory-size
specimens.
6) Varying the impact velocity and therefore the strain
rate affects both the material's properties as well as
360 COMPOSITES. SEPTEMBER 1991
the target response. Low velocity impact loading by
a heavy object induces an overall target response,
whereas high velocity impact by a light projectile
induces a localized mode of target deformation
resulting in energy being dissipated over a small
region immediate to the point of impact. In the
latest generation of tough composites matrix-
dominated modes of fracture appear to show a
distinct rate dependency and care should be taken
when using static tests to characterize dynamic
behaviour.
ACKNOWLEDGEMENTS
The authors would like to acknowledge the financial
support of the National Science Foundation Science
and Technology Center for High Performance
Polymers, Adhesives and their Composites at Virginia
Tech. This paper was originally submitted for 'Bonding
and Repair of Composites II', Zurich, Switzerland,
March 1991 (this conference was cancelled).
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AUTHORS
W . J . C a n t w e l l , w h o is with t h e L a b o r a t o i r e d e P o l y -
m e r e s , E c o l e P o l y t e c h n i c F t d t r a l e d e L a u s a n n e , 1007
L a u s a n n e , S w i t z e r l a n d , is c u r r e n t l y a visiting scientist
at V i r g i n i a P o l y t e c h n i c I n s t i t u t e a n d S t a t e U n i v e r s i t y .
J. M o r t o n is w i t h t h e D e p a r t m e n t o f E n g i n e e r i n g
Science and Mechanics, Virginia Polytechnic Institute
a n d S t a t e U n i v e r s i t y , B l a c k s b u r g , V A 24061--0219,
USA.