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Why Butanol?
the art
Economic evaluation
Conclusions
2 8-9-2009
BUTANOL (C4H9OH): Bulk chemical and fuel
Butanol is better biofuel than ethanol due to its more favorable chemical/physical
1-Butanol Ethanol
Properties
C4H9OH C2H5OH
LHV (MJth/kg) 33 27
Solubility (ml/100 ml H2O) 9 miscible
Vapor pressure (mmHg) 5 44
Flash point (oC) 37 15
Butanol can be shipped and distributed through existing pipelines and filling stations
3 8-9-2009
Acetone-butanol-ethanol (ABE) fermentation
Clostridia strains A:B:E 3:6:1 wt.
Sugars and starch
Biofuels USA
Canada
South Africa
China
Japan
URSS
Others
Pict. source: Jones, D. Clostridium X Workshop
4 8-9-2009
Challenges and research on butanol fermentation
high cost of raw material
low productivity
Thermophilic strains
Selective product formation
5 8-9-2009
Definition of process designed
6 8-9-2009
ABE fermentation parameters
Compound Formula wt %
Sugars CH2O -
Acetone C3H6O 9
Butanol C4H9OH 18
Ethanol C2H5OH 3
Acetic acid CH3COOH 1.5
Butyric acid C4H8O2 1.5
Hydrogen H2 1.6
Microbial cells CH1.8O0.5N0.2 12.7
Carbon dioxide CO2 49.7
7 8-9-2009
Product recovery
Product Removal (ISPR) required to optimize fermentation productivity
Gas recycle
8 8-9-2009
Main process sections
CHP 2 HEAT & Flue gases
POWER GENERATION
H2 Gas
Turbine
What straw H&P
Gas purge
Water
ABE
SIZE REDUCTION
ENZYMATIC FERMENTATION Acetone
+
HYDROLYSIS +
Sulph. acid + IN SITU PRODUCT PRODUCT
MILD ACID
SOLIDS-LIQUID REMOVAL (ISPR) UPGRADING Ethanol
PRETREATMENT
SEPARATION
CH4
Lime Water
CO2
Butanol
Enzymes RESIDUES TREATMENT
Nutrients
Water, N
Anaerobic Anaerobic
Digestion 1 Digestion 2
Water
CHP 1 HEAT & POWER
Air GENERATION
Digestate
Digestate Combustion Flue Gases
Ashes
Steam Turbine
H&P
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Overall mass & energy balance
Inputs Kton/year Value MW
Wheat straw (d.w., 9 wt% ash) 1416 835*
Heat demand 196
Electricity demand 61
Total input 1091
Outputs
Acetone 50
Butanol 100 181 *
Ethanol 17
Heat generation in CHPs 431
Electricity generation in CHPs 196
Total output 808
Net heat surplus 235
Net electricity surplus 136
*(LHV basis)
Process energy demand (steam and electricity) fully covered + large electricity export
Room for improvement via heat integration
Surplus heat could be used for sterilization or for cooling generation via Absorption Refrigeration Plant
Energy content in ABE + Electricity output
Energy efficiency = = 38%
Energy input (feedstock)
10 8-9-2009
Total production cost
* 0.07 /kWh
11 8-9-2009
Product sales revenues
PRODUCT
CHEMICALS PRODUCTION ANNUAL SALES
VALUE
PRODUCT
Selling Price
Kton/year M/year %
/Ton
Acetone 571 50 28 20
Ethanol 857 17 15 12
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Sensitivity analysis on Internal Rate of Return (IRR)
Total ABE sales as chemicals: 136 M/year
IRR=9,6%
40%
35%
30%
25%
20% Butanol
IRR
ratio in ABE
15%
mixture
10%
5%
0%
-60% -40% -20% 0% 20% 40% 60%
-5%
variation (%)
Product Capital Raw materials Electricity
ABEsales
sale price Capital
costcost Raw materials
cost price Electriciy
output output
FUELS CHEMICALS
PRODUCTS
LHV (MJth/kg) Fuel value /Ton* Market Price /Ton
Total ABE (3:6:1 wt) 31 440 814
*0.015 /MJth
13 8-9-2009
Life Cycle Analysis LCA
Inventory Interpretation
analysis
Impact
assessment
Life Cycle Assessment framework, with different steps of LCA and their interactions according to ISO standards
The goals of the screening LCA are to assess the environmental impacts of ABE production from
straw, in a cradle to gate analysis and to compare these impacts with those of ABE petrol-based
15 8-9-2009
Comparison ABE from wheat straw with gasoline and with
petrochemical ABE
1,E-13
8,E-14
6,E-14
Wheat Straw
Process
4,E-14
emissions
Normalization
2,E-14
Enzymes &
Nutrients
0,E+00
Abiotic depletion Acidification Eutrophication Global w arming Ozone layer Human toxicity Fresh w ater Marine aquatic Terrestrial Photochemical
(GWP100) depletion (ODP) aquatic ecotox. ecotoxicity ecotoxicity oxidation
-2,E-14
Electricity output
-4,E-14
-6,E-14
Normalization set: West Europe, 1995 Straw to ABE Gasoline ABE from petrol Functional unit: 1 MJ
16 8-9-2009
Overall conclusions and recommendations
Increase of butanol ratio to A:E produced improves energy efficiency and economics
17 8-9-2009
Thank for your attention
18 8-9-2009