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Milestones
2008 Commencement of urea factory construction
Establishment of PetroVietnam Ca Mau Fertilizer Company Limited, 100
2011 percent owned by PVN
2012 Launched operations and provided commercial products to the market
2013 Produced one million tonnes of products in July
2014 Equitized and transformed into PetroVietnam Ca Mau Fertilizer JSC
2015 Listed on HSX with ticker of DCM
Table 1: Milestones of PVCFC
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On January 30th, 2012, Ca Mau Fertilizer Plant launched the first commercial product line
granular urea. Ca Mau Fertilizer . Jade Seeds for Golden Crops is high quality granular
urea brand in Viet Nam (TCVN 2619) with many outstanding features such as slow
nitrogen resolution, enable the plants to absorb nutrients efficiently, make green trees and
save fertilizer, uniform granule size, easy to spread and mix because of no dust and so on.
Just over a year, Ca Mau fertilizer product has covered Mekong Delta region and
becomes the reliable choice of majority of farmers. The basic parameters of the product
such as nitrogen content, percentage of impurities and moisture are better than criteria
Vietnam standards.
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Granulating Technology of TEC produces many granular products with various
sizes corresponding to each use purposes such as closed pouring, aerial spraying
for forest, etc or to market requirements by changing the size of floor hole.
Based on applied factories and scientific researches, TEC has promoted the
improvement of design of dust filter equipment to collect dust better and reduce
installation cost. There is almost no nitrogen dust in exhaust air.
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Figure 2.2 : Detailed drawings of PVCF
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1.3 OVERVIEW OF UTILITY PLANT
All the sections surround the factory, control and help the Ammonia section and Ure
section run fluently and also provide water, gas, as feedstock for them.
Provide retreated gas for all the section in factory, remove the sulfur compounds which
are the Catalyst damage agent in Ammonia section.
The instrument & service air system shall be designed to supply all the units of the
Fertilizer Plant with the required instrument and plant air (service air).
The system is designed according to the following estimated consumption
Normal In design
Nm 3/h Nm3/h
Instrument air 2240 2800
Plant air 1722 3263
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A back-up line of compressed air drain from the Process Air Compressor (K04421) in
Ammonia Unit is connected to the system downstream the Compressed Air Receiver in
order to provide compressed air in case of electric power failure.
Air compressors starts and stops automatically and sequentially, operated by dedicated
pressure switches. A manual selector will allow the operator to choose the stand-by and
the operating units. Should the pressure in the instrument air network drop, due to a
compressor failure or higher instrument demand, a pressure controller will reduce or stop
the service air header, giving the priority to the instrument air demand with respect to the
service air demand. In case of system very low pressure, a pressure controller will be
switch to open the pressure control valve on the back up line from Ammonia Unit.
Demineralized water
Cooling water
The Circulation Cooling water system including Cooling tower system (20100) and Fresh
cooling water system (21200).
Cooling tower system is to treat river cooling water and provide the river cooling water
for Fertilizer Plant.
Make-up water for the river cooling water system is from the offsite water intake, after.
Fresh cooling water system is to treat fresh cooling water for removing heat, and to
provide the fresh cooling water for the Fertilizer Plant. Make-up water for the fresh
cooling water system is demineralized water.
Flare
Vietnam CA MAU fertilizer project requires an ammonia flare system to satisfy the
minor leakage permission of safety valve and pressure relief valve during normal running
and the requirements of flare gas discharging under abnormal operation in order to ensure
HSE production of the system.
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The steam generation system is integrated with the Fertilizer Plant process units, where
several steam producers / consumers are placed.
Main machinery equipment is provided with Steam turbine drivers, the number and type
of steam turbine have been selected considering the following guidelines:
Ensure safe operation and shutdown (when necessary) of the Ammonia plant in
the case of electric power failure
This section play a role is Treatment of contaminated water sources, retrieve Ammonia in
water before discharge to the environment. Concentration of toxins in discharge water
have to comply the requirements of the authorities.
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CHAPTER II: WATER AND ELEMENTS OF WATER AFFECT TO WATERS
QUALITTY IN FACTORY
Water is a transparent and nearly colorless chemical substance that is the main
constituent of Earth's streams, lakes, and oceans, and the fluids of most living organisms.
Its chemical formula is H2O, meaning that its molecule contains one oxygen and two
hydrogen atoms, that are connected by covalent bonds. Water strictly refers to the liquid
state of that substance, that prevails at standard ambient temperature and pressure; but it
often refers also to its solid state (ice) or its gaseous state (steam or water vapor). It also
occurs in nature as snow, glaciers, ice packs and icebergs, clouds, fog, dew, aquifers, and
atmospheric humidity.
Molecular formula of water is H2O and water molecule is not linear and the
oxygen atom has a higher electronegativity than hydrogen atoms, it is a polar molecule,
with an electrical dipole moment: the oxygen atom carries a slight negative charge,
whereas the hydrogen atoms are slightly positive. So thats the reason why water have
these characteristic:
- Because of its polarity, a molecule of water in the liquid or solid state can form
up to four hydrogen bonds with neighboring molecules. These bonds are the cause
of water's high surface tension and capillary forces. The capillary action refers to
the tendency of water to move up a narrow tube against the force of gravity.
- High heat capacity, high heat absorption capacity of steam, high melting
temperature, high boiling temperature, good solubility of mineral salts.
Pure water has a low electrical conductivity, which increases with the dissolution
of a small amount of ionic material such as common salt.
Suspended Solids:
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- Inorganic substances: clay, mud, silt, sand ... due to airborne contamination
Water have high total suspended solids also have high turbidity.
Usually are O2, CO2, CO, NO, NOx, SO2, H2Sdue to the process of exposure to
air (rain, flow) and Development of microorganisms and plants in water.
Figure 2.1: Graph that displays oxygen solubility in water at various temperatures.
Water-soluble substances:
-Anion: OH-, NO3-, NO2-, Cl-, SO4 2-, SO3 2-, CO3 2-, HCO3-, S2-, PO4 3-,
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These substances mix with water and creating homogeneous and transparent solutions.
Polar compounds, mineral salts and solids dissolved in water by solvatization process
Solubility of solids almost depend on temperature of environment but some of them are
not (salts of Mg, Ca, and sulfate.
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Figure 2.4: Solubility of salts in 100g of water. Figure 2.5: Solubility of CaSO4 in pure water.
Acidity and basicity of solution depend on what ion are contained in solution. It
combines with water and release ion H+ or OH-.
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If pH is less than 7 so solution is Basic solution, bring risk of fouling, scaling and
corrosion.
So that research and consider maintaining the pH in an allowable range is very important
in water treatment in industry.
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2.2 Triangle deposit creation
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Figure (4) Cost relations between the individual types of fouling.
Water source of PVCFC plant is fresh-water come from two fresh-water company are U
Minh and Khanh An. Based on operating conditions of PVCFC, we focus on Inorganic
scaling-fouling causative agents because corrosive substances and microbiological have
already removed.
Because of corrosive process, Chlorine are not allowed to add in fresh-water before to be
used in PVCFC plant, this was agreed in contract between fresh-water supplier and
factory.
Normal scale-foul:
- Calcium Carbonate CaCO3
- Calcium Sulfate CaSO4
- Calcium Phosphate Ca2(PO4)3
- Magnesium Silicate MgSiO3
- Silica SiO2
- Iron Oxide Fe2O3
- Manganese dioxide MnO2
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Ca2(PO4)3
Figure (5) and (6): Calcium Carbonate and Calcium Phosphate scale in pipe.
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CHAPTER III: WATER DEMINERALIZATION PROCESS
3.1 General information:
The Demineralized Water System comprises of all the facilities to treat and handle
raw water and condensate from Fertilizer Plant, and produce Demi-water for Fertilizer
Plant.
3.2 Using of demineralized water in PVCFC plant:
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