PVT Keyword

DESKTOP-PVTKeyword
Reference Manual
2001, 2002 Landmark Graphics Corporation
Part No. 159678 R2003.4

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Table of Contents
About This Manual

Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Audience . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Organization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
Related Documentation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . viii
Chapter 1
Introduction
1.1 Overview of the Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.2 Free Field Input . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-2
1.3 FORTRAN File Assignments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3
Chapter 2
Equation-of-State Properties
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5
2.2 Equation of State (EOS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-6
2.3 Component Names (Components) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8
2.4 Component Characteristics (PROPERTIES) . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-9
2.5 Binary Interaction Coefficients (DJK and DJKCOR) . . . . . . . . . . . . . . . . . . . 2-12
2.6 Lohrenz-Bray-Clark Viscosity Correlation . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-14
2.7 Pedersen et al. Viscosity Correlation (VISPE, VISK and VISKJ) . . . . . . . . . 2-15
2.8 Component K-Value Correlation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-17
2.9 Correlation of CO2 Saturated Water Properties . . . . . . . . . . . . . . . . . . . . . . 2-18
2.10 Ideal Gas State Enthalpy Coefficients (HIDEAL) . . . . . . . . . . . . . . . . . . . . 2-22
2.11 End of EOS Data (ENDEOS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-23
2.12 Output File for PVT Properties (PVTFILE) . . . . . . . . . . . . . . . . . . . . . . . . . 2-24
2.13 Output File for K-values (KVFILE) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-25
2.14 Selection of Water in Oil Option (WINOIL) . . . . . . . . . . . . . . . . . . . . . . . . . 2-25
R2003.4 - Landmark iii

DESKTOP-PVT KEYWORD REFERENCE MANUAL
2.15 Thermal Option (THERMAL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-26
Chapter 3
Simulating Laboratory Measurements
3.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-33
3.2 Gas Z-Factor (Z-FACTOR) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-33
3.3 Liquid Density (LIQDEN) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-36
3.4 Vapor Pressure (VP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-38
3.5 Saturation Pressure (PSAT) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-40
3.6 Liquid and Vapor Viscosity (VISC) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-42
3.7 Constant Composition Expansion (CCEXP) . . . . . . . . . . . . . . . . . . . . . . . . . 3-43
3.8 Constant Volume Depletion (CVDEP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-48
3.9 Swelling Test (SWELL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-54
3.10 Differential Expansion (DIFF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-55
3.11 Multiple Contact Vaporization Test (MCVAP) . . . . . . . . . . . . . . . . . . . . . . 3-59
3.12 Phase Envelope Calculation (ENVELOPE) . . . . . . . . . . . . . . . . . . . . . . . . . 3-62
3.13 Enthalpy Calculation (ENTHV or ENTHL) . . . . . . . . . . . . . . . . . . . . . . . . . 3-64
3.14 Liquid Water Properties (WATPRP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-66
3.15 Saturation Pressure with Water (PSATW) . . . . . . . . . . . . . . . . . . . . . . . . . . 3-67
3.16 Distillation Test (DISTIL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-69
3.17 Complete Phase Envelope Calculation (ENVPT) . . . . . . . . . . . . . . . . . . . . 3-77
3.18 Composition Variations with Depth (ZGRAD) . . . . . . . . . . . . . . . . . . . . . . 3-79
3.19 Properties of Carbon Dioxide Saturated Water (CO2TAB) . . . . . . . . . . . . 3-84
3.20 Multiple Contact Steam Vaporization Test (MCSVAP) . . . . . . . . . . . . . . . 3-86
3.21 Two Phase Isothermal Flash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-91
Chapter 4
Simulating Multistage Separators
4.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-95
4.2 Separator Conditions Data (SEPARATOR) . . . . . . . . . . . . . . . . . . . . . . . . . . 4-95
4.3 Separator Test with Regression (SEP) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-97
Chapter 5
Automatic Parameter Adjustment
5.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-103
iv Landmark - R2003.4
5.2 EOS Property Adjustment (REGRESS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105

5.3 Regression Variable Data (VARIABLE) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105
5.4 Nonlinear Regression Process (IMAX) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-106
5.5 Assignment of Regression Variables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-107
5.6 End of Regression Data (ENDREG) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-111
Chapter 6
Pseudoization
Chapter 7
Heavy Fraction Characterization
Chapter 8
Calculation Controls
8.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-125
8.2 Selection of Flash Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-125
8.3 Saturation Pressure Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-126
8.4 Flash Calculation Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-128
8.5 Expansion Tolerance Card . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-129
8.6 Saturation Pressure and Flash Calculations Output
(DBUGS and DEBUGF) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8-130
8.7 Selection of Viscosity Calculation Method . . . . . . . . . . . . . . . . . . . . . . . . . . 8-131
Chapter 9
Composition Specification
Appendix A
Unconstrained Minimization of
Least-Squares Functions
A.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-137
A.2 Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-139
A.3 Advantages of the Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . A-140
A.4 Defects in the Gauss-Newton Method . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-141
A.5 Method of Rotational Discrimination . . . . . . . . . . . . . . . . . . . . . . . . . . . . A-142
A.6 The Rotational Discrimination Algorithm . . . . . . . . . . . . . . . . . . . . . . . . A-144
R2003.4 - Landmark v
Appendix B
The Establishment of Bounds on Variables
B.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-149
B.2 Our Treatment of Bounded Variables . . . . . . . . . . . . . . . . . . . . . . . . . . . . . B-149
Appendix C
One-Dimensional Search Procedure
C.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-151
C.2 Assumptions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-151
C.3 Operating Characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-152
C.4 Description of the Search Procedure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . C-152
Appendix D
Example Problems
D.1 Example 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-155
D.1.1 Lab Report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-156
D.1.2 Sample Files . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-174
D.2 Example 2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-222
D.2.1 Lab Report . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-222
D.2.2 Sample File . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . D-236
Appendix E
References
Keyword Index
Subject Index
vi Landmark - R2003.4
Preface
About This Manual
Purpose
This manual describes the functions of DESKTOP-PVT, a program
designed to simulate the behavior of hydrocarbon fluid mixtures.
DESKTOP-PVTs purpose is to generate PVT properties or develop a
mathematical model which can be used in a compositional reservoir
simulator such as VIP-COMP to analyze oil and gas production
characteristics.
Audience
This manual is intended to assist new and experienced users of
DESKTOP-PVT in the generation of PVT properties where laboratory data
is limited, or the development of a mathematical model that agrees with
experimental data.
Organization
The information in this manual is arranged in a logical manner for
maximum ease-of-use. The following chapters are included:
Introduction.
Equation-of-State Properties.
Simulating Laboratory Measurement.
Simulating Multistage Separators.
Automatic Parameter Adjustment.
Pseudoization.
Heavy Fraction Characterization.
Calculation Controls.
Composition Specification.
R2003.4 - Landmark vii

About This Manual DESKTOP-PVT KEYWORD REFERENCE MANUAL
Related Documentation
The following manuals provide more information related to the material
in this manual. For more information, please consult the appropriate
manual listed below.
DESKTOP-PVT Users Manual. Characterizing equations of state for

compositional simulation.
viii Landmark - R2003.4

Chapter
1
Introduction
DESKTOP-PVT is used to simulate the behavior of fluid mixtures when

they are subjected to any of a variety of laboratory procedures. The fluids
may be either liquid or vapor and may undergo phase changes during the
simulated experiments.
The program can be used in a purely predictive mode to generate PVT

properties where laboratory data is limited, or it can be used to develop a
mathematical model that agrees with experimental data. In the latter case,
the mathematical model of the fluid system can then be used in a
compositional simulator such as VIP-COMP to analyze oil and gas
production characteristics. In addition, the tabular data necessary to
define fluid behavior in VIP-ENCORE may also be generated by
DESKTOP-PVT.
To aid in development of a fluid model that matches experimental data, a

nonlinear regression package is provided as an integral part of DESKTOP-
PVT. This facilitates the adjustment of unknown or uncertain parameters
that affect fluid behavior.
1.1 Overview of the Data

The data for DESKTOP-PVT is divided into six major parts:
1. Equation-of-state properties
2. Laboratory procedures
3. Surface separation
4. Automatic parameter adjustment
5. Pseudoization
6. Heavy fraction characterization
R2003.4 - Landmark 1-1

Introduction DESKTOP-PVT Keyword Reference Manual
1.2 Free Field Input

All data is read in "free field" format. Simply stated, this means that it is
not necessary to type numbers in specific columns. DESKTOP-PVT reads
each item of data or "word" by finding the leftmost character and then
decoding each successive character until a blank column or a comma
signifies the end of the word.
The data stream contains both numbers and alpha code words, the latter
used to identify subsequent numbers or to select program options. It is a
general rule that each new type of data is introduced by an alpha code
word.
In the data descriptions that follow, code words are identified by being
typed in upper case letters. They must appear in the data stream exactly as
typed in this manual. The names of variables whose values must be
supplied are typed in lower case letters. Appropriate numbers or names
must be entered in their proper place.
1-2 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Introduction
1.3 FORTRAN File Assignments

DESKTOP-PVT makes use of several different FORTRAN units for scratch
files for input and output. Figure 1-1 illustrates schematically the
DESKTOP-PVT I/O structure.
Figure 1-1: DESKTOP-PVT I/O Structure

Introduction DESKTOP-PVT Keyword Reference Manual

Chapter
2
Equation-of-State Properties
2.1 Introduction
The PVT properties of both vapors and liquids are predicted by
DESKTOP-PVT by means of a cubic equation of state. Available equations
of state include Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK),
Zudkevitch-Joffe-Redlich-Kwong (ZJRK), Peng-Robinson (PR), and the
three-parameter versions of PR, SRK, and RK.
In order to completely define fluid properties it is necessary only to define

fluid composition and various properties of individual components. The
individual components may be pure components, but frequently they are
themselves mixtures. For example, isobutane (i-C4) and normal butane (n-
C4) may be treated together simply as C4.
Heavy fractions are normally grouped together over a reasonably wide

range of molecular weights. For example, C16 - C20 may be grouped
together as a single component that is designated as C18.
The properties of a large number of components have been internally

coded, so they are automatically assigned unless the user elects to
override the default. For light components the internal values usually
represent pure component properties, but for heavier fractions the internal
values have been adjusted to produce improved results for naturally
occurring oils and gases at reservoir conditions.
Table 2-1 and Table 2-2 summarize the internally coded properties for all
components that can be automatically determined. Using one of the
component identification codes contained in these tables as data in the
COMPONENTS input data will cause the tabulated values to be loaded.
Unless these values are overridden by the user in the PROPERTIES data
section, they will be used by default.

Equation-of-State Properties DESKTOP-PVT KEYWORD REFERENCE MANUAL
2.2 Equation of State (EOS)

The equation of state to be used for PVT properties is specified on the EOS
data card.
RK
PR
PRORIG
SRK
EOS ZJRK
RK3P
PR3P
PROR3P
SRK3P
Definitions:
RK Redlich-Kwong equation-of-state.
PR Peng-Robinson equation-of-state.
PRORIG Original Peng-Robinson equation-of-state.
SRK Soave Redlich-Kwong equation-of-state.
ZJRK Zudkevitch-Joffe-Redlich-Kwong equation-of-
state.
RK3P, PR3P, Three-parameter version of RK, PR, PRORIG and
PROR3P, SRK3 SRK respectively
Example:
To specify the Peng-Robinson equation-of-state, the following data card is

required:
EOS PR
NOTE: 1. The original Peng-Robinson equation of state uses the same

equation to calculate the temperature dependent term of "a" for
all ranges of acentric factor. The default version of the Peng-
Robinson equation of state used in DESKTOP-PVT employs a
different equation to calculate the temperature dependent term of
"a" when the acentric factor is greater than 0.49.

DESKTOP-PVT KEYWORD REFERENCE MANUAL Equation-of-State Properties
2. For compatibility with VIP-CORE, the user does not have to use a
different keyword to specify the three parameter version of an
equation of state. The program recognizes that the volume shift
parameter should be used if the keyword VSHFT is included on
the second line of the PROPERTIES data card. For example, the
three parameter version of the Seave-Redlich Kwong EOS can be
spedifed by
EOS SRK
if VSHFT is also included on the PROPERTIES card.

2.3 Component Names (Components)

The alphameric labels that will be used to identify the components are
defined here. If any of the component names contained in Table 2-1 or
Table 2-2 is used, the properties data will be picked from the table, subject
to user override. If unrecognized labels are used, the user must directly
specify at least molecular weight data.
COMPONENTS
cmp1 cmp2. . . cmpn
(NCV ncv)
Definitions:
cmpn Component name. An alphameric label contain-

ing up to 6 characters. Using a name contained in
either Table 2-1 or Table 2-2 will cause the tabu-
lated properties to be automatically loaded.
ncv Number of volatile components. Use only in
experiments associated with VIP-THERM (STM-
DIS, PSATW).
Define the components in a fluid system that contains carbon dioxide,

nitrogen, methane through hexane, and heptanes plus. Either of the
following is acceptable:
(1) COMPONENTS
CO2 N2 C1 C2 C3 IC4 NC4 IC5 NC5 NC6 C7+
(2) COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C7+
In both components definitions, all components except C7+ will have

default properties. The user must enter properties data for C7+.

2.4 Component Characteristics (PROPERTIES)

Properties data are entered to define the PVT characteristics of individual
components. These are combined by appropriate mixing rules and used
with the equation of state to determine the properties of mixtures.
Default properties for internally defined components are given in Table 2-

1 and Table 2-2. Omitting the properties data card for these components
results in the use of the default properties.
For non-internally defined components, a minimum of molecular weight

data must be entered on the properties data card. Default properties for
these components are determined by table lookup on the internally
defined hydrocarbon component properties based on molecular weight.
All properties for internally-defined components and all except molecular

weight for non-internally defined components may be defaulted by
entering the alpha label X on the properties data card where the default
value is desired. The properties table may be truncated at any point after
molecular weight. All unread data is defaulted. The number of entries on
the table title and properties data must be the same.
F PSIA
C PSIG
PROPERTIES
K KPA
R KGCM2

PCHOR VSHFT NBP GRVL TREF
COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB
cmpi mwi tci pci zci wi o

al
o
bl
pchor
i
s
i
nbp
i
grvl
i
tref
i

. . . . . . . .

. . . . . . . .

. . . . . . . .
VSHFTD VSHFTE

d e
Definitions:
F, C, K, R Alpha label indicating that the units of all temperature

values are:
F Degrees Fahrenheit, F. This is the

default.
C Degrees Centigrade, C.
K Degrees Kelvin, K.

R Degrees Rankin, R.
(input optional)
PSIA, KPA, PSIG, Alpha label indicating that the units of the critical
KGCM2 pressure values (PC) are:
PSIA Psia. This the default.
KPA KPa.
PSIG Psig.
KGCM2 Kg/cm2.
(input optional)
cmpi Component name for component i. Must be identical

to one of the names included in the COMPONENTS
data.
mwi The molecular weight of component i.

tci Critical temperature of component i.
pci Critical pressure of component i.
zci Critical z-factor of component i. (This property
affects only viscosity calculations.)
wi Acentric factor of component i.
o o
ai ai for component i. This is treated as a universal
constant in the original formulations of the equations
of state (0.4274802 for RK, SRK, and ZJRK; 0.457235529
for PR). Additional flexibility in fitting data is gained
by allowing it to vary by component.
o o
bi bi for component i. This is treated as a universal
constant in the original formulation of the equations of
state (0.08664035 for RK, SRK and ZJRK; 0.077796074
for PR). Additional flexibility in fitting data is gained
by allowing it to vary by component.
14 3 12
pchori Parachor for component i, g -cm ( s mole ) .
(This property affects only interfacial tension calcula-
tions.)
si Dimensionless volume shift parameter. (This property

is used only if molar volume is corrected using the
three-parameter EOS option.)
nbpi Normal boiling point temperature for component i.

(This property is used in ZJRK only.)
grvli Specific gravity of component i at temperature trefi

relative to water at 60F. (This is used in ZJRK only.)
2-10 Landmark - R2003.4

trefi Reference temperature for component i specific grav-

ity. Default is 60F. (This is used in ZJRK only.)
d, e Parameters d and e for computing volume shift

parameter s,
s = 1 - d M-e
where M is the molecular weight of a component.
The default value for d is 1.74 and is 0.133 for e.
NOTE: l. If either of the temperature or pressure unit flags is specified,

then both must be specified.
2. Repeat the data card containing cmpi, mwi, etc. as necessary to

specify all properties correctly.
3. Only 80 columns are allowed for each card. By entering the alpha
label > at the end of a card, the data at the next card will be
treated as a continuation of this card.
4. For the non-internally defined components, the volume shift

parameters are calculated using d and e only if they are input,
otherwise, they are determined by table lookup on the internally
defined hydrocarbon component properties based on molecular
weight.
Example:
PROPERTIES
C7+ 206. 895.1 302.6 .3121 .8643 X X
C1 X X X X X .48521 .08261
R2003.4 - Landmark 2-11

2.5 Binary Interaction Coefficients (DJK and DJKCOR)

DJK and DJKCOR data are used to define binary interaction coefficients
(djk). The binary interaction coefficients are used in the mixing rules that
determine for mixtures the A parameter of the EOS. The binary interaction
coefficients are read in if the DJK card is specified, and are computed from
a correlation [4] if the DJKCOR card is specified.
Table 2-3 summarizes non-zero values of djk that have been internally
coded for various combinations of components. These values will be
automatically loaded as data when the corresponding component names
are entered in the COMPONENTS data. In addition, default values for the
interaction coefficients between methane and heavy fractions from C6
through C45 are given in Table 2-2. Interaction parameters between any of
the heavy fractions in Table 2-2 and CO2, N2, C2, and C3 are the same as
given for NC18 in Table 2-3. All binary combinations that involve an
unrecognized component name will be assigned default values of zero.
Any of the default values for binary interaction coefficients can be

overridden by means of the DJK or DJKCOR data.
DJK cmpj
cmpk djk
Definitions:
cmpj Component name of one component in a binary

mixture.
cmpk Component name of the second component in a
binary mixture.
djk The binary interaction coefficient for mixtures of
component j and component k.
NOTE: 1. Enter one data card for each component k that interacts with
component j.
2. Enter an entire set of data including the DJK card and cmpk cards
for each component j that requires djk specifications.
3. Remember that djk = dkj. It is not necessary to define both.
4. In some experiments associated with VIP-THERM, water appears

implicitly as a component. Binary interaction coefficients for
water may be input by replacing cmpj or cmpk with the alpha
label H2O.
2-12 Landmark - R2003.4

DJKCOR djkcor
Definition:
djkcor The exponent of the binary interaction coefficients as

[4]:
1 6 1 6 djkcor
2V c V c
j k
d jk = 1 ------------------------------
13 13
Vc + Vc
j k
where V c and V c are the critical volumes for com-

j k
ponent j and k, respectively. Default is 1.
Example:
Specify the interaction parameters between heavy component C7+ and

CO2, N2, C2, and C3:
DJK C7+
CO2 .15
N2 .12
C2 .01
C3 .01
Example:
DJKCOR 1.2
R2003.4 - Landmark 2-13

2.6 Lohrenz-Bray-Clark Viscosity Correlation

00 The Lohrenz-Bray-Clark viscosity calculation is as follows:
2 3 4 4 4
00 = b + ( [ C 1 + C 2 r + C 3 r + C 4 r + C 5 r ] 10 )
00 where is the phase viscosity, b is a base viscosity, is a function of

pseudo critical pressures, pseudo critical temperatures, and mixture
molecular weight, and r is a pseudo reduced phase density.
00 By default, the coefficients C1, C2, C3, C4, and C5 are equal to 0.1023,
0.023364, 0.058533,-0.040758, and 0.0093324, respectively. Use of the LBC
keyword allows the user to modify these default coefficients to obtain a
better match with experimental viscosities.
00 The LBC keyword is not required if the user wishes to retain the default
coefficients.
00 The LBC keyword can appear anywhere after the PROPERTIES keyword
and data and before the end of the ENDEOS keyword. The modified
coefficients will only apply for the current EOS table being defined.
LBC
C1 C2 C3 C4 C5
2-14 Landmark - R2003.4

2.7 Pedersen et al. Viscosity Correlation (VISPE, VISK and

VISKJ)
The Pedersen et al. viscosity correlation is based on the corresponding
states principle [10,11]. A group of substances obeys the corresponding
states principle if these substances have the same reduced viscosity at the
same reduced density and reduced temperature. In such case, only
comprehensive viscosity data for one component (the reference
component) in the group are needed. Others can be calculated from the
reduced viscosity. The Pedersen et al. viscosity correlation uses methane as
a reference substance.
This correlation is useful for heavy oils where the Lohrenz-Bray-Clark

correlation [2] fails to give a proper viscosity prediction for some cases. To
invoke the Pedersen et al. viscosity option, a keyword "VISPE" should be
entered before the laboratory test data (see Section 8.7). The user has the
option of specifying k1 to k7 (VISK card) for calculating the viscosity of the
reference component and binary interacting coefficients Xkj (VISKJ card)
for calculating the mixture pseudo-critical temperature used in the
viscosity correlation. VISK and VISKJ cards are optional. Default values
will be used if they are not entered. The default values are zero for all the
interacting coefficients Xkj and the following values for the coefficients kj.
k1 = 9.74602
k2 = 18.0834
k3 = 4126.66
k4 = 44.6055
k5 = 0.976544
k6 = 81.8134
k7 = 15649.9
Only those data overwriting the default values need to be entered.
VISK
j kj
. .
. .
. .
VISKJ
k j xk,j or cmpk cmpj xk,j
. . . . . .
. . . . . .
. . . . . .
ENDVIS
Definitions:
VISK The keyword for inputting kj values. Optional.
R2003.4 - Landmark 2-15

j Index for kj.

kj The kj values for calculating the viscosity of the
reference component.
VISKJ The keyword for inputting binary interaction
coefficients xkj. Optional.
k Component number k.
j Component number j.
cmpk Component name of component k
cmpj Component name of component j
xkj Binary interaction coefficient for components k
and j for calculating critical temperature used in
the viscosity correlation. Default is 0.0
ENDVIS The keyword marks the end of Pedersen et al.
viscosity data input.
Example:
VISK
1 42.5
2 0.0002279
3 11770.0
4 600.3
5 16.49
6 0.0552
VISKJ
3 5 -0.36409
3 6 -0.38517
3 7 -0.8
3 8 -0.62763
ENDVIS
2-16 Landmark - R2003.4

2.8 Component K-Value Correlation

In DESKTOP-PVT the component K-values are usually computed using
an equation of state. For distillation test, a correlation is available to
computed compute K-values of distillates. The component K-value is
expressed as
B Di
Ki = A i + -----i + C i P exp --------------- (2-1)
P T E i
where Ai to Ei are constant coefficients for component i, P is pressure in

psia and T is temperature in Rankin.
KVCOR
COMP A B C D E
k ak bk ck dk ek
. . . . . .
. . . . . .
Definitions:
KVCOR Alpha label indicating the coefficients of component

K-values correlation are to follow. (Input Optional)
k Component number k.
ak to ek Coefficients A to E of component K-value

correlation. (Input Optional)
Example:
KVCOR
COMP A B C D E
1 -1.0 0.1531431E+06 0.3614000E-02 0.7275900E+04 0.0
2 -1.0 0.9296972E+06 0.4227000E-02 0.1214770E+05 0.0
3 -1.0 0.3488022E+08 0.5141000E-02 0.2085317E+05 0.0
4 -1.0 0.2121159E+12 0.1246900E-01 0.4656781E+05 0.0
R2003.4 - Landmark 2-17

2.9 Correlation of CO2 Saturated Water Properties

Correlations were developed to calculate properties of carbon dioxide
saturated water as functions of temperature, pressure and salinity. These
properties include carbon dioxide solubility, formation volume factor,
compressibility and viscosity.
The solubility of carbon dioxide in pure water is calculated as a function of

temperature and pressure.
c P o
R sw = a P 1 b sin --- -------------------- if P < P
2 c P + 1
and
o o o
R sw = R sw + m ( P P ) if P P
where
ai ( 10 3 T )
i
a =
i=0
bi ( 10 3 T )
i
b = and 0<b<1
i=0
ci ( 10 3 T )
i
c = 10 3
i=0
2
o 2 sin1 ( b )
P = --- --------------------------------------------
2 2
c 1 --- sin1 ( b )

o o 3
R sw = a P ( 1 b )
c Po cP
o c Po
m = a 1 b sin --- ---------------------
- + --
- ---------------------
- cos --- ---------------------
-
2 c P o + 1 2 c Po + 1 2 c P o + 1
2-18 Landmark - R2003.4

with Rsw in scf of carbon dioxide per stb water, temperature (T) in degree
Fahrenheit, pressure (P) in psia and
a0 =1.16306, a1 =-16.6304, a2 =111.07305, a3 =-376.85925, a4 =524.88916
b0 =0.96509, b1 = -0.27255, b2 = 0.09234, b3 = -0.10083, b4 = 0.09979
c0 =1.28030, c1 =-10.75660, c2 = 52.69622, c3 =-222.39488, c4 =462.67255
This correlation matches the solubility data of Wiebe [22] for liquid and
supercritical carbon dioxide in water within 10 scf/stb for temperatures
between 54 and 212 degrees Fahrenheit and pressures up to 10,000 psia.
The calculated solubility in pure water is further adjusted for the effects of
salinity to obtain the solubility of carbon dioxide in brine
R sb
log -------- = s o S T s1
R sw
where S is salinity of brine in weight percent of solid, T is temperature in

degree Fahrenheit and
s0 = -0.028037
s1 = -0.12039
The measured data in NaCl Solutions from Malinin and Savelyeva [14],
Malinin and Kurovskaya [15], and McRee [16] were used to obtain
parameters s0 and s1.
The formation volume factor of carbon dioxide saturated water (or brine)
is calculated using
1
B w = ------ [ w, sc + 0.02066 R sb ]
w
w = w, atm + 10 3 d 1 R sb
where d1 = 5.8, Bw is in rb/stb, w,sc is water density at standard

temperature and pressure in lb/cu ft and w,atm is water density at
temperature and 14.7 psia in lb/cu ft. Both w,sc and w,atm are calculated
using the correlation from Rowe and Chou [17].
The correlation of carbon dioxide saturated water density is developed

using the data of Parkinson and De Nevers [18], and Sayegh and Najman
[19].
R2003.4 - Landmark 2-19

For pressures less than 5000 psia the water compressibility is calculated
using the correlation from Rowe and Chou [17]. For pressures greater than
5000 psia,
1 1
------- = ------------------ + 7.033 ( P 5000 )
Cw C w, 5000
where Cw,5000 is water compressibility at temperature and 5000 psia from

Rowe and Chou correlation in 1/psia. The above correlation is derived
from the water compressibility correlation by Osif [20].
Water viscosity is calculated from Kestin et al. correlation [21]. The effects
of carbon dioxide solubility are ignored in both compressibility and
viscosity calculations.
Default values of a0 to a4, b0 to b4, c0 to c4, s0, s1, and d1 as shown above
are given in the program. The default values may be overwritten by means
of CO2COR data. Only those data overwriting the default values need to
be entered.
CO2COR
ACOEF a0 a1 a2 a3 a4
BCOEF b0 b1 b2 b3 b4
CCOEF c0 c1 c2 c3 c4
SCOEF s0 s1
DCOEF d1
ENDCO2
Definitions:
CO2COR The keyword for inputting correlation coefficients

for properties of carbon dioxide saturated water.
ACOEF The keyword for inputting coefficients a0 to a4 for

computing solubility of carbon dioxide in water.
Five numbers corresponding to a0 to a4 must be
entered following the keyword.
BCOEF The keyword for inputting coefficients b0 to b4 for

Five numbers corresponding to b0 to b4 must be
CCOEF The keyword for inputting coefficients c0 to c4 for

Five numbers corresponding to c0 to c4 must be
2-20 Landmark - R2003.4

SCOEF The keyword for inputting coefficients s0 and s1 for

adjusting the salinity effects in computing solubility
of carbon dioxide in water. Two numbers
corresponding to s0 and s1 must be entered
following the keyword.
DCOEF The keyword for inputing coefficient d1 for

computing density of carbon dioxide saturated
water. Only one number corresponding to d1 need
to be entered following the keyword.
ENDCO2 The keyword indicates the end of inputting

correlation coefficients for properties of carbon
dioxide saturated water.
Example:
EOS PR
COMPONENTS
.
.
.
c
c ------------------------------------------------
c correlation of properties of co2 saturated water
c ------------------------------------------------
c
CO2COR
ACOEF 1.16306 -16.6304 111.07305 -376.85925 524.88916
BCOEF 0.96509 -0.27255 0.09234 -0.10083 0.09979
CCOEF 1.28030 -10.75660 52.69622 -222.39488 462.67255
SCOEF -0.028037 -0.12039
DCOEF 5.8000
ENDCO2
.
.
.
ENDEOS
R2003.4 - Landmark 2-21

2.10 Ideal Gas State Enthalpy Coefficients (HIDEAL)

The HIDEAL card is used to define component ideal gas state enthalpy
coefficients. The ideal gas state enthalpy for each component is given by
the fifth degree polynomial
* * * * 2 * 3 * 4 * 5
Hi = h i0 + h i1 T + h i2 T + h i3 T + h i4 T + h i5 T
*
where H i is the ideal gas state enthalpy of component i in Btu/lb-mole, T
*
is the temperature in degrees Rankin and h in are the ideal gas state
enthalpy coefficients of component i in Btu/lb-mole-(R)n.
Table 2-4 gives component Passut-Danner ideal gas state enthalpy

coefficients for pure components [6, 7] which have been internally coded.
Note that these coefficients are given on a mass rather than a molar basis.
These values will be automatically loaded when the corresponding
component names are entered in the COMPONENTS data.
For components not listed in Table 2-4, default ideal gas state enthalpy
coefficients are calculated using the Kesler and Lee correlation [8, 9, 10].
This correlation is not always applicable. It fails if the component critical
temperature is less than 60 F. The correlation requires component specific
gravity. If the component is a gas at standard conditions, then we use the
density at the vapor pressure at standard temperature. For the relatively
heavy components commonly used in thermal reservoir simulation, these
shortcomings are not a problem.
Any of the default values for ideal gas state enthalpy coefficients may be
overridden by means of HIDEAL data.
HIDEAL
cmpi * * * * * *
h i0 h i1 h i2 h i3 h i4 h i5
Definitions:
cmpi Component name for component i. Must be iden-

tical to one of the components included in the
COMPONENTS data.
*
h in Ideal gas state enthalpy coefficients for compo-
nent i, Btu/lb-mole-(R)n.
Example:
C7+ 26.6 -0.023 4.59E-04 -0.998E-07 1.085E-11 -0.33E-15
2-22 Landmark - R2003.4

2.11 End of EOS Data (ENDEOS)

The ENDEOS card terminates the reading of the equation-of-state
properties for the components whose mixture characteristics are to be
simulated. Data describing various laboratory procedures follow.
ENDEOS
Example:
EOS PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C7+
PROPERTIES
C7+ 206. 895.1 302.6 .3121 .8643 X X
C1 X X X X X .48521 .08261
DJK C7+
CO2 .15
N2 .12
C2 .01
C3 .01
ENDEOS
An equivalent set of data is as follows:
EOS PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C15
PROPERTIES
C15 206. 895.1 302.6 .3121 .8643 X X
C1 X X X X X .48521 .08261
ENDEOS
R2003.4 - Landmark 2-23

2.12 Output File for PVT Properties (PVTFILE)

The user may direct DESKTOP-PVT to write a disk file which contains all
information necessary for PVT calculations in VIP-EXECUTIVE. This
information consists of component names, component critical properties,
and equation-of-state parameters. The data is written in a form that is
syntactically correct for use in VIP-ENCORE. The keyword PVTFILE must
be included following the ENDEOS card to invoke the writing of this PVT
information.
PVTFILE
Example:
To specify the writing of PVT information, enter the following sequence of

data:
EOS PR
.
.
.
ENDEOS
PVTFILE
2-24 Landmark - R2003.4

2.13 Output File for K-values (KVFILE)

The user may direct DESKTOP-PVT to write a disk file which contains K-
value tables for use in VIP-ENCORE. The keyword KVFILE must be
included following the ENDEOS card and before the first laboratory data
to invoke the writing of K-value tables. Data written to this file will be
syntactically correct for input into VIP-ENCORE from isothermal tests and
into VIP-THERM from thermal tests. Only one occurrence of KVFILE is
required to produce this file for all constant volume expansion tests,
differential expansion tests, separator tests and distillation tests.
KVFILE
Example:
To specify the writing of K-value tables, enter the following sequence of

data:
EOS PR
.
.
.
ENDEOS
KVFILE
2.14 Selection of Water in Oil Option (WINOIL)

Water may be allowed to partition into the oil phase in the Multiple
Contact Steam Vaporization Test (MCSVAP), Steam Distillation Test
(STMDIS), and the Saturation Pressure with Water Calculation (PSATW).
In all of these tests, water is an implicitly defined component and, for VIP-
THERM applications, should not be defined as a component by the user in
the component properties data. Other tests are not affected by the selection
of this option.
WINOIL
R2003.4 - Landmark 2-25

2.15 Thermal Option (THERMAL)

This option allows user input of binary interaction coefficients DJK
between implicitly defined component H2O and user-defined
components. These interaction coefficients are pertinent only to the Steam
Distillation Test (STMDIS), Multiple Contact Steam Vaporization Test
(MCSVAP), and Saturation Pressure with Water Calculation (PSATW).
This option also causes the PVTFILE option to write EOS data in the
format required for direct input into VIP-THERM.
THERMAL
NOTE: Only PR equation of state is allowed with THERMAL option.
2-26 Landmark - R2003.4

Table 2-1: Component Properties Data - Pure Compounds
1 4. 3
Critical Properties g cm
Component M. W. Tc, F Pc, psia Zc * P , -------------------------
1 2. Tb, F s
s mol
H2O 18.015 705.2 3198.8 .2295 .3210 0.0 212.0 1.0 0.0
CO2 44.010 87.9 1070.9 .2742 .2225 49.6 -109.3 0.815 -0.1009
H2S 34.076 212.7 1036.0 .2660 .0920 80.1 -76.6 0.801 -0.1141
N2 28.013 -232.4 493.0 .2910 .0372 35.0 -320.4 0.300 -0.1740
C1 16.043 -116.6 667.8 .2890 .0126 71.0 -258.7 0.300 -0.1546
C2 30.070 90.1 707.8 .2850 .0978 111.0 -127.5 0.356 -0.0740
C3 44.097 206.0 616.3 .2810 .1541 151.0 -43.7 0.508 -0.0603
NC4 58.124 305.7 550.7 .2740 .2015 191. 31.1 0.584 -0.0675
IC4 58.124 275.0 529.1 .2830 .1840 191.0 10.9 0.563 -0.0798
NC5 72.151 385.7 488.6 .2620 .2524 231.0 96.9 0.631 -0.0369
IC5 72.151 369.1 490.4 .2730 .2286 231.0 82.1 0.625 -0.0640
NC6 86.178 453.7 436.9 .2640 .2998 271.0 155.7 0.664 -0.0036
NC7 100.210 512.8 396.8 .2630 .3498 321.6 209.2 0.688 0.0178
NC8 114.230 564.2 360.6 .2590 .3981 362.3 258.2 0.707 0.0455
NC9 128.260 610.7 332.0 .2510 .4452 403.0 303.5 0.722 0.0642
NC10 142.290 652.1 304.0 .2470 .4904 443.6 345.5 0.734 0.0919
NC11 156.300 690.0 285.0 .2410 .5349 484.3 384.6 0.744 0.0996
NC12 170.330 725.2 264.0 .2360 .5622 525.0 421.3 0.753 0.1245
NC13 184.350 756.7 250.0 .2390 .6231 565.6 455.8 0.760 0.1268
NC14 198.380 785.7 235.0 .2330 .6797 606.3 488.3 0.767 0.1402
NC15 212.410 812.5 220.0 .2290 .7060 647.0 519.1 0.772 0.1594
NC16 226.430 837.3 206.0 .2260 .7418 687.0 548.2 0.777 0.1801
NC17 240.460 860.4 191.0 .2160 .7699 728.3 575.9 0.782 0.2111
NC18 254.480 881.8 176.0 .2200 .7895 767.0 602.1 0.786 0.2471
* Adjusted to fit the vapor pressure curve using the P-R equation.
R2003.4 - Landmark 2-27

Table 2-2: Component Properties - Heavy Fractions*
1 4. 3
Component M. W. * djk P , ------------------------- Tb, F s
Tc, F Pc, psia 1 2.
s mol
C6 84 463 468.3 .2313 .0298 271.0 147.0 0.685 -0.02197
C7 96 525 449.4 .2718 .0350 311.0 197.5 0.722 0.00512
C8 107 576 429.8 .3151 .0381 351.0 242.0 0.745 0.04473
C9 121 625 402.0 .3636 .0407 391.0 288.0 0.764 0.06807
C10 134 668 379.6 .4176 .0427 431.0 330.5 0.778 0.09752
C11 147 706 359.3 .4680 .0442 471.0 369.0 0.789 0.11954
C12 161 743 340.2 .5147 .0458 511.3 407.0 0.800 0.13568
C13 175 776 323.9 .5575 .0473 551.6 441.0 0.811 0.14247
C14 190 810 308.8 .5982 .0488 591.9 475.5 0.822 0.14923
C15 206 844 294.3 .6445 .0502 632.2 511.0 0.832 0.15776
C16 222 872 280.0 .6889 .0512 672.5 542.0 0.839 0.16026
C17 237 900 269.3 .7315 .0523 712.8 572.0 0.847 0.16594
C18 251 920 258.7 .7664 .0530 753.1 595.0 0.852 0.16303
C19 263 940 251.3 .8002 .0537 793.4 617.0 0.857 0.16712
C20 275 961 244.7 .8415 .0544 833.7 640.5 0.862 0.17537
C21 291 982 235.4 .8750 .0551 874.0 664.0 0.867 0.17208
C22 300 1001 232.1 .9261 .0558 914.3 686.0 0.872 0.18694
C23 312 1020 226.9 .9629 .0565 954.6 707.0 0.877 0.19180
C24 324 1037 221.6 1.0045 .0571 994.9 727.0 0.881 0.19568
C25 337 1055 216.2 1.0382 .0575 1035.2 747.0 0.885 0.19833
C26 349 1071 211.5 1.0804 .0581 1075.5 766.0 0.889 0.20126
C27 360 1087 207.8 1.1167 .0586 1115.8 784.0 0.893 0.20571
C28 372 1102 203.4 1.1583 .0591 1156.1 802.0 0.896 0.20884
C29 382 1114 200.0 1.1987 .0595 1196.4 817.0 0.899 0.21080
C30 394 1129 196.2 1.2325 .0599 1236.7 834.0 0.902 0.21344
C31 404 1143 193.7 1.2706 .0605 1277.0 850.0 0.906 0.21737
2-28 Landmark - R2003.4

Table 2-2: Component Properties - Heavy Fractions*
1 4. 3
Component M. W. * djk P , ------------------------- Tb, F s
Tc, F Pc, psia 1 2.
s mol
C32 415 1156 190.5 1.3151 .0609 1317.3 866.0 0.909 0.22009
C33 426 1169 187.5 1.3494 .0613 1357.6 881.0 0.912 0.22189
C34 437 1180 184.2 1.3901 .0616 1397.9 895.0 0.914 0.22272
C35 445 1191 182.5 1.4284 .0620 1438.2 908.0 0.917 0.22689
C36 456 1202 179.5 1.4718 .0623 1478.5 922.0 0.919 0.22819
C37 464 1213 178.1 1.4993 .0627 1518.8 934.0 0.922 0.23141
C38 475 1223 175.2 1.5423 .0630 1559.1 947.0 0.924 0.23137
C39 484 1233 173.2 1.5781 .0633 1599.4 959.0 0.926 0.23376
C40 495 1243 170.6 1.6237 .0635 1639.7 972.0 0.928 0.23418
C41 502 1252 169.4 1.6494 .0638 1680.0 982.0 0.930 0.23721
C42 512 1260 166.9 1.6927 .0640 1720.3 993.0 0.931 0.23732
C43 521 1269 165.2 1.7294 .0642 1760.6 1004.0 0.933 0.23856
C44 531 1279 163.2 1.7829 .0645 1800.9 1017.0 0.935 0.24117
C45 539 1287 161.8 1.8213 .0648 1841.2 1027.0 0.937 0.24247
* Pc, and acentric factor have been adjusted to fit the liquid density and boiling point data of Katz and Firooza-
badi.[1]
R2003.4 - Landmark 2-29

Table 2-3: Binary Interaction Coefficients
H2O CO2 H2S N2 C1 C2 C3
H2O .0
CO2 .0 .0
H2S .0 .0 .0
N2 .0 .0 .0 .0
C1 .500 .150 .0 .120 .0
C2 .500 .150 .0 .120 .0 .0
C3 .480 .150 .0 .120 .0 .0 .0
NC4 .480 .150 .0 .120 .020 .010 .010
IC4 .480 .150 .0 .120 .020 .010 .010
NC5 .480 .150 .0 .120 .020 .010 .010
IC5 .480 .150 .0 .120 .020 .010 .010
NC6 .480 .150 .0 .120 .025 .010 .010
NC7 .480 .150 .0 .120 .025 .010 .010
NC8 .480 .150 .0 .120 .035 .010 .010
NC9 .480 .150 .0 .120 .035 .010 .010
NC10 .480 .150 .0 .120 .035 .010 .010
NC11 .480 .150 .0 .120 .0374 .010 .010
NC12 .480 .150 .0 .120 .0386 .010 .010
NC13 .480 .150 .0 .120 .0396 .010 .010
NC14 .480 .150 .0 .120 .0406 .010 .010
NC15 .480 .150 .0 .120 .0413 .010 .010
NC16 .480 .150 .0 .120 .0420 .010 .010
NC17 .480 .150 .0 .120 .0427 .010 .010
NC18 .480 .150 .0 .120 .0432 .010 .010
Note: All other binary interaction coefficients are zero, and djk = dkj.
2-30 Landmark - R2003.4

Table 2-4: Passut-Danner Ideal Gas State Enthalpy Coefficients BTU/LB-(R)n

4 7 11 15
COMPONENT h i0 h i1 h i2 ( *10 ) h i3 ( *10 ) h i4 ( *10 ) h i5 ( *10 )
HO2 854.01 0.45739 -0.52512 0.64594 -2.02760 2.36310
CO2 4.778 0.11443 1.01130 -0.26490 0.34706 -0.13140
H2S -0.617 0.23858 -0.24460 0.41070 -1.30126 1.44852
N2 -0.934 0.25520 -0.17790 0.15890 -0.32203 0.15893
C1 -6.977 0.57170 -2.94312 4.23157 -15.26740 19.45261
C2 -0.021 0.26488 -0.25014 2.92334 -12.86050 18.22060
C3 -0.738 0.17260 0.94041 2.15543 -10.70986 15.92794
NC4 7.430 0.09857 2.69180 0.51820 -4.20139 6.56042
IC4 11.498 0.04668 3.34801 0.14423 -3.16420 5.42893
NC5 27.172 -0.00280 4.40073 -0.86287 0.81764 -0.19715
IC5 27.623 -0.03150 4.69884 -0.98282 1.02985 -0.29485
NC6 -7.391 0.22911 -0.81569 4.52784 -25.23180 47.48019
NC7 -0.066 0.18021 0.34729 3.21879 -18.36600 33.76939
NC8 1.120 0.17308 0.48810 3.05401 -17.36459 31.24831
NC9 1.720 0.16906 0.58126 2.92611 -16.55850 29.29610
NC10 -2.993 0.20335 -0.34904 4.07057 -23.06441 42.96899
NC11 28.070 -0.02384 4.60773 -0.99839 1.08415 -0.33120
NC12 26.211 -0.01852 4.53893 -0.96464 1.01393 -0.29660
NC13 26.977 -0.02293 4.59517 -0.99758 1.08351 -0.33090
NC14 26.507 -0.02205 4.58079 -0.99164 1.07126 -0.32540
NC15 26.748 -0.02411 4.60717 -1.00768 1.10447 -0.34150
NC16 26.194 -0.02282 4.59024 -1.00021 1.08912 -0.33390
NC17 26.162 -0.02356 4.59907 -1.00665 1.10307 -0.34076
NC18 25.976 -0.02362 4.59950 -1.00804 1.10587 -0.34205
R2003.4 - Landmark 2-31

2-32 Landmark - R2003.4

Chapter
3
Simulating Laboratory Measurements
3.1 Introduction
DESKTOP-PVT can be used to simulate a variety of laboratory
procedures. The calculations can be entirely predictive or they can be
compared to experimental data. Any or all of the various laboratory
procedures can be simulated in an arbitrary sequence.
Fluid samples can vary in composition from one procedure to another,

and operating temperature can change. Multiple fluid samples can be
analyzed with a single laboratory procedure by sequentially simulating
the same procedure for each different sample.
The data set for each laboratory procedure is introduced by a unique code
word. Each data set follows its predecessor without any intervening data
cards. A card containing the code word END terminates data processing.
For each laboratory test in this section, the unit of measurement for
pressure and temperature may be optionally specified. The default
pressure unit is psia. The default temperature unit is degree Fahrenheit.
3.2 Gas Z-Factor (Z-FACTOR)

The z-factor for a mixture of gases is defined by the real gas law:
Z = PV
---------
RT
where
Z is the gas compressibility factor, dimensionless,

P is pressure,
V is molar volume,
R is the gas law constant,
T is absolute temperature.
R2003.4 - Landmark 3-33

Simulating Laboratory Measurements DESKTOP-PVT Keyword Reference Manual
Any consistent set of units can be used for P, V, R, and T.
Z-FACTOR
COMPOSITION y1 y2 . . .yn
F
C
TEMP t repeat
R
K
PSIA
PRES PSIG p1 p2 . . . pk as
KPA
KG C2
LB FT3
(DEXP GM CC d1 d2 . . . dk) necessary
(WT w1 w2 ... wk)
ZEXP zf1 zf2 . . . zfk)

(WT w1 w2 . . . wk)
(VEXP v1 v2 . . . vk)
(WT w1 w2 . . . wk)
Definitions:
yi Mole fraction of component i. The number of val-

ues must equal the number of components
defined in the component properties data (Chap-
ter 2).
t A value of temperature in units specified by one
of the labels F, C, R, or K.
pk A value of pressure in the units specified by one
of the labels PSIA, PSIG, KPA, or KG/C2.
zfk The z-factor measured at a pressure of pk and a
temperature of t. Enter the alpha character X, if no
data is available. (Input optional.)
3-34 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Simulating Laboratory Measurements
dk The gas density measured at a pressure of pk and

a temperature of t. The units are specified by one
of the labels LB/FT3 or GM/CC. Default is LB/
FT3. Enter the alpha character X if no data is
available. (Input optional.)
vk The gas viscosity measured at a pressure of pk
and a temperature of t in the units of cp. Enter the
alpha character X if no data is available. (Input
optional)
wk Weight factor for measured zfk, dk and vk. (Input
optional)
NOTE: 1. If the number of values required on the COMPOSITION, PRES,

ZEXP, DEXP, or VEXP cards is too large to fit on one card,
additional cards may be used as necessary.
2. Assignment of Weight Factors for Nonlinear Regression:
Weight factors can be assigned to the z-factor, density and/or

viscosity measurements by inserting a card entry with the
keyword WT followed by a string of weights wk corresponding
to the number of measurements. The WT card should
immediately follow the ZEXP, DEXP, and/or VEXP entries.
By defaults, the weight factors for z-factor, density, and viscosity

are 1.
Example:
C ---------------------------------------------------------------
C CALCULATE Z-FACTOR OF ENRICHED METHANE
C ---------------------------------------------------------------
Z-FACTOR
COMPOSITION
.0047 .0070 .9363 .0358 .0102 .0021 .0019 .0006 .0006 .0008 0. 0.
TEMP 144 F
PRES PSIA 200
R2003.4 - Landmark 3-35

3.3 Liquid Density (LIQDEN)

The density of a liquid mixture is calculated as a function of its
LIQDEN
COMPOSITION x1 x2 . . . xn
repeat
F
PRES C p1 p2 . . . pk
R
K
as
LB FT3
DEXP d 1 d 2 ...d k
GM CC
(WT w1 w2 . . . wk) necessary
(ZEXP zf1 zf2 . . . zfk)

(WT w1 w2 . . . wk)
(VEXP v1 v2 . . . vk)
(WT w1 w2 . . . wk)
Definitions:
xi Mole fraction of component i in the liquid. The

number of values must equal the total number of
components defined in the component properties
data (Chapter 2).
dk The liquid density measured at a pressure of pk
and a temperature of t. The units are specified by
one of the labels LB/FT3 or GM/CC. (Default is
LB/FT3). Enter the alpha character X, if no data is
available. (Input optional.)
zfk The Z-factor measured at a pressure pk and a
temperature of t. Enter the alpha character X, if
no data is available. (Input optional.)
vk The liquid viscosity measured at a pressure of pk
and a temperature of t in the units of cp. Enter the
alpha character X, if no data is available. (Input
optional)
3-36 Landmark - R2003.4

wk Weight factor for measured dk, zfk, and vk.

(Input optional.)

DEXP, ZEXP, and VEXP cards is to large to fit on one card,
additional cards may be added as necessary.
Weight factors can be assigned to the density, z-factor and/or

viscosity measurements by inserting a card entry with the
immediately follow the DEXP, ZEXP and/or VEXP entries.
By defaults, the weight factors for density, z-factor and viscosity

are 1.
Example:
C ------------------------
C LIQUID DENSITY
C ------------------------
LIQDEN
COMPOSITION .0584 .5043 .0965 .0875 .0589 .0295 .0229
0.044472 0.082646 0.014882
TEMP 276 F
PRES PSIG 6000 4375
DEXP .4924 .4530
R2003.4 - Landmark 3-37

3.4 Vapor Pressure (VP)

The vapor pressure of a pure component can be calculated as a function of
temperature. The component must be one of those defined in the
component properties data described in Chapter 2.
VP
COMPOSITION x1 x2 . . . xn
F
TEMP C t1 t2 . . . tk
R
K
PSIA
PEXP PSIG p1 p2 . . . pk
KPA
KG C2
(WT w1 w2 . . . wk)
DNSAT LB FT3 d d d
1 2 k
GM CC
z1 z2 zk

ZSAT
(WT w1 w2 . . . wk)
Definitions:
xi Mole fraction of component i in the fluid. The

data (Chapter 2), but only one value can be non-
zero.
tk A value of temperature in units specified by one
pk The value of vapor pressure measured at a tem-
perature tk. The units for pk are specified by one
of the labels PSIA, PSIG, KPA, or KG/C2. Enter
the alpha character X, if no data is available.
dk Oil densities at tk and pk (lb/cu ft, LB/FT3) or
(gm/cc, GM/CC) if DNSAT is specified. This
option should be used for oil samples. (Input
optional)
3-38 Landmark - R2003.4

zk Gas z-factor at tk and pk if ZSAT is specified. This

option should be used for gas samples. (Input
optional)
wk Weight factors for measured pk and dk (or zk).
(Input optional)
NOTE: 1. The vapor pressure calculation is not applicable to mixtures.
Weight factors can be assigned to the saturation pressure and/or

density/z-factor measurements by inserting a card entry with the
immediately follow the PEXP and/or DNSAT/ZSAT entries.
By default, the weight factor for saturation pressures is 10 and for

density, z-factors the weight is 5.
Example:
C -------------------------------------------------------------
C VAPOR PRESSURE CURVE FOR ETHANE
C -------------------------------------------------------------
VP
COMPOSITION 1. 0.
TEMP F -70. -50. 000. 025. 050. 075. 100.
PEXP PSIA 20. 100. 250. 325. 450. 550. 700.
R2003.4 - Landmark 3-39

3.5 Saturation Pressure (PSAT)

The dewpoint or bubblepoint of a mixture is calculated as a function of
temperature.
PSAT
COMPOSITION z1 z2 . . . zn
F
TEMP C t1 t2 . . . tk
R
K
PSIA
BPEXP PSIG p1 p2 . . . pk
DPEXP KPA
KG C2
(WT w 1 w 2 w k )
DNSAT LB FT3 d 1 d 2 ...d k

GM CC

ZSAT z 1 z ...z k
2
(WT w 1 w 2 w k )
Definitions:
zi Mole fraction of component i in the liquid. The

data (Chapter 2).
BPEXP The pressure values are bubble points.
DPEXP The pressure values are dewpoints.
pk The saturation pressure measured at a tempera-
ture of tk. The units for pk are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2. A realistic
value should be entered even if no data is avail-
able, since it will be used as the starting value for
the saturation pressure iteration. A poor estimate
can cause convergence failure.
3-40 Landmark - R2003.4


optional)
zk Gas z-factors at tk and pk if ZSAT is specified.
This option should be used for gas samples.
(Input optional)
(Input optional)
NOTE: Assignment of Weight Factors for Nonlinear Regression:

keyword WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately follow
the BPEXP/DPEXP and/or DNSAT/ZSAT entries.

Example:
C -------------------------------------------------------------
C SATURATION PRESSURE CALCULATION
C -------------------------------------------------------------
PSAT
COMPOSITION .0584 .5043 .0965 .0875 .0589 .0295 .0229
.109376 .020830 .011794
TEMP F 276
BPEXP PSIG 4375
WT 50
DNSAT GM/CC .453
R2003.4 - Landmark 3-41

3.6 Liquid and Vapor Viscosity (VISC)

Viscosities of either a liquid or a vapor are calculated as functions of
temperature and pressure, by default using the Lohrenz, Bray, and Clark
correlation [2]. This correlation was originally developed for use in
calculating liquid viscosities only, but it is extended to vapors for purposes
of consistency in compositional reservoir simulation. Fluid density and
critical volume are important parameters in this method.
VISC (GAS)
F
TEMP t C
R
K
PSIA
PRES PSIG p1 p2 . . . pk
KPA
KG C2
LB FT3
DEXP p 1 p 2 ...p k
GM CC
(WT w1 w2 . . . wk)
(ZEXP zf1 zf2 . . .zfk)

(WT w1 w2 . . . wk)
(VEXP v1 v2 . . . vk)
(WT w1 w2 . . . wk)
Definitions:
zi Mole fraction of component i in the fluid. The

data (Chapter 2).
vk The viscosity of the fluid measured at a pressure
of pk and a temperature of t in the unit of cp.
Enter the alpha character X, if no data is avail-
able.
3-42 Landmark - R2003.4

dk The density of the fluid measured at a pressure of

pk and a temperature of t. The units are specified
by one of the labels LB/FT3 or GM/CC. Default
is LB/FT3. Enter the alpha character X, if no data
is available. (Input optional)
zfk The z-factor if the fluid measured at a pressure of
pk and a temperature of t. Enter the alpha charac-
ter X, if no data is available. (Input optional)
wk Weight Factor for measured vk, dk and zfk.
GAS Indicates that the fluid is a vapor rather than a
liquid. (This selection can affect the root selected
when the cubic equation of state is solved for
density).

DEXP, ZEXP, or VEXP cards is too large to fit on one card,
additional cards may be added as necessary.
Weight factors can be assigned to the viscosity, density and/or z-

factor measurements by inserting a card entry with the keyword
WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately
follow the VEXP, DEXP and/or ZEXP entries.
By default, the weight factors for viscosity, density and/or z-

factor are 1.
Example:
C ----------------------------------------------
C OIL VISCOSITY CALCULATION
C ----------------------------------------------
VISC
COMPOSITION .0091 .0016 .3647 .0967 .0695 .0144 .0393 .0144 .0141
.0433 .156876 .111391 .064633
TEMP 220 F
PRES PSIA 2620. 3000. 4000. 5000.
DEXP .5986 .6035 .6155 .6268
VEXP .1580 .1620 .1755 .1881
3.7 Constant Composition Expansion (CCEXP)

The constant composition expansion procedure starts with a fluid sample
at a pressure above the saturation pressure. Pressure is reduced in a
sequence of discrete steps until the saturation pressure is reached. After
each pressure reduction, the volume is measured and normalized relative
to the volume at the saturation pressure.
R2003.4 - Landmark 3-43

Pressure is then reduced below the saturation pressure in a further

sequence of discrete steps. After each pressure reduction the vapor-liquid
mixture is equilibrated. The total volume of the mixture is normalized
relative to the volume at the saturation pressure, and sometimes the
volume fraction of liquid is measured.
CCEXP
F
TEMP t C
R
K
PSIA
BUBPT (WT w)
DEWPT psat PSIG
KPA
KG C2
(ZPSAT zpsat (WT w))
PRES VREL SLIQ ZG (ZL) (VISO) (VISG) (DENO) (DENG)

XLIQ
p1 v1 s1 zg1 (zl1) (viso1) (visg1) (deno1) (deng1)
p2 v2 s2 zg2 (zk2) (viso2) (visg2) (deno2 (deng2)
(WT w1 w2 w3 (w4) (w5) (w6) (w7) (w8))
. . . . . . . . .
. . . . . . . . .
. . . . . . . . .
pk vk sk zgk (zlk) (visok) (visgk) (denok) (dengk)
XCOMP

CMP 1 CMP 2 CMP i

x
11 x 21 x i1

( WT w1 w2 wi )

x x x
1k 2k ik
YCOMP

CMP CMP CMP
1 2 i
y y 21 y i1
11

y y ik
1k y 2k
3-44 Landmark - R2003.4

Definitions:
zi Mole fraction of component i in the mixture. The

data (Chapter 2).
t The temperature of the fluid in units specified by
one of the labels F, C, R, or K.
psat The saturation pressure of the fluid at tempera-
ture t. The label BUBPT or DEWPT indicates
whether the fluid has a bubblepoint or a dew-
point, and the pressure units are specified by one
pk A pressure level at which the total volume of the
fluid was measured. Units are specified by the
units label on the BUBPT or DEWPT card.
vk The total volume of the fluid mixture at pressure
pk divided by the volume measured at the satu-
ration pressure. Enter the alpha label X if no data
is available at this pressure.
sk The liquid volume measured at pressure pk,
divided by the total volume at the same pressure
if SLIQ is specified. If XLIQ is specified, sk is the
liquid volume measured at pressure pk, divided
by the total volume at saturation pressure. Enter
the alpha X if no data is available at this pressure.
zgk The gas z-factor measured at pressure pk. Enter
the alpha label X if no data is available at this
pressure.
zlk The oil z-factor measured at pressure pk. Enter
the alpha label X if no data is available at this
pressure.
visok Oil viscosity (cp) measured at pk if VISO is speci-
fied. (Input optional)
visgk Gas viscosity (cp) measured at pk if VISG is spec-
ified. (Input optional)
denok Oil density (gm/cc) measured at pk if DENO is
specified. (Input optional)
dengk Gas density (gm/cc) measured at pk if DENG is
w Weight factors for psat and measured quantities
at each pressure entry pk. (Input optional)
R2003.4 - Landmark 3-45

CMPi The alphametric label that identifies component

i. This must agree with the component names
defined in the component properties data.
xik Mole fraction of component i in the oleic phase at
the expansion pressure pk. The number and
order of pressure steps must be the same as those
under the PRES keyword.
yik Mole fraction of component i in the gaseous
phase at the expansion pressure pk. The number
and order of pressure steps must be the same as
those under the PRES keyword.
zpsat Z-factor measured at psat.
A weight factor for psat can be specified by including the keyword

WT followed by the psat weight in the BUBPT/DEWPT entry.
Weight factors for the individual measured quantities at each

pressure entry pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of weights
corresponding to the number of measurements.
By default, the weight factor for psat is 10 and for the measured
quantities at pk the weight is 1.
Example:
C -----------------------------------------------------------
C CONSTANT COMPOSITION EXPANSION
C -----------------------------------------------------------
CCEXP
COMPOS .5832 .1428 .0761 .0834 .0573 .0433 .0139
TEMP 190 F
DEWPT 4450 PSIG
PRES VREL SLIQ ZG
5580 .9525 X 1.1899
5400 .9589 X X
5000 .9737 X X
4800 .9819 X X
4600 .9916 X X
4500 .9972 X X
4420 1.0018 .4738 X
4388 1.0037 .5082 X
4339 1.0068 .5164 X
4300 1.0093 .5194 X
4180 1.0181 .5195 X
3993 1.0372 .5132 X
3780 1.0605 .5007 X
3490 1.1032 .4786 X
2998 1.2053 .4296 X
2505 1.3722 .3675 X
2000 1.6683 .2888 X
1485 2.2378 .2020 X
1058 3.1813 .1306 X
3-46 Landmark - R2003.4

3.8 Constant Volume Depletion (CVDEP)

The constant volume depletion begins with a fluid sample, usually a
condensate, at its saturation pressure at the temperature of interest. The
pressure is then reduced in a series of discrete steps by allowing the fluid
to expand. After each expansion, the PVT cell is equilibrated and then
returned to its original volume by withdrawing vapor at constant
pressure.
Data measured and reported at each pressure level usually includes the
+
composition of the produced gas, the molecular weight of the C 7 fraction,
the gas z-factor, the cumulative production of gas as a fraction of the gas
originally in place, and the fraction of the cell volume occupied by liquid
after returning to the original volume.
Black oil table data may be generated from a CVDEP test.
CVDEP
F
C
TEMP t R
K
PSIA
BUBPT psat PSIG (WT w)
DEWPT KPA
KG C2

PRES p1 p2 . . . pk
CMP1 y11 y12 . . . y1k
CMP2 y21 y22 . . . y2k
. . . . .
(WT w1 w2 . . . wk)
. . . . .
CMPn yn1 ya2 . . . yak

XCOMP

CMP 1 x 11 y 12 x 1k

CMP 2 x 21 y 22 x 2k

( WT w1 w2 wk )

CMP n y n1 y n2

x nk

MW CMPm1 CMPm2 mw1 mw2 . . . mwk
R2003.4 - Landmark 3-47

ZS zf1 zf2 . . . zfk
(ZL zl1 zl2 . . . zlk)
VPROD q1 q2 . . . qk
SLIQ s1 s2 . . . sk
(VISO viso1 viso2 . . . visok)
(VISG visg1 visg2 . . . visgk)
(DENO deno1 deno2 . . . denok)
(WT w1 w2 . . . wk)
BOETAB WHITSON
COATS
FIELD
BOUNIT METRIC
LAB
BOVISC EXPERIMENTAL
CALCULATED
BOPSAT bopsat1 bopsat2 .........bopsatk
BODP bodp1 bodp2 ............bodpk
BOSEP
STAGE TEMP PRES VFRAC VDEST LFRAC LDEST
1 t1 p1 vf11 vd11 lf11 ld11

X X X vf12 vd12 lf12 ld12
. . . . . . .
. . . . . . .
. . . . . . .
X X X vf1m vd1m lf1m ld1m
. . . . . . .
. . . . . . .
. . . . . . .
n tn pn vfn1 vdn1 lfn1 ldn1

X X X vfn2 vdn2 lfn2 ldn2
. . . . . . .
. . . . . . .
. . . . . . .
X X X vfnm vdnm lfnm ldnm
3-48 Landmark - R2003.4

Definitions:

data (Chapter 2).
point, and the pressure units are specified by one
pk A pressure level at which the fluids were equili-
brated and gas was withdrawn to maintain con-
stant volume.
CMPn The alphameric label that identifies component n.
This must agree with the component names
ynk The mole fraction of component n in the gas mix-
ture withdrawn from the PVT cell at pressure pk.
visok Oil viscosity measured at pk if VISO is specified.
(Input optional)
visgk Gas viscosity measured at pk if VISG is specified.
(Input optional)
denok Oil density (gm/cc) at pk if DENO is specified.
(Input optional)
CMPm1 The component labels for the highest and lowest
CMPm2 molecular weight components in a group of com-
ponents for which molecular weight is being
reported. Typically the molecular weight of the
fraction is reported. In this case CMPm1 would be
the name of the lowest molecular weight compo-
nent in the heavy fraction, and CMPm2 would be
the name of the heaviest component in the mix-
ture. If the heavy fraction is not split, enter the
same name for CMPm1 and CMPm2.
mwk The average molecular weight for the group of
components CMPm1 - CMPm2, measured at a
pressure of pk.
R2003.4 - Landmark 3-49

zfk The z-factor of the gas produced at a pressure of

pk.
qk The cumulative gas produced after returning the
PVT cell to its original volume at a pressure of pk.
This is expressed as a mole fraction of the original
gas in the cell.
sk The fraction of the PVT cell occupied by liquid
after returning it to its original volume at a pres-
sure of pk.
zlk The z-factor of liquid at a pressure of pk.
xnk The mole fraction of component n in the liquid
mixture at a pressure of pk.
BOETAB Optional keyword indicating that black oil data
are to be generated.
WHITSON Calculation algorithm selection. Either
WHITSON or COATS must be specified.
COATS Calculation algorithm selection. Either
WHITSON or COATS must be specified.
FIELD Output of black oil data in oilfield units.
METRIC Output of black oil data in metric units.
LAB Output of black oil data in laboratory units.
bopsatk Saturation pressures at which black oil data are
generated.
bodpk Pressure levels above saturation pressure at
which black oil data are generated
n Temperature of separator stage n.
tn Pressure of separator stage n.
pn Separator stage pressure.
vfnm Vapor fraction sent to output stream m of separa-
tor stage n.
vdnm Destination of output stream m of separator stage
n. The destination can be either the number of a
later stage, or the GAS production line.
lfnm Liquid fraction sent to output stream m of sepa-
rator stage n.
3-50 Landmark - R2003.4

ldnm Destination of output stream m of separator stage

n. The destination can be either the number of a
later stage, or the OIL production line.
X A symbol indicating that the same stage number,
or pressure, or temperature is to be used from the
data of the preceding input line.
NOTE: 1. Assignment of Weight Factors for Nonlinear Regression:
A weight factor for psat can be specified by including the

keyword WT followed by the psat weight in the BUBPT/DEWPT
entry.

pressure pk can be specified by inserting a card following the
card for a measured quantity with the keyword WT followed by
a string of weights corresponding to the number of pressures.
2. The keyword KILE may be entered to instruct the program to

write a table of K-values for use in VIP-ENCORE. KVFILE should
be entered after the EOS data and before the first laboratory data.
Only one occurrence of KVFILE is required to produce a file with
K-value tables for all constant volume expansion tests,
3. The entire collection of BOETAB input data must either all be

present or all be absent.
4. Each separator stage can have as many destinations as required

to define the stage, as long as the liquid fractions sum to 1, and
the vapor fractions sum to 1.
5. The separator battery can have as many stages as desired.
6. The keyword KVFILE may be entered to instruct the program to

differential expansion tests, separator tests, and distillation tests.
Data written to this file from constant volume depletion tests will
be syntactically correct for input into VIP-ENCORE.
Example:
C
C --------------------------------------------------
C CONSTANT VOLUME DEPLETION
C --------------------------------------------------
CVDEP
R2003.4 - Landmark 3-51

COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173

0.064447 0.020473 0.010029 0.004951
TEMP 256 F
DEWPT 6010 PSIG
PRES .6010 .5000 4000 .3000 .2100 .1200 .0700
C1 .6893 .7069 .7360 .7660 .7777 .7704 .7513
C2 .0864 .0868 .0873 .0883 .0897 .0938 .0983
C3 .0534 .0526 .0520 .0516 .0516 .0544 .0590
C6 .0173 .0148 .0125 .0108 .0101 .0107 .0125
MW C8 C34 158 146 134 123 115 110 109
ZGAS 1.1401 .015 .897 .853 .865 .902 .938
VPROD 0. .06624 .17478 .32927 .49901 .68146 .77902
SLIQ 0. .0780 .2130 .2500 .2440 .2250 .2100
C-----------------------------------------------------------
C Black oil table generation
C-----------------------------------------------------------
BOETAB WHITSON
BOUNIT FIELD
BOVISC EXPERIMENTAL
BOPSAT 500. 1000. 2000. 2200. 3000. 4000.
BODP 0. 500.
BOSEP
STAGE TEMPPRES VFRAC VDEST LFRACLDEST
1 100. 500. 1. GAS 1. 2
2 60. 100. 0.5 GAS 1. 3
X X X 0.5 3 0. OIL
3 60. 0. 1.0 GAS 1. OIL
3-52 Landmark - R2003.4

3.9 Swelling Test (SWELL)

The swelling test begins with a fluid sample, usually a liquid, at its
saturation pressure at the temperature of interest. A lean vapor is then
injected into the fluid sample in a series of discrete stages, causing an
elevation of saturation pressure. In the case of a liquid sample the fluid
may switch from a bubblepoint to a dewpoint between two stages,
spanning a critical mixture.
Data measured and reported at the end of each stage includes the
saturation pressure of the new mixture, the type of fluid (dewpoint or
bubblepoint), and the volume of the saturated mixture relative to the
saturated volume of the original sample.
SWELL
YINJ y1 y2 . . . yn
F
TEMP t C
R
K
PSIA
PSIG
KPA
KG C2
ZINJ VREL PSAT TYPE

zz1 v1 p1 DEWPT or BUBPT
zz2 v2 p2 DEWPT or BUBPT
. . . .
(WT w1 w2)
. . . .
. . . .
zzk vk pk DEWPT or BUBPT
Definitions:

data (Chapter 2).
yi Mole fraction of component i in the injection gas.
The number of values must equal the total num-
ber of components.
R2003.4 - Landmark 3-53

zzk Moles of injection gas in the mixture divided by

the total number of moles in the mixture at the
end of any stage.
vk The volume of the saturated mixture at the end of
any stage divided by the saturated volume of the
original mixture.
pk The saturation pressure of the mixture at the end
of any stage. The units of pressure we specified
by one of the labels PSIA, PSIG, KPA, or KG/C2.
DEWPT Indicates that the saturation pressure reported is
a dewpoint.
BUBPT Indicates that the saturation pressure reported is
a bubblepoint.
w Weight factors for vk and pk. (Input optional)
Weight factors for vk and pk of a swollen mixture can be specified by

inserting a card following a mixture input, with the keyword WT
followed by a string of weights corresponding to the number of
measurements.
By default, the weight factor for pk is 1.5 and for vk the weight is 1.
Example:
C -------------------------
C SWELLING TEST
C -------------------------
SWELL
COMPOSITION .679300.099000 .110800 .045000 .052966 .011941 .000993
YINJ .9468.0527.00050 0 0 0
TEMP 200 F
PSIG
ZINJ VREL PSAT TYPE
0 1.0 3428 DEWPT
.1271 1.1224 3635 DEWPT
.3046 1.3542 4015 DEWPT
.5384 1.9248 4610 DEWPT
.6538 2.5043 4880 DEWPT
3.10 Differential Expansion (DIFF)

The differential expansion begins with an oil sample at its saturation
pressure at the temperature of interest. The pressure is then reduced in a
series of discrete steps by allowing the fluid to expand. After each
expansion, the PVT cell is allowed to equilibrate and then all evolved gas
is removed from the cell at constant pressure.
3-54 Landmark - R2003.4

It is recommended that all differential liberation test data be entered into

the programs up to and including the flash at standard pressure and
reservoir temperature, and the flash to standard temperature and
pressure. If these data are not input, the program will perform a flash at
these last two conditions anyways.
Data measured and reported at each pressure level usually includes the
solution gas-oil ratio, relative oil volume, oil density, z-factor of the
withdrawn gas, and gravity of the withdrawn gas.
DIFF
F
TEMP t C
R
K
PSIA
KPA
KG C2

(BOPSAT bopsat (WT w))
(RSPSAT rspsat (WT w))
(TSTD tstd)
(PSTD pstd)
(METRIC)
RESV
PRES BO ZG VISO VISG DENO GRVG
RESSOL
pk bok rsk zgk vok vgk dok gk
. . . . . . . .
(WT w1 w2 w3 w4 w5 w6 w7)
. . . . . . . .
. . . . . . . .
pn bon rsn zgn von vgn don gn
Definitions:
zi The mole fraction of component i in the oil sam-

ple.
R2003.4 - Landmark 3-55


ture t. The label BUBPT indicates the fluid must
be a liquid at reservoir conditions. The pressure
units are specified by one of the labels PSIA,
PSIG, KPA, or KG/C2.
tstd Standard temperature in units specified on TEMP
entry. Default is 60 F. (Input optional)
pstd Standard pressure in units specified on BUBPT
entry. Default is 14.7 psia. (Input optional)
METRIC The METRIC keyword causes gas-oil ratio values
to be printed in metric units of SCM/STCM
rather than the (default) English units of SCF/
STB. (Input optional)
pk A pressure level at which the fluids were equili-
brated and gas withdrawn, in same units as psat.
bok Relative oil volume, barrels of oil at indicated
pressure, pk, per barrel of residual oil at 60 F.
rsk Gas-oil ratio, cubic feet of gas at standard pres-
sure and 60 F per barrel of residual oil at 60 F. If
RSEV is entered, rsk refers to cumulative gas that
has evolved. If RSSOL is entered, rsk refers to gas
that is still in solution.
zgk The z-factor of the gas produced at pressure pk.
vok The oil phase viscosity (cp) measured at pressure
pk.
vgk The gas phase viscosity (cp) measured at pres-
sure pk.
dok The oil phase density (gm/cc) at pressure pk.
gk The gravity of gas withdrawn at pressure pk.
bopsat Relative oil volume at psat, barrels of oil at psat
per barrel of residual oil at 60 F.
rspsat Gas-oil ratio, cubic feet of gas in solution (cor-
rected to standard conditions) at the begining of
differential expansion per barrel of residual oil at
60 F.
3-56 Landmark - R2003.4

A weight factor for psat can be specified by including the

keyword WT followed by the psat weight in the BUBPT entry.

pressure pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of
weights corresponding to the number of measurements.

Data written to this file from differential expansion test will be
syntactically correct for input into VIP-ENCORE.
Example:
C -----------------------------------------
C DIFFERENTIAL EXPANSION
C -----------------------------------------
DIFF
COMPOSITION .0091 .0016 .3647 .0967 .0695 .0144 .0393 .0144 .0141
.0433 .156876 .111391 .064633
TEMP 220 F
BUBPT 2620 PSIG
PRES BO RSSOL ZG VISO VISG DENO GRVG
2620 1.600 854 0.00X .373 X .6562 .00X
2350 1.554 763 0.846 .396 X .6655 .825
2100 1.515 684 0.851 .417 X .6731 .818
1850 1.479 612 0.859 .442 X .6808 .797
1600 1.445 544 0.872 .469 X .6889 .791
1350 1.412 479 0.887 .502 X .6969 .794
1100 1.382 416 0.903 .542 X .7044 .809
850 1.351 354 0.922 .592 X .7121 .831
600 1.320 292 0.941 .654 X .7198 .881
350 1.283 223 0.965 .738 X .7291 .988
159 1.244 157 0.984 .855 X .7382 1.231
000 1.075 0 X 1.286 X .7892 2.039
R2003.4 - Landmark 3-57

3.11 Multiple Contact Vaporization Test (MCVAP)

The multiple contact vaporization test begins with an oil sample at a given
pressure and temperature. The multiple contact vaporization test can
perform either a gas-cycling process (default) or an oil-cycling process. In
a gas-cycling process, gas will be injected into oil in a series of steps at
constant pressure. By default, this process is differential, in that all gas is
removed at the end of each contact step. The user may choose not to
remove any gas by entering CCOMP, indicating a constant composition
process. An oil-cycling process is selected with the keyword OILCYCLE.
In an oil-cycling process, after an initial contact of injected gas with oil, the
remaining oil is removed from the cell. For subsequent steps, the original
oil is added to the gas phase left from the previous step. The user may
request additional composition output for each step in either process by
defining three pseudo components, typically light components,
intermediate components, and heavy components. In this way, ternary
diagrams can easily be constructed to follow the mechanism of miscible
processes. The definition of the pseudo components is identical to the
definition of pseudo components in the PSEUDO function.
Data which is calculated at each step of the test include moles of gas (or
oil) removed, gas (or oil) z-factor, and liquid fraction. Required user input
includes the saturation pressure and composition of the fluid sample, the
composition of the injected gas (or oil), and the number of moles of gas (or
oil) added at each contact step.
MCVAP
YINJ y1 y2 . . .yn
(OILCYCLE)
(CCOMP)
F
TEMP t C
R
K
PSIA
KPA
KG C2
PRES p
3-58 Landmark - R2003.4


PSEUDO

PCMP 1 one or more of CMP i



ENDCMP
ADD REM ZG SLIQ
ak rk zgk sk
. . . .
(WT w1 w2 w3)
. . . .
. . . .
. . . .
an rn zgn sn
Definitions:
zi The mole fraction of component i in the oil sam-

ple.
yi The mole fraction of component i in the injection
gas fluid.
OILCYCLE Keyword that indicates oil cycling process.
CCOMP Keyword that indicates constant composition
process.
ture t. The fluid must be a liquid at reservoir con-
ditions. The pressure units are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2.
p The pressure level of the multiple contact vapor-
ization test in the same units as psat.
PSEUDO Keyword that indicates pseudo components are
specified.
PCMPi An alphanumeric label that identifies pseudo
component i. (Exactly three components are
required.)
CMPi An alphanumeric label that identifies component
i of the original fluid system. This must agree
with one of the component names defined in the
component properties data.
R2003.4 - Landmark 3-59

ENDCMP Keyword that terminates the reading of the

pseudo components.
ak The moles of gas (or oil) added at contact step k.
rk The moles of gas (or oil) removed after equilibra-
tion at contact step k.
zgk The z-factor of the gas removed at contact step k.
sk The liquid volume fraction before gas removed at
contact step k.
at each contact step. (Optional)
A weight factor for psat can be specified by including the keyword

WT followed by the psat weight in the BUBPT entry.
Weight factors for the individual measured quantities at each contact

step can be specified by inserting a card following the contact entry,
with the keyword WT followed by a string of weights corresponding
to the number of measurements.
quantities at each contact step the weight is 1.
Example:
C -------------------------------------------------------
C MULTIPLE CONTACT VAPORIZATION
C -------------------------------------------------------
MCVAP
COMPOSITION
.0022.0266.3324.0678.0643.0574.0430.0453.0538.0336.0378.1296.1062
YINJ
.0104.0014.6900.1219.0875.0495.0209.0000.0184 4*0.000
TEMP 256
BUBPT 2514.7
PRES 4514.7
ADD REM ZG SLIQ
.5 X X X
.5 X X X
.5 X X X
.5 X X X
.5 X X X
.5 X X X
.5 X X X
3-60 Landmark - R2003.4

3.12 Phase Envelope Calculation (ENVELOPE)

The phase envelope calculation consists of a series of bubblepoint and
dewpoint calculations to delineate the boundary of the two-phase region.
The calculation may be performed for both oil and gas fluid systems and
requires minimal user data input.
The convergence of the saturation pressure calculations using an equation

of state is dependent upon the starting value of pressure at a given
temperature. As a result, data which define starting values for pressure
and temperature must be specified. These starting values are defined by
specifying a range of pressure and temperature for both the upper and
lower portions of the phase envelope. The program will perform a
saturation pressure calculation for each of the temperatures specified in
this range, trying specified starting values for pressure until a calculation
converges. The critical point of the fluid system can easily be estimated by
noting the change in saturation pressure type from bubblepoint to
dewpoint.
ENVELOPE
F
TEMP C tu1 tu2 tuinc tl1 tl2 tlinc
R
K
PSIA
PSAT PSIG pu1 pu2 puinc pl1 pl2 plinc
KPA
KG C2
Definitions:
zi The mole fraction of component i in the oil or gas

sample.
tu1 The lowest temperature to calculate saturation
pressure for the upper portion of the phase enve-
lope. The temperature units are specified by one
tu2 The highest temperature to calculate saturation
pressure for the upper portion of the phase enve-
R2003.4 - Landmark 3-61

tuinc The increment to use in selecting temperature

values from tu1 to tu2 for the upper phase bound-
ary.
pu1 The lowest pressure to initialize the saturation
pressure calculation for the upper portion of the
phase envelope. The pressure units are specified
pu2 The highest pressure to initialize the saturation
pressure calculation for the upper portion of the
puinc The increment to use in selecting pressure values
from pu1 to pu2 for the upper phase boundary.
tl1 The lowest temperature to calculate saturation
pressure for the lower portion of the phase enve-
tl2 The highest temperature to calculate saturation
pressure for the lower portion of the phase enve-
tlinc The increment to use in selecting temperature
values from tl1 to tl2 for the lower phase bound-
ary.
pl1 The lowest pressure to initialize the saturation
pressure calculation for the lower portion of the
pl2 The highest pressure to initialize the saturation
pressure calculation for the lower portion of the
plinc The increment to use in selecting pressure values
from pl1 to pl2 for the lower phase boundary.
Example:
The data which follows instructs the program to build a phase envelope
for an oil system. The upper portion of the envelope will be found by
using temperatures every 20 degrees from -100 to 800F, and starting initial
3-62 Landmark - R2003.4

pressure values of 2000, 4000, and 6000 psig. The lower portion of the
envelope will be found by using temperatures every 20 degrees from 600
to 800F, and starting initial pressure values of 100, 200, and 300 psig.
C ----------------------------
C PHASE ENVELOPE
C ----------------------------
ENVELOPE
COMPOSITION .0584 .5043 .0965 .0875 .0589 .0295 .0229
.0445 .0826 .0149
TEMP F -100 0800 020 600 800 020
PSAT PSIG 2000 6000 2000 100 300 100
3.13 Enthalpy Calculation (ENTHV or ENTHL)

The enthalpy of a gas or liquid mixture is calculated as a function of its
ENTHV (or ENTHL)
COMPOSITION z1 z2 ... zn
F
TEMP t C repeat
R
K
PSIA
PRES PSIG p1 p2 ... pk as
KPA
KG C2
KBTU LBMOLE
HEXP h 1 h 2 h k necessary
J GMOLE
(WT w1 w2 ... wk)
DEXP LB FT3 d 1 d 2 d k

GM CC
ZEXP
(WT w1 w2 ... wk)
Definitions:
ENTHV Calculate gas enthalpy.

ENTHL Calculate liquid enthalpy.
R2003.4 - Landmark 3-63


data (Chapter 2).
t A value of temperature in the units specified by
one of the labels F, C, R or K.
of the labels PSIA, PSIG, KPA and KG/C2.
hk The enthalpy of the fluid measured at a pressure
of pk and a temperature of t in the units specified
by one of the labels KBTU/LBMOLE or J/
KGMOLE. Enter the alpha character X, if no data
is available. (Input optional)
dk The liquid density, if DEXP is specified, or z-fac-
tor, if ZEXP is specified, of the fluid measured at
a pressure of pk and a temperature of t. The units
for density are specified by one of the labels LB/
FT3 or GM/CC. Enter the alpha character X, if no
data is available. (Input optional)
wk Weight factors for measured hk and dk. (Input
optional)
Weight factors can be assigned to the enthalpy and/or density/z-

factor measurements by inserting a card entry with the keyword WT
followed by a string of weights wk corresponding to the number of
measurements. The WT card should immediately follow the HEXP
and/or DEXP/ZEXP entries.
By defaults, the weight factors for both enthalpy and density/z-factor

are 1.
Example:
C -----------------------------------------------
C GAS ENTHALPY CALCULATION
C -----------------------------------------------
C
ENTHV
COMPOSITION 1.0 0.0
C
TEMP 450F
PRES PSIA 10.0 110.0 210.0 310.0 410.0 422.17
HEXP KBTU/L 22.750 22.538 22.303 22.037 21.733 21.693
ZEXP 0.9960 0.9671 0.9356 0.9007 0.8615 0.8564
3-64 Landmark - R2003.4

3.14 Liquid Water Properties (WATPRP)

The liquid water properties of density, enthalpy, viscosity and fugacity
coefficient are calculated as a function of pressure and temperature.
WATPRP
PRES TEMP
p1 t1
p2 t2
. .
. .
. .
pk tk
Definitions:
pk A value of pressure in the units of PSIA.

tk A value of temperature in the units of F.
Example:
C -------------------------------------------
C LIQUID WATER PROPERTIES
C -------------------------------------------
C
WATPRP
PRES TEMP
0029.82 250.
0066.97 300.
0422.20 450.
1541.80 600.
0460.00 450.
0610.00 450.
1510.00 450.
1535.00 450.
1510.00 455.
R2003.4 - Landmark 3-65

3.15 Saturation Pressure with Water (PSATW)

The bubble point pressure of oil in the presence of water is calculated as a
function of temperature.
If the water in oil option (Section 2.14) has been selected, then the bubble
point pressure may also be a function of the amount of water present (only
if the oil is undersaturated with water). For this option, the composition
card specifies the water-free oil composition. The ZWAT card specifies the
overall water mole fraction in the water/oil system.
Water is an implicitly defined component and should not be defined as a

component in the component properties data (Chapter 2). The only water
properties which may be adjusted by the user are the H2O/component
binary interaction coefficients (DJK).
PSATW
F
TEMP C t1 t2 ... tk
R
K
ZWAT zw1 zw2 ... zwk
PSIA
BPEXP PSIG p1 p2 ... pk
KPA
KG C2
(WT w1 w2 ... wk)
DNSAT LB FT3 d1 d2 d k
GM CC

ZSAT z1 z2 z k
(WT w1 w2 ... wk)
Definitions:
zi Water-free mole fraction of component i in the

oil. The number of values must equal the total
number of components defined in the component
properties data (Chapter 2).
3-66 Landmark - R2003.4

zwk Overall water mole fraction in the water/oil sys-

tem for measurment k.
zwk The overall water mole fraction in the water/oil
system fraction. Ignored if water in oil option is
not selected.
pk The saturation pressure measured at a tempera-
ture of tk. The units for pk are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2. A realistic
value should be entered even if no data is avail-
able, since it will be used as the starting value for
the saturation pressure iteration. A poor estimate
can cause convergence failure.
optional)
zk Gas z-factors at tk and pk if ZSAT is specified.
This option should be used for gas samples.
(Input optional)
(Input optional)

keyword WT followed by a string of weights wk corresponding to the
number of measurements. The WT card should immediately follow
the BPEXP and/or DNSAT/ZSAT entries.

Example:
PSATW
COMPOSITION .0584 .5043 .0965 .0875 .0489 .0295
.0229 .109376 .020830 .011794 .01
TEMP F 276
ZWAT 0.0
BPEXP PSIG 4375
WT 50
DNSAT GM/CC 0.453
R2003.4 - Landmark 3-67

3.16 Distillation Test (DISTIL)

A laboratory distillation test can be calculated as a prediction or through
regression where experimental data is matched. The data required to
define this procedure is described as follows.
DISTIL
PSIA

PRES pres PSIG
KPA

KG C2
F
TZERO tzero C (WT w)
R
K
TS PS
ts ps
N TEMP WFRAC
VFRAC
n1(=1) t1 vfrac1
(WT w1)
n2(=2) t2 vfrac2
(WT w2)
. . .
. . .
. . .
ni ti vfraci
(TINC tinc)
MW CRUDE CMP1 CMP2

mwc cmp1 cmp2
(WT w)
MW RESID CMP1 CMP2 N
mwr n1 cmp1 n cmp2 n n1
1 1
(WT w2)
. . . .
. . . .
. . . .
mwr n2 cmp1 n cmp2 n n2
2 2
3-68 Landmark - R2003.4

WFRAC CRUDE CMP1 CMP2

wfrac cmp1 cmp2

( WT w)
API CRUDE

apic

( WT w)
API RESID N

apir 1 n 1

( WT w 1 )

apir 2 n 2

( WT w 2 )

. .
. .

. .
apir i n i

API DIST NDFRAC N1 N2

apid ndfrac 1 n1 1 n2 1
1
( WT w 1 )

apid ndfrac 2 n1 2 n2 2
2
( WT w 2 )

. . . .
. . . .

. . . .
apid ndfrac k n1 k n2 k
k
KVTBS

NDFRAC KVALUE
. . . .

. . . .
ndfrac K K K
k 1, k 2, k n, k

(WT wt 1, k wt 2, k wt n, k )

(WTC wtc 1, k wtc 2, k wtc n, k

. . . .
. . . .
R2003.4 - Landmark 3-69

WFRAC WFRAC WFRAC

BLEND CRUDE RESID N DIST NDFRAC API
VFRAC VFRAC VFRAC
nblend vfcrude n vfres ndfrac vfdis apib

1 1 i1 1 k1 1 1
( WT w
1
)
2 2 i2 2 k2 2 2
( WT w
2
)

j j ij j kj j j
VMIN vmin
VCRUDE TEMP PRES VISC ( WT )
t1 p1 visc 1 ( w1 )
t2 p2 visc 2 ( w2 )
. . . .
tm pm visc m (wm )
. . . .
VRESID N TEMP PRES VISC ( WT )
n1 t1 p1 visc 1 ( w2 )
n1 t2 p2 visc 2 ( w2 )
. . . . .
n1 tm p visc m (wm)
m
. . . . .
VDIST NDFRAC TEMP PRES VISC ( WT )
ndfrac k t1 p1 visc 1 ( w 1 )
ndfrac k t2 p2 visc 2 ( w2 )
. . . . .
ndfrac k tm pm visc m (wm)
. . . . .
VBLEND NBLEND TEMP PRES VISC ( WT )
nblend j t1 p1 visc 1 ( w 1 )
nblend j t2 p2 visc 2 ( w2 )
. . . . .
nblend j tm pm visc m (wm)
. . . . .
3-70 Landmark - R2003.4

Definitions:

data (Chapter 2).
pres The operating pressure in the units specified by
one of the labels PSIA, PSIG, KPA, and KG/CM2.
Default is 14.7 psia. (Input optional)
tzero The boiling point temperature (temperature at
zero volume fraction distillate) in the units speci-
fied by one of the labels F, C, R, and K.
ts Standard temperature in the units specified on
TZERO entry. Default is 60 F. (Input optional)
ps Standard pressure in the units specified on PRES
entry. Default is 14.7 psia. (Input optional.)
ni Data entry number for distillation curve, must
increase consecutively in VFRAC data.
ti The temperature at point ni on distillation curve
with the units specified on TZERO entry.
vfraci The volume fraction distillate at point ni on dis-
tillation curve if VFRAC is specified (equal to vol-
ume distilled divided by initial oil volume, all
volumes measured at standard conditions). If
WFRAC is specified, vfraci is the distillate weight
fraction at point ni on distillation curve (equal to
weight distilled divided by initial oil weight).
tinc The temperature increment used in stepping
through distillation curve, in the units specified
on TZERO entry. Default is 5 F. (Input optional)
cmp1, cmp2 The component labels for the highest and lowest
molecular weight components in a group of com-
ponents for which molecular weight is being
reported.
wfrac The weight fraction for the group of components
cmp1 - cmp2 in the original crude. (Input
optional)
mwc The average molecular weight for the group of
components cmp1 - cmp2 in the original crude.
(Input optional)
R2003.4 - Landmark 3-71

mwrn1 The average molecular weight for the group of

components cmp1 - cmp2 at point ni on distilla-
tion curve. (Input optional)
apic API gravity of original crude. (Input optional)
apiri API gravity of residue at point ni on distillation
curve. (Input optional)
apidk API gravity of distillate fraction ndfrack. (Input
optional)
ndfrack Distillate fraction number. (Input optional)
n1k, n2k Data point numbers on distillate curve which
define distillate fraction number ndfrack. The
distillate fraction defined by n1k, n2k is the distil-
late obtained from temperature tn1kto tempera-
ture tn2k. If n1k is set to 0, the distillate is
obtained from tzero to tn2k. If n1k is set to -1, the
distillate includes all distillate fractions at tem-
peratures less than tn2k. (Input optional)
KVTBS Alpha label indicating the measured component
K-values are to follow. (Input optional)
NDFRAC Alpha label indicating the following is for distil-
KVALUE late component K-value. (Input optional)
Kn,k Distillate K-value for component n and distillate
fraction number ndfrack. (Input optional)
wtn,k Weight factor for the measured K-value, Kn,k.
(Input optional) This weight factor is applied to
the residual of equation-of-state computed k-
value and measured k-value. To accomodate the
large variation in component K-values, the loga-
rithm of the K-values are used in computing the
residual.
wtcn,k Weight factor for the measured K-value, Kn,k.
(Input optional) This weight factor is applied
only to the residual of correlation computed K-
value and measured K-value. To accomodate the
large variation in component K-values, the loga-
rithm of the K-values are used in computing the
residual.
nblendj Blend number. (Input optional)
3-72 Landmark - R2003.4

vfcrudej Volume fraction of original crude in nblendj, if

VFRAC is specified. If WFRAC is specified,
vfcrudej is the weight fraction of the original
crude in nblendj. (Input optional)
vfresj Volume fraction of residue from point ni on dis-
tillation curve in nblendj, if VFRAC is specified.
If WFRAC is specified, vfresj is the weight frac-
tion of the residue from point ni on distillation
curve in nblendj. (Input optional)
vfdisj Volume fraction of distillate fraction ndfrack in
nblendj if VFRAC is specified. If WFRAC is spec-
ified, vfdisj is the weight fraction of the distillate
fraction ndfrack in nblendj. (Input optional)
apibj API gravity of nblendj. (Input optional)
w Weight factor for the measured data. (Input
optional)
vmin The limiting viscosity (cp) as temperature
approaches infinity. The default value is 0.2.
This value is used only in plotting the viscosity
data in the form of
ln ( ln ( + 1 vmin ) ) = A + B ln ( T )
where T is absolute temperature.
VCRUDE Alpha label indicating the measured viscosities
(cp) of original crude are to follow. (Input
optional) If one of the Twu viscosity correlations
is selected, a viscosity data file named "visc.log"
will be generated. This file will contain com-
puted component viscosities at the temperatures
specified in the crude viscosity table. The format
of the voscosity data in the file is syntactically
correct for input into VIP-THERM.
VRESID Alpha label indicating the measured viscosities
(cp) of residue are to follow. (Input Optional)
VDIST Alpha label indicating the measured viscosities
(cp) of distillate are to follow. (Input Optional)
VBLEND Alpha label indicating the measured viscosities
(cp) of blend are to follow. (Input Optional)
tm Temperature of the measured viscosity. The units
are the same as those specified in the TZERO
entry.
R2003.4 - Landmark 3-73

pm Pressure of the measured viscosity. The units are

the same as those specified in the PRES entry.
viscm Measured viscosity (cp) at tm and pm.
A weight factor for tzero can be specified by including the

keyword WT followed by the tzero weight in the TZERO
entry.
Weight factors for all other measured quantities can be

specified by inserting a card following the measured data
input, with the keyword WT followed by a weight.
By default, the weight factor for tzero is 2 and for all other
measured quantities is 1.
2. The keyword KVFILE may be entered to instruct the

program to write a table of K-value for use in VIP-THERM.
KVFILE should be entered after the EOS data and before
the first laboratory data.
Only on occurrence of KVFILE is required to produce a file

with K-value tables for all constant volume expansion tests,
differential expansion tests, separator test, and distillation
tests.
The format of the K-value table from distillation tests is

syntactically correct for input into VIP-THERM. The table
of K-value generated from distillation tests is the distillate
K-values.
The user must enter the keyword KVFILE as described

previously, and specify the distillate number in order to generate
the K-value table file.
Example:
C ------------------------------
C DISTILLATION TEST
C ------------------------------
C
DISTIL
COMPOSITION .19927.61835.18238
TZERO 515. F
N TEMP VFRAC
1 548 .021
2 564 .035
3 581 .056
4 586 .066
5 602 .075
6 612 .093
7 631 .111
8 650 .136
3-74 Landmark - R2003.4

9 668 .162
10 696 .188
11 708 .213
API CRUDE
11.5
API RESID N
10.58 3
9.80 7
8.50 11
27.83 1 1 3
24.63 2 4 7
21.27 3 8 11
BLEND CRUDE VFRAC RESIDN VFRAC DIST NDFRAC VFRAC API
1 .98 0 0. 1 .02 11.80
2 .96 0 0. 1 .04 12.12
Example:
DISTIL
COMPOSITION 0.234391 0.444724 0.250463 0.070421
PRES 0.0 PSIG
TZERO 299.9 F
C
N TEMP WFRAC
1 300.0 0.0000
2 400.0 0.0081
3 500.0 0.0394
4 600.0 0.1190
5 700.0 0.2197
6 800.0 0.3862
7 900.0 0.4688
8 1027.0 0.6511
C
API CRUDE
12.6
API RESID N
3.9 8
36.0 1 1 2
30.7 2 2 3
25.6 3 3 4
20.5 4 4 5
15.6 5 5 6
14.4 6 6 7
12.3 7 7 8
C
C ------------------
C DISTILLATE K-VALUE
C ------------------
C
KVTBS
NDFRAC KVALUE
3 0.1437896E+02 0.3973139E+00 0.1687528E-02 0.4442320E-12
4 0.6741022E+02 0.1413388E+01 0.1898595E-01 0.4679788E-09
C
C --------------
C VISCOSITY DATA
C --------------
C
VMIN 0.2
VCRUDE TEMP PRES VISC
102.63 0.0 2446.00
334.70 0.0 14.96
540.30 0.0 2.26
VRESID N TEMP PRES VISC
8 334.7 0.0 491.5
8 540.3 0.0 31.3
VDIST NDFRAC TEMP PRES VISC
3 102.63 0.0 6.50
3 334.70 0.0 1.55
3 540.30 0.0 1.18
R2003.4 - Landmark 3-75

4 102.63 0.0 18.77

4 334.70 0.0 1.81
4 540.30 0.0 1.23
3.17 Complete Phase Envelope Calculation (ENVPT)

The boundary of the two-phase region and the quality lines inside the
two-phase region are calculated in a complete phase envelope. The quality
lines can be specified as either liquid mole fraction or liquid volume
fraction. The step-size for temperature and pressure are adjusted
automatically so the computation can be performed in an efficient manner
while giving a clear picture of the phase envelope.
ENVPT
F

TEMP C t min t max t inc
R

K
PSIA

TEMP PSIG P min P max P inc
KPA

KG C2
LIQMF
l1 l2 l k
LIQSAT
Definitions:
zi The mole fraction of component i in the oil or gas

sample.
tmin The lowest temperature to calculate equilibrium
pressure. The units are specified by one of the
labels F, C, R, or K. (Input optional, default is 0
F.)
tmax The highest temperature to calculate equilibrium
pressure. (Input optional, default is 800 F.)
tinc The maximum temperature increment allowed.
(Input optional, default is 25 F.)
3-76 Landmark - R2003.4

pmin The lowest pressure to calculate equilibrium tem-

perature, and to initialize equilibrium pressure
calculation. The units are specified by one of the
labels PSIA, PSIG, KPA, or KG/C2. (Input
optional, default is 14.7 psia.)
pmax The highest pressure to calculate equilibrium
temperature, and to initialize equilibrium pres-
sure calculation. (Input optional, default is 8014.7
psia.)
pinc The maximum pressure increment allowed.
(Input optional, default is 250 psia.)
lk Liquid mole fraction if LIQMF is specified, or liq-
uid volume fraction if LIQSAT is specified. (Input
optional, defaults are 0.0, 0.25, 0.5, 0.75, and 1.0.)
Example:
C ----------------------------
C PHASE ENVELOPE
C ----------------------------
C
ENVPT
COMPOSITION 0.0618 0.0541 0.8170 0.0375 0.0094
0.0066 0.0030 0.0023 0.0083
C
TEMP F -200 0200 020
PRES PSIA 0014.7 3014.7 200
LIQSAT 0000.0 0000.01 001.0
C
R2003.4 - Landmark 3-77

3.18 Composition Variations with Depth (ZGRAD)

Considerable variations of hydrocarbon composition with depth have
been observed in several near critical reservoirs. In the top part of the
reservoir, the compositions are such that the fluid is classified as a gas
condensate. The heavy component composition increases as a function of
depth so that the fluid would be classified as a volatile oil at the bottom of
the reservoir. At some depth in the reservoir, the fluid would change
classification from gas to oil, but there is no classical gas-oil contact and no
two-phase region. This is because the hydrocarbon compositions are
always at temperatures and pressures that do not cross the equilibrium
two-phase envelope.
The composition variations of hydrocarbon fluids in an isothermal

reservoir are predicted in this test. We assume that the fluid has reached
the stationary state and no two-phase region exists in the reservoir. Only
the fluid component fugacities and gravity forces are considered in
calculating the composition variations. In addition to the tabular report, a
file named "zgrad.log" is written at the end of calculation. This file
contains the composition information that can be exported directly to VIP-
COMP.
3-78 Landmark - R2003.4

ZGRAD
F
TEMPI tref C
R
K
PSIA
PRESI perf PSIG
KPA
KG C2
BUBPT psat
DEWPT
DEPTHI dref FT
M
DEPTH d1 d2 dn
DEPMIN DEPMAX DEPINC
dmin dmax dinc
ZCOMP d1 d2 dn
cm p 1 z 11 z 12 z 1n
cm p 2 z 21 z 22 z 2n
(WT w1 w2 wn)

cm p m z m1 z m2 z mn
NEWTON

SS
(KNTMXZ DPMXZ DXMXZ TOLPZ TOLXZ TOLZ)

(kntmx dpmx dxmx tolp tolx told)
(DSTMIN DSTMAX DSTFAC)

(dstmn dstep dcut)
ON
DBUGZ
OFF
R2003.4 - Landmark 3-79

Definitions:
zi The hydrocarbon composition at the reference

depth in mole fraction. The number of values
must equal the total number of components
defined in the component properties data (Chap-
ter 2).
tref The reservoir temperature in units specified by
pref The reservoir pressure at the reference depth. The
pressure units are specified by one of the labels
PSIA, PSIG, KPA, or KG/C2.
psat The measured saturation pressure at the refer-
ence depth. The label BUBPT or DEWPT indi-
cates whether the fluid has a bubblepoint or a
dewpoint. The units are the same as those speci-
fied in pref.
dref The reference depth where composition, temper-
ature, pressure and saturation pressure are mea-
sured. The depth units are specified by one of the
labels FT or M.
dn or dmin, Two options are available to specify the depths
dmax, dinc where compositions are calculated. If the key-
word DEPTH is entered, then the numerical val-
ues of depth are entered directly. If the keyword
DEPMIN, DEPMAX and DEPINC are entered,
the depths are computed by specifying the mini-
mum (dmin), the maximum (dmax) and the incre-
ment (dinc) of depth. the depths are positive
downward.
cmpm The alphametric label that identifies component
defined in the component properties data. (Input
optional)
zmn Overall mole fraction of component m at the
depth entry dn. (Input optional)
wn Weight factors for the measured overall mole
fractions. The default value is 1. (Input optional)
NEWTON Two calculation methods are available. (Input
SS optional)
NEWTON Newton-Raphson method (Default)
SS Successive-substitution method
3-80 Landmark - R2003.4

kntmx The maximum number of iterations allowed to

compute composition at a depth. Default is 40.
(Input optional)
dpmx The maximum change in pressure for an itera-
tion. Default is 10. (Input optional)
dxmx The maximum change in composition for an iter-
ation. Default is 0.01. (Input optional)
tolp Convergence tolerance for pressure change
between iterations. Default is 0.01. (Input
optional)
tolx Convergence tolerance for compositional change
between iterations. Default is 0.00001. (Input
optional)
told Convergence tolerance for the damping factor of
the pressure and composition changes between
iterations. The composition calculation will fail if
the computed damping factor is less than the tol-
erance. Default is 0.001. (Input optional)
dstmn The minimum depth interval allowed in the com-
position calculation. If the computed depth inter-
val is less than this minimum value, the
calculation will be reported as a failure. Default is
1. (Input optional)
dstep The maximum depth interval allowed in the
composition calculation. If the user specified
depth interval is greater than this value, the com-
positions at additional intermediate depth inter-
val between the user specified depths. Default is
100. (Input optional)
dcut The factor for reducing the size of depth interval
when a composition calculation fails. If the com-
position calculation which failed was of size of
D, the next intermediate composition calcula-
tion will be of size D times this factor. Default is
0.2. (Input optional)
DBUGZ The user may request additional output of com-
position calculation by turning on the debug out-
put option. (Input optional)
ON Activate printing of detailed calcula-
tion output.
OFF Deactivate printing of detailed calcu-
lation output. (Default)
R2003.4 - Landmark 3-81

Example:
ZGRAD
COMPOSITION 0.780000 0.140000 0.080000
TEMPI 150.0 F
PRESI 3400.0 PSIA
DEWPT 3150.0
DEPTHI 10300.0 FT
DEPMIN DEPMAX DEPINC
8000.0 13000.0 200.0
3-82 Landmark - R2003.4

3.19 Properties of Carbon Dioxide Saturated Water (CO2TAB)

Properties of carbon dioxide saturated water are calculated using
correlations in this test. The correlations are shown in Section 2.9. These
properties include carbon dioxide solubility, formation volume factor,
compressibility and viscosity.
In addition to the tabular report, a file named "co2tab.log" is written at the

end of calculation. This file contains the properties of carbon dioxide
saturated water that can be exported directly to VIP-COMP.
CO2TAB
WT%
SALINITY s
PPM
F
C
TEMP t
R
K
PSIA
PRES
KPA
PSAT RSWCO2 BWCO2 CWCO2 VWCO2

p1 rsw1 bw1 cw1 vw1
p2 rsw2 bw2 cw2 vw2
. . . . .
. . . . .
(WT w1 w2 w3 w4)
. . . . .
. . . . .
pk rswk bwk cwk vwk
Definitions:
s Salinity of brine in the units specified by the one of

the label WT% (weight percent of solid) or PPM
(part per million of solid).
t The temperature at which all data were measured.

The units of temperature is specified by one of the
labels F, C, R, or K.
PRES A keyword for specifying pressure units in PSIA or

KPA.
pk A pressure stage at which water properties are

measured. The pressures must be entered in
decreasing order.
R2003.4 - Landmark 3-83

rswk Solubility of carbon dioxide in water. The units are

scf/stb if the pressure units are PSIA and are scm/
stcm if the pressure units are KPA.
bwk Formation volume factor of carbon dioxide

saturated water. The units are rb/stb if the pressure
units are PSIA and are cm/stcm if the pressure
units are KPA.
cwk Compressibility of carbon dioxide saturated water.

The units are inverse of pressure units.
vwk Viscosity of carbon dioxide saturated water in cp.
w Weight factor for the measured data. Default is 1.
Example:
CO2TAB
SALINITY 7.5 WT%
TEMP 121 F
PRES PSIA
PSAT RSWCO2 BWCO2 CWCO2 VWCO2
6000.0 150.1 1.046 0.232E-05 0.650
5000.0 145.2 1.045 0.236E-05 0.647
4500.0 142.8 1.045 0.240E-05 0.646
4000.0 140.4 1.044 0.245E-05 0.645
3500.0 137.6 1.044 0.249E-05 0.644
3000.0 134.3 1.043 0.253E-05 0.643
2500.0 129.9 1.042 0.257E-05 0.642
2000.0 123.3 1.040 0.262E-05 0.641
1500.0 112.7 1.038 0.266E-05 0.640
1000.0 94.5 1.034 0.270E-05 0.639
500.0 61.8 1.027 0.274E-05 0.638
14.7 0.0 1.013 0.278E-05 0.637
3-84 Landmark - R2003.4

3.20 Multiple Contact Steam Vaporization Test (MCSVAP)
NOTE: The Steam Distillation Test (STMDIS) is no longer updated, since for
heavy oils it is not an equilibrium process and should not be used to
characterize fluids for use in VIP-THERM, which assumes
equilibrium (a good assumption on the pore scale). However,
STMDIS simulation capability has not been removed from
DESKTOP-PVT.
A multiple contact steam vaporization test can be calculated as a

prediction or through regression where experimental data is matched.
This stepwise batch experiment is shown schematically below.
PGk
Vk
POk
PWk
Separator @ Ts, Ps
Fk
Vk,SGk
Lk,SOk
Wk,SWk
PVT Cell @ Tk, Pk
with volume VOLk
A specified initial amount of oil, LI, and optionally a specified initial

amount of water, WI, are charged to the PVT cell. For each contact k, a
specified amount of water (or steam), Fk is injected into the PVT cell and
the fluids are brought to equlibrium at temperature Tk and pressure Pk
with total cell volume VOLk such that a vapor phase is formed. A liquid
water phase may or may not be formed. The amount of vapor phase
formed at equilibrium, Vk, and the equilibrium phase saturations SGk,
SOk, and SWk are measured. Then, the vapor phase is completely
displaced from the PVT cell and is flashed to standard conditions, and
produced amounts of gas, oil and water phases (PGk, POk, and PWk,
respectively) are measured. The initial amounts of oil (LI), water (WI) and
the amounts of streams Fk, Vk, PGk, POk and PWk may be expressed in
mass (default), volumetric, or molar units. For the volumetric unit option,
LI is defined as ccs oil at standard conditions, WI and Fk are defined as ccs
H2O cwe (cold water equivalent), Vk is defined as ccs vapor phase at PVT
cell conditions, and PGk, POk, and PWk are defiend as ccs of gas, oil and
water, respectively, at standard conditions. For cases in which the initial
oil is saturated at standard conditions, the volumetric unit option should
not be used. This condition is not checked by the program.
R2003.4 - Landmark 3-85

Optionally, oil viscosities of the initial oil (crude) and of the PVT cell oil
and the produced oil for any contact may also be calculated as predictions
or through regression to match experimental data. Care should be taken
to insure that the specified temperatures and pressures at which
viscosities are to be calculated correspond to undersaturated conditions
for the relevant fluid composition. This is not checked by the program.
The program utilizes rigorous three phase flash algorithms for equilbrium
calculations both in the PVT cell and the separator. For most heavy oils,
the fluid in separator will be an undersaturated oil/water mixture (no
produced gas). If this condition is detected by calculation of the bubble
point, the separator flash calculation is of course bypassed. Water is
allowed to partition into the oil phase in all equilibrium/bubble point
calculations if the WINOIL option has been selected (Section 2.14).
Normally, H2O should not be defined as a component by the user. H2O is
defined implicitly and is treated by the equation of state as a component in
the gas and (optionally) oil phases with fixed properties which are
consistent with those used in VIP-THERM. The only properties associated
with H2O which may be modified by the user are the DKJ binaries.
MCSVAP

TUNIT C

R
K
PSIA

PUNIT PSIA

KPA

KG C2
G
SUNIT
CC
MOLES

TS PS

ts ps

API api

(LI li)
(WI wi)
TEMP PRES F VOL V ZG ZO SO SW XW YW PO PG PW API

t1 p1 f1 vol1 v1 zg1 zo1 so1 sw1 xw1 yw1 po1 pg1 pw1 api1
(WT wtvol1 wtv1 wtzq1 wtzo1 wtso1 wtsw1 wtxw1 wtyw1 wtpo1 wtpg1wtpw1
wtapi1)
t2 ...
(WT ...)
.
3-86 Landmark - R2003.4

.
.
tn ...
(WT ...)
(VMIN vmin)
( WT )
VCRUDE TEMP PRES VISC

t p visc ( wt )

( WT )
VOC N TEMP PRES VISC

n t p visc ( wt )

( WT )
VOP N TEMP PRES VISC

n t p visc ( wt )

Definitions:
zi Mole fraction of component i in the initial fluid LI.

The number of values must equal the total number of
components defined in the component properties data
(Chapter 2).
TUNIT Alpha label indicating that the following alpha string

defines the temperature unit. Optional, default unit is
degress F.
PUNIT Alpha label indicating that the following alpha string

defines the pressure unit. Optional, default unit is
psia.
SUNIT Alpha label indicating that the following alpha string

defines the stream unit (G, CC, or MOLES). Optional,
default unit is G (grams). For CC unit, stream units
are:
LI - ccs initial oil at Ts Ps.
R2003.4 - Landmark 3-87

WI - ccs initial H2O cwe (cold water

equivalent).
Fk - ccs H2O cwe.
Vk - ccs vapor at Tk, Pk.
PO, PG, PW - ccs produced phase at Ts, Ps.
The MOLES unit is LB moles.
ts Standard temperature in the units specified on the

TUNIT card. Optional, default is 60F.
ps Standard pressure in the units specified on the PUNIT

card. Optional, default is 14.7 psia.
api API gravity of the initial oil. Use only if initial oil is
undersaturated.
li Initial amount of oil in PVT cell in units specified on

SUNIT card. Optional, default is 100g, 100ccs, or 0.001
LB moles.
wi Initial amount of water in PVT cell in units specified

on SUNIT card (grams, ccs cwe, or moles). Optional,
default is 0.
t Temperature for contact k or for visocisty measure-

ment in units specified on TUNIT card. Required.
p Pressure for contact k or for viscosity measurement in

units specified on PUNIT card. Required.
fk Amount of H2O injected into cell on contact k in units

specified by SUNIT card (for CC, ccs cold water equil-
valent). Required.
volk Total cell volume for contact k at equilbrium after

injection of H2O, ccs. Input optional.
vk Amount of equilibrium vapor formed on contact k

and then withdrawn in units specified on SUNIT card
(for CC, ccs vapor at tk, pk). Input optional.
zgk Z-factor of equilibrium vapor formed on contact k.
Input optional.
zok Z-factor of equilibrium cell oil for contact k. Input

optional.
sok PVT cell oil saturation at equilibrium on contact k

(before withdrawal of vapor), fraction. Input optional.
swk PVT cell liquid water saturation at equilibrium on

contact k (before withdrawal of vapor), fraction. Input
optional.
3-88 Landmark - R2003.4

xwk Mole fraction H2O in the PVT cell oil. Ignored if water
in oil option is not selected. Input optional.
ywk Mole fraction H2O in the PVT cell vapor. Input

optional.
pok Amount of produced oil at ts, ps in units specified on

SUNIT card (grams, LB moles, or ccs). Input optional.
pgk Amount of produced gas at ts, ps for contact k in units

specified on SUNIT card (grams, LB moles, or ccs).
Input optional.
pwk Amount of liquid water produced at ts, ps for contact

k in units specified on SUNIT card (grams, LB moles,
or ccs). Input optional.
apik API gravity of produced oil for contact k. Input

optional.
vmin Minimum value of viscosity used for plotting viscos-

ity vs. temperature data on logarithmic scale:
ln ( ln ( + 1 min ) ) = F ( ln ( T ) )
Optional, default is 0.2. Internally reset to 0 if any
input or calculated viscosity value is less than vmin.
VCRUDE Alpha label designating viscosity table for initial oil.
VOC Alpha label designating viscosity table for PVT cell oil.
VOP Alpha label designating viscosity table for produced

oil.
n Contact number for cell oil and produced oil viscosity

data.
visc Measured viscosity values in viscosity tables, cp.
wt Weight factors for measured values used in regression.
NOTE: Optional data items in the table must be specified as a number,

specified as zero, or specified with the alpha label X. The table
header must appear as shown (do not eliminate columns for data not
specified.)
R2003.4 - Landmark 3-89

3.21 Two Phase Isothermal Flash
FL2I
COMPOSITION
z1 z2 . . . zn
F
TEMP t C
R
K
PSIA
PRES PSIG
KPA
KG C2
PRES (MLIQ) (ZG) (ZL) (VISO) (VISG) (DENO) (DENG)

XLIQ
p1 (l1) (zg1) (zl1) (viso1) (visg1) (deno1) (deng1)
p2 (l2) (zg2) (zl2) (viso2) (visg2) (deno2) (deng2)
(WT (w1) (w2) (w3) (w4) (w5) (w6) (w7) )
. . . . . . . . .
. . . . . . . . .
. . . . . . . . .
pk (lk) (zgk) (zlk) (visok) (visgk) (denok) (dengk)
XCOMP

CMP 1 CMP 2 CMP i

x
11 x 21 x i1

( WT w1 w2 wi )

x x x
1k 2k ik
YCOMP

CMP CMP CMP
1 2 i
y y i1
11 y 21

y y ik
1k y 2k
3-90 Landmark - R2003.4

Definitions:

data (Chapter 2).
pk A pressure level at which the flash is to be per-
formed. Units are set with the PRES keyword.
MLIQk The liquid volume fraction measured of the fluid
mixture at pressure pk. (Input optional)
zgk The gas z-factor measured at pressure pk. (Input
optional)
zlk The oil z-factor measured at pressure pk. (Input
optional)
visok Oil viscosity (cp) measured at pk if VISO is speci-
fied. (Input optional)
visgk Gas viscosity (cp) measured at pk if VISG is spec-
ified. (Input optional)
denok Oil density (gm/cc) measured at pk if DENO is
dengk Gas density (gm/cc) measured at pk if DENG is
CMPi The alphametric label that identifies component
xik Mole fraction of component i in the oleic phase at
the expansion pressure pk. The number and
order of pressure steps must be the same as those
under the PRES keyword.
yik Mole fraction of component i in the gaseous
phase at the expansion pressure pk. The number
and order of pressure steps must be the same as
those under the PRES keyword.
R2003.4 - Landmark 3-91


pressure entry pk can be specified by inserting a card following a
pressure entry, with the keyword WT followed by a string of weights
corresponding to the number of measurements.
By default, the weight factor for the measured quantities at pk is 1.
Example:
C -----------------------------------------------------------
C TWO PHASE ISOTHERMAL FLASH
C -----------------------------------------------------------
FL2I RUN1
COMPOSITION
.5832 .1428 .0761 .0834 .0573 .0433 .0139
TEMP 190 F
PRES PSIG
PRES
5580
5400
5000
3-92 Landmark - R2003.4

Chapter
4
Simulating Multistage Separators
4.1 Introduction
DESKTOP-PVT can be used to model the behavior of multistage surface
separation facilities. The calculations can be entirely predictive, or they
can be compared to experimental data. For any specified separator
configuration it is possible to predict behavior for a variety of feed
streams.
4.2 Separator Conditions Data (SEPARATOR)

Each separator battery may contain an arbitrary number of stages. Each
stage contains one feed stream and two output streams, one vapor and one
liquid. Each of the two output streams can itself be split into two streams,
each of which may be fed to (1) any downstream separator stage, (2) the
gas sales line or (3) the oil sales line.
F PSIA
SEPARATOR ibat C PSIG
R KPA
K KG C2
(label card) STAGE TEMP PRES VFRAC VDEST LFRAC LDEST

(type 1 data) n tn pn vfn1 vdn1 lfn1 ldn1
(type 2 data) X X X vfn2 vdn2 lfn2 ldn2
COMPOSITION z1 z2 . . . zk
(METRIC)
Definitions:
ibat The separator battery number.

n The separator stage number. Values range
from 1 to the total number of stages.
tn The operating temperature of separator stage
n in units indicated by one of the labels F, C,
R, or K.
R2003.4 - Landmark 4-95

Simulating Multistage Separators DESKTOP-PVT Keyword Reference Manual
pn The operating pressure of separator stage n in

units indicated by one of the labels PSIA,
PSIG, KPA, or KG/CM2.
vfni This fraction of the vapor stream leaving sep-
arator stage n will be sent to the destination
indicated by vdn1. Values must lie in the
range of 0-1. If vfn1 is less than 1.0, then a
type 2 data card must be provided for this
stage.
vdn1 Defines the destination of the first vapor
stream leaving stage n. Alternatives include a
downstream separator stage and the gas sales
line.
vdn1 = m (m is a stage number)
= GAS (alpha label)
lfn1 This fraction of the liquid stream leaving sep-
indicated by ldn1. Values must lie in the range
0-1. If lfn1 is less than 1.0, then a type 2 data
card must be provided for this stage.
ldn1 Defines the destination of the first liquid
downstream separator stage and the oil sales
line.
ldn1 = m (m is a stage number)
= OIL (alpha label)
X An alpha label that must be entered in the
first three locations on a type 2 data card.
vfn2 This fraction of the vapor stream leaving sep-
indicated by vdn2. The values of vfn1 and vfn2
must sum to exactly 1.0.
vdn2 Defines the destination of the second vapor
downstream separator stage and the gas sales
line.
lfn2 This fraction of the liquid stream leaving sep-
indicated by ldn2. The values of lfn1 and lfn2
must sum exactly to 1.0.
4-96 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Simulating Multistage Separators
ldn2 Defines the destination of the second liquid

downstream separator stage and the oil sales
line.
zi The mole fraction of component i in the feed
to the first stage of the separator battery.
METRIC The METRIC keyword causes output units to
be printed in metric units instead of English
units (optional).
NOTE: 1. If all values necessary to define a single feed composition will not
fit on one card, an additional card(s) may be used. Multiple feed
compositions can be modeled by entering additional
COMPOSITION data cards without redefining the separator
conditions.
2. Stock tank conditions should be entered as the last stage of

separation in order to obtain the stock tank liquid volume.
3. If no units are specified, pressure is in psia and temperature is in

degree Fahrenheit. If a unit specification is made, it must be made
for both pressure and temperature.
Example:
C --------------------------------------------------------
C SEPARATOR TEST (NO REGRESSION)
C --------------------------------------------------------
SEPARATOR 1 F PSIG
STAGE TEMP PRES VFRAC VDEST LFRAC LDEST
1 75. 450. 1. GAS 1. 2
2 75. 100. 1. GAS 1. 3
3 75. 0. 1. GAS 1. OIL
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
0.064447 0.020473 0.010029 0.004951
4.3 Separator Test with Regression (SEP)

A laboratory separator test may be calculated by DESKTOP-PVT as a
prediction, or through regression where experimental data is matched.
Optionally, the user may enter equation-of-state parameters for either
reservoir calculations or surface calculations, or both. The data must be
entered immediately following the composition data. If reservoir
parameters are entered, calculations of saturation pressure and oil volume
at reservoir conditions will be performed using these parameters, even in
a regression run that modifies these parameters. Therefore, a regression to
match surface separation data may be performed honoring the reservoir
data. Likewise, entering surface equation-of-state parameters will force all
surface calculations to use the input parameters.
R2003.4 - Landmark 4-97

The data required to define this procedure is described as follows.
4-98 Landmark - R2003.4

SEP
COMPOSITION z1 z2 . . . znc
OMEGA

a 1 a 2 a nc

OMEGB

b 1 b 2 b nc
OMEGAS 1

a1 a 2 a nc

OMEGAS 2

a1 a 2 a nc

OMEGAS n

a1 a 2 a nc

OMEGBS 1

b1 b 2 b nc

OMEGBS 2
b1 b 2 b nc

OMEGBS n
b1 b 2 b nc

F
TEMP t C
R
K
PSIA
BUBPT psat PSIG
DEWPT KPA
KG C2
(METRIC)

LB FT3
DNSAT d
GM CC

ZSAT z
(TSTD tstd)
(PSTD pstd)
BO bo
(WT w)
BG b g

(API api) (WT w)
(GORT gort) (WT w)
R2003.4 - Landmark 4-99

PRES TEMP GORSP GORST SVF GRVG

pk tk gspk gstk svfk gk
. . . . . .
(WT . w1 w2 w3 w4)
. . . . . .
. . . . . .
pn tn gspn gstn svfn gn
Definitions:
zi The mole fraction of component i in the feed to

the first stage of the separator battery.
o
ai a for component i either at reservoir conditions
if it is entered after the keyword OMEGA, or at
surface conditions if it is entered after the key-
word OMEGAS.
o
bi b for component i either at reservoir conditions
if it is entered after the keyword OMEGB, or at
surface conditions if it is entered after the key-
word OMEGBS.
point. The pressure units are specified by one of
the labels PSIA, PSIG, KPA, or KG/C2.
METRIC The METRIC keyword causes gas-oil ratio values
to be printed in metric units of SCM/STCM
rather than the (default) English units of SCF/
STB. (Input optional.)
bo Oil formation volume factor, barrels of saturated
oil at bubblepoint pressure and reservoir temper-
ature per barrel of stock tank oil at standard con-
ditions. (Optional).
api API gravity of stock tank oil at standard condi-
tions. (Optional).
gort The total gas-oil ratio calculated by separation
through all stages to surface conditions. Units are
standard cubic feet of gas per stock tank barrel of
oil.
pk The operating pressure of separator stage k, in
same units as for psat.
4-100 Landmark - R2003.4

tk The operating temperature of separator stage k,

in same units as for t.
gspk Gas-oil ratio in cubic feet of gas at standard con-
ditions per barrel of oil at pressure and tempera-
ture for stage k.
gstk Gas-oil ratio in cubic feet of gas at standard con-
ditions per barrel of stock tank oil at standard
conditions for stage k.
svfk Separator volume factor, barrels of oil at tempera-
ture and pressure of stage k per barrel of stock
tank oil at standard conditions.
gk Specific gravity of flashed gas from stage k.
d Oil density at t and psat (lb/cu ft, LB/FT3) or
(gm/cc, GM/CC). This option should be used for
oil samples. (Optional)
z Gas z-factor at t and psat. This option should be
used for gas samples. (Optional)
tstd Standard temperature in units specified on TEMP
entry. Default is 60 F. (Optional)
pstd Standard pressure in units specified on BUBPT/
DEWPT entry. Default is 14.7 psia. (Optional)
bg Gas formation volume factor, barrels of gas at t
and psat per thousand standard cubic feet of gas.
(Optional)
w Weight factors for bo, bg, api and measured
quantities at each separation stage. (Optional)
Weight factors for bo, bg and/or api can be specified by including

the keyword WT followed by a weight factor in the respective
BO/BG and/or API entries.

separation stage can be specified by inserting a card following a
stage input, with the keyword WT followed by a string of
weights corresponding to the number of measurements.
By default, weight factor for all measured quantities is 1.
2. Calculation of Formation Volume Factors:
R2003.4 - Landmark 4-101

The entries, TEMP, BUBPT/DEWPT and DNSAT/ZSAT must be

entered for calculating bo/bg. Formation volume factors are
calculated as,
Vsat/Vst
Vsat = (Molecular Weight)/d for oils

= zRT/psat for gases
Vst is oil or gas volume at standard conditions after separation.

Data written to this file from separator tests will be syntactically
correct for input into VIP-ENCORE.
Example:
C --------------------------------------------------
C SEPARATOR TEST (REGRESSION)
C --------------------------------------------------
SEP
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
0.064447 0.020473 0.010029 0.004951
TEMP 256 F
DEWPT 6010 PSIG
TSTD 75.
PSTD 0.
API 49.3
GORT 4699.7
450. 75. X 4276.1 X X
100. 75. X 0212. X X
0. 75. X 0211.6 X X
4-102 Landmark - R2003.4

Chapter
5
Automatic Parameter Adjustment
5.1 Introduction
A nonlinear regression package built into DESKTOP-PVT allows
automatic adjustment of the EOS properties of individual components. An
objective function measures the quality of the match between
experimental data and simulated phase behavior. The objective function is
defined as the sum of the squares of the weighted residuals. For example,
n 2
Q= w i res i (5-1)
i=1
where
Q = The objective function.

n = The total number of observations.
wi = Weight factor for observation i.
resi = Residual for observation i:
For each physical quantity, the residual is defined
as
resi = (icalc - iobs)/iobs
except for liquid fractions and mole fractions, in
which case the residual is defined as
resi = icalc - iobs
where
icalc = A calculated physical quantity.

iobs = The measured physical quantity.
Weight factors have default values which can be replaced by using the
keyword WT.
Regression variables are used to alter the initial values of various EOS
R2003.4 - Landmark 5-103

Automatic Parameter Adjustment DESKTOP-PVT Keyword Reference Manual
properties, usually by multiplying the initial value. For example:
init
T ci = X j T ci (5-2)
where
Xj = Regression variable j.
Tci = The current critical temperature of component i,
R, (K).
init
T ci = The initial critical temperature of component i, R,
(K).
The lone exception to this method of modifying parameters is the

treatment of binary interaction coefficients:
init
d ik = d ik + ( X j 1 ) (5-3)
where
Xj = Regression variable j.
dik = The binary interaction coefficient between com-
ponents i and k.
init
d ik = The initial binary interaction coefficient between
components i and k.
With this treatment of the regression variables, using values equal to 1.0
for all variables is equivalent to using the unaltered EOS properties.
Furthermore, there is no limitation on the use of single regression variable
to modify multiple EOS properties. For example, a single variable might
o +
frequently be used to modify the a parameter of all of the C 7
components. This lends certain consistency to the parameter modification.
The regression data appears as a block of data beginning with a REGRESS

card and ending with an ENDREG card. This block of data is placed at the
beginning of the data deck, preceding the EOS card. If you do not want to
modify any of the EOS parameters, simply omit the entire block of data.
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DESKTOP-PVT Keyword Reference Manual Automatic Parameter Adjustment
5.2 EOS Property Adjustment (REGRESS)

This keyword tells the program that EOS properties are to be adjusted.
REGRESS (COMP)
Definition:
COMP Only compositional data will be used to adjust EOS

properties. Default is to use all data. (Input
optional)
5.3 Regression Variable Data (VARIABLE)

The following data sets the initial value of each regression variable and
establishes upper and lower bounds on each variable.
VARIABLE MIN INIT MAX

i xmini xi xmaxi
. . . .
. . . .
. . . .
Definitions:
i The number of regression variable. These should

range from 1 to the total number of variables.
Order is not important.
xmini The smallest value allowed for variable i. A value
of 0.8 is suggested.
xi The initial value for variable i. This is normally
1.0 on the first attempt. If additional runs are
made, the last set of values from a previous run
may be used.
xmaxi The largest value allowed for variable i. A value

of 1.2 is suggested.
R2003.4 - Landmark 5-105

5.4 Nonlinear Regression Process (IMAX)

This data controls the operation of the nonlinear regression process. In
most cases the default values should be used, allowing this data to be omitted.
The use of this data is described in the Users Reference Manual for
ROTDIS, included as an appendix.
IMAX IPRINT H TOL1 TOL2 TOL3

imax iprint h tol1 tol2 tol3
Definitions:
imax The maximum number of iterations allowed.

Default is 5.
iprint Controls the quantity of output. Allowed values
are 0, 1, and 2. A value of 0 provides only the val-
ues of the objective function and the regression
variables at each regression iteration. A value of 1
also includes a table of calculated and observed
values. A value of 2 also includes details of the
internal regression calculation. Default is 1.
h Controls the length of the search vector. Default
is 0.2.
tol1 A tolerance used as a convergence criterion. (The
required length of the X vector.) Default is 0.001.
tol2 An increment used to perturb variables in order
to compute numerical derivatives. Default is
0.001.
tol3 A tolerance used as a convergence criterion. (The
required reduction in the sum-of-squares from
one iteration to the next.) Default is 0.01.
NOTE: Enter the alpha label X to obtain the default value for any parameter.
5-106 Landmark - R2003.4

5.5 Assignment of Regression Variables

The regression variables are assigned in much the same way that the EOS
properties are defined. Regression variable numbers are simply entered in
the places where data would appear in the PROPERTIES data (Section 2.4)
and DJK data (Section ).
COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB PCHOR VSHFT

cmpi xmwi xtci xpci xzci xwi xai xbi xpchori xsi
VSHFTD VSHFTE
xd xe
DJK cmpj
cmpk xdjk
REGZ
COMP Z
cmpn xzn
LBC
l xl
. .
ENDLBC
VISK
l xj
. .
. .
VISKJ
k j xxkj or cmpk cmpj xxkj
. . . . .
. . . . .
. . . . .
ENDVIS
KVCOR
COMP A B C D E
cmpi xai xbi xci xdi xei
. . . . .
. . . . .
CO2COR
ACOEF xa0 xa1 xa2 xa3 xa4
BCOEF xb0 xb1 xb2 xb3 xb4
CCOEF xc0 xc1 xc2 xc3 xc4
SCOEF xs0 xs1
DCOEF xd1
ENDCO2
R2003.4 - Landmark 5-107

Definitions:
cmpi Component name for component i. Must be iden-

tical to one of the names included in the COM-
PONENTS data.
xmwi The number of the regression variable that will be
used to adjust the molecular weight of the com-
ponent i. Enter the alpha label X if it is not to be
regressed.
xtci The number of the regression variables that will
be used to adjust the critical temperature of com-
ponent i. Enter the alpha label X if it is not to be
modified.
xpci The number of the regression variables that will
be used to adjust the critical pressure of compo-
nent i. Enter the alpha label X if it is not be modi-
fied.
xzci The number of the regression variables that will
be used to adjust the critical z-factor of compo-
nent i. Enter the alpha label X if it is not to be
modified. (This affects only viscosity calcula-
tions.)
xwi The number of the regression variable that will be
used to adjust the acentric factor of component i.
Enter the alpha label X if it is not to be modified.
xai The number of the regression variable that will be
used to adjust the a parameter of component i.
xbi The number of the regression variable that will be
used to adjust the b parameter of component i.
xpchori The number of the regression variables that will
be used to adjust the Parachor of component i.
(Input optional) Enter the alpha label X if it is not
to be modified. (This affects only interfacial ten-
sion calculations.)
xsi The number of the regression variables that will
be used to adjust the volume shift parameter of
component i. (Input optional) Enter the alpha
label X if it is not to be modified.
xd, xe Parameters d and e for computing volume shift
parameter s,
5-108 Landmark - R2003.4

s = 1 - d M-e
The default value for d is 1.74 and is 0.133 for e.
(Input optional) Enter the alpha label X if it is not
to be modified. These regression parameters are
applied to the non-internally defined compo-
nents only. Additionally, this option can not be
used if the xsi option has been invoked for these
components.
cmpj Component name of one component in a binary
mixture.
cmpk Component name of the second component in a
binary mixture.
xdjk The number of the regression variable that will be
used to adjust the binary interaction coefficient
for component j and component k.
cmpn Component name of component n for component
composition regression. Must be identical to one
of the names included in the COMPONENTS
data.
xzn The number of the regression variables that will
be used to adjust the component composition of
component n.
xl The number of the regression variables that will
be used to adjust the Cl values for calculation of
the phase viscosity using the Lohrenz-Bray-Clark
correlation. Here l is the index for Cl.
xj The number of the regression variables that will
be used to adjust the kj values for calculation of
the viscosity of the reference component in the
Pedersen et al. viscosity correlation. Here j is the
index for kj.
xxkj The number of the regression variables that will
be used to adjust the binary interaction coeffi-
cient xkj for calculating pseudo-critical tempera-
ture used indices in the Pedersen et al. viscosity
correlation. Here k (cmpk) and j (cmpj) are the
component indices (names).
xai to xei The number of regression variable that will be
used to adjust the coefficients A to E of K-value
correlation of component i. The component K-
value correlation is expressed as
R2003.4 - Landmark 5-109

B Di
Ki = A i + -----i + C i P exp ---------------
P T E i
where Ai to Ei are constant coefficients for com-

ponent i, P is pressure in psia and T is tempera-
ture in Rankin.
xa0 to xa4 The number of the regression variables that will
xb0 to xb4 be used to adjust the correlation coefficients that
xc0 to xc4 are used in computing solubility of carbon
dioxide in pure water. The correlation is shown in
Section 2.9.
xs0 and xs1 The number of the regression variables that will
be used to adjust the correlation coefficients that
are used in computing the effects of salinity on
carbon dioxide solubility in water. The correla-
tion is shown in Section 2.9.
xd1 The number of the regression variables that will
be used to adjust the correlation coefficients that
are used in computing density of carbon dioxide
saturated water. This density is then used in com-
puting water formation volume factor. The corre-
lation is shown in Section 2.9.
NOTE: 1. Attempting to adjust too many parameters simultaneously is

likely to create an ill-conditioned problem. The result may be to
generate physically meaningless values for some parameters. It is
wise to try to limit the number of variables.
2. A single variable can be used to modify the same property of

multiple components. When this is done, the various components
using the same variable should be closely related, such as heavy
fractions. This is frequently done for binary interaction
parameters.
3. Component cards are entered only for components that will be

adjusted. Others are simply omitted from the data.
4. The keyword REGZ is used to indicate regression on component

composition. A maximum of NC - 1 components may be
regressed upon. A regression variable of zero must be assigned to
a component composition which is used to preserve the mole
fraction constraint.
5. Water appears implicitly as a component in some experiments

associated with VIP-THERM (STMDIS and PSATW). Binary
interaction coefficients for water may be regressed upon by using
the alpha label H2O for cmpj or cmpk.
5-110 Landmark - R2003.4

5.6 End of Regression Data (ENDREG)

This keyword is used to terminate the regression data.
ENDREG
Example:
The data which follows defines a set of regression variables for tuning the
equation of state. The seven regression variables are the a and b of each
of three heavy fractions and the binary interaction coefficient between
methane and all the heavy fractions. Use a range of .7 to 1.25 for the
interaction coefficient variable. Use a maximum of ten regression
iterations and request maximum output.
REGRESS
VARIABLE MIN INIT MAX
1 X X X
2 X X X
3 X X X
4 X X X
5 X X X
6 X X X
7 .7 X 1.25
10 2 X X X X
HVY1 X X X X X 1 2
HVY2 X X X X X 3 4
HVY3 X X X X X 5 6
DJK C1
HVY1 7
HVY2 7
HVY3 7
ENDREG
R2003.4 - Landmark 5-111

5-112 Landmark - R2003.4

Chapter
6
Pseudoization
DESKTOP-PVT provides a calculation to combine components through a
process called pseudoization. The original fluid system is reduced to a
pseudo system by specifying which of the original components will be
lumped into which pseudo component.
This procedure is consistent with both the equation-of-state and the

viscosity correlation, in that the density and viscosity of the original
system is preserved in the pseudo system. Experience has shown that the
saturation pressure of the pseudo system may be slightly in error, but can
be easily adjusted through regression.
PSEUDO
F
TEMP t C
R
K
PSIA
BUBPT psat PSIG
DEWPT KPA
KG C2
PCMP1 one or more of CMPi

PCMP2 one or more of CMPi
. .
. .
. .
PCMPm one or more of CMPi
ENDCMP
R2003.4 - Landmark 6-113

Pseudoization DESKTOP-PVT Keyword Reference Manual
Definitions:
zi Mole fraction of component i in the original fluid

system. The number of values must equal the total
number of components defined in the component data
(Section 2.3).
t A value of temperature in units specified by one of

the labels F, C, R, or K. If no label is entered, the
temperature is in F.
psat The saturation pressure of the fluid at temperature t.

The label BUBPT or DEWPT indicates whether the
fluid has a bubblepoint or a dewpoint, and the
pressure units are specified by one of the labels PSIA,
PSIG, KPA, or KG/C2.
PCMPm An alphanumeric label that identifies pseudo

component m.
CMPi An alphanumeric label that identifies component i of

the original fluid system. This must agree with one of
the component names defined in the component
properties data.
Example:
C
C PSEUDOIZATION FROM 10 TO 5 COMPONENTS
C
EOS PR
COMPONENTS
CO2 N2 C1 C2 C3 NC4 NC5 NC6 C15 C20
PROPERTIES
ENDEOS
PSEUDO
COMPOSITION .015 .006 .732 .061 .042 .038 .034 .039 .021 .012
TEMP 251 F
DEWPT PSIG 4354
P1 C1 CO2
P2 C2 N2
P3 C3 NC4 NC5 NC6
P4 C15
P5 C20
ENDCMP
END
6-114 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Pseudoization
NOTE: 1. A pseudoization calculation may not be performed during a

regression run. In addition, each original component must be
included in one pseudo component.
2. On completion of the pseudoization, EOS parameters of the

pseudo system are written to a file.
3. DESKTOP-VIP allows the calculation of any laboratory test

following the pseudoization calculation.
R2003.4 - Landmark 6-115

Pseudoization DESKTOP-PVT Keyword Reference Manual
6-116 Landmark - R2003.4

Chapter
7
Heavy Fraction Characterization
DESKTOP-PVT provides a method to calculate a heavy fraction
characterization from laboratory measured properties of the heavy
fraction. Based upon user supplied heavy fraction molecular weight and
specific gravity, the program generates an extended analysis using a
modification of Whitsons method. The extended analysis can be
pseudoized into a user specified number of components or into a program
calculated number of components.
R2003.4 - Landmark 7-117

Heavy Fraction Characterization DESKTOP-PVT Keyword Reference Manual
The heavy fraction characterization procedure is a stand-alone calculation.

Only the data given below should be entered. After a fluid system has
been characterized, the user should enter the resulting component
properties in a subsequent program run to perform additional
calculations.
SPLIT
MWPLUS GPLUS ZPLUS (WTPLUS) (NCOMP NG ALPHA NLAST ETA WAT MAXIT MW MWGRP)
mwplus gplus zplus (wtplus) (ncomp ng alpha nlast eta wat maxit
mwgrp1 mwgrp2 . . .mwgrpng-1)
CORRELATION SIMULATION
PROPERTY
GENERALIZED EXPERIMENT
RIAZI DAUBERT

TC KESLER LEE

CAVETT
RIAZI DAUBERT

PC KESLER LEE

CAVETT
RIAZI DAUBERT
ZC
RIEDEL PITZER
EDMISTER

ACENTRIC KESLER LEE

WHITSON
PC ACENTRIC
ADJUST
VSH ACENTRIC
CONMWI

( MWC6C7 mwc6c7 )

( MWINIC mwinc )
VARMWI

MWBOUND

SCN MWBOUND

SCN ncomp MWBncomp

SCN MWB
K K

SCN MWB
nlast nlast
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DESKTOP-PVT Keyword Reference Manual Heavy Fraction Characterization
REGRES

MAXALPHA alpha
max
MINALPHA alpha
min

SCN MWSCN ZSCN SGSCN TBSCN
WTSCN

scn ncomp m w ncomp z ncomp sg ncomp tb ncomp

scn k m wk zk sg k tb k

scn nlast m w nlast z nlast sg nlast tb nlast
Definitions:
mwplus Molecular weight of the plus fraction.

gplus Specific gravity of the plus fraction, measured at
14.7 psia and 60 F.
zplus The mole fraction of the total fluid sample con-
tained in the heavy fraction.
ncomp The carbon number of the heavy fraction, i.e., for
+ +
C 7 enter 7, for C 10 enter 10. The default value is
7. (Input optional)
ng The number of pseudo component groups in the
final fluid system. A value of zero will instruct
the program to compute the optimal number of
components.
alpha A parameter in the gamma distribution. The
default value is 1. See note (1) below and refer-
ence [3]. (Input optional)
nlast The carbon number of the last component to be
considered in the extended distribution. The
default value is 45. (Input optional)
eta The minimum molecular weight expected to
occur in the plus fraction. The default value is
calculated from 14 x ncomp -6. (Input optional)
wat The average Watson characterization factor for
the entire plus fraction, in the range of 10 to 13. If
wat is not input, its value is calculated such that
the computed specific gravity of the plus fraction
equals the measured value, gplus. (Input
optional)
R2003.4 - Landmark 7-119

mwgrp The bracket molecular weights for the purpose of

regrouping the extended fractions into pseudo
components. For a specified value of ng, ng-1
molecular weight values must be entered. For
example, if ng is 3, two values must be entered
for mwgrp. All extended fractions with molecu-
lar weight less than or equal to mwgrp1 will be
lumped into pseudo component 1. All extended
fractions with molecular weight less than or
equal to mwgrp2 will be lumped into pseudo
component 2. All remaining fractions will be
lumped into pseudo component 3. This data is
optional. If mwgrp is present, the value of ng
must be equal to or greater than 2, and the ng
entry must be ahead of the mwgrp entry. (Input
optional)
wtplus The weight fraction of the plus fraction. The
WTPLUS keyword causes the component weight
fractions in the plus fraction to follow the gamma
distribution. See Note (1) below. (Input optional)
maxit The maximum number of iterations allowed to
adjust alpha to match the measured molar or
weight distribution data. The default value is 20.
(Input optional)
PROPERTY The PROPERTY keyword allow the user to spec-
ify the method for equation-of-state (EOS)
parameters calculation, e.g. Pc, Tc, etc. (Input
optional)
The EOS parameters are computed from correla-
tions (default) if the CORRELATION keyword is
entered after the PROPERTY keyword. The EOS
parameters are determined by table lookup using
the internally defined data given in Table 2-2 if
the GENERALIZED keyword is entered after the
PROPERTY keyword.
The keywords SIMULATION and EXPERI-
MENT indicate if SIMULATION or EXPERI-
MENTal data of molecular weights, specific
gravities, etc. are used to calculate EOS parame-
ters. The default is SIMULATION.
TC The keyword TC allows the user to select a criti-
cal temperature correlation. The options are
RIAZI-DAUBERT correlation (default), KESLER-
LEE correlation and CAVETT correlation. (Input
optional)
7-120 Landmark - R2003.4

PC The keyword PC allows the user to select a criti-

cal pressure correlation. The options are RIAZI-
DAUBERT correlation (default), KESLER-LEE
correlation and CAVETT correlation. (Input
optional)
ACENTRIC The keyword ACENTRIC allows the user to
select an acentric factor correlation. The options
are EDMISTER correlation (default), KESLER-
LEE correlation and WHITSON correlation.
(Input optional)
ADJUST The keyword ADJUST causes modifications of
the plus fraction component EOS parameters
from correlations to match the component spe-
cific gravity and normal boiling point. The
default is no adjustment. (Input optional)
The component critical pressure and acentric fac-
tor are adjusted if the keyword PC/ACENTRIC
is used, and the component volume shift parame-
ter and acentric factor are adjusted if the keyword
VSH/ACENTRIC is used.
CONMWI The keyword indicates a constant molecular
weight interval is used to compute the molar (or
weight) distribution. This is the default. (Input
optional)
mwc6c7 The upper molecular boundary of C6. The default
value is calculated from 84 + 0.5 x mwinc. This
input must follow the keyword CONMWI imme-
diately. (Input optional)
mwinc The constant molecular weight interval for com-
puting the molar (or weight) distribution. The
default is 14. (Input optional)
VARMWI The keyword indicates a variable molecular
weight interval is used to compute the molar (or
weight) distribution. (Input optional)
scnk The carbon number of the heavy fraction compo-
nent k. These numbers must increase consecu-
tively from ncomp to nlast. (Input optional)
R2003.4 - Landmark 7-121

mwbk The upper molecular weight boundary of the

heavy fraction component k. The keyword
MWBOUND, and the scnk and mwbk input must
follow the keyword VARMWI immediately. This
option is applicable only if the REGRES keyword
is not used. The defaults are the mid value of the
internally defined molecular weight data given in
Table 2-2 . (Input optional)
REGRES The keyword REGRES causes the adjustment of
the alpha value in the gamma function to match
the measured molar or weight distribution data.
The default is no adjustment. (Input optional)
alphamax The maximum alpha allowed during adjustment.
The default is 3. (Input optional)
alphamin The minimum alpha allowed during adjustment.
The default is 0.5. (Input optional)
mwk The molecular weight of the heavy fraction com-
ponent k. (Input optional)
zk The mole fraction or weight fraction of the heavy
fraction component k in the hydrocarbon mix-
ture. If ZSCN keyword is used, zk is the mole
fraction, and if WTSCN keyword is used, zk is
treated as the weight fraction. The keyword
WTSCN must be entered, if the keyword
WTPLUS is entered. Otherwise, the keyword
ZSCN must be used and the zk value is assumed
mole fraction. (Input optional)
sgk The specific gravity of the heavy fraction compo-
nent k. the alpha label X can be entered only if
the EXPERIMENT option in the PROPERTY key-
word is not used. (Input optional)
tbk The normal boiling point temperature in degree F
of the heavy fraction component k. The alpha
label X can be entered only if the EXPERIMENT
option in the PROPERTY keyword is not used.
(Input optional)
NOTE: 1. Extended Analysis:
An extended analysis of the plus fraction is calculated assuming

the carbon numbers in the plus fraction follow the gamma
distribution. The user is required to define the shape of the
gamma function. For example, alpha should be specified. By
default, alpha is 1 (exponential). Suggested values should lie in
the range of 0.5 (accelerated exponential) to 1.5 (skewed normal).
7-122 Landmark - R2003.4

2. EOS Parameters:
A constant Watson factor is assumed for all carbon numbers in

the plus fraction. Gravities and boiling points of the carbon
numbers are then calculated from molecular weights and the
Watson characterization factor as proposed by Whitson.
3. Extended Analysis Pseudoization:
Pseudoization of the calculated extended analysis is performed

using Sturges rule.
4. Parameter Output:
On completion of the split, EOS parameters of the heavy fraction

are written to a file.
Example:
The following data is available concerning the properties of the heavy

fraction of an oil sample:
Molecular weight of the heavy fraction .0218

Gravity of the heavy fraction .8515
Mole fraction of the heavy fraction .3329
Carbon number of the heavy fraction .0007
Use a distribution parameter of .75 to generate an extended analysis for

this fluid. Group this extended analysis into four heavy pseudo-
components.
SPLIT
MWPLUS GPLUS ZPLUS NCOMP NG ALPHA
218. 8515 .3329 7 4 .75
END
Example:
The alpha parameter of the gamma function is adjusted in this example to

match the distillation data of a gas sample:
SPLIT
MWPLUS GPLUS ZPLUS NCOMPNG NLAST ALPHA ETA
141.28 0.79293 0.0154 7 16 22 1.0 93
C
PROPERTY CORRELATION
TC RIAZI-DAUBERT
PC RIAZI-DAUBERT
ACENTRIC EDMISTER
ADJUST VSH/ACENTRIC
C
CONMWI
MWINC 14
C
REGRES
R2003.4 - Landmark 7-123

MAXALPHA 3.0
MINALPHA 0.5
C
SCN MWSCNZSCN SGSCN TBSCN
7 100.00.003610.745 209.19
8 114.00.002850.753 258.22
9 128.00.002220.773 303.45
10 142.00.001580.779 345.44
11 156.00.001210.793 384.60
12 170.00.000970.804 421.32
13 184.00.000830.816 455.87
14 198.00.000690.836 488.48
15 212.00.000500.840 519.35
16 226.00.000340.839 548.71
17 240.00.000230.835 576.63
18 254.00.000150.850 603.3
19 268.00.000100.865 628.81
20 282.00.000060.873 653.24
21 296.00.000040.876 674.0
22 310.00.000020.878 695.0
C
END
7-124 Landmark - R2003.4

Chapter
8
Calculation Controls
8.1 Introduction
The default values for phase behavior calculation parameters in
DESKTOP-PVT are quite adequate for most fluid systems. However, for
some difficult near-critical fluid systems, some parameters in the
saturation pressure and flash calculations may need to be changed from
the default.
The data described in this section allows the user to select alternative flash
calculation methods, specify saturation pressure parameters, specify flash
calculation parameters, specify expansion calculation parameters, and
request debug output. This data should be entered before the keyword
that introduces the laboratory test to which the data should be applied.
8.2 Selection of Flash Method

For flash calculations in DESKTOP-PVT, the user may select the Newton-
Raphson method, the method of accelerated successive-substitution or the
Gibbs energy minimization method. The Newton-Raphson method is the
default. Entry of one of the keywords described below will cause all
succeeding calculations to use that method. The data to select the flash
method should be entered before the keyword that introduces the
laboratory test to which the method should be applied.
NEWTON
SS
GIBBS
Definitions:
NEWTON Use the Newton-Raphson flash calculation

method, which is the default method.
SS Use the accelerated successive-substitution flash
calculation method. This method may be
required for some difficult fluids that do not con-
verge with the Newton-Raphson method.
R2003.4 - Landmark 8-125

Calculation Controls DESKTOP-PVT Keyword Reference Manual
GIBBS Use the Gibbs energy minimization method for

flash calculation.
Example:
Use the accelerated successive-substitution calculation method for a

constant composition expansion test and switch to the Newton-Raphson
method for a differential expansion test.
EOS PR
.
.
.
ENDEOS
C
C --------------------------------------
C SELECT THE SS METHOD
C --------------------------------------
SS
C
CCEXP
.
.
.
C
C----------------------------------------------------------------
C SELECT THE NEWTON-RAPHSON METHOD
C ---------------------------------------------------------------
NEWTON
C
DIFF
.
.
.
END
8.3 Saturation Pressure Tolerance Card

The user may change any of the parameters which control the
convergence of the saturation pressure calculation in DESKTOP-PVT. Any
or all of the keywords described below may be entered in any order on the
parameter names data card. The data values which occur on the card
following the parameter names data card must be in the same order as the
parameter names.
KNTMXS DPMXS DXMXS TOLPS TOLXS TOLKS TOLS

knt dp dx tolp tolx tolk tol
8-126 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Calculation Controls
Definitions:
knt The maximum number of iterations in the satura-

tion pressure calculation. Default value is 40.
dp The maximum change in pressure for an iteration
when searching for a saturation pressure. Default
value is 500. psia.
dx The maximum change in composition for an iter-
ation in the saturation pressure calculation.
Default value is .05.
tolp Convergence criterion for pressure change
between iterations of the saturation pressure cal-
culation.
tolx Convergence criterion for composition change
between iterations of the saturation pressure cal-
culation. Default value is .00001.
tolk Tolerance for the heavy component K-value dur-
ing the saturation pressure calculation. The calcu-
lation will fail if the heavy component K-value is
less than 1.-tolk. Default value is .00001.
tol Convergence tolerance for the scaled changes of
mole fraction and pressure during the saturation
pressure calculation. The calculation will fail if
the changes are less than tol. Default value is
.00001.
Example:
Change the number of saturation pressure calculation iterations to 50 and

change the maximum pressure interval to 250. psia. Also adjust the heavy
component K-value tolerance to .0001.
KNTMXS TOLKS DPMXS

50 .0001 250.
R2003.4 - Landmark 8-127

8.4 Flash Calculation Tolerance Card

The user may change any of the parameters which control the
convergence of the flash calculations in DESKTOP-PVT or all of the
keywords described below may be entered in any order on the parameter
names data card. The data values which occur on the card following the
parameter names data card must be in the same order as the parameter
names.
KNTMXF DXMXF DRIFT TOLXF TOLKF TOLF

knt dx drift tolx tolk tol
Definitions:
knt The maximum number of iterations in the flash

calculation. Default value is 20.
dx The maximum target change in composition and
liquid/vapor fraction for an iteration in the flash
calculation. Default value is .05.
drift The maximum amount of deviation for the target
change in liquid/vapor fraction allowed in the
flash calculation. Default value is .01.
tolx Convergence criterion for composition and liq-
uid/vapor fraction changes between iterations of
the flash calculation. Default value is .00001.
tolk Tolerance for the heavy component K-value dur-
ing the flash calculation. The calculation will fail
if the heavy component K-value is less than 1.-
tolk. Default value is .00001.
tol Convergence tolerance for the scaled changes of
mole fraction and liquid/vapor fraction during
the flash calculation. The calculation will fail if
the changes are less than tol. Default value is
.00001.
Example:
Change the number of flash iterations to 35 and change the targeted

composition to .07 and the drift to .005.
KNTMXF DXMXF DRIFT

35 0.07 0.005
8-128 Landmark - R2003.4

8.5 Expansion Tolerance Card

The user may change any of the parameters which control the selection of
pressure intervals in the flash calculations of the expansion tests in
DESKTOP-PVT. Any or all of the keywords described below may be
entered in any order on the parameter names data card. The data values
which occur on the card following the parameter names data card must be
in the same order as the parameter names.
DPMAX DPFAC DPMIN

dpmax dpfac dpmin
Definitions:
dpmax The maximum pressure interval to be used dur-

ing a flash calculation in constant composition,
constant volume, and differential expansion tests.
When flashing from pressure p2 down to pres-
sure p1, if p2-p1 is greater than dpmax, an inter-
mediate flash will be performed at p2-dpmax.
For some difficult fluids, an adjustment of dpmax
may be required for convergence. Default value
is 500. psia.
dpfac The factor for reduction in size of pressure inter-
val when an intermediate flash fails. If the flash
which failed was of size dp, the next intermediate
flash calculation will be of size dp*dpfac. Default
value is .1.
dpmin The minimum pressure interval to be used dur-
ing a flash calculation in constant composition,
constant volume, and differential expansion tests.
If the pressure interval is less than dpmin, the
calculation will be reported as a failure. Default
value is .001 psia.
Example:
Specify a maximum pressure interval of 200. psia, a minimum pressure

interval of 1. psia, and a reduction factor of .25 for flash calculations.
DPMAX DPMIN DPFAC

200. 1. .25
R2003.4 - Landmark 8-129

8.6 Saturation Pressure and Flash Calculations Output

(DBUGS and DEBUGF)
The user may request additional output from the program for saturation
pressure and flash calculations. This output gives detailed print of each
iteration of the calculations, with phase compositions, z-factors, residuals,
and scale factors for each sub-interval. The volume of output can be quite
large, so the user is cautioned to use this option with discretion.
DBUGS ON
OFF
DBUGF ON
OFF
Definitions:
DBUGS Control switch for debug output for the satura-

tion pressure calculation. This switch can be
turned on or off by the appropriate keyword.
Default value for this switch is off.
DEBUGF Control switch for debug output for the flash cal-
culations. This switch can be turned on or off by
the appropriate keyword. Default value for this
switch is off.
Example:
Request debug output for the saturation pressure and flash calculations
for a constant composition expansion, but turn off this output for a
differential expansion. Include the changes to calculation parameters used
in examples in this chapter.
EOSPR
.
.
.
ENDEOS
C
C ------------------------------
C DEBUG OUTPUT ON
C ------------------------------
DBUGS ON
DBUGF ON
8-130 Landmark - R2003.4

C
KNTMXS TOLK DPMXS
50 .0001 250.
KNTMXF DXMXF DRIFT
35 .07 .005
DPMAX DPMIN DPFAC
200. 1. .25
SS
C
CCEXP
.
.
.
C
C
C --------------------------------
C DEBUG OUTPUT OFF
C -------------------------------
DBUGS OFF
DBUGF OFF
C
NEWTON
C
DIFF
.
.
.
END
8.7 Selection of Viscosity Calculation Method

The fluid viscosity can be calculated using either the Lohrenz, Bray, and
Clark (LBC) viscosity correlation [2] (default), the viscosity correlation
described by Reid, Prausnitz and Sherwood (RPS) [5], the Pedersen et al.
viscosity correlation [10, 11], or the cTwu viscosity correlations [12,13].
Entry of one of the keywords described below causes all succeeding
viscosity calculations to use that method.
The keyword that selects the viscosity calculation method should be

entered immediately before the keyword that introduces the laboratory
test to which the method should be applied.
LBC
RPS
VISPE
TWU1
TWU2
R2003.4 - Landmark 8-131

Definitions:
LBC Selects the Lohrenz, Bray, and Clark viscosity cor-

relation. Default.
RPS Selects the viscosity correlation described by
Reid, Prausnitz, and Sherwood.
VISPE Selects the Pedersen et al. viscosity correlation.
TWU1 Select the 1985 Twu viscosity correlation [12]. In
this option, the component viscosities at a given
temperature is first computed using the Twu vis-
cosity correlation. Then the oil viscosity is com-
puted from component viscosities using the
mixing rule
x x x
11 22 ncnc
The Twu viscosity correlation is based on pertur-

bation theory using n-alkanes as a reference. This
correlation is intended to predict liquid viscosi-
ties of petroleum fractions.
TWU2 Select the 1986 Twu viscosity correlation [13]. In
this option, the component viscosities at a given
temperature is first computed using the Twu vis-
cosity correlation. Then the oil viscosity is com-
puted from component viscosities using the
mixing rule
x x x
11 22 ncnc
This correlation uses a corresponding states prin-

ciple based on the viscosities of two reference flu-
ids. This correlation was development to
represent the Watson (viscosity) plot.
Example:
EOS PR
.
.
.
ENDEOS
C
C ---------------------------------------------------------
C SELECT THE LBC VISCOSITY METHOD
C ---------------------------------------------------------
LBC
CCEXP
.
.
.
C
8-132 Landmark - R2003.4

C ---------------------------------------------------------
C SELECT THE RPS VISCOSITY METHOD
C ---------------------------------------------------------
RPS
DIFF
.
.
.
END
R2003.4 - Landmark 8-133

8-134 Landmark - R2003.4

Chapter
9
Composition Specification
Throughout this manual, fluid composition has been entered via the
COMPOSITION data card. In some cases, the composition that is needed
for a calculation is actually the composition of some intermediate step in
another laboratory test. An alternative method of composition
specification is presented here which allows the reference to compositions
from previously entered tests. The tests for which this composition
specification is available include constant composition expansion,
constant volume depletion, swelling, differential expansion, and
composition variations with depth.
The data described below allows the user to replace the COMPOSITION
data card in any of the calculations in this manual with an alternative
specification. The only restriction is that reference to the composition from
a type of test pertains to the most recently entered test of that type in the
data stream.
CCEXPX ccexpxi
CCEXPY ccexpyi
CCEXPZ ccexpzi
CVDEPX cvdepxi
CVDEPY cvdepyi
CVDEPZ cvdepzi
SWELLX swellxi
SWELLY swellyi
SWELLZ swellzi
DIFFX diffxi
DIFFY diffyi
DIFFZ diffzi
ZGRADX zgradxi
ZGRADY zgradyi
ZGRADZ zgradzi
Definitions:
ccexpxi Reference to the composition of the liquid phase

at pressure entry i in the previous constant com-
position expansion test.
ccexpyi Reference to the composition of the vapor phase
at pressure entry i in the previous constant com-
position expansion test.
R2003.4 - Landmark 9-133

Composition Specification DESKTOP-PVT Keyword Reference Manual
ccexpzi Reference to the overall composition at pressure

entry i in the previous constant composition
expansion test.
cvdepxi Reference to the composition of the liquid phase
at pressure entry i in the previous constant vol-
ume depletion test.
cvdepyi Reference to the composition of the vapor phase
at pressure entry i in the previous constant vol-
ume depletion test.
cvdepzi Reference to the overall composition at pressure
entry i in the previous constant volume depletion
test.
swellxi Reference to the composition of the liquid phase
at entry i in the previous swelling test.
swellyi Reference to the composition of the vapor phase
at entry i in the previous swelling test.
swellzi Reference to the overall composition at entry i in
the previous swelling test.
diffxi Reference to the composition of the liquid phase
at pressure entry i in the previous differential
expansion test.
diffyi Reference to the composition of the vapor phase
at pressure entry i in the previous differential
expansion test.
diffzi Reference to the overall composition at pressure
entry i in the previous differential expansion test.
zgradxi Reference to the composition of the equilibrium
liquid phase at depth entry i in the previous com-
position variations with depth.
zgradyi Reference to the composition of the equilibrium
vapor phase at depth entry i in the previous com-
position variations with depth.
zgradzi Reference to the overall composition at depth
entry i in the previous composition variations
with depth.
9-134 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Composition Specification
Example:
Perform a surface separation calculation for the vapor phase at 4000. psig
from a constant volume depletion.
C
C---------------------------------------
C CONSTANT VOLUME DEPLETION
C---------------------------------------
CVDEP
COMPOSITION .0011 .6893 .0864 .0534 .0348 .0178 .0173
.064447 .020473 .010029 .004951
TEMP 256 F
BUBPT 6010 PSIG
PRES 6010 5000 4000 3000 2100 1200 700
C1 .6893 .7069 .7360 .7660 .7777 .7704 .7513
C2 .0864 .0868 .0873 .0883 .0897 .0938 .0983
C .0173 .0148 .0125 .0108 .0101 .0107 .0125
MW C8 C34 158 146 134 123 115 110 109
ZGAS 1.140 1.015 .897 .853 .865 .902 .938
VPROD 0. .06624 .17478 .32927 .49901 .68146 .77902
SLIQ 0. .0780 .2130 .2500 .2440 .2250 .2100
C
C-----------------------------------------
C SURFACE SEPARATION
C-----------------------------------------
SEP
C---------------------------------------------
C REFER TO CONSTANT VOLUME VAPOR AT PRESSURE 3
C---------------------------------------------
CVDEPY 3
C
TEMP 256 F
BUBPT 6010 PSIG
385. 100. X X X X
0. 60. X X X X
R2003.4 - Landmark 9-135

Composition Specification DESKTOP-PVT Keyword Reference Manual
9-136 Landmark - R2003.4

Appendix
A
Unconstrained Minimization of
Least-Squares Functions
A.1 Introduction
The unconstrained minimum of any function Q(x1,x2,...,xn) can occur only
at a stationary point, that is a point where
Q
-------- = 0, i = 1, , n (A-1)
x i
or expressed in vector notation,

Q (X) = 0 (A-2)
If Q' is expanded in a finite Taylor series about some base point Xo, where
o
x1
o
x2
o
X = (A-3)

o
xn
the following expression is obtained:
o T
Q' ( X ) = Q' ( X ) + Q'' ( X ) X + ( X X ) (A-4)
R2003.4 - Landmark A-137

Unconstrained Minimization of Least-Squares Functions DESKTOP-PVT Keyword Reference Manual
2 2 2
------------
Q- Q Q
-------------------------
-------------------------
2 x 1 x 2 x 1 x n
x 1
Q" = (A-5)
2 2 2
Q Q Q

------------------------- ------------------------- ---------------
x n x 1 x n x 2 2
x n
x1 x o
1
x2 x o
2
X = (A-6)

xn x o
n
If the remainder term is neglected, the substitution of this expression into

Equation A-2 results in:
o o
Q' ( X ) + Q'' ( X ) X = 0 (A-7)
Thus X is an approximation to a vector Xs directed from the base point

to a stationary point of the function Q. If Q' is nonsingular, X can be
calculated by:
o 1 o
X = [ Q'' ( X ) ] Q' ( X ) (A-8)
In general, the vector X does not equal Xs; however, it can be used to
update the base point Xo and establish an iterative solution technique:
k o k 1 o k
( X ) = [ Q'' ( X ) ] Q' ( X ) (A-9)
o k+1 o k k
(X ) = ( X ) + ( X ) (A-10)
If the function is sufficiently well behaved, the procedure will converge

rapidly to a stationary point. Unfortunately, it has a number of serious
drawbacks:
1. The stationary point, rather than being a minimum, may actually be a

maximum or a saddle point.
A-138 Landmark -R2003.4

DESKTOP-PVT Keyword Reference Manual Unconstrained Minimization of Least-Squares Functions
2. Unless Q has a simple function form, it is necessary to calculate the

elements of Q"numerically. This can require an excessive amount of
computation time.
3. Quite frequently the iterative procedure will diverge.
These problems make the method outlined above so inefficient and

unreliable that it is of little utility; however, there are variations of the
basic method that overcome its limitations. Two such techniques are the
Gauss-Newton method and the method of rotational discrimination.
A.2 Gauss-Newton Method

For the special case of sum-of-squares objective functions, it is possible to
obtain a good estimate of the second derivative terms in Q without
actually computing second differences. The approximation that makes this
possible is the distinguishing characteristic of the Gauss-Newton
minimization method.
A sum-of-squares objective function is a function that can be expressed in

the following form:
Ri ( X ) ,
2
Q( X ) = (A-11)
i=1
where Ri is the ith residual of the minimization problem. Each of the

residuals may be a nonlinear function of the variables (xi,x2,...,xn).
If Equation A-11 is differentiated with respect to one of the variables, xj,

the following result is obtained:
Q
m
R i
-------- = 2 R i -------- (A-12)
x j x j
i=1
If this expression is now differentiated with respect to a second variable,

xk, the result is:
m R R 2
2 m Ri
Q i i
------------------------ = 2
x k x j ----------
x k x
- -------------- + 2 R ------------------------
i x x (A-13)
i=1 j i=1 k j
Let us now assume that the first sum in this expression is much larger than
the second. This is always a valid assumption if the base point is
sufficiently near the solution to the problem. (If a set of nonlinear
equations is being solved, all of the residuals, by definition, are zero at the
solution, so the second term drops out entirely. In nonlinear regression

problems, the residuals usually are rather evenly distributed between

positive and negative values, so once again the second sum should be
fairly small, and the assumption is valid.)
Once this assumption is made, Equation A-13 reduces to:
2 m R R
Q i i
------------------------ =
x k x j
2 x
----------- -------------- .
x
(A-14)
i=1 k j
Thus, a second derivative of Q is approximated by a sum composed

entirely of products of the first derivatives of its residuals.
If each element of the matrix Q", defined in Equation A-5, is approximated

according to Equation A-14, the resulting matrix G is called a Gauss-
Newton matrix. The Gauss-Newton minimization technique is an iterative
procedure similar to the one defined by Equation A-9, but using G in place
of Q":
k o k 1 o k
( X ) = [ G ( X ) ] Q' ( X ) (A-15)
o k+1 o k k
(X ) = ( X ) + ( X ) (A-16)
In addition to the substitution of G for Q", this method differs from the
previous one in that the vector X is multiplied by a scalar , which may
assume a different value for each iteration. Thus we no longer think of X
as being a direct approximation to Xs, but as an estimate of the direction
in which the minimum lies. By adjusting the value of , we determine how
far along the direction we will move in picking the base point for the next
iteration.
A.3 Advantages of the Gauss-Newton Method

This method has three significant advantages over the basic iterative
procedure defined by Equation A-9.
First of all, the numerical evaluation of the matrix Q" requires at least
n(n+3)/2 evaluations of Q, assuming that the value at the base point is
already known. In contrast, the construction of G requires only n function
evaluations. Therefore, when the computational effort required to perform
a single function evaluation is significant, a Gauss-Newton iteration can
be performed much more rapidly than an iteration of the basic method.
Second, the Gauss-Newton direction X is one that, in the neighborhood

of the base point, always leads to a lower sum-of-squares. Thus, if is
sufficiently small, each iteration of the procedure must result in a reduced
objective function, assuming, of course, that the base point is not itself a
stationary point. This is known as the property of truncation convergence.

The Gauss-Newton has this property because the definition of G insures

that it is either positive definite or positive semi-definite. This means that
none of its eigenvalues in the vicinity of a maximum and a mixture of
positive and negative values near a saddle. Thus G never accurately
approximates Q" near either of these types of stationary points, and the
Gauss-Newton method converges only to minima.
The final advantage of the Gauss-Newton method is that the distance

factor can be used to accelerate convergence. If a one-dimensional search
for the minimum of Q is conducted along the vector [(Xo)k + (X)k] , an
optimum value of can be determined for each iteration. This sometimes
accelerates convergence appreciably, particularly when the original base
point is a great distance from the minimum.
A.4 Defects in the Gauss-Newton Method

The primary objective to the Gauss-Newton minimization method is that
the matrix G is frequently ill-conditioned. If it ever becomes singular, its
inverse does not exist and the method fails. In this situation, G, will have
one or more zero eigenvalues.
Even when the matrix is nonsingular, one of its eigenvalues may be

sufficiently close to zero that it is approaching singularity. This leads to
serious roundoff error in the inverse of G, usually characterized by one or
more values of xi that are unusually large. Even with an optimum choice
of , there will be little or no improvement, in either the sum-of-squares or
the values of the unknowns.
This type of problem is not at all uncommon. It occurs any time that
variable has a negligible effect on the sum-of-squares relative to the
remaining variables. A variable with this characteristic is said to be null-
effect.
The most obvious source of null-effect variables is an overdefined or

unwisely formulated problem. This can be caused by attempting to regress
on a excessively large number of variables simultaneously. Even when a
problem is quite well defined near the minimum, it may be found that one
or more variables are null-effect in other regions of the n-dimensional
space. This is most likely to cause problems when the initial estimates of
the unknown parameters are poor.

A.5 Method of Rotational Discrimination

In its most general form, the method of rotational discrimination can be
applied to objective functions of arbitrary form. However, since we are
presently considering only functions of the sum-of-squares type, we will
present a specialized form of the more general method. The principal
difference is that the least-squares version employs the Gauss-Newton
matrix G, whereas the general method uses the second derivative matrix
Q".
It should be remembered from the previous discussion that the problems

with the Gauss-Newton method are caused by the matrix G being ill-
conditioned. The method of rotational discrimination circumvents these
problems by substituting a diagonalization procedure for the matrix
inversion in calculating X.
Let us consider for the moment a rearranged version of Equation A-15,

omitting the iteration notation:
o o
G X X = Q' X . (A-17)
Now the elements of the matrix G are computed according to
m R R
i i
g kj = 2 X
------------ -------------- .
X
(A-18)
i=1 k j
where gkj is the element located in the kth row and jth column of G. It
should be obvious from this definition that G is a symmetric matrix.
For the particular case of a symmetric matrix, we can always find a matrix
S. such that
T
S G S = D, (A-19)
where
S = [ V 1, V 2, , V n ] (A-20)
Vi is an n-dimensional vector that is orthogonal to the remaining Vj, j

i. (The term "orthogonal" means that the dot product of Vi and Vj is zero.)
D is a matrix whose only nonzero terms appear on the principal diagonal.
The vectors Vi that satisfy these requirements are called the eigenvectors
or characteristic vectors of G. If each of these eigenvectors is normalized so
that its magnitude is one, then the diagonal elements of D are the
eigenvalues of G. These eigenvectors and eigenvalues are readily
calculated by applying an algorithm by Jacobi.

Since we have defined S so that its columns are composed of mutually

orthogonal, normalized vectors, it follows that
T
S S = I (A-21)
where I is the identity matrix, a matrix having only ones on the principal
diagonal and only zeros elsewhere. Making use of this identity and
multiplying both sides of Equation A-17 by ST, we show that
T T T
S G S S X = S Q' . (A-22)
This can be written in a more compact form by defining some new terms
and using Equation A-19:
Q
D Y = ------- (A-23)
Y
where
T
Y = S X (A-24)
Q
-----------
y 1
Q
-----------
y 2
Q T
--------- = S Q = (A-25)
Y

Q
-----------
y n
Since D is a diagonal matrix, the solution to Equation A-23 is simply
1 Q
y i = -------- ------------- , i = 1, , n (A-26)
d ii y i
Once the Y-vector has been calculated, it is a simple matter to convert it

back into a X-vector
.X = SY (A-27)
The X calculated in this manner clearly must be the same as the one
defined by Equation A-15. The net effect of this diagonalization procedure
has been to rotate the X-coordinates about the base point Xo. This
essentially creates a new coordinate system in which the Gauss-Newton
search direction is defined by Y rather than X.

The new coordinate system has a significant advantage over the original
one, however. In the neighborhood of the base point, each of the variables
yi has an effect on Q that is independent of the effects of the other
variables. In general, this is not true of the xi. Because of the local
independence of the yis, the value of each can be altered almost arbitrarily
without destroying the truncation convergence property of the search
direction Y. The only restriction is that each must have the same algebraic
sign as if it were calculated from Equation A-26.
A.6 The Rotational Discrimination Algorithm

The rotational discrimination method, or R-D method, is basically an
empirical scheme for choosing a search vector in terms of the rotated
coordinates, yi, that is either equal or superior to the one defined by
Equation A-26. The logic of the method presupposes that the variables xi
have been scaled, or normalized, in such a fashion that the following
assumptions are valid:
1. Any component of the vector Y, calculated from Equation A-26, that

exceeds some maximum value h is indicative of the matrix G being ill-
conditioned.
2. The eigenvalues of G provide a direct measure of the importance of

the corresponding yis. Any eigenvalue that is many orders of
magnitude smaller than the largest indicates that the corresponding yi
is locally null-effect.
Thus, if yi calculated from Equation A-26 is less than h in magnitude, and

if the associated eigenvalue is sufficiently large, then yi is left unchanged.
Otherwise empirical procedures are used to alter the calculated value.
The basic instructions for the application of the R-D minimization

algorithm are as follows:
1. Select a base point, Xo, and maximum allowable distance factor h.
2. Compute Q and G from Equation A-12 and Equation A-18.
3. Find the eigenvalues and normalized eigenvectors of G. Order D and S

of Equation A-19 so that the dii are in descending algebraic order.
4. Starting with yi, compute the elements of Y according to Equation A-

26,
1 Q-
y i = ------------------- (A-28)
d ii y i
until one of the following occurs:
a: i=n (A-29)

d kk 8
b: ----------- 10 (A-30)
d ii
c: yi > h (A-31)
5. If step 4 is terminated at the kth parameter for reason (b), set yk and
all remaining yi equal to zero and skip to step 7. If it is terminated for
reason (c), then
Q
y k = h sign ----------- (A-32)
y k
6. If there are parameters in the list after the kth one, calculate them
according to the method of scaled steepest descent

Q
-------------

yi

-------------------
yi = yk si (A-33)
Q-
-------------
y k

where si is a scale factor defined by
a
si = P (A-34)
where
0.5- ----------
a = 1 exp ---------
d kk
- . (A-35)
ln
l nP d
ii
(P is a constant, usually in the range of 10-100.)
(This expression produces scale factors that vary from 1 to P as dii

varies between dkk and zero.) If |yi|>h when calculated in this
manner, it should be truncated so that |yi| = h.
7. Convert the resulting Y-vector back into a X-vector by Equation A-27:
X = S Y (A-36)
8. Perform a one-dimensional search for the optimum along the vector
o
X = X + X (A-37)

9. Update the distance factor h according to
hk+1 = hk exp[0.88255 tan-1(0.56654 ln )]
This has the effect of multiplying hk by a factor between 0.25 and 4 as

varies from 0 to . For = 1, hk+1 = hk.
10. Convergence is achieved when either the change in Q over an iteration

is within a tolerance, or the magnitude of X is very small. If
convergence is not met, update Xo and return to step 2.
It is not difficult to demonstrate that the Y calculated in this manner

produces a X with the property of truncation convergence. To do this, we
expand the differential of the objective function with respect to in terms
of the yi variables.
m
dQ Q dy i
--------- =
d --------- -------------
y i d
(A-38)
i=1
The search for vector Y can be expressed as a function of in the following

manner:
For 0 < i < k,
Q
y i = -------- ------------- (A-39)
d ii y i
For i = k,
Q
y i = h sign ----------- (A-40)
y i
For k < i n,
Q Q
--------- ---------
y i y i Q
yi = yk si ---------------- = h si ---------------- sign ----------- (A-41)
Q Q y k
----------- -----------
y k y k
Substituting these expressions into Equation A-38 we obtain
k1
dQ Q 2 1 Q Q
--------- =
d --------- -------- h -------------
y i d ii y k
sign -----------
y k
(A-42)
i=1

Q 2
---------
n y i Q
h si . -------------------
Q
sign -----------
y k
(A-43)
i = k+1 -----------
y k
Since dii, h, and si are all positive by definition, it is obvious that dQ/d is
negative at the base point, and hence truncation convergence is achieved.
This clearly remains true even if one of the yi is truncated, as described in
step 6, or if one of the yi is set to zero as in step 5.


Appendix
B
The Establishment of Bounds on Variables
B.1 Introduction
Oftentimes physical or practical considerations dictate that the value of an
unknown parameter not exceed some upper or lower bound. Porosity, for
example, is restricted by its definition to lie between zero and one.
Similarly, negative values of permeability are physically impossible. At
other times, a reasonably good estimate of the optimum value of some
parameter may be available from previous work. Thus it is known that the
optimum should lie within some relatively narrow range of values.
In such situations, it is usually desirable to establish inequality constraints

on the parameters of a minimization problem. This often speeds
convergence to the proper solution, as well as preventing convergence to
an infeasible or unlikely solution. This is particularly valuable in solving
problems that are ill-conditioned, since it prevents excessively wide
fluctuations in parameter values.
B.2 Our Treatment of Bounded Variables

During the problem definition and initialization state of a least-squares
problem, we require that both a lower bound, ximin, and an upper bound,
ximax be specified for each minimization variable. Furthermore, we require
that the initial estimate of the value of each parameter lie within its
bounds.
Once the problem has been initialized, the base point for each succeeding
iteration is determined by a one-dimensional search for the optimum
along the vector.
X = Xo + . X. (B-1)
If the base point for the iteration lies in the feasible region, we can always
calculate a number max such that the constraints are satisfied for all
max. This number is calculated as follows:
x b x o
i i
max = 0.999 MIN -------------------- (B-2)
x i

R2003.4 - Landmark B-149

The Establishment of Bounds on Variables DESKTOP-PVT Keyword Reference Manual
where MIN is the minimum over all i,
b max
xi = xi if x i > 0, and (B-3)
b min
xi = xi if x i < 0. (B-4)
If the optimum for an iteration is less than max, then the constraints are
inactive and we proceed just as though the problem were unconstrained.
If, on the other hand, the optimum value exceeds the maximum we set
equal to max in computing the base point for the next iteration.
When this is done, the resulting base point will lie very close to the
boundary of the feasible region. Consequently, if the new iteration
produces a similar search direction, the distance from the base point to the
boundary will be very short, and the search direction will be unprofitable.
Therefore, when we find that
n 0.5
2
max ( x )
j
< (B-5)
i=1
where is a small positive number, we modify the minimization

procedure to produce a more profitable search direction.
In calculating this new search direction, we deactivate the variable that is

attempting to violate its bounds, effectively reducing the dimensionality
of the problem. We then recalculate the incremental changes in the
remaining variables and determine a new max. This is done just as before
except that we use a Gauss-Newton matrix that has only (n-1) rows and
columns rather than n. No additional function evaluations are required,
since the necessary derivatives are always stored at the beginning of each
iteration.
If necessary, the dimensionality of the problem for a given iteration can be

reduced still further by repeated application of the above process.
However, regardless of the number of variables deactivated in the
previous iteration, each new iteration begins with the full set of n
variables. Thus a parameter constrained at an upper or lower bound for
several iterations can move back toward the middle of its permitted range
in subsequent iterations.
B-150 Landmark -R2003.4

Appendix
C
One-Dimensional Search Procedure
C.1 Introduction
Each iteration of the minimization program concludes wicne-dimensional
search for the producing the lowest sum-of-squares along the vector
X = Xo + . X (C-1)
The search procedure employed is designed to accomplish the following

objectives:
1. Locate a point at which the sum-of-squares is lower than at the base

point.
2. Determine values of both larger and smaller than the optimum value,
and then perform a quadratic interpolation to estimate the optimum.
3. Perform the smallest number of function evaluations possible without

compromising the first two objectives. This can often mean that opt is
determined with rather low precision; however, it is considered more
productive to compute a new search direction than to further refine the
estimate of opt.
C.2 Assumptions
In order to minimize the number of function evaluations required to locate
opt, we make use of several assumptions.
1. There is only one relative minimum along any given search direction.
2. Objective function is continuous for 0 con, where con is some

positive number.
3. The optimum is always greater than or equal to zero. (This assumes

that the least-squares minimization program has the property of
truncation convergence, discussed in Appendix A.)
R2003.4 - Landmark C-151

One-Dimensional Search Procedure DESKTOP-PVT Keyword Reference Manual
4. There is a high a priori probability that opt is a number close to one.

(This is generally a good assumption except on the first couple of
iterations or when the numerical derivatives used to compute the
search direction are in significant error due to roundoff or truncation
error.)
C.3 Operating Characteristics

The search routine is programmed so that it always performs at least two
function evaluations. Frequently, it will use three or four evaluations on
the first couple of searches and two thereafter. The average number
required for the entire solution will usually fall in the range of 2.3-2.7 per
iteration.
C.4 Description of the Search Procedure

In initiating the 1-D search for a given iteration, the rotational
discrimination program supplies the search routine with the equivalent of
the following information:
Xo - The location of the base point.
X - The search direction.
Qo - The value of the objective function at the base point.

dQ
-------- The derivative of the objective function along the
d
search direction,evaluated at the base point.
max - The maximum permissible value of , discussed in

Appendix B.
max - The largest change in permitted in one step of the

search procedure.
- The increment used by the R-D program to

compute numerical derivatives.
The value of max is determined by the magnitude of the search vector,

the dimensionality of the problem, and the parameter h of the R-D
algorithm:
hn
max = ------------
X
where
n 0.5
X = 2
(X )
i
(C-2)
i=1
C-152 Landmark -R2003.4

DESKTOP-PVT Keyword Reference Manual One-Dimensional Search Procedure
The search normally begins with a function evaluation for =1. (This is
modified when max <1.333.) Then, depending on the value of the
objective function, it follows one of two courses.
When the objective function is smaller than Qo, the search is extended to
larger values of until a point is found where the objective function
increases over the preceeding value. At this point a quadratic
interpolation is used to estimate the location of the minimum.
At the time the interpolation is applied we have saved the value of the
objective function for the three most recent points, Q1, Q2 and Q3,
corresponding to 1, 2, and 3. These points have the following
properties:
Q1 > Q2 < Q3 (C-3)

1 < 2 <3 (C-4)
The minimum of parabola fit to three such points must lie between 1 and
3, its location being given by
C
1 1
test = --- ---------- (C-5)
2 C2
where
Q3 Q1 Q2 Q1 1
C 2 = ------------------------ ------------------------ -------------------------- (C-6)
3 1 1 ( 3 2 )
Q2 Q1
- ( + ) C
C 1 = ----------------------- (C-7)
2 1 2 1 2
The objective function at test may or may not be evaluated, depending on

its proximity to 2.
In situations where the first function evaluation, at = 1, produces an

objective function greater than at the base point, we use another quadratic
interpolation procedure to estimate the location of the minimum. In this
case = 1 serves as an upper bound on the permissible values of . This
interpolation scheme may be applied several times in succession if the
estimated minimum, test, produces an objective function, Qtest, greater
than the base value on each trial. Each time this occurs, the upper bound,
2, is reduced to test from the preceding trial.
In general, the interpolation problem becomes on the fitting a quadratic to
dQ/d, Qo, and Q2 corresponds to 2. The minimum of such parabola
occurs at
R2003.4 - Landmark C-153

One-Dimensional Search Procedure DESKTOP-PVT Keyword Reference Manual
1 C1
test = --- -------- (C-8)
2 C2
where
C 1 = dQ
--------- (C-9)
d
Q2 Qo C 1 2
C 2 = ------------------------------------------------- (C-10)
2
( )
2
In the event that 2 . Xis reduced to a value smaller than , the search
is terminated and opt is set to zero.
C-154 Landmark -R2003.4

Appendix
D
Example Problems
D.1 Example 1
The following example documents the use of DESKTOP-PVT in the
analysis of a fluid sample with an equation-of-state. Included is a standard
laboratory report for a volatile oil sample, with a constant composition
expansion test, a constant volume depletion test, and a surface separation
test. Following the laboratory report are three DESKTOP-PVT program
output listings.
The first listing shows the generation of a heavy fraction characterization

using the SPLIT feature of DESKTOP-PVT. An extended analysis to carbon
number 45 is produced with a pseudoization back to three components.
The resulting component properties are written to a disk file for use in
subsequent runs.
The second listing shows the use of non-linear regression to adjust

equation-of-state parameters to match laboratory measurements. In this
example, a, and b of each of the three heavy components and methane,
and the binary interaction parameters between methane and the heavy
components are adjusted to produce an excellent match of the observed
data.
The third listing shows the adjustment of component zc parameters to

match laboratory measured viscosity data. Note that changes of zc do not
effect the equation-of-state calculated PVT properties. The zc parameters
are used only in the viscosity correlation.
R2003.4 - Landmark D-155

Example Problems DESKTOP-PVT Keyword Reference Manual
D.1.1 Lab Report

CORE LABORATORIES, Inc.
Reservoir Fluid Analysis
Reservoir Fluid Study

for
GOOD OIL COMPANY
Volatile Oil No. 8 Well

Good Oil Company

P.O. Box 100
Oil City, TX
Attention: Mr. John Jones
Subject: Reservoir Fluid Study

Gentlemen:
Samples of separator liquid and vapor were collected from the subject well by a representative of Core
Laboratories, Inc. Presented in this report are the results of a reservoir fluid study performed using these
samples.
The producing gas-liquid ratio was measured to be 2527 cubic feet of separator gas at 14.696 psia and
60F per barrel of stock tank liquid at 60F. This ratio has been corrected for gas gravity and
supercompressibility. In the laboratory it was found that he ratio is equivalent to 2355 standard cubic
feet of separator gas per barrel of separator liquid. This ratio was used in conjunction with the measured
compositions of the separator products to calculate the composition of the well stream material. These
data are reported on page two.
The separator products were physically recombined to the producing ratio and examined in a visual cell
at the reservoir temperature of 276F. During a constant composition expansion a bubble point was
observed at 4375 psig. Comparison of this value to the reservoir pressure indicates that the fluid exists
in an undersaturated condition. Observation of the system at pressures immediately below the bubble
point pressure shows that the liquid exhibits a very rapid shrinkage which indicates this system to be a
volatile oil, or one which is near critical in nature.
Since a large amount of the production from this type of reservoir comes from the gaseous phase, a
constant volume depletion study was performed on a sample of the recombined fluid to enable
calculation of the production during depletion below the bubble point pressure. The depletion consisted
of a series of expansions and constant pressure displacements terminating at the original cell volume.
D-156 Landmark - R2003.4

DESKTOP-PVT Keyword Reference Manual Example Problems
This has the effect of maintaining a constant reservoir volume. The produced gas phase was charged to
low temperature, fractional distillation equipment for analysis and volume measurement. The results of
the depletion are tabulated on page five of the report.
The quantity of plant products available in the gas phases alone is shown on page six. A plant efficiency
of 100 percent has been assumed.
The well stream composition and equilibrium ratios of the literature were used to calculate the stock
tank liquid and sales gas recoveries that will be obtained as the pressure declines from reservoir
pressure to the bubble point pressure. THese recoveries are based upon one MMSCF of the fluid in
place at the bubble point pressure. One MMSCF is the gaseous equivalent of 842.8 barrels of bubble
point liquid.

Good Oil Company Page Two

The viscosity of the liquid phase was measured from pressures exceeding reservoir pressure to
atmospheric pressure. These data are presented on page eight together with the calculated gas phase
viscosity.
The data concerning the shrinkage of the liquid in the reservoir are shown on page nine of this report.
Thank you for this opportunity to be of service. If you have any questions or if we may assist you
further, please do not hesitate to contact us.
Very truly yours,
CORE LABORATORIES, INC.
Manager
















D.1.2 Sample Files

******************************************************************************
* *
* DDDDDD EEEEEEE SSSSS KK KK TTTTTTTT OOOOO PPPPPP *
* DD DD EE SS SS KK KK TT OO OO PP PP *
* DD DD EE SS KK KK TT OO OO PP PP *
* DD DD EEEEE SSSSS KKKK TT OO OO PPPPPP *
* DD DD EE SS KK KK TT OO OO PP *
* DD DD EE SS SS KK KK TT OO OO PP *
* DDDDDD EEEEEEE SSSSS KK KK TT OOOOO PP *
* *
* PPPPPP VV VV TTTTTTTT *
* PP PP V V TT *
* PP PP VV VV TT *
* PPPPPP V V TT *
* PP VVVV TT *
* PP VV TT *
* PP VV TT *
* *
* PHASE BEHAVIOUR PROGRAM *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* LANDMARK GRAPHICS CORPORATION *
* ALL RIGHTS RESERVED *
* *
* VERSION 1998.0.0 CREATED 01 MAR 1998 *
* *
* LL AAAAA N NN DDDDDD M M AAAAA RRRRRR KK KK *
* LL AA AA NN NN DD DD MM MM AA AA RR RR KK KK *
* LL AA AA NNN NN DD DD M M M M AA AA RR RR KK KK *
* LL AAAAAAA NN N NN DD DD M MM M AAAAAAA RRRRRR KKKK *
* LL AA AA NN NNN DD DD M M AA AA RR RR KK KK *
* LL AA AA NN NN DD DD M M AA AA RR RR KK KK *
* LLLLLLL AA AA NN N DDDDDD M M AA AA RR RR KK KK *
* *
* GGGGG RRRRRR AAAAA PPPPPP HH HH IIII CCCCC SSSSS *
* GG GG RR RR AA AA PP PP HH HH II CC CC SS SS *
* GG RR RR AA AA PP PP HH HH II CC SS *
* GG RRRRRR AAAAAAA PPPPPP HHHHHHH II CC SSSSS *
* GG GGG RR RR AA AA PP HH HH II CC SS *
* GG GG RR RR AA AA PP HH HH II CC CC SS SS *
* GGGGG RR RR AA AA PP HH HH IIII CCCCC SSSSS *
* *
***************************************************************************
1 ************************************************
* *
* D E S K T O P - P V T *
* *
* *
* VERSION 1998.0.0 *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* *
************************************************
SEQUENCE
NUMBER CARD IMAGES OF THE INPUT DATA
-------- ---------------------------------------------------------------------
X C
X C EOSPAK EXAMPLE PROBLEM #1
X C GOOD OIL #8 - SPLIT
X C -------------------------
X C
X C ----------------------------------------
X C MW OF PLUS FRACTION 183
X C GRAVITY OF PLUS FRACTION 0.8345
X C MOLE FRACTION OF PLUS FRACTION 0.1420
X C CARBON NUMBER OF PLUS FRACTION 7
X C NUMBER OF GROUP 3
X C DISTRIBUTION PATAMETER (ALPHA) 1.0
X C GROUPING MOLECULAR WEIGHTS 125 130

X C ----------------------------------------
X C
1 S SPLIT
X C
2 S MWPLUS GPLUS ZPLUS NCOMP NG ALPHA MWGRP
3 S 183 0.8345 0.1420 7 3 1.0 125 300
X C
4 S END
1HEAVY FRACTION CHARACTERIZATION
-------------------------------
SPLIT ITERATION SUMMARY

-----------------------
ITR ALPHA M. W.+ GRAV+ NLAST N45 Z45+ MW45+ GV45+

--- ----- ------ ------ ----- --- ------ ------ -------
0 1.000 183.0 0.829 45 45 0.0065 656.0 1.0017
CONTROL DATA
------------
MOLECULAR WEIGHT OF THE PLUS FRACTION ...... MWPLUS 183.00000

SPECIFIC GRAVITY OF THE PLUS FRACTION ...... GPLUS 0.83450
MOLE FRACTION FOR THE HEAVY FRACTION ....... ZPLUS 0.14200
WEIGHT FRACTION FOR THE HEAVY FRACTION ..... WTPLUS 0.00000
CARBON NUMBER OF THE HEAVY FRACTION ........ NCOMP 7
HIGHEST CARBON NUMBER IN THE DISTRIBUTION .. NLAST 45
FINAL NUMBER OF PSEUDO COMPONENT GROUPS .... NG 3
BRACKET MOLECULAR WEIGHTS FOR REGROUPING ... MWGRP 125.00000 300.00000
GAMMA DISTRIBUTION ALPHA PARAMETER ......... ALPHA 1.00000

MINIMUM MOLECULAR WEIGHT IN PLUS FRACTION .. ETA 92.00000
AVERAGE WATSON CHARACTERIZATION FACTOR ..... WAT 0.00000
MAXIMUM NUMBER OF ITERATIONS ............... MAXIT 20
CRITICAL PROPERTIES COMPUTED FROM .......... CORRELATIONS

CRITICAL TEMPERATURE CORRELATION ........... RIAZI AND DAUBERT
CRITICAL PRESSURE CORRELATION .............. RIAZI AND DAUBERT
CRITICAL Z-FACTOR CORRELATION .............. RIAZI AND DAUBERT
ACENTRIC FACTOR CORRELATION ................ EDMISTER
SPECIFIC GRAVITY AND BOILING POINT DATA .... SIMULATION
CONSTANT MOLECULAR WEIGHT INTERVAL ......... MWINC 12.00000

C6 TO C7 MOLECULAR WEIGHT BOUNDARY ......... MWC6C7 92.00000
SCN MOLE WEIGHT MOLE FRACTION WT FRACTION SPEC GRAV BOIL PT F UPPER WAT
DATA CALC DATA CALC DATA CALC DATA CALC DATA CALC MW BD K-FAC
--- ----- ----- ------ ------ ------ ------ ----- ----- ----- ----- ----- -----
7 0. 98. 0.0000 0.0175 0.0000 0.0000 0.000 0.740 0. 218. 104. 11.86
8 0. 110. 0.0000 0.0154 0.0000 0.0000 0.000 0.754 0. 256. 116. 11.86
9 0. 122. 0.0000 0.0135 0.0000 0.0000 0.000 0.767 0. 292. 128. 11.86
10 0. 134. 0.0000 0.0118 0.0000 0.0000 0.000 0.778 0. 327. 140. 11.86
11 0. 146. 0.0000 0.0104 0.0000 0.0000 0.000 0.789 0. 359. 152. 11.86
12 0. 158. 0.0000 0.0091 0.0000 0.0000 0.000 0.799 0. 391. 164. 11.86
13 0. 170. 0.0000 0.0080 0.0000 0.0000 0.000 0.808 0. 421. 176. 11.86
14 0. 182. 0.0000 0.0070 0.0000 0.0000 0.000 0.817 0. 450. 188. 11.86
15 0. 194. 0.0000 0.0061 0.0000 0.0000 0.000 0.825 0. 478. 200. 11.86
16 0. 206. 0.0000 0.0054 0.0000 0.0000 0.000 0.833 0. 506. 212. 11.86
17 0. 218. 0.0000 0.0047 0.0000 0.0000 0.000 0.841 0. 532. 224. 11.86
18 0. 230. 0.0000 0.0041 0.0000 0.0000 0.000 0.848 0. 558. 236. 11.86
19 0. 242. 0.0000 0.0036 0.0000 0.0000 0.000 0.855 0. 583. 248. 11.86
20 0. 254. 0.0000 0.0032 0.0000 0.0000 0.000 0.861 0. 607. 260. 11.86
21 0. 266. 0.0000 0.0028 0.0000 0.0000 0.000 0.868 0. 631. 272. 11.86
22 0. 278. 0.0000 0.0024 0.0000 0.0000 0.000 0.874 0. 654. 284. 11.86
23 0. 290. 0.0000 0.0021 0.0000 0.0000 0.000 0.880 0. 677. 296. 11.86
24 0. 302. 0.0000 0.0019 0.0000 0.0000 0.000 0.885 0. 699. 308. 11.86
25 0. 314. 0.0000 0.0016 0.0000 0.0000 0.000 0.891 0. 720. 320. 11.86
26 0. 326. 0.0000 0.0014 0.0000 0.0000 0.000 0.896 0. 742. 332. 11.86
27 0. 338. 0.0000 0.0013 0.0000 0.0000 0.000 0.901 0. 763. 344. 11.86
28 0. 350. 0.0000 0.0011 0.0000 0.0000 0.000 0.906 0. 783. 356. 11.86
29 0. 362. 0.0000 0.0010 0.0000 0.0000 0.000 0.911 0. 803. 368. 11.86
30 0. 374. 0.0000 0.0008 0.0000 0.0000 0.000 0.916 0. 823. 380. 11.86
31 0. 386. 0.0000 0.0007 0.0000 0.0000 0.000 0.921 0. 843. 392. 11.86
32 0. 398. 0.0000 0.0006 0.0000 0.0000 0.000 0.925 0. 862. 404. 11.86
33 0. 410. 0.0000 0.0006 0.0000 0.0000 0.000 0.929 0. 881. 416. 11.86
34 0. 422. 0.0000 0.0005 0.0000 0.0000 0.000 0.934 0. 899. 428. 11.86
35 0. 434. 0.0000 0.0004 0.0000 0.0000 0.000 0.938 0. 917. 440. 11.86

36 0. 446. 0.0000 0.0004 0.0000 0.0000 0.000 0.942 0. 935. 452. 11.86
37 0. 458. 0.0000 0.0003 0.0000 0.0000 0.000 0.946 0. 953. 464. 11.86
38 0. 470. 0.0000 0.0003 0.0000 0.0000 0.000 0.950 0. 971. 476. 11.86
39 0. 482. 0.0000 0.0003 0.0000 0.0000 0.000 0.954 0. 988. 488. 11.86
40 0. 494. 0.0000 0.0002 0.0000 0.0000 0.000 0.957 0. 1005. 500. 11.86
41 0. 506. 0.0000 0.0002 0.0000 0.0000 0.000 0.961 0. 1022. 512. 11.86
42 0. 518. 0.0000 0.0002 0.0000 0.0000 0.000 0.965 0. 1039. 524. 11.86
43 0. 530. 0.0000 0.0002 0.0000 0.0000 0.000 0.968 0. 1055. 536. 11.86
44 0. 542. 0.0000 0.0001 0.0000 0.0000 0.000 0.972 0. 1071. 548. 11.86
45 0. 656. 0.0000 0.0009 0.0000 0.0000 0.000 1.002 0. 1218. 0. 11.86
1PLUS FRACTION EXTENDED ANALYSIS
-------------------------------
SCN MOL FRAC M. W. TC PC ZC AC GRAV P-R DJK

(F) (PSIA)
--- -------- ------ -------- -------- ------- ------- ------- -------
7 0.01754 97.9 549.83 442.10 0.2651 0.2913 0.7403 0.0368
8 0.01538 109.9 590.04 406.13 0.2590 0.3232 0.7541 0.0388
9 0.01348 121.9 627.43 376.39 0.2536 0.3537 0.7666 0.0405
10 0.01181 133.9 662.45 351.33 0.2488 0.3832 0.7781 0.0421
11 0.01035 145.9 695.46 329.88 0.2445 0.4117 0.7888 0.0436
12 0.00907 157.9 726.71 311.29 0.2406 0.4395 0.7988 0.0450
13 0.00795 169.9 756.43 295.00 0.2371 0.4666 0.8081 0.0463
14 0.00697 181.8 784.68 280.64 0.2338 0.4932 0.8169 0.0476
15 0.00611 193.8 811.82 267.79 0.2308 0.5195 0.8252 0.0487
16 0.00536 205.8 837.86 256.25 0.2280 0.5454 0.8332 0.0498
17 0.00469 217.8 862.91 245.81 0.2254 0.5710 0.8407 0.0509
18 0.00411 229.8 887.07 236.33 0.2230 0.5965 0.8479 0.0519
19 0.00361 241.8 910.41 227.67 0.2207 0.6217 0.8548 0.0529
20 0.00316 253.8 932.99 219.73 0.2185 0.6469 0.8614 0.0538
21 0.00277 265.8 954.88 212.41 0.2165 0.6720 0.8677 0.0547
22 0.00243 277.8 976.12 205.64 0.2146 0.6970 0.8738 0.0555
23 0.00213 289.8 996.76 199.36 0.2127 0.7220 0.8797 0.0564
24 0.00187 301.8 1016.84 193.52 0.2110 0.7470 0.8854 0.0572
25 0.00163 313.8 1036.40 188.06 0.2093 0.7721 0.8909 0.0579
26 0.00143 325.8 1055.48 182.95 0.2077 0.7972 0.8962 0.0587
27 0.00126 337.8 1074.09 178.16 0.2062 0.8225 0.9014 0.0594
28 0.00110 349.7 1092.27 173.66 0.2048 0.8478 0.9064 0.0601
29 0.00096 361.7 1110.04 169.42 0.2034 0.8733 0.9113 0.0608
30 0.00085 373.7 1127.42 165.41 0.2020 0.8989 0.9160 0.0614
31 0.00074 385.7 1144.44 161.62 0.2007 0.9247 0.9206 0.0621
32 0.00065 397.7 1161.12 158.03 0.1995 0.9507 0.9251 0.0627
33 0.00057 409.7 1177.46 154.62 0.1983 0.9769 0.9295 0.0633
34 0.00050 421.7 1193.49 151.38 0.1971 1.0034 0.9338 0.0639
35 0.00044 433.7 1209.22 148.30 0.1960 1.0300 0.9379 0.0645
36 0.00038 445.7 1224.66 145.36 0.1949 1.0570 0.9420 0.0651
37 0.00034 457.7 1239.83 142.56 0.1939 1.0842 0.9460 0.0656
38 0.00029 469.7 1254.74 139.88 0.1929 1.1118 0.9499 0.0662
39 0.00026 481.7 1269.40 137.31 0.1919 1.1396 0.9537 0.0667
40 0.00023 493.7 1283.82 134.86 0.1909 1.1678 0.9574 0.0672
41 0.00020 505.7 1298.01 132.50 0.1900 1.1964 0.9611 0.0678
42 0.00017 517.7 1311.98 130.24 0.1891 1.2253 0.9647 0.0683
43 0.00015 529.7 1325.74 128.07 0.1882 1.2546 0.9682 0.0687
44 0.00013 541.7 1339.29 125.99 0.1874 1.2843 0.9716 0.0692
45 0.00092 656.0 1459.48 109.47 0.1802 1.5921 1.0017 0.0734
1PLUS FRACTION PSEUDOIZATION
---------------------------
NO. MOL FRAC M. W. TC PC ZC AC GRAV P-R DJK

(F) (PSIA)
--- -------- ------ -------- -------- ------- ------- ------- -------
1 0.04640 108.8 585.69 411.09 0.2609 0.3200 0.7533 0.0387
2 0.08054 187.5 790.04 283.80 0.2411 0.5033 0.8239 0.0485
3 0.01507 387.4 1138.35 165.63 0.2067 0.9360 0.9243 0.0626
---------------------------------------------------------------------
AVG 0.14200 183.0 760.23 312.85 0.2643 0.4893 0.8290 0.0493
PLUS PROPERTIES WRITTEN TO UNIT 22

1
**************************************************************************
* *
* *
* PP PP V V TT *
* PP PP VV VV TT *
* PPPPPP V V TT *
* PP VVVV TT *
* PP VV TT *
* PP VV TT *
* *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997 *
* *
* VERSION 4.0 CREATED 01 JUN 1997 *
* *
* *
* *
***************************************************************************
1 *********************************************
* *
* *
* *
* VERSION 4.0 *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997 *
* *
*********************************************
SEQUENCE
-------- ---------------------------------------------------------------------
X C ------------------------------
X C DESKTOP-PVT EXAMPLE PROBLEM #1
X C GOOD OIL #8 - REGRESSION
X C VOLATILE OIL EXAMPLE
X C ------------------------------
X C
X C
X C -------------------------
X C REGRESSION VARIABLES ARE:
X C (1) OMEGA C8
X C (2) OMEGB C8
X C (3) OMEGA C14
X C (4) OMEGB C14

X C (5) OMEGA C30

X C (6) OMEGB C30
X C (7) DJK C1-C8
X C (8) DJK C1-C14
X C (9) DJK C1-C30
X C (10) OMEGA C1
X C (11) OMEGA C1
X C -------------------------
X C
1 R REGRESS
2 R VARIABLE MIN INIT MAX
3 R 1 .7 1. 1.3
4 R 2 .7 1. 1.3
5 R 3 .7 1. 1.3
6 R 4 .7 1. 1.3
7 R 5 .7 1. 1.3
8 R 6 .7 1. 1.3
9 R 7 .7 1. 1.3
10 R 8 .7 1. 1.3
11 R 9 .7 1. 1.3
12 R 10 .7 1. 1.3
13 R 11 .7 1. 1.3
X C
14 R IMAX IPRINT H TOL1 TOL2 TOL3
15 R 20 0 X X X X
X C
16 R COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB
17 R C1 X X X X X 10 11
18 R C8 X X X X X 1 2
19 R C14 X X X X X 3 4
20 R C30 X X X X X 5 6
X C
21 R DJK C1
22 R C8 7
23 R C14 8
24 R C30 9
X C
25 R ENDREG
X C
X C ----------------------------------------
X C INITIALIZE AFTER SPLIT OF HEAVY FRACTION
X C ----------------------------------------
X C
1 EOS PR
2 COMPONENTS
3 CO2 C1 C2 C3 NC4 NC5 C6 C8 C14 C30
4 PROPERTIES
5 COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB
6 C8 108.82 585.69 411.09 0.26093 0.32000 X X
7 C14 187.49 790.04 283.80 0.24105 0.50331 X X
8 C30 387.42 1138.35 165.63 0.20672 0.93601 X X
X C
9 DJK C1
10 C8 0.038665
11 C14 0.048547
12 C30 0.062598
X C
13 ENDEOS
X C
X PVTFILE
X C
X C -------------------
X C SATURATION PRESSURE
X C -------------------
X C
14 PSAT
15 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
16 0.046396 0.080535 0.015069
17 TEMP F 276
18 BPEXP PSIG 4375
X C
X C --------------
X C PHASE ENVELOPE
X C --------------
X C
19 ENVELOPE
20 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
21 0.046396 0.080535 0.015069
22 TEMP F -100 800 10 600 800 10
23 PSAT PSIG 2000 6000 2000 100 300 100
X C

X C --------------
X C LIQUID DENSITY
X C --------------
X C
X C NOTE: LIQUID DENSITY DATA IS GIVEN IN THE REPORT
X C IN THE CONSTANT COMPOSITION EXPANSION TEST.
X C
24 LIQDEN
25 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
26 0.046396 0.080535 0.015069
27 TEMP 276 F
28 PRES PSIG 6000 4375
29 DEXP GM/CC .4924 .4530
X C
X C ------------------------------
X C CONSTANT COMPOSITION EXPANSION
X C ------------------------------
X C
X C NOTE: XLIQ IS USED BECAUSE DATA IS DEFINED AS
X C LIQUID VOLUME AT PRESSURE RELATIVE TO
X C VOLUME AT SATURATION PRESSURE.
X C
30 CCEXP
31 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
32 0.046396 0.080535 0.015069
33 TEMP 276 F
34 BUBPT 4375 PSIG
35 PRES VREL XLIQ ZG
36 6000 0.9200 X X
37 5000 0.9613 X X
38 4500 0.9909 X X
39 4375 1.0000 1.000 X
40 4328 1.0052 X X
41 4300 X .651 X
42 4267 1.0117 X X
43 4230 1.0158 X X
44 4150 X .570 X
45 4059 1.0368 X X
46 3960 X .530 X
47 3709 1.0883 X X
48 3408 1.1472 X X
49 2688 1.3595 X X
50 1962 1.7834 X X
51 1271 2.7310 X X
52 951 3.6866 X X
X C
X C -------------------------
X C CONSTANT VOLUME DEPLETION
X C -------------------------
X C
53 CVDEP
54 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
55 0.046396 0.080535 0.015069
56 TEMP 276 F
57 BUBPT 4375 PSIG
58 PRES 4375 3700 3000 2200 1400 700
59 CO2 .0584 .0632 .0661 .0686 .0695 .0696
60 C1 .5043 .6053 .6226 .6337 .6263 .5813
61 C2 .0965 .0996 .1011 .1043 .1089 .1154
62 C3 .0875 .0827 .0824 .0836 .0883 .1024
63 C6 .0229 .0142 .0121 .0128 .0107 .0130
64 MW C8 C30 183 138 129 120 115 116
65 ZGAS X .893 .858 .860 .892 .939
66 VPROD X .08753 .19629 .35179 .52727 .69232
67 SLIQ X .501 .450 .414 .376 .333
X C
X C ------------------
X C SURFACE SEPARATION
X C ------------------
X C
68 SEP
69 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
70 0.046396 0.080535 0.015069
71 TEMP 276 F
72 BUBPT 4375 PSIG
73 DNSAT .4530 GM/CC
74 TSTD 80.
75 PSTD 0.
76 BO 2.852
77 PRES TEMP GORSP GORST SVF GRVG
78 385. 80. X 2187. X X

79 50. 80. X 294. X X

80 0. 80. X 173. X X
X C
81 END
1NONLINEAR REGRESSION DATA
-------------------------
CONTROL VARIABLES
-----------------

---- ------ ------- ------- ------- -------
20 0 0.2000 0.0010 0.0010 0.0100
INITIAL VALUES OF REGRESSION VARIABLES

-----------------------------------------
VARIABLE MINIMUM INITIAL MAXIMUM

-------- ------- ------- -------
1 0.7000 1.0000 1.3000
2 0.7000 1.0000 1.3000
3 0.7000 1.0000 1.3000
4 0.7000 1.0000 1.3000
5 0.7000 1.0000 1.3000
6 0.7000 1.0000 1.3000
7 0.7000 1.0000 1.3000
8 0.7000 1.0000 1.3000
9 0.7000 1.0000 1.3000
10 0.7000 1.0000 1.3000
11 0.7000 1.0000 1.3000
REGRESSION VARIABLE ASSIGNMENTS

-------------------------------
COMPONENT ACENTRIC OMEGA OMEGA

NO. NAME MW TC PC ZC FACTOR A B PCHOR VSHFT
--- ------ ---- ---- ---- ---- -------- ----- ----- ----- ------
1 CO2 0 0 0 0 0 0 0 0 0
2 C1 0 0 0 0 0 10 11 0 0
3 C2 0 0 0 0 0 0 0 0 0
4 C3 0 0 0 0 0 0 0 0 0
5 NC4 0 0 0 0 0 0 0 0 0
6 NC5 0 0 0 0 0 0 0 0 0
7 C6 0 0 0 0 0 0 0 0 0
8 C8 0 0 0 0 0 1 2 0 0
9 C14 0 0 0 0 0 3 4 0 0
10 C30 0 0 0 0 0 5 6 0 0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO MOLE FRACTIONS.
BINARY INTERACTION COEFFICIENTS

-------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0
3 0 0
4 0 0 0
5 0 0 0 0
6 0 0 0 0 0
7 0 0 0 0 0 0
8 0 7 0 0 0 0 0
9 0 8 0 0 0 0 0 0
10 0 9 0 0 0 0 0 0 0
PARAMETERS D AND E FOR VOLUME SHIFT PARAMETER CALCULATION

D E
0 0

K-COEFFICIENT OF PEDERSEN ET AL. VISCOSITY CORRELATION

K-COEFFICIENT REGRESSION VARIABLE
------------- -------------------
k(1) 0
k(2) 0
k(3) 0
k(4) 0
k(5) 0
k(6) 0
k(7) 0
BINARY INTERACTION COEFFICIENTS FOR COMPUTING PSEUDO-

CRITICAL TEMPERATURE OF PEDERSEN ET AL. VISCOSITY CORRELATION
------------------------------------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0
3 0 0
4 0 0 0
5 0 0 0 0
6 0 0 0 0 0
7 0 0 0 0 0 0
8 0 0 0 0 0 0 0
9 0 0 0 0 0 0 0 0
10 0 0 0 0 0 0 0 0 0
1EQUATION OF STATE: PENG-ROBINSON
COMPONENT PROPERTIES
--------------------
COMPONENT MOLE TC PC CRITICAL ACENTRIC OMEGA OMEGA PCHOR

NO. NAME WEIGHT DEG F PSIA Z-FACTOR FACTOR A B
-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 CO2 44.01 87.90 1070.90 0.2742 0.22250 0.45724 0.07780 49.6
2 C1 16.04 -116.60 667.80 0.2890 0.01260 0.45724 0.07780 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.45724 0.07780 111.0
4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0
5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.2698 0.23130 0.45724 0.07780 271.0
8 C8 108.82 585.69 411.09 0.2609 0.32000 0.45724 0.07780 351.0
9 C14 187.49 790.04 283.80 0.2411 0.50331 0.45724 0.07780 591.9
10 C30 387.42 1138.35 165.63 0.2067 0.93601 0.45724 0.07780 1236.7
NUMBER OF VOLATILE COMPONENTS: 10

-------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.1500
3 0.1500 0.0000
4 0.1500 0.0000 0.0000
5 0.1500 0.0200 0.0100 0.0100
6 0.1500 0.0200 0.0100 0.0100 0.0000
7 0.1500 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1500 0.0387 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1500 0.0485 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1500 0.0626 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000
k-COEFFICIENT OF THE PEDERSEN ET AL. VISCOSITY CORRELATION

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02
k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

BINARY INTERACTION COEFFICIENTS FOR THE

PEDERSEN ET AL. VISCOSITY CORRELATION
---------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
CORRELATION OF SOLUBILITY OF CO2 IN WATER

-----------------------------------------
Rsw(pure water) = A*P*( 1 - B*sin(C*P/(C*P+1) )
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4
log( Rsw[brine]/Rsw[pure water] ) = S0 * S * T**S1
where Rsw in scf/stb

P in psia
T in degree F
S in weight percent solid
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4
1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464
S0 S1
-0.0280370 -0.1203900
CORRELATION OF DENSITY OF CO2 SATURATED WATER

----------------------------------------------
Den(lb/cu ft) = Den,1atm(lb/cuft) + 0.001 * D1 * Rsw(scf/stb)
D1 = 5.80000
IDEAL GAS STATE ENTHALPY COEFFICIENTS

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT
NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 CO2 0.210E+03 0.504E+01 0.445E-02 -0.117E-05 0.153E-09 -0.578E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12
4 C3 -0.325E+02 0.761E+01 0.415E-02 0.950E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.392E+01 0.447E-01 -0.629E-05 0.000E+00 0.000E+00
9 C14 0.000E+00 0.297E+01 0.741E-01 -0.974E-05 0.000E+00 0.000E+00
10 C30 0.000E+00 0.111E+03 0.215E+00 -0.360E-04 0.000E+00 0.000E+00
PVT PROPERTIES FORMATTED FOR SIMULATOR INPUT HAVE BEEN WRITTEN TO UNIT 22
1SATURATION PRESSURE CALCULATION
-------------------------------
COMPONENT MOLE FRACTION

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890

NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE SATURATION PRESSURE (PSIG ) DEN AT PSAT (LB/FT3) Z-FAC AT PSAT

DEGREES F DATA CALC TYPE DATA CALC DATA CALC
----------- -------- -------- ---- -------- -------- ------ ------
276.00 4375.000 3919.877 BP 0.0000 28.5103 0.0000 0.8891
1CALCULATED COMPOSITIONS:
------------------------
P = 3919.9 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.85827 YY = 0.64949E-01 0.60176E+00 0.98682E-01 0.81770E-01 0.49343E-01
0.22724E-01 0.16209E-01 0.27810E-01 0.34297E-01 0.24527E-02
ZX = 0.88908 XX = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
KV = 0.11121E+01 0.11933E+01 0.10226E+01 0.93451E+00 0.83774E+00
0.77032E+00 0.70783E+00 0.59941E+00 0.42586E+00 0.16276E+00
1PHASE ENVELOPE CALCULATION
--------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE SATURATION PRESSURE (PSIG )

DEGREES F ESTIMATE COMPUTED TYPE
----------- -------- -------- ------
-100.00 ** NONE FOUND **
-90.00 ** NONE FOUND **
-80.00 ** NONE FOUND **
-70.00 2000.000 842.706 BUBPT
-60.00 ** NONE FOUND **
-50.00 ** NONE FOUND **
-40.00 2000.000 1221.923 BUBPT
-30.00 2000.000 1362.726 BUBPT
-20.00 2000.000 1505.560 BUBPT
-10.00 4000.000 1647.812 BUBPT
0.00 4000.000 1787.778 BUBPT
10.00 4000.000 1924.407 BUBPT
20.00 4000.000 2057.060 BUBPT
30.00 4000.000 2185.349 BUBPT
40.00 4000.000 2309.043 BUBPT
50.00 4000.000 2428.013 BUBPT
60.00 4000.000 2542.194 BUBPT
70.00 4000.000 2651.565 BUBPT
80.00 4000.000 2756.138 BUBPT
90.00 4000.000 2855.942 BUBPT
100.00 4000.000 2951.023 BUBPT
110.00 4000.000 3041.434 BUBPT
120.00 6000.000 3127.238 BUBPT
130.00 6000.000 3208.498 BUBPT
140.00 6000.000 3285.283 BUBPT
150.00 6000.000 3357.661 BUBPT
160.00 6000.000 3425.703 BUBPT
170.00 6000.000 3489.477 BUBPT
180.00 6000.000 3549.052 BUBPT
190.00 6000.000 3604.495 BUBPT
200.00 6000.000 3655.872 BUBPT
210.00 6000.000 3703.248 BUBPT
220.00 6000.000 3746.685 BUBPT
230.00 6000.000 3786.243 BUBPT
240.00 6000.000 3821.982 BUBPT
250.00 6000.000 3853.959 BUBPT
260.00 6000.000 3882.228 BUBPT

270.00 6000.000 3906.842 BUBPT

280.00 6000.000 3927.852 BUBPT
290.00 6000.000 3945.306 BUBPT
300.00 6000.000 3959.250 BUBPT
310.00 6000.000 3969.730 BUBPT
320.00 6000.000 3976.788 BUBPT
330.00 6000.000 3980.462 BUBPT
340.00 6000.000 3980.792 BUBPT
350.00 6000.000 3977.812 BUBPT
360.00 6000.000 3971.557 BUBPT
370.00 6000.000 3962.058 BUBPT
380.00 6000.000 3949.342 BUBPT
390.00 6000.000 3933.436 BUBPT
400.00 6000.000 3914.364 BUBPT
410.00 6000.000 3892.147 BUBPT
420.00 6000.000 3866.802 BUBPT
430.00 4000.000 3838.345 DEWPT
440.00 4000.000 3806.787 DEWPT
450.00 4000.000 3772.137 DEWPT
460.00 4000.000 3734.398 DEWPT
470.00 4000.000 3693.571 DEWPT
480.00 4000.000 3649.651 DEWPT
490.00 4000.000 3602.628 DEWPT
500.00 4000.000 3552.487 DEWPT
510.00 4000.000 3499.206 DEWPT
520.00 4000.000 3442.754 DEWPT
530.00 4000.000 3383.093 DEWPT
540.00 4000.000 3320.174 DEWPT
550.00 4000.000 3253.937 DEWPT
560.00 4000.000 3184.308 DEWPT
570.00 4000.000 3111.193 DEWPT
580.00 4000.000 3034.481 DEWPT
590.00 4000.000 2954.034 DEWPT
600.00 4000.000 2869.682 DEWPT
610.00 4000.000 2781.214 DEWPT
620.00 4000.000 2688.367 DEWPT
630.00 4000.000 2590.808 DEWPT
640.00 4000.000 2488.109 DEWPT
650.00 4000.000 2379.707 DEWPT
660.00 4000.000 2264.846 DEWPT
670.00 4000.000 2142.469 DEWPT
680.00 4000.000 2011.038 DEWPT
690.00 4000.000 1868.153 DEWPT
700.00 4000.000 1709.715 DEWPT
710.00 4000.000 1527.542 DEWPT
720.00 4000.000 1299.471 DEWPT
730.00 ** NONE FOUND **
740.00 ** NONE FOUND **
750.00 ** NONE FOUND **
760.00 ** NONE FOUND **
770.00 ** NONE FOUND **
780.00 ** NONE FOUND **
790.00 ** NONE FOUND **
800.00 ** NONE FOUND **
800.00 ** NONE FOUND **
790.00 ** NONE FOUND **
780.00 ** NONE FOUND **
770.00 ** NONE FOUND **
760.00 ** NONE FOUND **
750.00 ** NONE FOUND **
740.00 ** NONE FOUND **
730.00 ** NONE FOUND **
720.00 100.000 518.064 DEWPT
710.00 100.000 393.076 DEWPT
700.00 100.000 311.905 DEWPT
690.00 100.000 252.350 DEWPT
680.00 100.000 206.187 DEWPT
670.00 100.000 169.276 DEWPT
660.00 100.000 139.179 DEWPT
650.00 100.000 114.315 DEWPT
640.00 100.000 93.591 DEWPT
630.00 100.000 76.210 DEWPT
620.00 100.000 61.573 DEWPT
610.00 100.000 49.215 DEWPT
600.00 ** ONLY DUPLICATE FOUND **
1LIQUID DENSITY CALCULATION
--------------------------

--------- -------------

CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE PRESSURE LIQUID DEN (GM/CC ) ---- Z-FACTOR ----

DEGREES F PSIG DATA CALC DATA CALC
----------- -------- -------- --------- -------- --------
276.00 6000.000 0.4924 0.5079 0.00000 1.22203
4375.000 0.4530 0.4704 0.00000 0.96307
1CONSTANT COMPOSITION EXPANSION
------------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
SATURATION PRESSURE: NEWTON-RAPHSON

FLASH CALCULATIONS: NEWTON-RAPHSON
VISCOSITY CORRELATION: LOHRENZ, BRAY AND CLARK
TEMPERATURE = 276.00 DEGREES F
OBSERVED PSAT = 4375.00 PSIG (BUBPT)

CALCULATED PSAT = 3919.88 PSIG (BUBPT)
OBSERVED Z-FACTOR AT PSAT = 0.0000
CALCULATED Z-FACTOR AT PSAT = 0.8891
OIL DENSITY AT PSAT = 0.4567 GM/CC
GAS DENSITY AT PSAT = 0.3288 GM/CC
PRES REL. VOLUME LIQ VOL FRAC LIQ MOLE FRAC

------- --------------- --------------- ---------------
PSIG DATA CALC DATA CALC DATA CALC
------- ------ ------ ------ ------ ------ ------
6000.0 0.9200 0.8991 0.0000 0.8991 0.0000 1.0000
5000.0 0.9613 0.9386 0.0000 0.9386 0.0000 1.0000
4500.0 0.9909 0.9638 0.0000 0.9638 0.0000 1.0000
4375.0 1.0000 0.9709 1.0000 0.9709 0.0000 1.0000
4328.0 1.0052 0.9737 0.0000 0.9737 0.0000 1.0000
4300.0 0.0000 0.9753 0.6510 0.9753 0.0000 1.0000
4267.0 1.0117 0.9773 0.0000 0.9773 0.0000 1.0000
4230.0 1.0158 0.9796 0.0000 0.9796 0.0000 1.0000
4150.0 0.0000 0.9846 0.5700 0.9846 0.0000 1.0000
4059.0 1.0368 0.9905 0.0000 0.9905 0.0000 1.0000
3960.0 0.0000 0.9972 0.5300 0.9972 0.0000 1.0000
3709.0 1.0883 1.0310 0.0000 0.8338 0.0000 0.8034
3408.0 1.1472 1.0847 0.0000 0.7258 0.0000 0.6657
2688.0 1.3595 1.2817 0.0000 0.6033 0.0000 0.4938
1962.0 1.7834 1.6740 0.0000 0.5286 0.0000 0.3834
1271.0 2.7310 2.5538 0.0000 0.4666 0.0000 0.2963
951.0 3.6866 3.4459 0.0000 0.4363 0.0000 0.2573
PRES OIL Z-FACTOR GAS Z-FACTOR OIL DENSITY GAS DENSITY

------- --------------- --------------- --------------- ---------------
PSIG DATA CALC DATA CALC DATA CALC DATA CALC
------- ------ ------ ------ ------ ------ ------ ------ ------
6000.0 0.0000 1.2220 0.0000 0.0000 0.0000 0.5079 0.0000 0.0000
5000.0 0.0000 1.0636 0.0000 0.0000 0.0000 0.4866 0.0000 0.0000
4500.0 0.0000 0.9833 0.0000 0.0000 0.0000 0.4738 0.0000 0.0000
4375.0 0.0000 0.9631 0.0000 0.0000 0.0000 0.4704 0.0000 0.0000
4328.0 0.0000 0.9555 0.0000 0.0000 0.0000 0.4690 0.0000 0.0000
4300.0 0.0000 0.9509 0.0000 0.0000 0.0000 0.4682 0.0000 0.0000

4267.0 0.0000 0.9456 0.0000 0.0000 0.0000 0.4673 0.0000 0.0000

4230.0 0.0000 0.9396 0.0000 0.0000 0.0000 0.4662 0.0000 0.0000
4150.0 0.0000 0.9266 0.0000 0.0000 0.0000 0.4638 0.0000 0.0000
4059.0 0.0000 0.9118 0.0000 0.0000 0.0000 0.4611 0.0000 0.0000
3960.0 0.0000 0.8956 0.0000 0.0000 0.0000 0.4580 0.0000 0.0000
3709.0 0.0000 0.8733 0.0000 0.8440 0.0000 0.4770 0.0000 0.2989
3408.0 0.0000 0.8433 0.0000 0.8303 0.0000 0.4989 0.0000 0.2636
2688.0 0.0000 0.7462 0.0000 0.8184 0.0000 0.5393 0.0000 0.1936
1962.0 0.0000 0.6158 0.0000 0.8298 0.0000 0.5746 0.0000 0.1336
1271.0 0.0000 0.4575 0.0000 0.8618 0.0000 0.6080 0.0000 0.0829
951.0 0.0000 0.3701 0.0000 0.8842 0.0000 0.6245 0.0000 0.0612
PRES OIL VISCOSITY GAS VISCOSITY SURF TENS

------- --------------- --------------- -----------
PSIG DATA CALC DATA CALC DYNE/CM
------- ------ ------ ------ ------ -----------
6000.0 0.0000 0.0850 0.0000 0.0000 0.0000E+00
5000.0 0.0000 0.0754 0.0000 0.0000 0.0000E+00
4500.0 0.0000 0.0705 0.0000 0.0000 0.0000E+00
4375.0 0.0000 0.0693 0.0000 0.0000 0.0000E+00
4328.0 0.0000 0.0688 0.0000 0.0000 0.0000E+00
4300.0 0.0000 0.0686 0.0000 0.0000 0.0000E+00
4267.0 0.0000 0.0683 0.0000 0.0000 0.0000E+00
4230.0 0.0000 0.0679 0.0000 0.0000 0.0000E+00
4150.0 0.0000 0.0671 0.0000 0.0000 0.0000E+00
4059.0 0.0000 0.0662 0.0000 0.0000 0.0000E+00
3960.0 0.0000 0.0652 0.0000 0.0000 0.0000E+00
3709.0 0.0000 0.0706 0.0000 0.0358 0.9039E-01
3408.0 0.0000 0.0776 0.0000 0.0314 0.2797E+00
2688.0 0.0000 0.0934 0.0000 0.0239 0.1355E+01
1962.0 0.0000 0.1110 0.0000 0.0190 0.3711E+01
1271.0 0.0000 0.1315 0.0000 0.0160 0.7633E+01
951.0 0.0000 0.1429 0.0000 0.0151 0.1019E+02
1OIL PHASE EXPERIMENTAL DATA
---------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
SIMULATED OIL PHASE COMPOSITIONS

--------------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584
0.0584 0.0565 0.0540 0.0473 0.0385 0.0276 0.0215
C1 0.5043 0.5043 0.5043 0.5043 0.5043 0.5043 0.5043 0.5043 0.5043 0.5043
0.5043 0.4773 0.4425 0.3608 0.2723 0.1803 0.1353
C2 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965
0.0965 0.0958 0.0947 0.0906 0.0822 0.0668 0.0557
C3 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875
0.0875 0.0891 0.0910 0.0947 0.0957 0.0889 0.0801
NC4 0.0589 0.0589 0.0589 0.0589 0.0589 0.0589 0.0589 0.0589 0.0589 0.0589

0.0589 0.0616 0.0650 0.0733 0.0814 0.0857 0.0835

NC5 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295
0.0295 0.0314 0.0339 0.0403 0.0478 0.0549 0.0569
C6 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229
0.0229 0.0248 0.0273 0.0338 0.0418 0.0508 0.0550
C8 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464
0.0464 0.0516 0.0587 0.0769 0.0999 0.1295 0.1472
C14 0.0805 0.0805 0.0805 0.0805 0.0805 0.0805 0.0805 0.0805 0.0805 0.0805
0.0805 0.0935 0.1104 0.1519 0.2012 0.2647 0.3061
C30 0.0151 0.0151 0.0151 0.0151 0.0151 0.0151 0.0151 0.0151 0.0151 0.0151
0.0151 0.0184 0.0223 0.0304 0.0393 0.0508 0.0586
1GAS PHASE EXPERIMENTAL DATA
---------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
SIMULATED GAS PHASE COMPOSITIONS

--------------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0660 0.0671 0.0693 0.0708 0.0714 0.0712
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.6148 0.6274 0.6443 0.6486 0.6408 0.6321
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0992 0.1000 0.1023 0.1054 0.1090 0.1106
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0811 0.0805 0.0805 0.0824 0.0869 0.0901
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0480 0.0467 0.0449 0.0449 0.0476 0.0504
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0217 0.0206 0.0189 0.0181 0.0188 0.0200
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0152 0.0141 0.0123 0.0112 0.0111 0.0118
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0250 0.0219 0.0167 0.0131 0.0114 0.0115
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0277 0.0210 0.0109 0.0055 0.0030 0.0024
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0014 0.0006 0.0001 0.0000 0.0000 0.0000
------------------------
0 P = 3709.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.84401 YY = 0.65990E-01 0.61476E+00 0.99227E-01 0.81073E-01 0.48000E-01
0.21713E-01 0.15196E-01 0.24981E-01 0.27682E-01 0.13727E-02
ZX = 0.87330 XX = 0.56543E-01 0.47727E+00 0.95833E-01 0.89073E-01 0.61567E-01
0.31406E-01 0.24785E-01 0.51636E-01 0.93468E-01 0.18421E-01
KV = 0.11671E+01 0.12881E+01 0.10354E+01 0.91019E+00 0.77963E+00
0.69137E+00 0.61312E+00 0.48380E+00 0.29617E+00 0.74518E-01
0 P = 3408.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01

ZY = 0.83034 YY = 0.67144E-01 0.62738E+00 0.10001E+00 0.80500E-01 0.46657E-01

0.20644E-01 0.14110E-01 0.21939E-01 0.20983E-01 0.63298E-03
ZX = 0.84326 XX = 0.54009E-01 0.44249E+00 0.94739E-01 0.91015E-01 0.65048E-01
0.33947E-01 0.27314E-01 0.58677E-01 0.11044E+00 0.22318E-01
KV = 0.12432E+01 0.14178E+01 0.10556E+01 0.88448E+00 0.71727E+00
0.60811E+00 0.51658E+00 0.37389E+00 0.18999E+00 0.28362E-01
0 P = 2688.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.81840 YY = 0.69261E-01 0.64430E+00 0.10227E+00 0.80452E-01 0.44865E-01
0.18917E-01 0.12262E-01 0.16670E-01 0.10908E-01 0.98405E-04
ZX = 0.74618 XX = 0.47266E-01 0.36079E+00 0.90585E-01 0.94725E-01 0.73288E-01
0.40349E-01 0.33806E-01 0.76869E-01 0.15191E+00 0.30415E-01
KV = 0.14654E+01 0.17858E+01 0.11290E+01 0.84932E+00 0.61217E+00
0.46883E+00 0.36271E+00 0.21686E+00 0.71805E-01 0.32354E-02
0 P = 1962.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82979 YY = 0.70775E-01 0.64855E+00 0.10538E+00 0.82428E-01 0.44917E-01
0.18139E-01 0.11166E-01 0.13117E-01 0.55134E-02 0.13377E-04
ZX = 0.61576 XX = 0.38501E-01 0.27232E+00 0.82225E-01 0.95657E-01 0.81386E-01
0.47769E-01 0.41769E-01 0.99912E-01 0.20118E+00 0.39280E-01
KV = 0.18383E+01 0.23816E+01 0.12816E+01 0.86171E+00 0.55189E+00
0.37973E+00 0.26732E+00 0.13128E+00 0.27406E-01 0.34055E-03
0 P = 1271.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.86175 YY = 0.71389E-01 0.64076E+00 0.10900E+00 0.86910E-01 0.47626E-01
0.18795E-01 0.11137E-01 0.11395E-01 0.29821E-02 0.18192E-05
ZX = 0.45748 XX = 0.27557E-01 0.18028E+00 0.66813E-01 0.88901E-01 0.85670E-01
0.54918E-01 0.50831E-01 0.12950E+00 0.26468E+00 0.50846E-01
KV = 0.25906E+01 0.35543E+01 0.16315E+01 0.97761E+00 0.55592E+00
0.34225E+00 0.21909E+00 0.87992E-01 0.11267E-01 0.35779E-04
0 P = 951.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.88421 YY = 0.71186E-01 0.63209E+00 0.11062E+00 0.90055E-01 0.50367E-01
0.19998E-01 0.11796E-01 0.11489E-01 0.23924E-02 0.73112E-06
ZX = 0.37009 XX = 0.21484E-01 0.13533E+00 0.55725E-01 0.80125E-01 0.83537E-01
0.56935E-01 0.54959E-01 0.14718E+00 0.30615E+00 0.58574E-01
KV = 0.33134E+01 0.46706E+01 0.19851E+01 0.11239E+01 0.60293E+00
0.35123E+00 0.21464E+00 0.78063E-01 0.78145E-02 0.12482E-04
1CONSTANT VOLUME DEPLETION
-------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507


PRES MW(C8 -C30 ) CUM GAS PROD LIQ VOL FRAC LIQ MOLE FRAC
------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
4375.0 183.00 0.00 0.0000 0.0000 0.0000 1.0000 0.0000 1.0000
3700.0 138.00 156.01 0.0875 0.0323 0.5010 0.8293 0.0000 0.7978
3000.0 129.00 144.84 0.1963 0.1509 0.4500 0.6418 0.0000 0.5517
2200.0 120.00 135.08 0.3518 0.3127 0.4140 0.5405 0.0000 0.4080
1400.0 115.00 126.64 0.5273 0.4956 0.3760 0.4658 0.0000 0.3040
700.0 116.00 120.68 0.6923 0.6672 0.3330 0.4051 0.0000 0.2258

PRES OIL Z-FACTOR GAS Z-FACTOR OIL DENSITY

------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
4375.0 0.0000 0.9631 0.0000 0.0000 0.0000 0.4704
3700.0 0.0000 0.8725 0.8930 0.8435 0.0000 0.4778
3000.0 0.0000 0.7924 0.8580 0.8205 0.0000 0.5231
2200.0 0.0000 0.6629 0.8600 0.8234 0.0000 0.5636
1400.0 0.0000 0.4898 0.8920 0.8520 0.0000 0.6012
700.0 0.0000 0.2897 0.9390 0.8986 0.0000 0.6352

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
4375.0 0.0000 0.0693 0.0000 0.0000 0.0000E+00
3700.0 0.0000 0.0708 0.0000 0.0356 0.9434E-01
3000.0 0.0000 0.0865 0.0000 0.0267 0.7651E+00
2200.0 0.0000 0.1051 0.0000 0.0204 0.2773E+01
1400.0 0.0000 0.1269 0.0000 0.0165 0.6693E+01
700.0 0.0000 0.1501 0.0000 0.0144 0.1223E+02
---------------------------
PRESSURE - PSIG
---------------
OIL COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
OIL PHASE SIMULATED DATA

------------------------
PRESSURE - PSIG
---------------
OIL COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0565 0.0504 0.0417 0.0301 0.0165
C1 0.5043 0.4762 0.3965 0.3016 0.1965 0.0960
C2 0.0965 0.0958 0.0928 0.0860 0.0720 0.0479
C3 0.0875 0.0891 0.0933 0.0962 0.0933 0.0763
NC4 0.0589 0.0617 0.0697 0.0790 0.0869 0.0857
NC5 0.0295 0.0315 0.0375 0.0452 0.0539 0.0602
C6 0.0229 0.0249 0.0309 0.0388 0.0487 0.0587
C8 0.0464 0.0518 0.0686 0.0911 0.1208 0.1576
C14 0.0805 0.0940 0.1334 0.1835 0.2484 0.3347
C30 0.0151 0.0185 0.0271 0.0367 0.0493 0.0664
---------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0632 0.0661 0.0686 0.0695 0.0696
C1 0.5043 0.6053 0.6226 0.6337 0.6263 0.5813
C2 0.0965 0.0996 0.1011 0.1043 0.1089 0.1154
C3 0.0875 0.0827 0.0824 0.0836 0.0883 0.1024
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0229 0.0142 0.0121 0.0128 0.0107 0.0130
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
GAS PHASE SIMULATED DATA

------------------------
PRESSURE - PSIG

PRODUCED ---------------
GAS COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0660 0.0684 0.0705 0.0720 0.0712
C1 0.0000 0.6152 0.6387 0.6475 0.6370 0.5949
C2 0.0000 0.0992 0.1012 0.1047 0.1107 0.1194
C3 0.0000 0.0811 0.0803 0.0818 0.0880 0.1033
NC4 0.0000 0.0480 0.0454 0.0447 0.0478 0.0597
NC5 0.0000 0.0217 0.0195 0.0183 0.0187 0.0234
C6 0.0000 0.0152 0.0130 0.0114 0.0110 0.0135
C8 0.0000 0.0249 0.0187 0.0140 0.0114 0.0123
C14 0.0000 0.0274 0.0145 0.0069 0.0033 0.0022
C30 0.0000 0.0013 0.0002 0.0000 0.0000 0.0000
------------------------
0 P = 3700.0 ZZ = 0.58145E-01 0.50060E+00 0.96408E-01 0.87715E-01 0.59265E-01
0.29761E-01 0.23158E-01 0.47114E-01 0.82307E-01 0.15527E-01
ZY = 0.84350 YY = 0.66029E-01 0.61522E+00 0.99249E-01 0.81050E-01 0.47952E-01
0.21676E-01 0.15159E-01 0.24878E-01 0.27446E-01 0.13406E-02
ZX = 0.87251 XX = 0.56467E-01 0.47619E+00 0.95803E-01 0.89135E-01 0.61675E-01
0.31483E-01 0.24862E-01 0.51850E-01 0.93990E-01 0.18548E-01
KV = 0.11693E+01 0.12920E+01 0.10360E+01 0.90930E+00 0.77750E+00
0.68850E+00 0.60973E+00 0.47981E+00 0.29201E+00 0.72275E-01
0 P = 3000.0 ZZ = 0.56707E-01 0.48131E+00 0.95733E-01 0.88755E-01 0.61198E-01
0.31188E-01 0.24583E-01 0.51085E-01 0.91776E-01 0.17665E-01
ZY = 0.82051 YY = 0.68447E-01 0.63869E+00 0.10124E+00 0.80272E-01 0.45430E-01
0.19543E-01 0.12957E-01 0.18684E-01 0.14510E-01 0.22334E-03
ZX = 0.79245 XX = 0.50377E-01 0.39646E+00 0.92762E-01 0.93328E-01 0.69699E-01
0.37466E-01 0.30851E-01 0.68553E-01 0.13343E+00 0.27068E-01
KV = 0.13587E+01 0.16110E+01 0.10914E+01 0.86011E+00 0.65180E+00
0.52162E+00 0.41997E+00 0.27255E+00 0.10875E+00 0.82512E-02
0 P = 2200.0 ZZ = 0.53449E-01 0.44219E+00 0.93611E-01 0.90382E-01 0.65070E-01
0.34233E-01 0.27686E-01 0.59806E-01 0.11176E+00 0.21817E-01
ZY = 0.82335 YY = 0.70544E-01 0.64749E+00 0.10475E+00 0.81844E-01 0.44750E-01
0.18257E-01 0.11403E-01 0.14039E-01 0.69045E-02 0.26613E-04
ZX = 0.66295 XX = 0.41747E-01 0.30165E+00 0.85988E-01 0.96226E-01 0.78981E-01
0.45169E-01 0.38833E-01 0.91138E-01 0.18354E+00 0.36734E-01
KV = 0.16898E+01 0.21465E+01 0.12181E+01 0.85054E+00 0.56659E+00
0.40419E+00 0.29363E+00 0.15404E+00 0.37620E-01 0.72446E-03
0 P = 1400.0 ZZ = 0.46738E-01 0.37155E+00 0.87408E-01 0.91230E-01 0.71341E-01
0.39878E-01 0.33729E-01 0.77339E-01 0.15106E+00 0.29725E-01
ZY = 0.85205 YY = 0.71963E-01 0.63705E+00 0.11072E+00 0.88040E-01 0.47769E-01
0.18660E-01 0.11016E-01 0.11440E-01 0.33392E-02 0.28050E-05
ZX = 0.48978 XX = 0.30108E-01 0.19653E+00 0.72035E-01 0.93333E-01 0.86882E-01
0.53865E-01 0.48704E-01 0.12078E+00 0.24844E+00 0.49319E-01
KV = 0.23901E+01 0.32415E+01 0.15371E+01 0.94329E+00 0.54982E+00
0.34642E+00 0.22618E+00 0.94716E-01 0.13440E-01 0.56874E-04
0 P = 700.0 ZZ = 0.34098E-01 0.25633E+00 0.70891E-01 0.84991E-01 0.77348E-01
0.48357E-01 0.44159E-01 0.11090E+00 0.22787E+00 0.45060E-01
ZY = 0.89862 YY = 0.71237E-01 0.59490E+00 0.11942E+00 0.10332E+00 0.59699E-01
0.23443E-01 0.13514E-01 0.12287E-01 0.21795E-02 0.41661E-06
ZX = 0.28967 XX = 0.16516E-01 0.96040E-01 0.47917E-01 0.76312E-01 0.85703E-01
0.60151E-01 0.58667E-01 0.15759E+00 0.33471E+00 0.66393E-01
KV = 0.43132E+01 0.61942E+01 0.24922E+01 0.13540E+01 0.69658E+00
0.38974E+00 0.23035E+00 0.77968E-01 0.65117E-02 0.62749E-05
1SEPARATOR CALCULATION
---------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507

OBSERVED DNSAT = 0.4530 GM/CC

STANDARD TEMP = 80.0 DEGREES F

STANDARD PRES = 0.0 PSIG
OBSERVED OIL FVF = 2.8520 RB/STB

CALCULATED OIL FVF = 2.5873 RB/STB
CALCULATED API GRAV. = 65.4

CALCULATED TOTAL GOR = 2481.75 SCF/STB
CALCULATED TOTAL OGR = 402.94 STB/MMSCF
PRES TEMP GOR (SEP) GOR (ST) SEP FVF GAS GRAVITY
------ ------ --------------- --------------- --------------- --------------
PSIG F DATA CALC DATA CALC DATA CALC DATA CALC
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
385.0 80.0 0. 1718. 2187. 2080. 0.0000 1.2104 0.0000 0.7853
50.0 80.0 0. 240. 294. 260. 0.0000 1.0860 0.0000 1.1306
0.0 80.0 0. 141. 173. 141. 0.0000 1.0000 0.0000 1.6646
PRES TEMP LIQ. MOLE FRACTION LIQ. Z-FACTOR LIQ. DENSITY,GM/CC

------ ------ ------------------ ------------------ ------------------
PSIG F DATA CALC DATA CALC DATA CALC
------ ------ -------- -------- -------- -------- -------- --------
385.0 80.0 0.3765 0.3464 0.0000 0.1676 0.0000 0.6850
50.0 80.0 0.2927 0.2646 0.0000 0.0319 0.0000 0.7066
0.0 80.0 0.2434 0.2201 0.0000 0.0080 0.0000 0.7179
------------
0STAGE 1 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89705 YY = 0.77918E-01 0.72223E+00 0.10926E+00 0.64760E-01 0.19967E-01
0.40294E-02 0.14266E-02 0.40843E-03 0.74285E-05 0.11024E-09
ZX = 0.16763 XX = 0.21577E-01 0.93151E-01 0.72430E-01 0.13040E+00 0.13235E+00
0.77554E-01 0.63413E-01 0.13316E+00 0.23246E+00 0.43499E-01
KV = 0.36111E+01 0.77533E+01 0.15085E+01 0.49661E+00 0.15087E+00
0.51956E-01 0.22497E-01 0.30672E-02 0.31956E-04 0.25343E-08
0STAGE 2 ZZ = 0.21577E-01 0.93151E-01 0.72430E-01 0.13040E+00 0.13235E+00
0.77554E-01 0.63413E-01 0.13316E+00 0.23246E+00 0.43499E-01
ZY = 0.96343 YY = 0.78657E-01 0.36824E+00 0.21530E+00 0.22541E+00 0.87496E-01
0.17586E-01 0.58968E-02 0.13948E-02 0.14788E-04 0.14542E-11
ZX = 0.03188 XX = 0.39153E-02 0.80307E-02 0.28222E-01 0.10100E+00 0.14623E+00
0.96110E-01 0.81210E-01 0.17393E+00 0.30439E+00 0.56959E-01
KV = 0.20089E+02 0.45854E+02 0.76289E+01 0.22317E+01 0.59833E+00
0.18298E+00 0.72612E-01 0.80193E-02 0.48582E-04 0.25530E-10
0STAGE 3 ZZ = 0.39153E-02 0.80307E-02 0.28222E-01 0.10100E+00 0.14623E+00
0.96110E-01 0.81210E-01 0.17393E+00 0.30439E+00 0.56959E-01
ZY = 0.98105 YY = 0.22053E-01 0.46657E-01 0.14585E+00 0.39294E+00 0.28681E+00
0.73227E-01 0.26165E-01 0.62325E-02 0.59725E-04 0.43413E-11
ZX = 0.00802 XX = 0.25188E-03 0.22896E-03 0.44624E-02 0.42038E-01 0.11784E+00
0.10073E+00 0.92328E-01 0.20780E+00 0.36586E+00 0.68463E-01
KV = 0.87554E+02 0.20378E+03 0.32685E+02 0.93474E+01 0.24339E+01
0.72695E+00 0.28340E+00 0.29993E-01 0.16325E-03 0.63411E-10
0REGRESSION ITERATION 1
REGRESSION VARIABLE SUMMARY

---------------------------
0INDEX X VARIABLE DELTA X DELTA VAR.
----- ----------- ----------- ----------- -----------
10 1.00000000 0.45723553 0.00000000 0.00000000
11 1.00000000 0.07779608 0.00000000 0.00000000
1 1.00000000 0.45723553 0.00000000 0.00000000
2 1.00000000 0.07779608 0.00000000 0.00000000
3 1.00000000 0.45723553 0.00000000 0.00000000
4 1.00000000 0.07779608 0.00000000 0.00000000
5 1.00000000 0.45723553 0.00000000 0.00000000
6 1.00000000 0.07779608 0.00000000 0.00000000
7 1.00000000 0.03866500 0.00000000 0.00000000
8 1.00000000 0.04854700 0.00000000 0.00000000
9 1.00000000 0.06259800 0.00000000 0.00000000
0OBJECTIVE FUNCTION VALUE = 5.360378E+00
0WEIGHTED ROOT MEAN SQUARE ERROR = 2.711884E-01

---------------------------
----- ----------- ----------- ----------- -----------

10 0.98997035 0.45264962 -0.01002965 -0.00458591

11 1.04435557 0.08124677 0.04435557 0.00345069
1 0.90126155 0.41208880 -0.09873845 -0.04514673
2 1.07204499 0.08340089 0.07204499 0.00560482
3 0.94565441 0.43238680 -0.05434559 -0.02484874
4 0.93319920 0.07259924 -0.06680080 -0.00519684
5 1.02656261 0.46938090 0.02656261 0.01214537
6 0.93464197 0.07271148 -0.06535803 -0.00508460
7 0.93414702 -0.02718798 -0.06585298 -0.06585298
8 0.97176036 0.02030736 -0.02823964 -0.02823964
9 0.97397476 0.03657275 -0.02602524 -0.02602524

---------------------------
----- ----------- ----------- ----------- -----------
10 0.96465912 0.44107643 -0.02531123 -0.01157319
11 1.06518319 0.08286707 0.02082762 0.00162031
1 0.83764209 0.38299973 -0.06361946 -0.02908908
2 1.13863163 0.08858107 0.06658664 0.00518018
3 0.94346149 0.43138412 -0.00219292 -0.00100268
4 0.91548948 0.07122149 -0.01770971 -0.00137775
5 1.01735580 0.46517122 -0.00920680 -0.00420968
6 0.92699430 0.07211652 -0.00764767 -0.00059496
7 0.90343984 -0.05789516 -0.03070717 -0.03070717
8 0.92895679 -0.02249621 -0.04280357 -0.04280357
9 0.95359810 0.01619609 -0.02037666 -0.02037666
0OBJECTIVE FUNCTION VALUE = 1.354564E-01

---------------------------
----- ----------- ----------- ----------- -----------
10 0.94260968 0.43099464 -0.02204945 -0.01008179
11 1.08721713 0.08458123 0.02203394 0.00171415
1 0.86752181 0.39666180 0.02987972 0.01366207
2 1.19543167 0.09299989 0.05680004 0.00441882
3 0.97647782 0.44648035 0.03301633 0.01509624
4 0.92776461 0.07217645 0.01227513 0.00095496
5 1.03034410 0.47110993 0.01298830 0.00593871
6 0.92510856 0.07196982 -0.00188574 -0.00014670
7 0.81251216 -0.14882284 -0.09092768 -0.09092768
8 0.89463450 -0.05681850 -0.03432229 -0.03432229
9 0.90486958 -0.03253242 -0.04872851 -0.04872851

---------------------------
----- ----------- ----------- ----------- -----------
10 0.92296783 0.42201369 -0.01964185 -0.00898095
11 1.10989433 0.08634542 0.02267720 0.00176420
1 0.90098962 0.41196447 0.03346781 0.01530267
2 1.22570971 0.09535541 0.03027804 0.00235551
3 0.96016769 0.43902278 -0.01631013 -0.00745757
4 0.91223191 0.07096806 -0.01553270 -0.00120838
5 1.02029570 0.46651545 -0.01004840 -0.00459449
6 0.91115266 0.07088410 -0.01395590 -0.00108571
7 0.76458625 -0.19674875 -0.04792591 -0.04792591
8 0.86455731 -0.08689569 -0.03007719 -0.03007719
9 0.86497927 -0.07242273 -0.03989031 -0.03989031

---------------------------
----- ----------- ----------- ----------- -----------
10 0.90677868 0.41461143 -0.01618915 -0.00740225

11 1.11604213 0.08682370 0.00614780 0.00047828

1 0.91216884 0.41707601 0.01117922 0.00511154
2 1.23515489 0.09609020 0.00944518 0.00073480
3 0.96130164 0.43954127 0.00113395 0.00051848
4 0.90734805 0.07058812 -0.00488387 -0.00037995
5 1.01059323 0.46207913 -0.00970247 -0.00443631
6 0.90911537 0.07072561 -0.00203729 -0.00015849
7 0.74530347 -0.21603153 -0.01928278 -0.01928278
8 0.83687662 -0.11457638 -0.02768069 -0.02768069
9 0.86876650 -0.06863551 0.00378722 0.00378722

---------------------------
----- ----------- ----------- ----------- -----------
10 0.94186743 0.43065526 0.03508875 0.01604382
11 1.13515688 0.08831075 0.01911474 0.00148705
1 0.92113529 0.42117579 0.00896645 0.00409978
2 1.23979827 0.09645144 0.00464338 0.00036124
3 0.97178839 0.44433618 0.01048675 0.00479491
4 0.91797895 0.07141516 0.01063091 0.00082704
5 0.97700727 0.44672244 -0.03358596 -0.01535669
6 0.91288012 0.07101849 0.00376475 0.00029288
7 0.74151545 -0.21981955 -0.00378802 -0.00378802
8 0.86170592 -0.08974708 0.02482930 0.02482930
9 0.92224351 -0.01515849 0.05347702 0.05347702

---------------------------
----- ----------- ----------- ----------- -----------
10 0.93694933 0.42840653 -0.00491810 -0.00224873
11 1.13620111 0.08839199 0.00104423 0.00008124
1 0.93193306 0.42611291 0.01079777 0.00493712
2 1.25622075 0.09772904 0.01642248 0.00127760
3 0.97971279 0.44795950 0.00792440 0.00362332
4 0.91724545 0.07135810 -0.00073351 -0.00005706
5 0.98147683 0.44876608 0.00446956 0.00204364
6 0.91418342 0.07111988 0.00130330 0.00010139
7 0.73704488 -0.22429012 -0.00447057 -0.00447057
8 0.84689945 -0.10455355 -0.01480648 -0.01480648
9 0.91773965 -0.01966235 -0.00450386 -0.00450386

---------------------------
----- ----------- ----------- ----------- -----------
10 0.93529252 0.42764897 -0.00165681 -0.00075755
11 1.14352670 0.08896189 0.00732559 0.00056990
1 0.94226198 0.43083566 0.01032891 0.00472275
2 1.27092965 0.09887334 0.01470890 0.00114429
3 0.98984704 0.45259324 0.01013425 0.00463374
4 0.91612139 0.07127065 -0.00112406 -0.00008745
5 0.97408052 0.44538423 -0.00739631 -0.00338186
6 0.90636233 0.07051143 -0.00782109 -0.00060845
7 0.72521284 -0.23612216 -0.01183204 -0.01183204
8 0.82900075 -0.12245225 -0.01789869 -0.01789869
9 0.90715409 -0.03024791 -0.01058556 -0.01058556

---------------------------
----- ----------- ----------- ----------- -----------
10 0.92588645 0.42334818 -0.00940607 -0.00430079
11 1.14132524 0.08879062 -0.00220146 -0.00017127

1 0.94503228 0.43210234 0.00277031 0.00126668

2 1.27235680 0.09898437 0.00142715 0.00011103
3 0.98606153 0.45086237 -0.00378551 -0.00173087
4 0.91171014 0.07092747 -0.00441125 -0.00034318
5 0.96882459 0.44298103 -0.00525593 -0.00240320
6 0.90097856 0.07009260 -0.00538378 -0.00041884
7 0.72560686 -0.23572814 0.00039401 0.00039401
8 0.81855197 -0.13290103 -0.01044879 -0.01044879
9 0.90279246 -0.03460954 -0.00436163 -0.00436163

---------------------------
----- ----------- ----------- ----------- -----------
10 0.92588645 0.42334818 0.00000000 0.00000000
11 1.14132524 0.08879062 0.00000000 0.00000000
1 0.94503228 0.43210234 0.00000000 0.00000000
2 1.27235680 0.09898437 0.00000000 0.00000000
3 0.98606153 0.45086237 0.00000000 0.00000000
4 0.91171014 0.07092747 0.00000000 0.00000000
5 0.96882459 0.44298103 0.00000000 0.00000000
6 0.90097856 0.07009260 0.00000000 0.00000000
7 0.72560686 -0.23572814 0.00000000 0.00000000
8 0.81855197 -0.13290103 0.00000000 0.00000000
9 0.90279246 -0.03460954 0.00000000 0.00000000
0TOTAL NUMBER OF FUNCTION EVALUATIONS = 141
0REGRESSION TERMINATING NORMALLY:
THE DISTANCE MOVED WAS LESS THAN TOL2 = 0.00100
--------------------

-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 CO2 44.01 87.90 1070.90 0.2742 0.22250 0.45724 0.07780 49.6
2 C1 16.04 -116.60 667.80 0.2890 0.01260 0.42335 0.08879 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.45724 0.07780 111.0
4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0
5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.2698 0.23130 0.45724 0.07780 271.0
8 C8 108.82 585.69 411.09 0.2609 0.32000 0.43210 0.09898 351.0
9 C14 187.49 790.04 283.80 0.2411 0.50331 0.45086 0.07093 591.9
10 C30 387.42 1138.35 165.63 0.2067 0.93601 0.44298 0.07009 1236.7

-------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.1500
3 0.1500 0.0000
4 0.1500 0.0000 0.0000
5 0.1500 0.0200 0.0100 0.0100
6 0.1500 0.0200 0.0100 0.0100 0.0000
7 0.1500 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1500-0.2357 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1500-0.1329 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1500-0.0346 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02

k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

---------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

-----------------------------------------
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4

P in psia
T in degree F
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4
1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464
S0 S1
-0.0280370 -0.1203900

----------------------------------------------
D1 = 5.80000

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT
NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 CO2 0.210E+03 0.504E+01 0.445E-02 -0.117E-05 0.153E-09 -0.578E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12
4 C3 -0.325E+02 0.761E+01 0.415E-02 0.950E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
9 C14 0.000E+00 0.171E+02 0.786E-01 -0.118E-04 0.000E+00 0.000E+00
10 C30 0.000E+00 0.702E+01 0.153E+00 -0.199E-04 0.000E+00 0.000E+00
1SATURATION PRESSURE CALCULATION
-------------------------------

--------- -------------

CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE SATURATION PRESSURE (PSIG ) DEN AT PSAT (LB/FT3) Z-FAC AT PSAT

DEGREES F DATA CALC TYPE DATA CALC DATA CALC
----------- -------- -------- ---- -------- -------- ------ ------
276.00 4375.000 4376.455 BP 0.0000 28.8245 0.0000 0.9814
------------------------
P = 4376.5 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.96892 YY = 0.59654E-01 0.52080E+00 0.97188E-01 0.86811E-01 0.57363E-01
0.28343E-01 0.21689E-01 0.46595E-01 0.70472E-01 0.11089E-01
ZX = 0.98144 XX = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
KV = 0.10215E+01 0.10327E+01 0.10071E+01 0.99213E+00 0.97390E+00
0.96078E+00 0.94712E+00 0.10043E+01 0.87505E+00 0.73585E+00
1PHASE ENVELOPE CALCULATION
--------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE SATURATION PRESSURE (PSIG )

DEGREES F ESTIMATE COMPUTED TYPE
----------- -------- -------- ------
-100.00 6000.000 1598.823 BUBPT
-90.00 6000.000 1508.558 BUBPT
-80.00 6000.000 1482.259 BUBPT
-70.00 6000.000 1501.492 BUBPT
-60.00 6000.000 1553.468 BUBPT
-50.00 6000.000 1629.061 BUBPT
-40.00 6000.000 1721.601 BUBPT
-30.00 6000.000 1826.118 BUBPT
-20.00 6000.000 1938.845 BUBPT
-10.00 6000.000 2056.891 BUBPT
0.00 6000.000 2178.017 BUBPT
10.00 6000.000 2300.479 BUBPT
20.00 6000.000 2422.914 BUBPT
30.00 6000.000 2544.262 BUBPT
40.00 6000.000 2663.699 BUBPT
50.00 6000.000 2780.592 BUBPT
60.00 6000.000 2894.458 BUBPT
70.00 6000.000 3004.935 BUBPT
80.00 6000.000 3111.751 BUBPT
90.00 6000.000 3214.710 BUBPT
100.00 6000.000 3313.667 BUBPT
110.00 6000.000 3408.526 BUBPT
120.00 6000.000 3499.218 BUBPT
130.00 6000.000 3585.705 BUBPT
140.00 6000.000 3667.965 BUBPT
150.00 6000.000 3745.991 BUBPT
160.00 6000.000 3819.792 BUBPT
170.00 6000.000 3889.381 BUBPT
180.00 6000.000 3954.782 BUBPT
190.00 6000.000 4016.023 BUBPT
200.00 6000.000 4073.137 BUBPT
210.00 6000.000 4126.159 BUBPT

220.00 6000.000 4175.130 BUBPT

230.00 6000.000 4220.089 BUBPT
240.00 6000.000 4261.079 BUBPT
250.00 6000.000 4298.143 BUBPT
260.00 6000.000 4331.326 BUBPT
270.00 6000.000 4360.671 BUBPT
280.00 6000.000 4386.223 BUBPT
290.00 6000.000 4408.026 BUBPT
300.00 6000.000 4426.125 BUBPT
310.00 6000.000 4440.562 BUBPT
320.00 6000.000 4451.379 DEWPT
330.00 6000.000 4458.619 DEWPT
340.00 6000.000 4462.322 DEWPT
350.00 6000.000 4462.528 DEWPT
360.00 6000.000 4459.273 DEWPT
370.00 6000.000 4452.597 DEWPT
380.00 6000.000 4442.532 DEWPT
390.00 6000.000 4429.113 DEWPT
400.00 6000.000 4412.373 DEWPT
410.00 6000.000 4392.339 DEWPT
420.00 6000.000 4369.040 DEWPT
430.00 6000.000 4342.502 DEWPT
440.00 6000.000 4312.748 DEWPT
450.00 6000.000 4279.796 DEWPT
460.00 6000.000 4243.667 DEWPT
470.00 6000.000 4204.373 DEWPT
480.00 6000.000 4161.926 DEWPT
490.00 6000.000 4116.333 DEWPT
500.00 6000.000 4067.596 DEWPT
510.00 6000.000 4015.715 DEWPT
520.00 4000.000 3960.683 DEWPT
530.00 6000.000 3902.487 DEWPT
540.00 6000.000 3841.108 DEWPT
550.00 6000.000 3776.520 DEWPT
560.00 6000.000 3708.686 DEWPT
570.00 6000.000 3637.562 DEWPT
580.00 6000.000 3563.091 DEWPT
590.00 6000.000 3485.201 DEWPT
600.00 6000.000 3403.804 DEWPT
610.00 6000.000 3318.792 DEWPT
620.00 6000.000 3230.031 DEWPT
630.00 6000.000 3137.358 DEWPT
640.00 6000.000 3040.569 DEWPT
650.00 6000.000 2939.411 DEWPT
660.00 6000.000 2833.563 DEWPT
670.00 6000.000 2722.619 DEWPT
680.00 6000.000 2606.044 DEWPT
690.00 6000.000 2483.130 DEWPT
700.00 4000.000 2352.902 DEWPT
710.00 4000.000 2213.963 DEWPT
720.00 4000.000 2064.204 DEWPT
730.00 4000.000 1900.159 DEWPT
740.00 4000.000 1715.403 DEWPT
750.00 4000.000 1495.015 DEWPT
760.00 4000.000 1176.379 DEWPT
770.00 ** NONE FOUND **
780.00 ** NONE FOUND **
790.00 ** NONE FOUND **
800.00 ** NONE FOUND **
800.00 ** NONE FOUND **
790.00 ** NONE FOUND **
780.00 ** NONE FOUND **
770.00 ** NONE FOUND **
760.00 100.000 694.696 DEWPT
750.00 100.000 489.484 DEWPT
740.00 100.000 380.506 DEWPT
730.00 100.000 305.100 DEWPT
720.00 100.000 248.303 DEWPT
710.00 100.000 203.643 DEWPT
700.00 100.000 167.614 DEWPT
690.00 100.000 138.061 DEWPT
680.00 100.000 113.544 DEWPT
670.00 100.000 93.048 DEWPT
660.00 100.000 75.822 DEWPT
650.00 100.000 61.291 DEWPT
640.00 100.000 49.007 DEWPT
1LIQUID DENSITY CALCULATION

--------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507
TEMPERATURE PRESSURE LIQUID DEN (GM/CC ) ---- Z-FACTOR ----

DEGREES F PSIG DATA CALC DATA CALC
----------- -------- -------- --------- -------- --------
276.00 6000.000 0.4924 0.4989 0.00000 1.24402
4375.000 0.4530 0.4617 0.00000 0.98120
------------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507



------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
6000.0 0.9200 0.9254 0.0000 0.9254 0.0000 1.0000
5000.0 0.9613 0.9665 0.0000 0.9665 0.0000 1.0000
4500.0 0.9909 0.9927 0.0000 0.9927 0.0000 1.0000
4375.0 1.0000 1.0001 1.0000 0.9672 0.0000 0.9666
4328.0 1.0052 1.0049 0.0000 0.6967 0.0000 0.6869
4300.0 0.0000 1.0078 0.6510 0.6563 0.0000 0.6431
4267.0 1.0117 1.0113 0.0000 0.6278 0.0000 0.6111
4230.0 1.0158 1.0153 0.0000 0.6067 0.0000 0.5866
4150.0 0.0000 1.0244 0.5700 0.5787 0.0000 0.5519
4059.0 1.0368 1.0353 0.0000 0.5596 0.0000 0.5262
3960.0 0.0000 1.0479 0.5300 0.5456 0.0000 0.5057
3709.0 1.0883 1.0843 0.0000 0.5235 0.0000 0.4689
3408.0 1.1472 1.1382 0.0000 0.5063 0.0000 0.4361
2688.0 1.3595 1.3369 0.0000 0.4725 0.0000 0.3703
1962.0 1.7834 1.7349 0.0000 0.4364 0.0000 0.3076
1271.0 2.7310 2.6357 0.0000 0.3943 0.0000 0.2460
951.0 3.6866 3.5558 0.0000 0.3692 0.0000 0.2147

------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
6000.0 0.0000 1.2440 0.0000 0.0000 0.0000 0.4989 0.0000 0.0000

5000.0 0.0000 1.0832 0.0000 0.0000 0.0000 0.4777 0.0000 0.0000

4500.0 0.0000 1.0017 0.0000 0.0000 0.0000 0.4651 0.0000 0.0000
4375.0 0.0000 0.9817 0.0000 0.9683 0.0000 0.4625 0.0000 0.4358
4328.0 0.0000 0.9844 0.0000 0.9556 0.0000 0.4779 0.0000 0.4179
4300.0 0.0000 0.9842 0.0000 0.9498 0.0000 0.4836 0.0000 0.4106
4267.0 0.0000 0.9831 0.0000 0.9438 0.0000 0.4892 0.0000 0.4031
4230.0 0.0000 0.9813 0.0000 0.9376 0.0000 0.4945 0.0000 0.3957
4150.0 0.0000 0.9760 0.0000 0.9258 0.0000 0.5040 0.0000 0.3816
4059.0 0.0000 0.9683 0.0000 0.9140 0.0000 0.5127 0.0000 0.3675
3960.0 0.0000 0.9585 0.0000 0.9026 0.0000 0.5208 0.0000 0.3535
3709.0 0.0000 0.9293 0.0000 0.8787 0.0000 0.5375 0.0000 0.3216
3408.0 0.0000 0.8882 0.0000 0.8572 0.0000 0.5540 0.0000 0.2868
2688.0 0.0000 0.7709 0.0000 0.8292 0.0000 0.5879 0.0000 0.2128
1962.0 0.0000 0.6268 0.0000 0.8286 0.0000 0.6202 0.0000 0.1471
1271.0 0.0000 0.4606 0.0000 0.8542 0.0000 0.6539 0.0000 0.0910
951.0 0.0000 0.3712 0.0000 0.8758 0.0000 0.6729 0.0000 0.0669

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
6000.0 0.0000 0.0807 0.0000 0.0000 0.0000E+00
5000.0 0.0000 0.0719 0.0000 0.0000 0.0000E+00
4500.0 0.0000 0.0675 0.0000 0.0000 0.0000E+00
4375.0 0.0000 0.0667 0.0000 0.0596 0.4477E-04
4328.0 0.0000 0.0713 0.0000 0.0555 0.1137E-02
4300.0 0.0000 0.0731 0.0000 0.0539 0.2507E-02
4267.0 0.0000 0.0750 0.0000 0.0524 0.4840E-02
4230.0 0.0000 0.0768 0.0000 0.0509 0.8419E-02
4150.0 0.0000 0.0802 0.0000 0.0482 0.1985E-01
4059.0 0.0000 0.0836 0.0000 0.0457 0.3953E-01
3960.0 0.0000 0.0869 0.0000 0.0434 0.6991E-01
3709.0 0.0000 0.0943 0.0000 0.0386 0.1967E+00
3408.0 0.0000 0.1026 0.0000 0.0339 0.4677E+00
2688.0 0.0000 0.1232 0.0000 0.0254 0.1879E+01
1962.0 0.0000 0.1482 0.0000 0.0196 0.4900E+01
1271.0 0.0000 0.1811 0.0000 0.0161 0.1004E+02
951.0 0.0000 0.2031 0.0000 0.0150 0.1357E+02
---------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0584 0.0584 0.0584 0.0575 0.0571 0.0567 0.0563 0.0556 0.0548
0.0540 0.0521 0.0498 0.0434 0.0352 0.0251 0.0194
C1 0.5043 0.5043 0.5043 0.5037 0.4919 0.4870 0.4821 0.4771 0.4677 0.4581
0.4485 0.4256 0.3989 0.3312 0.2536 0.1697 0.1277

C2 0.0965 0.0965 0.0965 0.0965 0.0960 0.0958 0.0956 0.0953 0.0949 0.0944
0.0940 0.0927 0.0911 0.0860 0.0771 0.0619 0.0513
C3 0.0875 0.0875 0.0875 0.0875 0.0880 0.0882 0.0884 0.0886 0.0890 0.0894
0.0898 0.0906 0.0916 0.0933 0.0926 0.0847 0.0756
NC4 0.0589 0.0589 0.0589 0.0590 0.0601 0.0605 0.0610 0.0614 0.0623 0.0632
0.0641 0.0663 0.0689 0.0755 0.0821 0.0849 0.0820
NC5 0.0295 0.0295 0.0295 0.0295 0.0304 0.0307 0.0311 0.0314 0.0321 0.0328
0.0335 0.0352 0.0373 0.0430 0.0499 0.0564 0.0580
C6 0.0229 0.0229 0.0229 0.0229 0.0238 0.0242 0.0245 0.0249 0.0256 0.0264
0.0271 0.0289 0.0311 0.0372 0.0451 0.0541 0.0582
C8 0.0464 0.0464 0.0464 0.0464 0.0463 0.0462 0.0462 0.0462 0.0463 0.0464
0.0466 0.0474 0.0491 0.0560 0.0677 0.0832 0.0902
C14 0.0805 0.0805 0.0805 0.0809 0.0881 0.0911 0.0942 0.0973 0.1033 0.1094
0.1157 0.1307 0.1485 0.1938 0.2478 0.3186 0.3675
C30 0.0151 0.0151 0.0151 0.0152 0.0180 0.0191 0.0202 0.0213 0.0233 0.0251
0.0268 0.0303 0.0336 0.0405 0.0490 0.0612 0.0702
---------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6000. 5000. 4500. 4375. 4328. 4300. 4267. 4230. 4150. 4059.
3960. 3709. 3408. 2688. 1962. 1271. 951.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0597 0.0605 0.0608 0.0611 0.0614 0.0619 0.0624
0.0629 0.0640 0.0651 0.0672 0.0687 0.0693 0.0691
C1 0.0000 0.0000 0.0000 0.5213 0.5315 0.5354 0.5392 0.5428 0.5494 0.5556
0.5614 0.5738 0.5858 0.6061 0.6157 0.6135 0.6073
C2 0.0000 0.0000 0.0000 0.0972 0.0976 0.0978 0.0980 0.0982 0.0985 0.0988
0.0991 0.0998 0.1006 0.1027 0.1051 0.1078 0.1089
C3 0.0000 0.0000 0.0000 0.0868 0.0864 0.0862 0.0861 0.0859 0.0856 0.0854
0.0852 0.0847 0.0843 0.0841 0.0852 0.0884 0.0907
NC4 0.0000 0.0000 0.0000 0.0573 0.0564 0.0560 0.0556 0.0553 0.0547 0.0541
0.0535 0.0523 0.0511 0.0491 0.0486 0.0504 0.0526
NC5 0.0000 0.0000 0.0000 0.0283 0.0276 0.0273 0.0270 0.0268 0.0263 0.0258
0.0254 0.0244 0.0234 0.0216 0.0205 0.0207 0.0217
C6 0.0000 0.0000 0.0000 0.0216 0.0209 0.0206 0.0203 0.0200 0.0195 0.0191
0.0186 0.0176 0.0165 0.0145 0.0130 0.0127 0.0133
C8 0.0000 0.0000 0.0000 0.0466 0.0467 0.0467 0.0467 0.0467 0.0466 0.0464
0.0462 0.0455 0.0443 0.0408 0.0369 0.0344 0.0344
C14 0.0000 0.0000 0.0000 0.0701 0.0639 0.0614 0.0591 0.0567 0.0525 0.0485
0.0446 0.0362 0.0280 0.0139 0.0062 0.0028 0.0021
C30 0.0000 0.0000 0.0000 0.0110 0.0086 0.0077 0.0069 0.0062 0.0050 0.0039
0.0030 0.0016 0.0008 0.0001 0.0000 0.0000 0.0000
------------------------
0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.96834 YY = 0.59695E-01 0.52134E+00 0.97211E-01 0.86789E-01 0.57313E-01
0.28305E-01 0.21649E-01 0.46600E-01 0.70142E-01 0.10960E-01
ZX = 0.98170 XX = 0.58355E-01 0.50371E+00 0.96475E-01 0.87525E-01 0.58955E-01

0.29541E-01 0.22943E-01 0.46389E-01 0.80894E-01 0.15211E-01

KV = 0.10230E+01 0.10350E+01 0.10076E+01 0.99160E+00 0.97214E+00
0.95815E+00 0.94361E+00 0.10046E+01 0.86708E+00 0.72055E+00
0 P = 4328.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.95556 YY = 0.60478E-01 0.53154E+00 0.97649E-01 0.86367E-01 0.56361E-01
0.27585E-01 0.20896E-01 0.46678E-01 0.63854E-01 0.85962E-02
ZX = 0.98442 XX = 0.57453E-01 0.49189E+00 0.95977E-01 0.88016E-01 0.60057E-01
0.30373E-01 0.23813E-01 0.46267E-01 0.88138E-01 0.18019E-01
KV = 0.10527E+01 0.10806E+01 0.10174E+01 0.98127E+00 0.93845E+00
0.90823E+00 0.87748E+00 0.10089E+01 0.72448E+00 0.47706E+00
0 P = 4300.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.94982 YY = 0.60779E-01 0.53541E+00 0.97820E-01 0.86209E-01 0.55998E-01
0.27310E-01 0.20607E-01 0.46687E-01 0.61438E-01 0.77407E-02
ZX = 0.98416 XX = 0.57080E-01 0.48704E+00 0.95768E-01 0.88217E-01 0.60510E-01
0.30715E-01 0.24172E-01 0.46234E-01 0.91133E-01 0.19136E-01
KV = 0.10648E+01 0.10993E+01 0.10214E+01 0.97724E+00 0.92544E+00
0.88914E+00 0.85252E+00 0.10098E+01 0.67415E+00 0.40452E+00
0 P = 4267.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.94378 YY = 0.61076E-01 0.53920E+00 0.97991E-01 0.86055E-01 0.55644E-01
0.27040E-01 0.20324E-01 0.46682E-01 0.59056E-01 0.69348E-02
ZX = 0.98312 XX = 0.56697E-01 0.48209E+00 0.95551E-01 0.88420E-01 0.60973E-01
0.31066E-01 0.24540E-01 0.46214E-01 0.94206E-01 0.20246E-01
KV = 0.10772E+01 0.11185E+01 0.10255E+01 0.97325E+00 0.91260E+00
0.87040E+00 0.82819E+00 0.10101E+01 0.62688E+00 0.34252E+00
0 P = 4230.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.93764 YY = 0.61363E-01 0.54284E+00 0.98159E-01 0.85908E-01 0.55302E-01
0.26778E-01 0.20049E-01 0.46660E-01 0.56749E-01 0.61936E-02
ZX = 0.98133 XX = 0.56311E-01 0.47714E+00 0.95331E-01 0.88622E-01 0.61436E-01
0.31418E-01 0.24909E-01 0.46210E-01 0.97301E-01 0.21325E-01
KV = 0.10897E+01 0.11377E+01 0.10297E+01 0.96938E+00 0.90016E+00
0.85232E+00 0.80489E+00 0.10097E+01 0.58323E+00 0.29044E+00
0 P = 4150.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.92581 YY = 0.61890E-01 0.54940E+00 0.98474E-01 0.85647E-01 0.54684E-01
0.26302E-01 0.19548E-01 0.46573E-01 0.52529E-01 0.49502E-02
ZX = 0.97600 XX = 0.55567E-01 0.46768E+00 0.94898E-01 0.89004E-01 0.62323E-01
0.32097E-01 0.25621E-01 0.46252E-01 0.10327E+00 0.23284E-01
KV = 0.11138E+01 0.11747E+01 0.10377E+01 0.96228E+00 0.87743E+00
0.81946E+00 0.76298E+00 0.10069E+01 0.50865E+00 0.21260E+00
0 P = 4059.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.91403 YY = 0.62398E-01 0.55560E+00 0.98787E-01 0.85404E-01 0.54096E-01
0.25844E-01 0.19067E-01 0.46422E-01 0.48476E-01 0.39031E-02
ZX = 0.96830 XX = 0.54800E-01 0.45810E+00 0.94441E-01 0.89387E-01 0.63226E-01
0.32792E-01 0.26352E-01 0.46372E-01 0.10940E+00 0.25124E-01
KV = 0.11387E+01 0.12128E+01 0.10460E+01 0.95545E+00 0.85559E+00
0.78813E+00 0.72357E+00 0.10011E+01 0.44309E+00 0.15535E+00
0 P = 3960.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.90265 YY = 0.62887E-01 0.56144E+00 0.99097E-01 0.85180E-01 0.53538E-01
0.25406E-01 0.18605E-01 0.46209E-01 0.44601E-01 0.30416E-02
ZX = 0.95853 XX = 0.54014E-01 0.44845E+00 0.93961E-01 0.89767E-01 0.64141E-01
0.33502E-01 0.27098E-01 0.46579E-01 0.11566E+00 0.26826E-01
KV = 0.11643E+01 0.12519E+01 0.10547E+01 0.94890E+00 0.83469E+00
0.75834E+00 0.68658E+00 0.99206E+00 0.38562E+00 0.11339E+00
0 P = 3709.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.87873 YY = 0.63962E-01 0.57379E+00 0.99820E-01 0.84723E-01 0.52338E-01
0.24443E-01 0.17589E-01 0.45479E-01 0.36231E-01 0.16301E-02
ZX = 0.92927 XX = 0.52100E-01 0.42559E+00 0.92740E-01 0.90645E-01 0.66333E-01
0.35228E-01 0.28916E-01 0.47435E-01 0.13072E+00 0.30291E-01
KV = 0.12277E+01 0.13482E+01 0.10763E+01 0.93467E+00 0.78901E+00
0.69387E+00 0.60826E+00 0.95877E+00 0.27717E+00 0.53814E-01
0 P = 3408.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.85719 YY = 0.65074E-01 0.58581E+00 0.10064E+00 0.84324E-01 0.51140E-01
0.23448E-01 0.16531E-01 0.44318E-01 0.27956E-01 0.75735E-03
ZX = 0.88819 XX = 0.49770E-01 0.39890E+00 0.91141E-01 0.91607E-01 0.68935E-01
0.37327E-01 0.31136E-01 0.49083E-01 0.14853E+00 0.33576E-01
KV = 0.13075E+01 0.14686E+01 0.11043E+01 0.92049E+00 0.74186E+00
0.62817E+00 0.53092E+00 0.90291E+00 0.18822E+00 0.22556E-01
0 P = 2688.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82916 YY = 0.67217E-01 0.60608E+00 0.10270E+00 0.84068E-01 0.49124E-01
0.21558E-01 0.14463E-01 0.40767E-01 0.13920E-01 0.10495E-03
ZX = 0.77087 XX = 0.43404E-01 0.33119E+00 0.85962E-01 0.93337E-01 0.75527E-01
0.43007E-01 0.37249E-01 0.55969E-01 0.19383E+00 0.40520E-01

KV = 0.15486E+01 0.18300E+01 0.11947E+01 0.90069E+00 0.65041E+00

0.50127E+00 0.38829E+00 0.72839E+00 0.71813E-01 0.25900E-02
0 P = 1962.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82856 YY = 0.68706E-01 0.61568E+00 0.10513E+00 0.85240E-01 0.48577E-01
0.20454E-01 0.13046E-01 0.36922E-01 0.62295E-02 0.11536E-04
ZX = 0.62675 XX = 0.35205E-01 0.25363E+00 0.77070E-01 0.92586E-01 0.82133E-01
0.49859E-01 0.45077E-01 0.67717E-01 0.24777E+00 0.48957E-01
KV = 0.19516E+01 0.24275E+01 0.13641E+01 0.92065E+00 0.59144E+00
0.41023E+00 0.28942E+00 0.54524E+00 0.25143E-01 0.23563E-03
0 P = 1271.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.85425 YY = 0.69279E-01 0.61347E+00 0.10779E+00 0.88416E-01 0.50400E-01
0.20717E-01 0.12713E-01 0.34382E-01 0.28347E-02 0.11857E-05
ZX = 0.46057 XX = 0.25062E-01 0.16975E+00 0.61917E-01 0.84693E-01 0.84948E-01
0.56415E-01 0.54117E-01 0.83212E-01 0.31864E+00 0.61243E-01
KV = 0.27643E+01 0.36140E+01 0.17408E+01 0.10440E+01 0.59330E+00
0.36722E+00 0.23492E+00 0.41318E+00 0.88962E-02 0.19361E-04
0 P = 951.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.87580 YY = 0.69054E-01 0.60727E+00 0.10887E+00 0.90744E-01 0.52579E-01
0.21713E-01 0.13262E-01 0.34433E-01 0.20778E-02 0.41087E-06
ZX = 0.37119 XX = 0.19432E-01 0.12767E+00 0.51266E-01 0.75636E-01 0.82019E-01
0.57982E-01 0.58151E-01 0.90152E-01 0.36751E+00 0.70185E-01
KV = 0.35537E+01 0.47566E+01 0.21235E+01 0.11997E+01 0.64107E+00
0.37448E+00 0.22807E+00 0.38195E+00 0.56539E-02 0.58541E-05
-------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507


------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
4375.0 183.00 175.94 0.0000 0.0001 0.0000 0.9672 0.0000 0.9666
3700.0 138.00 148.25 0.0875 0.0811 0.5010 0.5229 0.0000 0.4677
3000.0 129.00 134.26 0.1963 0.1903 0.4500 0.4767 0.0000 0.3889
2200.0 120.00 122.90 0.3518 0.3455 0.4140 0.4287 0.0000 0.3124
1400.0 115.00 115.80 0.5273 0.5267 0.3760 0.3790 0.0000 0.2416
700.0 116.00 112.60 0.6923 0.6997 0.3330 0.3290 0.0000 0.1802

------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
4375.0 0.0000 0.9817 0.0000 0.9683 0.0000 0.4625
3700.0 0.0000 0.9281 0.8930 0.8780 0.0000 0.5380
3000.0 0.0000 0.8258 0.8580 0.8380 0.0000 0.5746
2200.0 0.0000 0.6794 0.8600 0.8265 0.0000 0.6117
1400.0 0.0000 0.4959 0.8920 0.8474 0.0000 0.6496
700.0 0.0000 0.2917 0.9390 0.8922 0.0000 0.6891


------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
4375.0 0.0000 0.0667 0.0000 0.0596 0.4477E-04
3700.0 0.0000 0.0946 0.0000 0.0384 0.2028E+00
3000.0 0.0000 0.1145 0.0000 0.0287 0.1129E+01
2200.0 0.0000 0.1410 0.0000 0.0212 0.3777E+01
1400.0 0.0000 0.1765 0.0000 0.0166 0.9029E+01
700.0 0.0000 0.2239 0.0000 0.0143 0.1687E+02
---------------------------
PRESSURE - PSIG
---------------
OIL COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

------------------------
PRESSURE - PSIG
---------------
OIL COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0520 0.0463 0.0381 0.0272 0.0147
C1 0.5037 0.4248 0.3609 0.2788 0.1840 0.0906
C2 0.0965 0.0927 0.0885 0.0807 0.0663 0.0427
C3 0.0875 0.0907 0.0928 0.0936 0.0886 0.0697
NC4 0.0590 0.0664 0.0726 0.0802 0.0862 0.0821
NC5 0.0295 0.0353 0.0404 0.0475 0.0555 0.0604
C6 0.0229 0.0290 0.0344 0.0422 0.0520 0.0616
C8 0.0464 0.0475 0.0523 0.0622 0.0766 0.0893
C14 0.0809 0.1312 0.1737 0.2290 0.3019 0.4062
C30 0.0152 0.0304 0.0381 0.0477 0.0617 0.0827
---------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0632 0.0661 0.0686 0.0695 0.0696
C1 0.5043 0.6053 0.6226 0.6337 0.6263 0.5813
C2 0.0965 0.0996 0.1011 0.1043 0.1089 0.1154
C3 0.0875 0.0827 0.0824 0.0836 0.0883 0.1024
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0229 0.0142 0.0121 0.0128 0.0107 0.0130
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 4375. 3700. 3000. 2200. 1400. 700.
-------- ------ ------ ------ ------ ------ ------
CO2 0.0597 0.0640 0.0664 0.0685 0.0696 0.0685
C1 0.5213 0.5742 0.5989 0.6138 0.6119 0.5795
C2 0.0972 0.0998 0.1018 0.1047 0.1090 0.1146
C3 0.0868 0.0847 0.0841 0.0849 0.0893 0.1008
NC4 0.0573 0.0523 0.0498 0.0486 0.0505 0.0605
NC5 0.0283 0.0244 0.0223 0.0206 0.0206 0.0249
C6 0.0216 0.0176 0.0153 0.0133 0.0126 0.0149
C8 0.0466 0.0454 0.0422 0.0375 0.0333 0.0346
C14 0.0701 0.0360 0.0190 0.0081 0.0032 0.0017

C30 0.0110 0.0016 0.0003 0.0000 0.0000 0.0000

------------------------
0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80537E-01 0.15070E-01
ZY = 0.96834 YY = 0.59695E-01 0.52134E+00 0.97211E-01 0.86789E-01 0.57313E-01
0.28305E-01 0.21649E-01 0.46600E-01 0.70142E-01 0.10960E-01
ZX = 0.98170 XX = 0.58355E-01 0.50371E+00 0.96475E-01 0.87525E-01 0.58955E-01
0.29541E-01 0.22943E-01 0.46389E-01 0.80894E-01 0.15211E-01
KV = 0.10230E+01 0.10350E+01 0.10076E+01 0.99160E+00 0.97214E+00
0.95815E+00 0.94361E+00 0.10046E+01 0.86708E+00 0.72055E+00
0 P = 3700.0 ZZ = 0.57907E-01 0.49814E+00 0.96205E-01 0.87746E-01 0.59482E-01
0.29948E-01 0.23371E-01 0.46479E-01 0.84463E-01 0.16257E-01
ZY = 0.87798 YY = 0.63997E-01 0.57418E+00 0.99845E-01 0.84709E-01 0.52298E-01
0.24411E-01 0.17555E-01 0.45448E-01 0.35959E-01 0.15938E-02
ZX = 0.92813 XX = 0.52032E-01 0.42479E+00 0.92695E-01 0.90675E-01 0.66411E-01
0.35289E-01 0.28981E-01 0.47474E-01 0.13125E+00 0.30400E-01
KV = 0.12300E+01 0.13517E+01 0.10771E+01 0.93421E+00 0.78750E+00
0.69175E+00 0.60574E+00 0.95733E+00 0.27397E+00 0.52428E-01
0 P = 3000.0 ZZ = 0.56759E-01 0.48456E+00 0.95444E-01 0.88243E-01 0.60785E-01
0.30985E-01 0.24466E-01 0.47051E-01 0.93295E-01 0.18415E-01
ZY = 0.83801 YY = 0.66418E-01 0.59887E+00 0.10185E+00 0.84058E-01 0.49821E-01
0.22261E-01 0.15250E-01 0.42241E-01 0.18980E-01 0.25343E-03
ZX = 0.82582 XX = 0.46310E-01 0.36089E+00 0.88520E-01 0.92771E-01 0.72646E-01
0.40423E-01 0.34436E-01 0.52254E-01 0.17369E+00 0.38062E-01
KV = 0.14342E+01 0.16594E+01 0.11505E+01 0.90609E+00 0.68580E+00
0.55071E+00 0.44286E+00 0.80839E+00 0.10927E+00 0.66582E-02
0 P = 2200.0 ZZ = 0.53981E-01 0.45391E+00 0.93253E-01 0.89036E-01 0.63682E-01
0.33441E-01 0.27106E-01 0.49310E-01 0.11350E+00 0.22776E-01
ZY = 0.82653 YY = 0.68472E-01 0.61378E+00 0.10468E+00 0.84899E-01 0.48565E-01
0.20631E-01 0.13333E-01 0.37526E-01 0.80824E-02 0.24599E-04
ZX = 0.67936 XX = 0.38111E-01 0.27881E+00 0.80733E-01 0.93568E-01 0.80240E-01
0.47470E-01 0.42192E-01 0.62217E-01 0.22896E+00 0.47695E-01
KV = 0.17966E+01 0.22014E+01 0.12967E+01 0.90735E+00 0.60525E+00
0.43462E+00 0.31601E+00 0.60314E+00 0.35300E-01 0.51576E-03
0 P = 1400.0 ZZ = 0.47985E-01 0.39346E+00 0.87221E-01 0.88937E-01 0.68723E-01
0.38371E-01 0.32676E-01 0.55432E-01 0.15570E+00 0.31492E-01
ZY = 0.84737 YY = 0.69648E-01 0.61187E+00 0.10902E+00 0.89297E-01 0.50513E-01
0.20558E-01 0.12553E-01 0.33313E-01 0.32343E-02 0.19020E-05
ZX = 0.49594 XX = 0.27207E-01 0.18397E+00 0.66317E-01 0.88591E-01 0.86190E-01
0.55457E-01 0.51978E-01 0.76648E-01 0.30195E+00 0.61697E-01
KV = 0.25600E+01 0.33260E+01 0.16439E+01 0.10080E+01 0.58606E+00
0.37070E+00 0.24150E+00 0.43463E+00 0.10711E-01 0.30828E-04
0 P = 700.0 ZZ = 0.36180E-01 0.28622E+00 0.71461E-01 0.82108E-01 0.73451E-01
0.46156E-01 0.42928E-01 0.67430E-01 0.24443E+00 0.49641E-01
ZY = 0.89224 YY = 0.68470E-01 0.57955E+00 0.11457E+00 0.10079E+00 0.60519E-01
0.24862E-01 0.14887E-01 0.34613E-01 0.17465E-02 0.20785E-06
ZX = 0.29174 XX = 0.14651E-01 0.90646E-01 0.42720E-01 0.69655E-01 0.82073E-01
0.60354E-01 0.61624E-01 0.89311E-01 0.40623E+00 0.82737E-01
KV = 0.46733E+01 0.63936E+01 0.26819E+01 0.14469E+01 0.73738E+00
0.41194E+00 0.24158E+00 0.38755E+00 0.42993E-02 0.25121E-05
---------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507

OBSERVED DNSAT = 0.4530 GM/CC


OBSERVED OIL FVF = 2.8520 RB/STB

CALCULATED OIL FVF = 2.7888 RB/STB

------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
385.0 80.0 0. 1783. 2187. 2259. 0.0000 1.2669 0.0000 0.8041
50.0 80.0 0. 261. 294. 292. 0.0000 1.1190 0.0000 1.1812
0.0 80.0 0. 174. 173. 174. 0.0000 1.0000 0.0000 1.8612

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
385.0 80.0 0.3765 0.3414 0.0000 0.1652 0.0000 0.6962
50.0 80.0 0.2927 0.2563 0.0000 0.0314 0.0000 0.7236
0.0 80.0 0.2434 0.2055 0.0000 0.0080 0.0000 0.7416
------------
0STAGE 1 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.90303 YY = 0.77703E-01 0.71530E+00 0.10955E+00 0.65623E-01 0.20470E-01
0.41623E-02 0.14786E-02 0.57141E-02 0.22666E-05 0.00000E+00
ZX = 0.16517 XX = 0.21160E-01 0.97222E-01 0.71328E-01 0.12971E+00 0.13304E+00
0.78384E-01 0.64228E-01 0.12488E+00 0.23591E+00 0.44142E-01
KV = 0.36722E+01 0.73574E+01 0.15358E+01 0.50593E+00 0.15386E+00
0.53102E-01 0.23021E-01 0.45756E-01 0.96080E-05 0.00000E+00
0STAGE 2 ZZ = 0.21160E-01 0.97222E-01 0.71328E-01 0.12971E+00 0.13304E+00
0.78384E-01 0.64228E-01 0.12488E+00 0.23591E+00 0.44142E-01
ZY = 0.96098 YY = 0.73985E-01 0.36439E+00 0.20596E+00 0.22278E+00 0.88951E-01
0.18117E-01 0.60952E-02 0.19721E-01 0.55682E-05 0.19770E-12
ZX = 0.03145 XX = 0.36348E-02 0.85898E-02 0.26665E-01 0.98830E-01 0.14767E+00
0.98377E-01 0.83513E-01 0.15977E+00 0.31417E+00 0.58786E-01
KV = 0.20355E+02 0.42421E+02 0.77240E+01 0.22542E+01 0.60237E+00
0.18415E+00 0.72985E-01 0.12344E+00 0.17724E-04 0.33630E-11
0STAGE 3 ZZ = 0.36348E-02 0.85898E-02 0.26665E-01 0.98830E-01 0.14767E+00
0.98377E-01 0.83513E-01 0.15977E+00 0.31417E+00 0.58786E-01
ZY = 0.97689 YY = 0.17548E-01 0.42425E-01 0.11997E+00 0.34938E+00 0.28097E+00
0.75911E-01 0.27638E-01 0.86140E-01 0.22523E-04 0.58072E-12
ZX = 0.00796 XX = 0.19677E-03 0.22905E-03 0.36097E-02 0.36920E-01 0.11473E+00
0.10393E+00 0.97320E-01 0.17796E+00 0.39179E+00 0.73312E-01
KV = 0.89182E+02 0.18522E+03 0.33235E+02 0.94631E+01 0.24490E+01
0.73042E+00 0.28399E+00 0.48403E+00 0.57489E-04 0.79212E-11

1
******************************************************************************
* *
* *
* PP PP V V TT *
* PP PP VV VV TT *
* PPPPPP V V TT *
* PP VVVV TT *
* PP VV TT *
* PP VV TT *
* *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* *
* *
* *
* *
*****************************************************************************
1 **********************************************
* *
* *
* *
* VERSION 1998.0.0 *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* *
**********************************************
SEQUENCE
-------- ---------------------------------------------------------------------
X C ------------------------------
X C DESKTOP-PVT EXAMPLE PROBLEM #1
X C TO MATCH VISCOSITY ONLY
X C BY ADJUSTING ZC
X C ------------------------------
X C
X C
1 R REGRESS
3 R 1 .25 1. 1.75
4 R 2 .25 1. 1.75
5 R 3 .25 1. 1.75
6 R 4 .25 1. 1.75

7 R 5 .25 1. 1.75
X C
9 R 10 0 X X X X
X C
11 R C1 X X X 1 X X X
12 R C6 X X X 2 X X X
13 R C8 X X X 3 X X X
14 R C14 X X X 4 X X X
15 R C30 X X X 5 X X X
X C
16 R ENDREG
X C
X C
X C ------------------------------------------------
X C EQUATION OF STATE DATA PRODUCED FROM DESKTOP-PVT
X C ------------------------------------------------
X C
1 EOS PR
2 COMPONENTS
3 CO2 C1 C2 C3 NC4 NC5 C6 C8 C14 C30
4 PROPERTIES F PSIA
5 COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB PCHOR
6 CO2 44.01 87.90 1070.90 0.2742 0.2225 0.4572355 0.0777961 49.6
7 C1 16.04 -116.60 667.80 0.2890 0.0126 0.4233482 0.0887906 71.0
8 C2 30.07 90.10 707.80 0.2850 0.0978 0.4572355 0.0777961 111.0
9 C3 44.10 206.00 616.30 0.2810 0.1541 0.4572355 0.0777961 151.0
10 NC4 58.12 305.70 550.70 0.2740 0.2015 0.4572355 0.0777961 191.0
11 NC5 72.15 385.70 488.60 0.2620 0.2524 0.4572355 0.0777961 231.0
12 C6 84.00 463.00 468.30 0.2698 0.2313 0.4572355 0.0777961 271.0
13 C8 108.82 585.69 411.09 0.2609 0.3200 0.4321023 0.0989844 351.0
14 C14 187.49 790.04 283.80 0.2411 0.5033 0.4508624 0.0709275 591.9
15 C30 387.42 1138.35 165.63 0.2067 0.9360 0.4429810 0.0700926 1236.7
16 DJK C1
17 CO2 0.1500000
18 DJK C2
19 CO2 0.1500000
20 C1 0.0000000
21 DJK C3
22 CO2 0.1500000
23 C1 0.0000000
24 C2 0.0000000
25 DJK NC4
26 CO2 0.1500000
27 C1 0.0200000
28 C2 0.0100000
29 C3 0.0100000
30 DJK NC5
31 CO2 0.1500000
32 C1 0.0200000
33 C2 0.0100000
34 C3 0.0100000
35 NC4 0.0000000
36 DJK C6
37 CO2 0.1500000
38 C1 0.0298000
39 C2 0.0100000
40 C3 0.0100000
41 NC4 0.0000000
42 NC5 0.0000000
43 DJK C8
44 CO2 0.1500000
45 C1 -0.2357281
46 C2 0.0100000
47 C3 0.0100000
48 NC4 0.0000000
49 NC5 0.0000000
50 C6 0.0000000
51 DJK C14
52 CO2 0.1500000
53 C1 -0.1329010
54 C2 0.0100000
55 C3 0.0100000
56 NC4 0.0000000
57 NC5 0.0000000
58 C6 0.0000000
59 C8 0.0000000
60 DJK C30
61 CO2 0.1500000
62 C1 -0.0346095

63 C2 0.0100000
64 C3 0.0100000
65 NC4 0.0000000
66 NC5 0.0000000
67 C6 0.0000000
68 C8 0.0000000
69 C14 0.0000000
X C
70 ENDEOS
X C
X PVTFILE
X C
X C ------------------------------
X C CONSTANT COMPOSITION EXPANSION
X C ------------------------------
X C
X C NOTE: XLIQ IS USED BECAUSE DATA IS DEFINED AS
X C LIQUID VOLUME AT PRESSURE RELATIVE TO
X C VOLUME AT SATURATION PRESSURE.
X C
71 CCEXP
72 COMPOSITION 0.0584 0.5043 0.0965 0.0875 0.0589 0.0295 0.0229
73 0.046396 0.080535 0.015069
74 TEMP 276 F
75 BUBPT 4375 PSIG
76 PRES VREL SLIQ ZG VISO VISG
77 6200 X X X .106 X
78 5780 X X X .102 X
79 5415 X X X .098 X
80 4980 X X X .095 X
81 4620 X X X .093 X
82 4375 X X X .091 X
83 4225 X X X .099 X
84 4100 X X X .101 X
85 3900 X X X .105 X
86 3700 X X X .109 .026
87 3400 X X X .114 X
88 3000 X X X .125 .022
89 2600 X X X .137 X
90 2200 X X X .153 .018
91 1800 X X X .172 X
92 1400 X X X .199 .015
93 1000 X X X .231 X
94 700 X X X .260 .014
95 0 X X X .821 X
X C
96 END
-------------------------
CONTROL VARIABLES
-----------------

---- ------ ------- ------- ------- -------
10 0 0.2000 0.0010 0.0010 0.0100

-----------------------------------------

-------- ------- ------- -------
1 0.2500 1.0000 1.7500
2 0.2500 1.0000 1.7500
3 0.2500 1.0000 1.7500
4 0.2500 1.0000 1.7500
5 0.2500 1.0000 1.7500

-------------------------------

--- ------ ---- ---- ---- ---- -------- ----- ----- ----- ------
1 CO2 0 0 0 0 0 0 0 0 0

2 C1 0 0 0 1 0 0 0 0 0
3 C2 0 0 0 0 0 0 0 0 0
4 C3 0 0 0 0 0 0 0 0 0
5 NC4 0 0 0 0 0 0 0 0 0
6 NC5 0 0 0 0 0 0 0 0 0
7 C6 0 0 0 2 0 0 0 0 0
8 C8 0 0 0 3 0 0 0 0 0
9 C14 0 0 0 4 0 0 0 0 0
10 C30 0 0 0 5 0 0 0 0 0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO

BINARY INTERACTION COEFFICIENTS.

D E
0 0

------------- -------------------
k(1) 0
k(2) 0
k(3) 0
k(4) 0
k(5) 0
k(6) 0
k(7) 0

------------------------------------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0
3 0 0
4 0 0 0
5 0 0 0 0
6 0 0 0 0 0
7 0 0 0 0 0 0
8 0 0 0 0 0 0 0
9 0 0 0 0 0 0 0 0
10 0 0 0 0 0 0 0 0 0
--------------------

-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 CO2 44.01 87.90 1070.90 0.2742 0.22250 0.45724 0.07780 49.6
2 C1 16.04 -116.60 667.80 0.2890 0.01260 0.42335 0.08879 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.45724 0.07780 111.0
4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0
5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.2698 0.23130 0.45724 0.07780 271.0
8 C8 108.82 585.69 411.09 0.2609 0.32000 0.43210 0.09898 351.0
9 C14 187.49 790.04 283.80 0.2411 0.50330 0.45086 0.07093 591.9
10 C30 387.42 1138.35 165.63 0.2067 0.93600 0.44298 0.07009 1236.7

-------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.1500
3 0.1500 0.0000

4 0.1500 0.0000 0.0000

5 0.1500 0.0200 0.0100 0.0100
6 0.1500 0.0200 0.0100 0.0100 0.0000
7 0.1500 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1500-0.2357 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1500-0.1329 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1500-0.0346 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02
k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

---------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

-----------------------------------------
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4

P in psia
T in degree F
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4
1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464
S0 S1
-0.0280370 -0.1203900

----------------------------------------------
D1 = 5.80000

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT
NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 CO2 0.210E+03 0.504E+01 0.445E-02 -0.117E-05 0.153E-09 -0.578E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12

3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12

4 C3 -0.325E+02 0.761E+01 0.415E-02 0.951E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
9 C14 0.000E+00 0.171E+02 0.786E-01 -0.118E-04 0.000E+00 0.000E+00
10 C30 0.000E+00 0.702E+01 0.153E+00 -0.199E-04 0.000E+00 0.000E+00
------------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507



------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
6200.0 0.0000 0.9185 0.0000 1.0000 0.0000 1.0000
5780.0 0.0000 0.9334 0.0000 1.0000 0.0000 1.0000
5415.0 0.0000 0.9479 0.0000 1.0000 0.0000 1.0000
4980.0 0.0000 0.9674 0.0000 1.0000 0.0000 1.0000
4620.0 0.0000 0.9860 0.0000 1.0000 0.0000 1.0000
4375.0 0.0000 1.0001 0.0000 0.9680 0.0000 0.9676
4225.0 0.0000 1.0159 0.0000 0.5950 0.0000 0.5838
4100.0 0.0000 1.0303 0.0000 0.5505 0.0000 0.5367
3900.0 0.0000 1.0560 0.0000 0.5105 0.0000 0.4955
3700.0 0.0000 1.0857 0.0000 0.4816 0.0000 0.4678
3400.0 0.0000 1.1398 0.0000 0.4439 0.0000 0.4353
3000.0 0.0000 1.2356 0.0000 0.3941 0.0000 0.3979
2600.0 0.0000 1.3711 0.0000 0.3416 0.0000 0.3626
2200.0 0.0000 1.5697 0.0000 0.2859 0.0000 0.3281
1800.0 0.0000 1.8769 0.0000 0.2278 0.0000 0.2936
1400.0 0.0000 2.3917 0.0000 0.1686 0.0000 0.2580
1000.0 0.0000 3.3740 0.0000 0.1107 0.0000 0.2197
700.0 0.0000 4.9100 0.0000 0.0703 0.0000 0.1877
0.0 0.00 280.93 0.0000 0.0007 0.0000 0.0741

------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
6200.0 0.0000 1.2759 0.0000 0.0000 0.0000 0.5027 0.0000 0.0000
5780.0 0.0000 1.2089 0.0000 0.0000 0.0000 0.4946 0.0000 0.0000
5415.0 0.0000 1.1503 0.0000 0.0000 0.0000 0.4871 0.0000 0.0000
4980.0 0.0000 1.0800 0.0000 0.0000 0.0000 0.4773 0.0000 0.0000
4620.0 0.0000 1.0213 0.0000 0.0000 0.0000 0.4683 0.0000 0.0000
4375.0 0.0000 0.9817 0.0000 0.9684 0.0000 0.4625 0.0000 0.4358
4225.0 0.0000 0.9810 0.0000 0.9368 0.0000 0.4952 0.0000 0.3947
4100.0 0.0000 0.9719 0.0000 0.9192 0.0000 0.5089 0.0000 0.3737
3900.0 0.0000 0.9521 0.0000 0.8963 0.0000 0.5251 0.0000 0.3455

3700.0 0.0000 0.9281 0.0000 0.8780 0.0000 0.5380 0.0000 0.3205

3400.0 0.0000 0.8870 0.0000 0.8567 0.0000 0.5544 0.0000 0.2859
3000.0 0.0000 0.8247 0.0000 0.8377 0.0000 0.5737 0.0000 0.2436
2600.0 0.0000 0.7548 0.0000 0.8277 0.0000 0.5918 0.0000 0.2044
2200.0 0.0000 0.6771 0.0000 0.8258 0.0000 0.6096 0.0000 0.1678
1800.0 0.0000 0.5906 0.0000 0.8322 0.0000 0.6276 0.0000 0.1334
1400.0 0.0000 0.4941 0.0000 0.8474 0.0000 0.6471 0.0000 0.1010
1000.0 0.0000 0.3855 0.0000 0.8721 0.0000 0.6697 0.0000 0.0705
700.0 0.0000 0.2936 0.0000 0.8977 0.0000 0.6909 0.0000 0.0489
0.0 0.0000 0.0086 0.0000 0.9962 0.0000 0.7800 0.0000 0.0011

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
6200.0 0.1060 0.0824 0.0000 0.0000 0.0000E+00
5780.0 0.1020 0.0788 0.0000 0.0000 0.0000E+00
5415.0 0.0980 0.0756 0.0000 0.0000 0.0000E+00
4980.0 0.0950 0.0718 0.0000 0.0000 0.0000E+00
4620.0 0.0930 0.0686 0.0000 0.0000 0.0000E+00
4375.0 0.0910 0.0667 0.0000 0.0596 0.4442E-04
4225.0 0.0990 0.0770 0.0000 0.0507 0.8978E-02
4100.0 0.1010 0.0821 0.0000 0.0468 0.2973E-01
3900.0 0.1050 0.0887 0.0000 0.0422 0.9333E-01
3700.0 0.1090 0.0946 0.0260 0.0384 0.2028E+00
3400.0 0.1140 0.1028 0.0000 0.0338 0.4770E+00
3000.0 0.1250 0.1139 0.0220 0.0287 0.1112E+01
2600.0 0.1370 0.1259 0.0000 0.0246 0.2146E+01
2200.0 0.1530 0.1393 0.0180 0.0212 0.3689E+01
1800.0 0.1720 0.1549 0.0000 0.0186 0.5869E+01
1400.0 0.1990 0.1739 0.0150 0.0166 0.8859E+01
1000.0 0.2310 0.1993 0.0000 0.0152 0.1296E+02
700.0 0.2600 0.2268 0.0140 0.0143 0.1715E+02
0.0 0.8210 0.3676 0.0000 0.0126 0.3715E+02
---------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0563 0.0551 0.0536 0.0520
0.0497 0.0463 0.0425 0.0381 0.0331 0.0272 0.0203 0.0146 0.0003
C1 0.5043 0.5043 0.5043 0.5043 0.5043 0.5037 0.4765 0.4623 0.4428 0.4248
0.3982 0.3615 0.3223 0.2802 0.2349 0.1862 0.1342 0.0936 0.0016
C2 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0953 0.0946 0.0937 0.0927
0.0911 0.0885 0.0851 0.0806 0.0743 0.0655 0.0531 0.0407 0.0009
C3 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0886 0.0892 0.0900 0.0907
0.0916 0.0927 0.0934 0.0933 0.0917 0.0871 0.0774 0.0643 0.0018

NC4 0.0589 0.0589 0.0589 0.0589 0.0589 0.0590 0.0615 0.0628 0.0647 0.0664
0.0690 0.0726 0.0764 0.0801 0.0833 0.0851 0.0828 0.0752 0.0028
NC5 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0315 0.0325 0.0339 0.0353
0.0374 0.0404 0.0438 0.0475 0.0515 0.0553 0.0579 0.0568 0.0029
C6 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0250 0.0260 0.0275 0.0290
0.0312 0.0344 0.0381 0.0423 0.0471 0.0524 0.0576 0.0600 0.0044
C8 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0462 0.0463 0.0467 0.0475
0.0491 0.0524 0.0571 0.0633 0.0710 0.0802 0.0892 0.0930 0.0060
C14 0.0805 0.0805 0.0805 0.0805 0.0805 0.0809 0.0977 0.1067 0.1193 0.1312
0.1490 0.1735 0.1998 0.2287 0.2619 0.3028 0.3589 0.4215 0.7760
C30 0.0151 0.0151 0.0151 0.0151 0.0151 0.0152 0.0215 0.0243 0.0277 0.0304
0.0337 0.0375 0.0414 0.0459 0.0513 0.0584 0.0686 0.0803 0.2033
---------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0597 0.0614 0.0622 0.0632 0.0640
0.0651 0.0664 0.0674 0.0683 0.0689 0.0693 0.0691 0.0685 0.0631
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.5213 0.5433 0.5529 0.5647 0.5742
0.5861 0.5987 0.6078 0.6137 0.6163 0.6149 0.6085 0.5992 0.5445
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0972 0.0982 0.0986 0.0993 0.0998
0.1007 0.1018 0.1030 0.1043 0.1057 0.1073 0.1087 0.1094 0.1042
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0868 0.0859 0.0855 0.0851 0.0847
0.0843 0.0840 0.0841 0.0847 0.0858 0.0876 0.0904 0.0929 0.0944
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0573 0.0553 0.0543 0.0532 0.0523
0.0511 0.0498 0.0490 0.0486 0.0487 0.0498 0.0522 0.0551 0.0634
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0283 0.0267 0.0260 0.0252 0.0244
0.0234 0.0223 0.0214 0.0207 0.0204 0.0205 0.0215 0.0232 0.0316
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0217 0.0200 0.0193 0.0183 0.0176
0.0165 0.0153 0.0143 0.0134 0.0128 0.0127 0.0131 0.0143 0.0244
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0466 0.0467 0.0465 0.0461 0.0454
0.0443 0.0424 0.0403 0.0381 0.0362 0.0347 0.0343 0.0356 0.0496
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0702 0.0565 0.0502 0.0424 0.0360
0.0278 0.0191 0.0127 0.0082 0.0052 0.0033 0.0022 0.0018 0.0249
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0110 0.0061 0.0043 0.0026 0.0016
0.0007 0.0003 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
------------------------
0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.96835 YY = 0.59694E-01 0.52132E+00 0.97210E-01 0.86790E-01 0.57314E-01
0.28306E-01 0.21651E-01 0.46600E-01 0.70152E-01 0.10964E-01
ZX = 0.98169 XX = 0.58357E-01 0.50373E+00 0.96476E-01 0.87524E-01 0.58953E-01
0.29540E-01 0.22942E-01 0.46389E-01 0.80883E-01 0.15207E-01
KV = 0.10229E+01 0.10349E+01 0.10076E+01 0.99161E+00 0.97220E+00
0.95823E+00 0.94372E+00 0.10046E+01 0.86733E+00 0.72102E+00
0 P = 4225.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01

0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01

ZY = 0.93685 YY = 0.61399E-01 0.54329E+00 0.98180E-01 0.85890E-01 0.55260E-01
0.26746E-01 0.20015E-01 0.46656E-01 0.56461E-01 0.61040E-02
ZX = 0.98105 XX = 0.56262E-01 0.47651E+00 0.95302E-01 0.88647E-01 0.61495E-01
0.31463E-01 0.24956E-01 0.46211E-01 0.97695E-01 0.21459E-01
KV = 0.10913E+01 0.11401E+01 0.10302E+01 0.96890E+00 0.89861E+00
0.85007E+00 0.80200E+00 0.10096E+01 0.57793E+00 0.28445E+00
0 P = 4100.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.91916 YY = 0.62178E-01 0.55293E+00 0.98650E-01 0.85508E-01 0.54350E-01
0.26042E-01 0.19276E-01 0.46496E-01 0.50231E-01 0.43383E-02
ZX = 0.97194 XX = 0.55138E-01 0.46231E+00 0.94644E-01 0.89219E-01 0.62829E-01
0.32485E-01 0.26029E-01 0.46310E-01 0.10670E+00 0.24334E-01
KV = 0.11277E+01 0.11960E+01 0.10423E+01 0.95841E+00 0.86505E+00
0.80167E+00 0.74054E+00 0.10040E+01 0.47078E+00 0.17828E+00
0 P = 3900.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89634 YY = 0.63161E-01 0.56465E+00 0.99276E-01 0.85059E-01 0.53228E-01
0.25160E-01 0.18346E-01 0.46057E-01 0.42441E-01 0.26203E-02
ZX = 0.95206 XX = 0.53552E-01 0.44284E+00 0.93673E-01 0.89986E-01 0.64676E-01
0.33919E-01 0.27538E-01 0.46741E-01 0.11933E+00 0.27746E-01
KV = 0.11794E+01 0.12751E+01 0.10598E+01 0.94524E+00 0.82300E+00
0.74176E+00 0.66621E+00 0.98538E+00 0.35567E+00 0.94440E-01
0 P = 3700.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.87798 YY = 0.63997E-01 0.57418E+00 0.99845E-01 0.84709E-01 0.52299E-01
0.24412E-01 0.17555E-01 0.45448E-01 0.35960E-01 0.15939E-02
ZX = 0.92813 XX = 0.52032E-01 0.42480E+00 0.92695E-01 0.90675E-01 0.66410E-01
0.35289E-01 0.28981E-01 0.47474E-01 0.13125E+00 0.30399E-01
KV = 0.12300E+01 0.13517E+01 0.10771E+01 0.93421E+00 0.78751E+00
0.69176E+00 0.60575E+00 0.95733E+00 0.27399E+00 0.52434E-01
0 P = 3400.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.85671 YY = 0.65101E-01 0.58610E+00 0.10067E+00 0.84315E-01 0.51111E-01
0.23423E-01 0.16505E-01 0.44283E-01 0.27758E-01 0.74180E-03
ZX = 0.88702 XX = 0.49706E-01 0.39818E+00 0.91095E-01 0.91632E-01 0.69005E-01
0.37384E-01 0.31197E-01 0.49137E-01 0.14900E+00 0.33656E-01
KV = 0.13097E+01 0.14719E+01 0.11051E+01 0.92015E+00 0.74069E+00
0.62655E+00 0.52905E+00 0.90123E+00 0.18629E+00 0.22041E-01
0 P = 3000.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.83772 YY = 0.66370E-01 0.59865E+00 0.10178E+00 0.84040E-01 0.49845E-01
0.22293E-01 0.15284E-01 0.42396E-01 0.19091E-01 0.25353E-03
ZX = 0.82474 XX = 0.46337E-01 0.36150E+00 0.88514E-01 0.92737E-01 0.72604E-01
0.40408E-01 0.34427E-01 0.52450E-01 0.17353E+00 0.37492E-01
KV = 0.14323E+01 0.16560E+01 0.11498E+01 0.90622E+00 0.68654E+00
0.55168E+00 0.44396E+00 0.80831E+00 0.11002E+00 0.67623E-02
0 P = 2600.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82766 YY = 0.67434E-01 0.60782E+00 0.10297E+00 0.84121E-01 0.48967E-01
0.21376E-01 0.14253E-01 0.40295E-01 0.12688E-01 0.81257E-04
ZX = 0.75484 XX = 0.42519E-01 0.32233E+00 0.85132E-01 0.93440E-01 0.76361E-01
0.43780E-01 0.38100E-01 0.57120E-01 0.19980E+00 0.41415E-01
KV = 0.15860E+01 0.18857E+01 0.12095E+01 0.90026E+00 0.64125E+00
0.48826E+00 0.37410E+00 0.70545E+00 0.63503E-01 0.19620E-02
0 P = 2200.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82577 YY = 0.68297E-01 0.61373E+00 0.10428E+00 0.84655E-01 0.48551E-01
0.20706E-01 0.13425E-01 0.38146E-01 0.81791E-02 0.24376E-04
ZX = 0.67708 XX = 0.38134E-01 0.28021E+00 0.80565E-01 0.93325E-01 0.80093E-01
0.47507E-01 0.42302E-01 0.63291E-01 0.22870E+00 0.45877E-01
KV = 0.17910E+01 0.21903E+01 0.12944E+01 0.90710E+00 0.60618E+00
0.43586E+00 0.31736E+00 0.60271E+00 0.35763E-01 0.53134E-03
0 P = 1800.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.83218 YY = 0.68933E-01 0.61628E+00 0.10574E+00 0.85772E-01 0.48741E-01
0.20361E-01 0.12849E-01 0.36150E-01 0.51628E-02 0.68466E-05
ZX = 0.59061 XX = 0.33058E-01 0.23487E+00 0.74268E-01 0.91657E-01 0.83343E-01
0.51488E-01 0.47082E-01 0.71048E-01 0.26188E+00 0.51309E-01
KV = 0.20852E+01 0.26240E+01 0.14238E+01 0.93580E+00 0.58482E+00
0.39546E+00 0.27292E+00 0.50882E+00 0.19714E-01 0.13344E-03
0 P = 1400.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.84737 YY = 0.69263E-01 0.61492E+00 0.10729E+00 0.87633E-01 0.49804E-01
0.20512E-01 0.12654E-01 0.34659E-01 0.32634E-02 0.18258E-05
ZX = 0.49413 XX = 0.27159E-01 0.18617E+00 0.65461E-01 0.87117E-01 0.85060E-01
0.55348E-01 0.52367E-01 0.80151E-01 0.30277E+00 0.58402E-01
KV = 0.25502E+01 0.33031E+01 0.16390E+01 0.10059E+01 0.58552E+00
0.37061E+00 0.24165E+00 0.43242E+00 0.10779E-01 0.31262E-04
0 P = 1000.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01

ZY = 0.87207 YY = 0.69117E-01 0.60849E+00 0.10872E+00 0.90354E-01 0.52173E-01

0.21506E-01 0.13131E-01 0.34338E-01 0.21680E-02 0.48206E-06
ZX = 0.38550 XX = 0.20333E-01 0.13423E+00 0.53087E-01 0.77362E-01 0.82794E-01
0.57895E-01 0.57598E-01 0.89226E-01 0.35889E+00 0.68591E-01
KV = 0.33992E+01 0.45333E+01 0.20480E+01 0.11679E+01 0.63015E+00
0.37147E+00 0.22798E+00 0.38484E+00 0.60410E-02 0.70280E-05
0 P = 700.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89770 YY = 0.68521E-01 0.59920E+00 0.10938E+00 0.92858E-01 0.55131E-01
0.23189E-01 0.14324E-01 0.35638E-01 0.17548E-02 0.18709E-06
ZX = 0.29363 XX = 0.14603E-01 0.93613E-01 0.40741E-01 0.64314E-01 0.75210E-01
0.56812E-01 0.60014E-01 0.92953E-01 0.42146E+00 0.80280E-01
KV = 0.46923E+01 0.64008E+01 0.26849E+01 0.14438E+01 0.73302E+00
0.40817E+00 0.23867E+00 0.38340E+00 0.41635E-02 0.23304E-05
0 P = 0.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.99620 YY = 0.63053E-01 0.54454E+00 0.10415E+00 0.94360E-01 0.63390E-01
0.31627E-01 0.24382E-01 0.49629E-01 0.24868E-01 0.53901E-06
ZX = 0.00863 XX = 0.27662E-03 0.16170E-02 0.91596E-03 0.18038E-02 0.28099E-02
0.29244E-02 0.43890E-02 0.60019E-02 0.77595E+00 0.20331E+00
KV = 0.22794E+03 0.33676E+03 0.11371E+03 0.52312E+02 0.22559E+02
0.10815E+02 0.55553E+01 0.82690E+01 0.32049E-01 0.26511E-05

---------------------------
----- ----------- ----------- ----------- -----------
1 1.00000000 0.28900000 0.00000000 0.00000000
2 1.00000000 0.26980001 0.00000000 0.00000000
3 1.00000000 0.26089999 0.00000000 0.00000000
4 1.00000000 0.24110000 0.00000000 0.00000000
5 1.00000000 0.20670000 0.00000000 0.00000000

---------------------------
----- ----------- ----------- ----------- -----------
1 1.01423220 0.29311311 0.01423220 0.00411311
2 0.97102764 0.26198326 -0.02897236 -0.00781674
3 0.92489923 0.24130620 -0.07510077 -0.01959379
4 1.01792504 0.24542173 0.01792504 0.00432173
5 1.22315734 0.25282662 0.22315734 0.04612662

---------------------------
----- ----------- ----------- ----------- -----------
1 1.12402743 0.32484393 0.10979523 0.03173082
2 0.94937711 0.25614195 -0.02165054 -0.00584131
3 0.84873991 0.22143624 -0.07615932 -0.01986997
4 0.86975197 0.20969720 -0.14817307 -0.03572453
5 1.52833219 0.31590626 0.30517485 0.06307964

---------------------------
----- ----------- ----------- ----------- -----------
1 1.08466183 0.31346727 -0.03936561 -0.01137666
2 1.01153286 0.27291157 0.06215575 0.01676962
3 0.98691399 0.25748585 0.13817408 0.03604962
4 0.76975791 0.18558863 -0.09999406 -0.02410857
5 1.74977833 0.36167918 0.22144614 0.04577292


---------------------------
----- ----------- ----------- ----------- -----------
1 1.07657204 0.31112933 -0.00808978 -0.00233795
2 1.61547698 0.43585570 0.60394412 0.16294413
3 0.76115014 0.19858406 -0.22576386 -0.05890179
4 0.76010579 0.18326150 -0.00965212 -0.00232713
5 1.74977833 0.36167918 0.00000000 0.00000000
THE RELATIVE CHANGE IN THE OBJECTIVE FUNCTION WAS LESS THAN TOL3 = 0.01000
--------------------

-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 CO2 44.01 87.90 1070.90 0.2742 0.22250 0.45724 0.07780 49.6
2 C1 16.04 -116.60 667.80 0.3111 0.01260 0.42335 0.08879 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.45724 0.07780 111.0
4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0
5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.4359 0.23130 0.45724 0.07780 271.0
8 C8 108.82 585.69 411.09 0.1986 0.32000 0.43210 0.09898 351.0
9 C14 187.49 790.04 283.80 0.1833 0.50330 0.45086 0.07093 591.9
10 C30 387.42 1138.35 165.63 0.3617 0.93600 0.44298 0.07009 1236.7

-------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.1500
3 0.1500 0.0000
4 0.1500 0.0000 0.0000
5 0.1500 0.0200 0.0100 0.0100
6 0.1500 0.0200 0.0100 0.0100 0.0000
7 0.1500 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1500-0.2357 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1500-0.1329 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1500-0.0346 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02
k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

---------------------------------------
1 2 3 4 5 6 7 8 9 10
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000


-----------------------------------------
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4

P in psia
T in degree F
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4
1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464
S0 S1
-0.0280370 -0.1203900

----------------------------------------------
D1 = 5.80000

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT
NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 CO2 0.210E+03 0.504E+01 0.445E-02 -0.117E-05 0.153E-09 -0.578E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12
4 C3 -0.325E+02 0.761E+01 0.415E-02 0.951E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00
9 C14 0.000E+00 0.171E+02 0.786E-01 -0.118E-04 0.000E+00 0.000E+00
10 C30 0.000E+00 0.702E+01 0.153E+00 -0.199E-04 0.000E+00 0.000E+00
------------------------------

--------- -------------
CO2 0.05840
C1 0.50430
C2 0.09650
C3 0.08750
NC4 0.05890
NC5 0.02950
C6 0.02290
C8 0.04640
C14 0.08054
C30 0.01507





------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
6200.0 0.0000 0.9185 0.0000 1.0000 0.0000 1.0000
5780.0 0.0000 0.9334 0.0000 1.0000 0.0000 1.0000
5415.0 0.0000 0.9479 0.0000 1.0000 0.0000 1.0000
4980.0 0.0000 0.9674 0.0000 1.0000 0.0000 1.0000
4620.0 0.0000 0.9860 0.0000 1.0000 0.0000 1.0000
4375.0 0.0000 1.0001 0.0000 0.9680 0.0000 0.9676
4225.0 0.0000 1.0159 0.0000 0.5950 0.0000 0.5838
4100.0 0.0000 1.0303 0.0000 0.5505 0.0000 0.5367
3900.0 0.0000 1.0560 0.0000 0.5105 0.0000 0.4955
3700.0 0.0000 1.0857 0.0000 0.4816 0.0000 0.4678
3400.0 0.0000 1.1398 0.0000 0.4439 0.0000 0.4353
3000.0 0.0000 1.2356 0.0000 0.3941 0.0000 0.3979
2600.0 0.0000 1.3711 0.0000 0.3416 0.0000 0.3626
2200.0 0.0000 1.5697 0.0000 0.2859 0.0000 0.3281
1800.0 0.0000 1.8769 0.0000 0.2278 0.0000 0.2936
1400.0 0.0000 2.3917 0.0000 0.1686 0.0000 0.2580
1000.0 0.0000 3.3740 0.0000 0.1107 0.0000 0.2197
700.0 0.0000 4.9100 0.0000 0.0703 0.0000 0.1877
0.0 0.00 280.93 0.0000 0.0007 0.0000 0.0741

------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
6200.0 0.0000 1.2759 0.0000 0.0000 0.0000 0.5027 0.0000 0.0000
5780.0 0.0000 1.2089 0.0000 0.0000 0.0000 0.4946 0.0000 0.0000
5415.0 0.0000 1.1503 0.0000 0.0000 0.0000 0.4871 0.0000 0.0000
4980.0 0.0000 1.0800 0.0000 0.0000 0.0000 0.4773 0.0000 0.0000
4620.0 0.0000 1.0213 0.0000 0.0000 0.0000 0.4683 0.0000 0.0000
4375.0 0.0000 0.9817 0.0000 0.9684 0.0000 0.4625 0.0000 0.4358
4225.0 0.0000 0.9810 0.0000 0.9368 0.0000 0.4952 0.0000 0.3947
4100.0 0.0000 0.9719 0.0000 0.9192 0.0000 0.5089 0.0000 0.3737
3900.0 0.0000 0.9521 0.0000 0.8963 0.0000 0.5251 0.0000 0.3455
3700.0 0.0000 0.9281 0.0000 0.8780 0.0000 0.5380 0.0000 0.3205
3400.0 0.0000 0.8870 0.0000 0.8567 0.0000 0.5544 0.0000 0.2859
3000.0 0.0000 0.8247 0.0000 0.8377 0.0000 0.5737 0.0000 0.2436
2600.0 0.0000 0.7548 0.0000 0.8277 0.0000 0.5918 0.0000 0.2044
2200.0 0.0000 0.6771 0.0000 0.8258 0.0000 0.6096 0.0000 0.1678
1800.0 0.0000 0.5906 0.0000 0.8322 0.0000 0.6276 0.0000 0.1334
1400.0 0.0000 0.4941 0.0000 0.8474 0.0000 0.6471 0.0000 0.1010
1000.0 0.0000 0.3855 0.0000 0.8721 0.0000 0.6697 0.0000 0.0705
700.0 0.0000 0.2936 0.0000 0.8977 0.0000 0.6909 0.0000 0.0489
0.0 0.0000 0.0086 0.0000 0.9962 0.0000 0.7800 0.0000 0.0011

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
6200.0 0.1060 0.0886 0.0000 0.0000 0.0000E+00
5780.0 0.1020 0.0844 0.0000 0.0000 0.0000E+00
5415.0 0.0980 0.0807 0.0000 0.0000 0.0000E+00
4980.0 0.0950 0.0763 0.0000 0.0000 0.0000E+00
4620.0 0.0930 0.0727 0.0000 0.0000 0.0000E+00
4375.0 0.0910 0.0705 0.0000 0.0612 0.4442E-04
4225.0 0.0990 0.0855 0.0000 0.0507 0.8978E-02
4100.0 0.1010 0.0931 0.0000 0.0465 0.2973E-01
3900.0 0.1050 0.1028 0.0000 0.0418 0.9333E-01
3700.0 0.1090 0.1109 0.0260 0.0381 0.2028E+00
3400.0 0.1140 0.1215 0.0000 0.0336 0.4770E+00
3000.0 0.1250 0.1344 0.0220 0.0288 0.1112E+01
2600.0 0.1370 0.1476 0.0000 0.0248 0.2146E+01
2200.0 0.1530 0.1621 0.0180 0.0215 0.3689E+01
1800.0 0.1720 0.1791 0.0000 0.0188 0.5869E+01
1400.0 0.1990 0.2006 0.0150 0.0168 0.8859E+01
1000.0 0.2310 0.2305 0.0000 0.0152 0.1296E+02
700.0 0.2600 0.2641 0.0140 0.0144 0.1715E+02
0.0 0.8210 0.8003 0.0000 0.0126 0.3715E+02
---------------------------

PRESSURE - PSIG
-----------------
OIL COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
OIL COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0584 0.0584 0.0584 0.0584 0.0584 0.0584 0.0563 0.0551 0.0536 0.0520
0.0497 0.0463 0.0425 0.0381 0.0331 0.0272 0.0203 0.0146 0.0003
C1 0.5043 0.5043 0.5043 0.5043 0.5043 0.5037 0.4765 0.4623 0.4428 0.4248
0.3982 0.3615 0.3223 0.2802 0.2349 0.1862 0.1342 0.0936 0.0016
C2 0.0965 0.0965 0.0965 0.0965 0.0965 0.0965 0.0953 0.0946 0.0937 0.0927
0.0911 0.0885 0.0851 0.0806 0.0743 0.0655 0.0531 0.0407 0.0009
C3 0.0875 0.0875 0.0875 0.0875 0.0875 0.0875 0.0886 0.0892 0.0900 0.0907
0.0916 0.0927 0.0934 0.0933 0.0917 0.0871 0.0774 0.0643 0.0018
NC4 0.0589 0.0589 0.0589 0.0589 0.0589 0.0590 0.0615 0.0628 0.0647 0.0664
0.0690 0.0726 0.0764 0.0801 0.0833 0.0851 0.0828 0.0752 0.0028
NC5 0.0295 0.0295 0.0295 0.0295 0.0295 0.0295 0.0315 0.0325 0.0339 0.0353
0.0374 0.0404 0.0438 0.0475 0.0515 0.0553 0.0579 0.0568 0.0029
C6 0.0229 0.0229 0.0229 0.0229 0.0229 0.0229 0.0250 0.0260 0.0275 0.0290
0.0312 0.0344 0.0381 0.0423 0.0471 0.0524 0.0576 0.0600 0.0044
C8 0.0464 0.0464 0.0464 0.0464 0.0464 0.0464 0.0462 0.0463 0.0467 0.0475
0.0491 0.0524 0.0571 0.0633 0.0710 0.0802 0.0892 0.0930 0.0060
C14 0.0805 0.0805 0.0805 0.0805 0.0805 0.0809 0.0977 0.1067 0.1193 0.1312
0.1490 0.1735 0.1998 0.2287 0.2619 0.3028 0.3589 0.4215 0.7760
C30 0.0151 0.0151 0.0151 0.0151 0.0151 0.0152 0.0215 0.0243 0.0277 0.0304
0.0337 0.0375 0.0414 0.0459 0.0513 0.0584 0.0686 0.0803 0.2033
---------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

--------------------------------
PRESSURE - PSIG
-----------------
GAS COMP 6200. 5780. 5415. 4980. 4620. 4375. 4225. 4100. 3900. 3700.
3400. 3000. 2600. 2200. 1800. 1400. 1000. 700. 0.
-------- ------ ------ ------ ------ ------ ------ ------ ------ ------ ------
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0597 0.0614 0.0622 0.0632 0.0640
0.0651 0.0664 0.0674 0.0683 0.0689 0.0693 0.0691 0.0685 0.0631
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.5213 0.5433 0.5529 0.5647 0.5742
0.5861 0.5987 0.6078 0.6137 0.6163 0.6149 0.6085 0.5992 0.5445
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0972 0.0982 0.0986 0.0993 0.0998
0.1007 0.1018 0.1030 0.1043 0.1057 0.1073 0.1087 0.1094 0.1042
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0868 0.0859 0.0855 0.0851 0.0847
0.0843 0.0840 0.0841 0.0847 0.0858 0.0876 0.0904 0.0929 0.0944
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0573 0.0553 0.0543 0.0532 0.0523
0.0511 0.0498 0.0490 0.0486 0.0487 0.0498 0.0522 0.0551 0.0634
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0283 0.0267 0.0260 0.0252 0.0244
0.0234 0.0223 0.0214 0.0207 0.0204 0.0205 0.0215 0.0232 0.0316
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0217 0.0200 0.0193 0.0183 0.0176
0.0165 0.0153 0.0143 0.0134 0.0128 0.0127 0.0131 0.0143 0.0244
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0466 0.0467 0.0465 0.0461 0.0454
0.0443 0.0424 0.0403 0.0381 0.0362 0.0347 0.0343 0.0356 0.0496
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0702 0.0565 0.0502 0.0424 0.0360
0.0278 0.0191 0.0127 0.0082 0.0052 0.0033 0.0022 0.0018 0.0249
C30 0.0000 0.0000 0.0000 0.0000 0.0000 0.0110 0.0061 0.0043 0.0026 0.0016
0.0007 0.0003 0.0001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
------------------------
0 P = 4375.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.96835 YY = 0.59694E-01 0.52132E+00 0.97210E-01 0.86790E-01 0.57314E-01
0.28306E-01 0.21651E-01 0.46600E-01 0.70152E-01 0.10964E-01
ZX = 0.98169 XX = 0.58357E-01 0.50373E+00 0.96476E-01 0.87524E-01 0.58953E-01
0.29540E-01 0.22942E-01 0.46389E-01 0.80883E-01 0.15207E-01
KV = 0.10229E+01 0.10349E+01 0.10076E+01 0.99161E+00 0.97220E+00
0.95823E+00 0.94372E+00 0.10046E+01 0.86733E+00 0.72102E+00
0 P = 4225.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.93685 YY = 0.61399E-01 0.54329E+00 0.98180E-01 0.85890E-01 0.55260E-01
0.26746E-01 0.20015E-01 0.46656E-01 0.56461E-01 0.61040E-02
ZX = 0.98105 XX = 0.56262E-01 0.47651E+00 0.95302E-01 0.88647E-01 0.61495E-01
0.31463E-01 0.24956E-01 0.46211E-01 0.97695E-01 0.21459E-01
KV = 0.10913E+01 0.11401E+01 0.10302E+01 0.96890E+00 0.89861E+00
0.85007E+00 0.80200E+00 0.10096E+01 0.57793E+00 0.28445E+00
0 P = 4100.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.91916 YY = 0.62178E-01 0.55293E+00 0.98650E-01 0.85508E-01 0.54350E-01
0.26042E-01 0.19276E-01 0.46496E-01 0.50231E-01 0.43383E-02
ZX = 0.97194 XX = 0.55138E-01 0.46231E+00 0.94644E-01 0.89219E-01 0.62829E-01
0.32485E-01 0.26029E-01 0.46310E-01 0.10670E+00 0.24334E-01
KV = 0.11277E+01 0.11960E+01 0.10423E+01 0.95841E+00 0.86505E+00
0.80167E+00 0.74054E+00 0.10040E+01 0.47078E+00 0.17828E+00
0 P = 3900.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89634 YY = 0.63161E-01 0.56465E+00 0.99276E-01 0.85059E-01 0.53228E-01
0.25160E-01 0.18346E-01 0.46057E-01 0.42441E-01 0.26203E-02
ZX = 0.95206 XX = 0.53552E-01 0.44284E+00 0.93673E-01 0.89986E-01 0.64676E-01
0.33919E-01 0.27538E-01 0.46741E-01 0.11933E+00 0.27746E-01
KV = 0.11794E+01 0.12751E+01 0.10598E+01 0.94524E+00 0.82300E+00
0.74176E+00 0.66621E+00 0.98538E+00 0.35567E+00 0.94440E-01
0 P = 3700.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.87798 YY = 0.63997E-01 0.57418E+00 0.99845E-01 0.84709E-01 0.52299E-01
0.24412E-01 0.17555E-01 0.45448E-01 0.35960E-01 0.15939E-02
ZX = 0.92813 XX = 0.52032E-01 0.42480E+00 0.92695E-01 0.90675E-01 0.66410E-01
0.35289E-01 0.28981E-01 0.47474E-01 0.13125E+00 0.30399E-01
KV = 0.12300E+01 0.13517E+01 0.10771E+01 0.93421E+00 0.78751E+00
0.69176E+00 0.60575E+00 0.95733E+00 0.27399E+00 0.52434E-01
0 P = 3400.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.85671 YY = 0.65101E-01 0.58610E+00 0.10067E+00 0.84315E-01 0.51111E-01
0.23423E-01 0.16505E-01 0.44283E-01 0.27758E-01 0.74180E-03
ZX = 0.88702 XX = 0.49706E-01 0.39818E+00 0.91095E-01 0.91632E-01 0.69005E-01
0.37384E-01 0.31197E-01 0.49137E-01 0.14900E+00 0.33656E-01
KV = 0.13097E+01 0.14719E+01 0.11051E+01 0.92015E+00 0.74069E+00

0.62655E+00 0.52905E+00 0.90123E+00 0.18629E+00 0.22041E-01

0 P = 3000.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.83772 YY = 0.66370E-01 0.59865E+00 0.10178E+00 0.84040E-01 0.49845E-01
0.22293E-01 0.15284E-01 0.42396E-01 0.19091E-01 0.25353E-03
ZX = 0.82474 XX = 0.46337E-01 0.36150E+00 0.88514E-01 0.92737E-01 0.72604E-01
0.40408E-01 0.34427E-01 0.52450E-01 0.17353E+00 0.37492E-01
KV = 0.14323E+01 0.16560E+01 0.11498E+01 0.90622E+00 0.68654E+00
0.55168E+00 0.44396E+00 0.80831E+00 0.11002E+00 0.67623E-02
0 P = 2600.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82766 YY = 0.67434E-01 0.60782E+00 0.10297E+00 0.84121E-01 0.48967E-01
0.21376E-01 0.14253E-01 0.40295E-01 0.12688E-01 0.81257E-04
ZX = 0.75484 XX = 0.42519E-01 0.32233E+00 0.85132E-01 0.93440E-01 0.76361E-01
0.43780E-01 0.38100E-01 0.57120E-01 0.19980E+00 0.41415E-01
KV = 0.15860E+01 0.18857E+01 0.12095E+01 0.90026E+00 0.64125E+00
0.48826E+00 0.37410E+00 0.70545E+00 0.63503E-01 0.19620E-02
0 P = 2200.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.82577 YY = 0.68297E-01 0.61373E+00 0.10428E+00 0.84655E-01 0.48551E-01
0.20706E-01 0.13425E-01 0.38146E-01 0.81791E-02 0.24376E-04
ZX = 0.67708 XX = 0.38134E-01 0.28021E+00 0.80565E-01 0.93325E-01 0.80093E-01
0.47507E-01 0.42302E-01 0.63291E-01 0.22870E+00 0.45877E-01
KV = 0.17910E+01 0.21903E+01 0.12944E+01 0.90710E+00 0.60618E+00
0.43586E+00 0.31736E+00 0.60271E+00 0.35763E-01 0.53134E-03
0 P = 1800.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.83218 YY = 0.68933E-01 0.61628E+00 0.10574E+00 0.85772E-01 0.48741E-01
0.20361E-01 0.12849E-01 0.36150E-01 0.51628E-02 0.68466E-05
ZX = 0.59061 XX = 0.33058E-01 0.23487E+00 0.74268E-01 0.91657E-01 0.83343E-01
0.51488E-01 0.47082E-01 0.71048E-01 0.26188E+00 0.51309E-01
KV = 0.20852E+01 0.26240E+01 0.14238E+01 0.93580E+00 0.58482E+00
0.39546E+00 0.27292E+00 0.50882E+00 0.19714E-01 0.13344E-03
0 P = 1400.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.84737 YY = 0.69263E-01 0.61492E+00 0.10729E+00 0.87633E-01 0.49804E-01
0.20512E-01 0.12654E-01 0.34659E-01 0.32634E-02 0.18258E-05
ZX = 0.49413 XX = 0.27159E-01 0.18617E+00 0.65461E-01 0.87117E-01 0.85060E-01
0.55348E-01 0.52367E-01 0.80151E-01 0.30277E+00 0.58402E-01
KV = 0.25502E+01 0.33031E+01 0.16390E+01 0.10059E+01 0.58552E+00
0.37061E+00 0.24165E+00 0.43242E+00 0.10779E-01 0.31262E-04
0 P = 1000.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.87207 YY = 0.69117E-01 0.60849E+00 0.10872E+00 0.90354E-01 0.52173E-01
0.21506E-01 0.13131E-01 0.34338E-01 0.21680E-02 0.48206E-06
ZX = 0.38550 XX = 0.20333E-01 0.13423E+00 0.53087E-01 0.77362E-01 0.82794E-01
0.57895E-01 0.57598E-01 0.89226E-01 0.35889E+00 0.68591E-01
KV = 0.33992E+01 0.45333E+01 0.20480E+01 0.11679E+01 0.63015E+00
0.37147E+00 0.22798E+00 0.38484E+00 0.60410E-02 0.70280E-05
0 P = 700.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.89770 YY = 0.68521E-01 0.59920E+00 0.10938E+00 0.92858E-01 0.55131E-01
0.23189E-01 0.14324E-01 0.35638E-01 0.17548E-02 0.18709E-06
ZX = 0.29363 XX = 0.14603E-01 0.93613E-01 0.40741E-01 0.64314E-01 0.75210E-01
0.56812E-01 0.60014E-01 0.92953E-01 0.42146E+00 0.80280E-01
KV = 0.46923E+01 0.64008E+01 0.26849E+01 0.14438E+01 0.73302E+00
0.40817E+00 0.23867E+00 0.38340E+00 0.41635E-02 0.23304E-05
0 P = 0.0 ZZ = 0.58400E-01 0.50430E+00 0.96500E-01 0.87500E-01 0.58900E-01
0.29500E-01 0.22900E-01 0.46396E-01 0.80535E-01 0.15069E-01
ZY = 0.99620 YY = 0.63053E-01 0.54454E+00 0.10415E+00 0.94360E-01 0.63390E-01
0.31627E-01 0.24382E-01 0.49629E-01 0.24868E-01 0.53901E-06
ZX = 0.00863 XX = 0.27662E-03 0.16170E-02 0.91596E-03 0.18038E-02 0.28099E-02
0.29244E-02 0.43890E-02 0.60019E-02 0.77595E+00 0.20331E+00
KV = 0.22794E+03 0.33676E+03 0.11371E+03 0.52312E+02 0.22559E+02
0.10815E+02 0.55553E+01 0.82690E+01 0.32049E-01 0.26511E-05

D.2 Example 2
The following example demonstrates the use of DESKTOP-PVT to
calculate equation-of-state parameters to match surface separation
measurements. Included is a standard laboratory report for a gas
condensate sample; with a constant composition expansion test, a constant
volume depletion test, and separation tests for each gas sample from the
constant volume depletion test.
The DESKTOP-PVT listing, which follows the laboratory report, shows the
final step in the fluid analysis process. In this step, a set of separator
equation-of-state parameters, a and b, are calculated, distinct from the
reservoir parameters. The reservoir parameters have been calculated by
regression in a previous run and are used as the starting values for this
run. The data that is matched in this run is derived from page 5 of the
laboratory report.
D.2.1 Lab Report

Reservoir Fluid Study

GOOD OIL COMPANY
Condensate No. 7 Well
Productive Field
Samson County, Texas
RFL 82000

Good Oil Company

P.O. Box 100
Oil City, TX
Attention: Mr. John Jones
Subject: Reservoir Fluid Study

Product Field
Samson County, Texas
RFL 82000
Gentlemen:

Samples of separator liquid and vapor were collected rom the subject well by a representative of Core
Laboratories, Inc. on March 23, 1982. The samples represent production from the Pay Sand and they
were collected for use in a reservoir fluid study. Presented in the following report are the results of this
study as requested by Good Oil Company.
Using the factors shown on page one, the producing gas/luiquid ratio was claculated to be 4697 cubic
feet of separator gas at 14.65 psia and 60 F. per barrel of stock tank liquid at 60F. The separator liquid
shrinkage factor was determined experimentally in the laboratory and the producing ratio was found to
be equivalent to 3944 standard cubic feet of separator gas per barrel of separator liquid at 440 psig and
60F. The separator products were then physically recombined in this gas/liquid ratio and the resulting
fluid was used for teh entire study. The measured hydrocarbon compositions of the separator products
were used in conjunction with the producing gas/liquid ratio to calculate the hydrocarbon composition
of the well stream material. All of the aforementioned compositional data may be found on page two.
A small quantity of the reservoir fluid was then charged to a high pressure visual cell and thermally
expanded to the reported reservoir temperature of 256F. During a constant composition expansion at
this temperature, the fluid exhibited a retrograde dew point at 6010 psig. The results of the pressure-
volume measurements at 256F may be found on page three, along with the deviation factor
measurements at the dew point pressure and above.
A large smaple of the reservoir fluid was then charged to a high pressure visual cell at 256F and the
volume at the dew point was determined. A simulated constant volume depletion was then performed
by making a series of expansions and constant pressure displacements, with each displacement
terminating at the original saturated volume. The well stream displaced at each displacement level was
charged to low temperature fractional distillation equipment for volume measurement and
compositional analysis. The results of the constant volume depletion at the reservoir temperature may
be found on page four.
The smooth well stream compositons were then used with published equilibrium ratios to calculate the
comulative and instantaneous surface recoveries tha may be expected during pressure depletion of teh
reseroivr. The cumulative recovery calculatiosn were based upon one MMSCF of oroginal fluid and
they are presented on page five. A summary of the instantaneous surface recovery calculatiosn is given
on page six.
Good Oil Company Page Two

Visual measurements of the retrograde condensate were performed at several points during the constant
composition expansion and at each point during the constant voluem depletion at the reservoir
temperature. The maximum observed volume of retrograde condensate was 25.0 percent of the
hydrocarbon pore space. A tabulation of the retrograde liquid measurements may be found on page
seven; a graphical interpretation of these data is given on page twelve.

Thank you for the opportunity to be of service to Good Oil Company. Shoudl you have any quetion or if
we may be of further assistanc ein any manner, please feel free to call upon us.
Very truly yours,
CORE LABORATORIES, INC.
Manager













D.2.2 Sample File

1
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* *
* *
* PP PP V V TT *
* PP PP VV VV TT *
* PPPPPP V V TT *
* PP VVVV TT *
* PP VV TT *
* PP VV TT *
* *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* *
* *
* *
* *
******************************************************************************
1 *********************************************
* *
* *
* *
* VERSION 1998.0.0 *
* *
* COPYRIGHT 1984, 1985, 1986, 1987, 1988 *
* 1989, 1990, 1991, 1992, 1993 *
* 1994, 1995, 1996, 1997, 1998 *
* *
*********************************************
SEQUENCE
-------- ---------------------------------------------------------------------
X C -------------------------
X C EOSPAK EXAMPLE PROBLEM #2
X C GAS CONDENSATE EXAMPLE
X C -------------------------
X C
X C -------------------------
X C MATCH SEPARATOR DATA ONLY
X C WITH NEW OMEGAA, OMEGAB
X C -------------------------

X C
X C
X C -------------------------
X C REGRESSION VARIABLES ARE:
X C (1) OMEGA C1
X C (2) OMEGB C1
X C (3) OMEGA C2
X C (4) OMEGB C2
X C (5) OMEGA C8
X C (6) OMEGB C8
X C (7) OMEGA C14
X C (8) OMEGB C14
X C (9) OMEGB C20
X C (10) OMEGB C20
X C (11) OMEGB C34
X C (12) OMEGB C34
X C -------------------------
X C
1 R REGRESS
X C
3 R 1 .5 1.0 1.5
4 R 2 .5 1.0 1.5
5 R 3 .5 1.0 1.5
6 R 4 .5 1.0 1.5
7 R 5 .5 1.0 1.5
8 R 6 .5 1.0 1.5
9 R 7 .5 1.0 1.5
10 R 8 .5 1.0 1.5
11 R 9 .5 1.0 1.5
12 R 10 .5 1.0 1.5
13 R 11 .5 1.0 1.5
14 R 12 .5 1.0 1.5
X C
16 R 10 0 X X X X
X C
18 R C1 X X X X X 1 2
19 R C2 X X X X X 3 4
20 R C8 X X X X X 5 6
21 R C14 X X X X X 7 8
22 R C20 X X X X X 9 10
23 R C34 X X X X X 11 12
X C
24 R ENDREG
X C
X C
X C ----------------------------------------
X C INITIALIZE AFTER SPLIT OF HEAVY FRACTION
X C ----------------------------------------
X C
1 EOS PR
2 COMPONENTS
3 N2 C1 C2 C3 NC4 NC5 C6 C8 C14 C20 C34
4 PROPERTIES
5 COMP MW TC PC ZC ACENTRIC OMEGAA OMEGAB
6 N2 28.01 -232.40 493.00 0.2910 0.0372 0.4572355 0.0777961 35.0
7 C1 16.04 -116.60 667.80 0.2890 0.0126 0.4572355 0.0777961 71.0
8 C2 30.07 90.10 707.80 0.2850 0.0978 0.4572355 0.0777961 111.0
9 C3 44.10 206.00 616.30 0.2810 0.1541 0.4572355 0.0777961 151.0
10 NC4 58.12 305.70 550.70 0.2740 0.2015 0.4572355 0.0777961 191.0
11 NC5 72.15 385.70 488.60 0.2620 0.2524 0.4572355 0.0777961 231.0
12 C6 84.00 463.00 468.30 0.2698 0.2313 0.4572355 0.0777961 271.0
13 C8 109.30 602.85 415.02 0.2618 0.3227 0.4047023 0.0816778 351.0
14 C14 183.86 807.42 282.76 0.2350 0.4996 0.4554216 0.0759684 591.9
15 C20 279.75 1000.71 207.54 0.2156 0.7045 0.4356328 0.0799298 833.7
16 C34 438.36 1238.40 150.02 0.1979 1.0493 0.4635509 0.0735474 1397.9
17 DJK C1
18 N2 0.1200000
19 DJK C2
20 N2 0.1200000
21 C1 0.0000000
22 DJK C3
23 N2 0.1200000
24 C1 0.0000000
25 C2 0.0000000
26 DJK NC4
27 N2 0.1200000
28 C1 0.0200000
29 C2 0.0100000

30 C3 0.0100000
31 DJK NC5
32 N2 0.1200000
33 C1 0.0200000
34 C2 0.0100000
35 C3 0.0100000
36 NC4 0.0000000
37 DJK C6
38 N2 0.1200000
39 C1 0.0298000
40 C2 0.0100000
41 C3 0.0100000
42 NC4 0.0000000
43 NC5 0.0000000
44 DJK C8
45 N2 0.1200000
46 C1 0.1346893
47 C2 0.0100000
48 C3 0.0100000
49 NC4 0.0000000
50 NC5 0.0000000
51 C6 0.0000000
52 DJK C14
53 N2 0.1200000
54 C1 0.0357530
55 C2 0.0100000
56 C3 0.0100000
57 NC4 0.0000000
58 NC5 0.0000000
59 C6 0.0000000
60 C8 0.0000000
61 DJK C20
62 N2 0.1200000
63 C1 0.0164643
64 C2 0.0100000
65 C3 0.0100000
66 NC4 0.0000000
67 NC5 0.0000000
68 C6 0.0000000
69 C8 0.0000000
70 C14 0.0000000
71 DJK C34
72 N2 0.1200000
73 C1 0.0848269
74 C2 0.0100000
75 C3 0.0100000
76 NC4 0.0000000
77 NC5 0.0000000
78 C6 0.0000000
79 C8 0.0000000
80 C14 0.0000000
81 C20 0.0000000
X C
82 ENDEOS
X C
X PVTFILE
X C
X C
X C -------------------------
X C CONSTANT VOLUME DEPLETION
X C -------------------------
X C
83 CVDEP
84 COMPOSITION 0.0011 0.6893 0.0864 0.0534 0.0348 0.0178 0.0173
85 0.064447 0.020473 0.010029 0.004951
86 TEMP 256 F
87 DEWPT 6010 PSIG
88 PRES 6010 5000 4000 3000 2100 1200 700
89 MW C8 C34 X X X X X X X
90 ZGAS X X X X X X X
91 VPROD X X X X X X X
92 SLIQ X X X X X X X
X C
X C
X C -------------------------------
X C SEPARATOR TESTS
X C FLASH EACH CVDEP GAS TO SURFACE
X C -------------------------------
X C
X C -------------------------
X C ORIGINAL GAS AT PSAT=6010

X C -------------------------
X C
93 SEP
94 CVDEPY 1
95 TEMP 256 F
96 DEWPT 6010 PSIG
97 TSTD 75.
98 PSTD 0.
99 API 49.3
100 GORT 4699.7
102 450. 75. X 4276.1 X X
103 100. 75. X 212.0 X X
104 0. 75. X 211.6 X X
X C
X C ----------------------------
X C GAS FROM 5000. PSIG IN CVDEP
X C ----------------------------
X C
105 SEP
106 CVDEPY 2
107 TEMP 256 F
108 DEWPT 5000 PSIG
109 TSTD 75.
110 PSTD 0.
111 API 51.7
112 GORT 5727.2
114 450. 75. X 5277.0 X X
115 100. 75. X 223.0 X X
116 0. 75. X 227.2 X X
X C
X C ----------------------------
X C ----------------------------
X C
117 SEP
118 CVDEPY 3
119 TEMP 256 F
120 DEWPT 4000 PSIG
121 TSTD 75.
122 PSTD 0.
123 API 55.4
124 GORT 8399
126 450. 75. X 7828.0 X X
127 100. 75. X 248.0 X X
128 0. 75. X 263.0 X X
X C
X C ----------------------------
X C ----------------------------
X C
129 SEP
130 CVDEPY 4
131 TEMP 256 F
132 DEWPT 3000 PSIG
133 TSTD 75.
134 PSTD 0.
135 API 60.4
136 GORT 14396.6
138 450. 75. X 13774.0 X X
139 100. 75. X 289.6 X X
140 0. 75. X 333.0 X X
X C
X C ----------------------------
X C ----------------------------
X C
141 SEP
142 CVDEPY 5
143 TEMP 256 F
144 DEWPT 2100 PSIG
145 TSTD 75.
146 PSTD 0.
147 API 64.6
148 GORT 20564.2
150 450. 75. X 19863.0 X X
151 100. 75. X 304.8 X X

152 0. 75. X 396.4 X X

X C
X C ----------------------------
X C ----------------------------
X C
153 SEP
154 CVDEPY 6
155 TEMP 256 F
156 DEWPT 1200 PSIG
157 TSTD 75.
158 PSTD 0.
159 API 67.5
160 GORT 22972.4
162 450. 75. X 22121.0 X X
163 100. 75. X 369.8 X X
164 0. 75. X 481.6 X X
X C
X C ----------------------------
X C ----------------------------
X C
165 SEP
166 CVDEPY 7
167 TEMP 256 F
168 DEWPT 700 PSIG
169 TSTD 75.
170 PSTD 0.
171 API 68.6
172 GORT 20400.
174 450. 75. X 19475.0 X X
175 100. 75. X 366.8 X X
176 0. 75. X 558.2 X X
X C
177 END
-------------------------
CONTROL VARIABLES
-----------------

---- ------ ------- ------- ------- -------
10 0 0.2000 0.0010 0.0010 0.0100

-----------------------------------------

-------- ------- ------- -------
1 0.5000 1.0000 1.5000
2 0.5000 1.0000 1.5000
3 0.5000 1.0000 1.5000
4 0.5000 1.0000 1.5000
5 0.5000 1.0000 1.5000
6 0.5000 1.0000 1.5000
7 0.5000 1.0000 1.5000
8 0.5000 1.0000 1.5000
9 0.5000 1.0000 1.5000
10 0.5000 1.0000 1.5000
11 0.5000 1.0000 1.5000
12 0.5000 1.0000 1.5000

-------------------------------

--- ------ ---- ---- ---- ---- -------- ----- ----- ----- ------
1 N2 0 0 0 0 0 0 0 0 0
2 C1 0 0 0 0 0 1 2 0 0
3 C2 0 0 0 0 0 3 4 0 0
4 C3 0 0 0 0 0 0 0 0 0

5 NC4 0 0 0 0 0 0 0 0 0
6 NC5 0 0 0 0 0 0 0 0 0
7 C6 0 0 0 0 0 0 0 0 0
8 C8 0 0 0 0 0 5 6 0 0
9 C14 0 0 0 0 0 7 8 0 0
10 C20 0 0 0 0 0 9 10 0 0
11 C34 0 0 0 0 0 11 12 0 0
THERE ARE NO REGRESSION VARIABLES CORRESPONDING TO

BINARY INTERACTION COEFFICIENTS.

D E
0 0

------------- -------------------
k(1) 0
k(2) 0
k(3) 0
k(4) 0
k(5) 0
k(6) 0
k(7) 0

------------------------------------------------------------------
1 2 3 4 5 6 7 8 9 10 11
1
2 0
3 0 0
4 0 0 0
5 0 0 0 0
6 0 0 0 0 0
7 0 0 0 0 0 0
8 0 0 0 0 0 0 0
9 0 0 0 0 0 0 0 0
10 0 0 0 0 0 0 0 0 0
11 0 0 0 0 0 0 0 0 0 0
--------------------

-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 N2 28.01 -232.40 493.00 0.2910 0.03720 0.45724 0.07780 35.0
2 C1 16.04 -116.60 667.80 0.2890 0.01260 0.45724 0.07780 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.45724 0.07780 111.0
4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0
5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.2698 0.23130 0.45724 0.07780 271.0
8 C8 109.30 602.85 415.02 0.2618 0.32270 0.40470 0.08168 351.0
9 C14 183.86 807.42 282.76 0.2350 0.49960 0.45542 0.07597 591.9
10 C20 279.75 1000.71 207.54 0.2156 0.70450 0.43563 0.07993 833.7
11 C34 438.36 1238.40 150.02 0.1979 1.04930 0.46355 0.07355 1397.9

-------------------------------
1 2 3 4 5 6 7 8 9 10
11
1
2 0.1200

3 0.1200 0.0000
4 0.1200 0.0000 0.0000
5 0.1200 0.0200 0.0100 0.0100
6 0.1200 0.0200 0.0100 0.0100 0.0000
7 0.1200 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1200 0.1347 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1200 0.0358 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1200 0.0165 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000
11 0.1200 0.0848 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02
k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

---------------------------------------
1 2 3 4 5 6 7 8 9 10
11
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
11 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

-----------------------------------------
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4

P in psia
T in degree F
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4
1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464
S0 S1
-0.0280370 -0.1203900

----------------------------------------------
D1 = 5.80000

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT

NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 N2 -0.262E+02 0.715E+01 -0.498E-03 0.445E-06 -0.902E-10 0.445E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12
4 C3 -0.325E+02 0.761E+01 0.415E-02 0.951E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.252E+01 0.436E-01 -0.568E-05 0.000E+00 0.000E+00
9 C14 0.000E+00 0.278E+01 0.725E-01 -0.949E-05 0.000E+00 0.000E+00
10 C20 0.000E+00 0.827E+02 0.166E+00 -0.285E-04 0.000E+00 0.000E+00
11 C34 0.000E+00 0.109E+03 0.228E+00 -0.367E-04 0.000E+00 0.000E+00
-------------------------

--------- -------------
N2 0.00110
C1 0.68930
C2 0.08640
C3 0.05340
NC4 0.03480
NC5 0.01780
C6 0.01730
C8 0.06445
C14 0.02047
C20 0.01003
C34 0.00495

OBSERVED PSAT = 6010.00 PSIG (DEWPT)

CALCULATED PSAT = 6010.24 PSIG (DEWPT)
------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
6010.0 0.00 158.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
5000.0 0.00 146.47 0.0000 0.0767 0.0000 0.1162 0.0000 0.0861
4000.0 0.00 134.08 0.0000 0.1837 0.0000 0.2365 0.0000 0.1696
3000.0 0.00 121.63 0.0000 0.3339 0.0000 0.2833 0.0000 0.1840
2100.0 0.00 114.72 0.0000 0.4998 0.0000 0.2716 0.0000 0.1556
1200.0 0.00 111.46 0.0000 0.6836 0.0000 0.2424 0.0000 0.1185
700.0 0.00 110.61 0.0000 0.7882 0.0000 0.2207 0.0000 0.0963

------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
6010.0 0.0000 1.4430 0.0000 1.1357 0.0000 0.5479
5000.0 0.0000 1.2753 0.0000 0.9979 0.0000 0.5470
4000.0 0.0000 1.0554 0.0000 0.8935 0.0000 0.5314
3000.0 0.0000 0.8751 0.0000 0.8448 0.0000 0.5451
2100.0 0.0000 0.6958 0.0000 0.8426 0.0000 0.5721
1200.0 0.0000 0.4684 0.0000 0.8766 0.0000 0.6054
700.0 0.0000 0.3087 0.0000 0.9095 0.0000 0.6269

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
6010.0 0.0000 0.1062 0.0000 0.0562 0.2480E-01
5000.0 0.0000 0.1037 0.0000 0.0453 0.9043E-01

4000.0 0.0000 0.0945 0.0000 0.0341 0.2844E+00

3000.0 0.0000 0.0994 0.0000 0.0244 0.1195E+01
2100.0 0.0000 0.1122 0.0000 0.0184 0.3412E+01
1200.0 0.0000 0.1308 0.0000 0.0148 0.7802E+01
700.0 0.0000 0.1437 0.0000 0.0136 0.1147E+02
---------------------------
PRESSURE - PSIG
---------------
OIL COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C20 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C34 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

------------------------
PRESSURE - PSIG
---------------
OIL COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0008 0.0008 0.0007 0.0005 0.0004 0.0002 0.0001
C1 0.5712 0.5398 0.5090 0.4316 0.3288 0.2008 0.1191
C2 0.0841 0.0833 0.0833 0.0811 0.0744 0.0582 0.0416
C3 0.0559 0.0569 0.0591 0.0624 0.0640 0.0589 0.0484
NC4 0.0404 0.0424 0.0456 0.0518 0.0585 0.0625 0.0590
NC5 0.0221 0.0237 0.0263 0.0315 0.0383 0.0454 0.0476
C6 0.0232 0.0254 0.0287 0.0357 0.0453 0.0574 0.0642
C8 0.0962 0.1071 0.1218 0.1545 0.2002 0.2632 0.3077
C14 0.0426 0.0526 0.0628 0.0807 0.1042 0.1400 0.1725
C20 0.0213 0.0280 0.0352 0.0441 0.0551 0.0730 0.0898
C34 0.0424 0.0399 0.0275 0.0261 0.0308 0.0405 0.0498
---------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C20 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C34 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0011 0.0011 0.0012 0.0012 0.0013 0.0012 0.0012
C1 0.6893 0.7034 0.7284 0.7560 0.7692 0.7662 0.7450
C2 0.0864 0.0867 0.0871 0.0878 0.0895 0.0930 0.0968
C3 0.0534 0.0531 0.0521 0.0510 0.0512 0.0540 0.0591
NC4 0.0348 0.0341 0.0324 0.0303 0.0295 0.0311 0.0357
NC5 0.0178 0.0172 0.0159 0.0142 0.0131 0.0133 0.0156
C6 0.0173 0.0165 0.0148 0.0124 0.0108 0.0104 0.0122
C8 0.0644 0.0604 0.0519 0.0409 0.0332 0.0299 0.0339
C14 0.0205 0.0174 0.0113 0.0049 0.0019 0.0008 0.0005
C20 0.0100 0.0083 0.0045 0.0013 0.0003 0.0001 0.0000
C34 0.0049 0.0017 0.0002 0.0000 0.0000 0.0000 0.0000

------------------------
0 P = 6010.0 ZZ = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64447E-01 0.20473E-01 0.10029E-01
0.49510E-02
ZY = 1.13573 YY = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64446E-01 0.20472E-01 0.10029E-01
0.49499E-02
ZX = 1.44300 XX = 0.84286E-03 0.57116E+00 0.84098E-01 0.55871E-01 0.40384E-01
0.22074E-01 0.23151E-01 0.96162E-01 0.42557E-01 0.21262E-01
0.42434E-01
KV = 0.13051E+01 0.12068E+01 0.10274E+01 0.95577E+00 0.86172E+00
0.80639E+00 0.74724E+00 0.67018E+00 0.48105E+00 0.47166E+00
0.11665E+00
0 P = 5000.0 ZZ = 0.10974E-02 0.68813E+00 0.86376E-01 0.53428E-01 0.34860E-01
0.17847E-01 0.17364E-01 0.64781E-01 0.20724E-01 0.10170E-01
0.52248E-02
ZY = 0.99794 YY = 0.11312E-02 0.70339E+00 0.86692E-01 0.53067E-01 0.34083E-01
0.17240E-01 0.16533E-01 0.60424E-01 0.17446E-01 0.83360E-02
0.16524E-02
ZX = 1.27534 XX = 0.76882E-03 0.53976E+00 0.83300E-01 0.56928E-01 0.42410E-01
0.23745E-01 0.25436E-01 0.10712E+00 0.52589E-01 0.27991E-01
0.39947E-01
KV = 0.14714E+01 0.13032E+01 0.10407E+01 0.93218E+00 0.80365E+00
0.72605E+00 0.64998E+00 0.56406E+00 0.33174E+00 0.29781E+00
0.41366E-01
0 P = 4000.0 ZZ = 0.10854E-02 0.68284E+00 0.86284E-01 0.53596E-01 0.35176E-01
0.18096E-01 0.17699E-01 0.66464E-01 0.21966E-01 0.10908E-01
0.58817E-02
ZY = 0.89351 YY = 0.11890E-02 0.72843E+00 0.87079E-01 0.52140E-01 0.32444E-01
0.15948E-01 0.14810E-01 0.51948E-01 0.11260E-01 0.45355E-02
0.21612E-03
ZX = 1.05542 XX = 0.69051E-03 0.50904E+00 0.83251E-01 0.59150E-01 0.45592E-01
0.26283E-01 0.28714E-01 0.12181E+00 0.62782E-01 0.35206E-01
0.27483E-01
KV = 0.17219E+01 0.14310E+01 0.10460E+01 0.88149E+00 0.71162E+00
0.60678E+00 0.51577E+00 0.42647E+00 0.17935E+00 0.12883E+00
0.78638E-02
0 P = 3000.0 ZZ = 0.10491E-02 0.66636E+00 0.85941E-01 0.54177E-01 0.36266E-01
0.18977E-01 0.18883E-01 0.72237E-01 0.25822E-01 0.13086E-01
0.72056E-02
ZY = 0.84483 YY = 0.12464E-02 0.75596E+00 0.87803E-01 0.51024E-01 0.30346E-01
0.14185E-01 0.12448E-01 0.40862E-01 0.48630E-02 0.12523E-02
0.10406E-04
ZX = 0.87513 XX = 0.53223E-03 0.43156E+00 0.81061E-01 0.62437E-01 0.51778E-01
0.31536E-01 0.35743E-01 0.15445E+00 0.80743E-01 0.44094E-01
0.26060E-01
KV = 0.23418E+01 0.17517E+01 0.10832E+01 0.81721E+00 0.58606E+00
0.44979E+00 0.34827E+00 0.26456E+00 0.60228E-01 0.28402E-01
0.39929E-03
0 P = 2100.0 ZZ = 0.97947E-03 0.63225E+00 0.84773E-01 0.55168E-01 0.38517E-01
0.20926E-01 0.21552E-01 0.85166E-01 0.33743E-01 0.17331E-01
0.95947E-02
ZY = 0.84259 YY = 0.12591E-02 0.76923E+00 0.89462E-01 0.51187E-01 0.29474E-01
0.13101E-01 0.10831E-01 0.33243E-01 0.19316E-02 0.28130E-03
0.45219E-06
ZX = 0.69580 XX = 0.36010E-03 0.32884E+00 0.74387E-01 0.63986E-01 0.58547E-01
0.38258E-01 0.45300E-01 0.20017E+00 0.10420E+00 0.55097E-01
0.30845E-01
KV = 0.34966E+01 0.23392E+01 0.12027E+01 0.79997E+00 0.50344E+00
0.34243E+00 0.23908E+00 0.16607E+00 0.18537E-01 0.51056E-02
0.14660E-04
0 P = 1200.0 ZZ = 0.83708E-03 0.55443E+00 0.79984E-01 0.55836E-01 0.42840E-01
0.25343E-01 0.28010E-01 0.11728E+00 0.52903E-01 0.27368E-01
0.15169E-01
ZY = 0.87658 YY = 0.12246E-02 0.76619E+00 0.93017E-01 0.54018E-01 0.31076E-01
0.13323E-01 0.10437E-01 0.29893E-01 0.76430E-03 0.54545E-04
0.14629E-07
ZX = 0.46839 XX = 0.18994E-03 0.20080E+00 0.58219E-01 0.58873E-01 0.62487E-01
0.45415E-01 0.57356E-01 0.26321E+00 0.13997E+00 0.72982E-01
0.40500E-01
KV = 0.64474E+01 0.38158E+01 0.15977E+01 0.91754E+00 0.49732E+00
0.29336E+00 0.18197E+00 0.11357E+00 0.54603E-02 0.74738E-03
0.36122E-06
0 P = 700.0 ZZ = 0.67811E-03 0.46027E+00 0.71690E-01 0.54223E-01 0.46345E-01
0.30161E-01 0.35844E-01 0.15846E+00 0.78777E-01 0.40882E-01
0.22665E-01
ZY = 0.90953 YY = 0.11587E-02 0.74495E+00 0.96767E-01 0.59100E-01 0.35748E-01
0.15594E-01 0.12158E-01 0.33947E-01 0.54904E-03 0.24940E-04
0.23308E-08
ZX = 0.30874 XX = 0.10211E-03 0.11910E+00 0.41635E-01 0.48379E-01 0.59045E-01

0.47617E-01 0.64232E-01 0.30769E+00 0.17253E+00 0.89848E-01

0.49829E-01
KV = 0.11348E+02 0.62549E+01 0.23242E+01 0.12216E+01 0.60544E+00
0.32749E+00 0.18928E+00 0.11033E+00 0.31823E-02 0.27758E-03
0.46775E-07
---------------------

--------- -------------
N2 0.00110
C1 0.68930
C2 0.08640
C3 0.05340
NC4 0.03480
NC5 0.01780
C6 0.01730
C8 0.06445
C14 0.02047
C20 0.01003
C34 0.00495


CALCULATED ZSAT = 1.1357

CALCULATED GAS FVF = 0.7732 RB/MSCF
OBSERVED API GRAV. = 49.3

OBSERVED TOTAL GOR = 4699.70 SCF/STB
------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 3314. 4276. 3942. 0.0000 1.1897 0.0000 0.6744
100.0 75.0 0. 161. 212. 178. 0.0000 1.1102 0.0000 0.8606
0.0 75.0 0. 180. 212. 180. 0.0000 1.0000 0.0000 1.5898

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.2169 0.0000 0.1934 0.0000 0.6576
100.0 75.0 0.0000 0.1814 0.0000 0.0532 0.0000 0.6753
0.0 75.0 0.0000 0.1456 0.0000 0.0077 0.0000 0.6890
------------
0STAGE 1 ZZ = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64446E-01 0.20472E-01 0.10029E-01
0.49499E-02
ZY = 0.89574 YY = 0.13830E-02 0.84615E+00 0.90488E-01 0.41072E-01 0.14055E-01
0.31343E-02 0.14398E-02 0.22787E-02 0.15766E-05 0.11410E-07
0.92737E-10
ZX = 0.19339 XX = 0.78230E-04 0.12297E+00 0.71639E-01 0.97915E-01 0.10971E+00
0.70755E-01 0.74567E-01 0.28892E+00 0.94389E-01 0.46240E-01
0.22823E-01
KV = 0.17678E+02 0.68812E+01 0.12631E+01 0.41946E+00 0.12811E+00
0.44298E-01 0.19309E-01 0.78869E-02 0.16703E-04 0.24676E-06
0.40633E-08
0STAGE 2 ZZ = 0.78230E-04 0.12297E+00 0.71639E-01 0.97915E-01 0.10971E+00
0.70755E-01 0.74567E-01 0.28892E+00 0.94389E-01 0.46240E-01
0.22823E-01
ZY = 0.95671 YY = 0.44740E-03 0.63002E+00 0.19600E+00 0.11547E+00 0.40803E-01
0.84444E-02 0.36043E-02 0.52113E-02 0.18073E-05 0.67078E-08

0.19420E-15
ZX = 0.05325 XX = 0.60958E-05 0.23890E-01 0.47339E-01 0.94485E-01 0.12317E+00
0.82930E-01 0.88433E-01 0.34436E+00 0.11283E+00 0.55276E-01
0.27283E-01
KV = 0.73395E+02 0.26372E+02 0.41404E+01 0.12221E+01 0.33128E+00
0.10183E+00 0.40757E-01 0.15133E-01 0.16017E-04 0.12135E-06
0.71181E-14
0STAGE 3 ZZ = 0.60958E-05 0.23890E-01 0.47339E-01 0.94485E-01 0.12317E+00
0.82930E-01 0.88433E-01 0.34436E+00 0.11283E+00 0.55276E-01
0.27283E-01
ZY = 0.98210 YY = 0.30658E-04 0.11865E+00 0.21149E+00 0.32532E+00 0.22111E+00
0.58554E-01 0.26509E-01 0.38336E-01 0.10728E-04 0.31899E-07
0.55640E-15
ZX = 0.00766 XX = 0.52481E-07 0.57399E-03 0.69515E-02 0.37691E-01 0.99073E-01
0.88927E-01 0.10367E+00 0.41965E+00 0.14059E+00 0.68876E-01
0.33996E-01
KV = 0.58416E+03 0.20671E+03 0.30423E+02 0.86311E+01 0.22318E+01
0.65845E+00 0.25571E+00 0.91351E-01 0.76309E-04 0.46313E-06
0.16367E-13
---------------------

--------- -------------
N2 0.00113
C1 0.70339
C2 0.08669
C3 0.05307
NC4 0.03408
NC5 0.01724
C6 0.01653
C8 0.06042
C14 0.01745
C20 0.00834
C34 0.00165




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 3958. 5277. 4806. 0.0000 1.2145 0.0000 0.6763
100.0 75.0 0. 176. 223. 198. 0.0000 1.1249 0.0000 0.8657
0.0 75.0 0. 202. 227. 202. 0.0000 1.0000 0.0000 1.6085

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1968 0.0000 0.1830 0.0000 0.6476
100.0 75.0 0.0000 0.1637 0.0000 0.0503 0.0000 0.6670
0.0 75.0 0.0000 0.1300 0.0000 0.0072 0.0000 0.6815
------------
0STAGE 1 ZZ = 0.11312E-02 0.70339E+00 0.86692E-01 0.53067E-01 0.34083E-01
0.17240E-01 0.16533E-01 0.60424E-01 0.17446E-01 0.83360E-02
0.16524E-02

ZY = 0.89515 YY = 0.13886E-02 0.84499E+00 0.90254E-01 0.41621E-01 0.14580E-01

0.32986E-02 0.15146E-02 0.23557E-02 0.15204E-05 0.10262E-07
0.00000E+00
ZX = 0.18305 XX = 0.80856E-04 0.12549E+00 0.72154E-01 0.99785E-01 0.11368E+00
0.74141E-01 0.77832E-01 0.29743E+00 0.88645E-01 0.42359E-01
0.83969E-02
KV = 0.17173E+02 0.67335E+01 0.12508E+01 0.41711E+00 0.12825E+00
0.44491E-01 0.19459E-01 0.79201E-02 0.17152E-04 0.24226E-06
0.00000E+00
0STAGE 2 ZZ = 0.80856E-04 0.12549E+00 0.72154E-01 0.99785E-01 0.11368E+00
0.74141E-01 0.77832E-01 0.29743E+00 0.88645E-01 0.42359E-01
0.83969E-02
ZY = 0.95622 YY = 0.45038E-03 0.62735E+00 0.19466E+00 0.11705E+00 0.42403E-01
0.89072E-02 0.37978E-02 0.53836E-02 0.17376E-05 0.61684E-08
0.76468E-16
ZX = 0.05029 XX = 0.62914E-05 0.24224E-01 0.47434E-01 0.96302E-01 0.12807E+00
0.87304E-01 0.92770E-01 0.35636E+00 0.10653E+00 0.50907E-01
0.10091E-01
KV = 0.71587E+02 0.25898E+02 0.41039E+01 0.12154E+01 0.33110E+00
0.10203E+00 0.40938E-01 0.15107E-01 0.16310E-04 0.12117E-06
0.75777E-14
0STAGE 3 ZZ = 0.62914E-05 0.24224E-01 0.47434E-01 0.96302E-01 0.12807E+00
0.87304E-01 0.92770E-01 0.35636E+00 0.10653E+00 0.50907E-01
0.10091E-01
ZY = 0.98170 YY = 0.30345E-04 0.11544E+00 0.20422E+00 0.32269E+00 0.22777E+00
0.61869E-01 0.28090E-01 0.39875E-01 0.10381E-04 0.29477E-07
0.21869E-15
ZX = 0.00722 XX = 0.53220E-07 0.56734E-03 0.67705E-02 0.37590E-01 0.10221E+00
0.93900E-01 0.10954E+00 0.43844E+00 0.13416E+00 0.64109E-01
0.12708E-01
KV = 0.57018E+03 0.20347E+03 0.30164E+02 0.85846E+01 0.22285E+01
0.65888E+00 0.25643E+00 0.90948E-01 0.77377E-04 0.45979E-06
0.17208E-13
---------------------

--------- -------------
N2 0.00119
C1 0.72843
C2 0.08708
C3 0.05214
NC4 0.03244
NC5 0.01595
C6 0.01481
C8 0.05195
C14 0.01126
C20 0.00454
C34 0.00022




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 5440. 7828. 6807. 0.0000 1.2513 0.0000 0.6798
100.0 75.0 0. 193. 248. 222. 0.0000 1.1489 0.0000 0.8754
0.0 75.0 0. 236. 263. 236. 0.0000 1.0000 0.0000 1.6434


------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1597 0.0000 0.1716 0.0000 0.6368
100.0 75.0 0.0000 0.1324 0.0000 0.0469 0.0000 0.6578
0.0 75.0 0.0000 0.1032 0.0000 0.0067 0.0000 0.6735
------------
0STAGE 1 ZZ = 0.11890E-02 0.72843E+00 0.87079E-01 0.52140E-01 0.32444E-01
0.15948E-01 0.14810E-01 0.51948E-01 0.11260E-01 0.45355E-02
0.21612E-03
ZY = 0.89406 YY = 0.13991E-02 0.84289E+00 0.89848E-01 0.42551E-01 0.15566E-01
0.36127E-02 0.16483E-02 0.24890E-02 0.12436E-05 0.69671E-08
0.00000E+00
ZX = 0.17163 XX = 0.83619E-04 0.12638E+00 0.72512E-01 0.10258E+00 0.12123E+00
0.80834E-01 0.84040E-01 0.31211E+00 0.70482E-01 0.28393E-01
0.13529E-02
KV = 0.16732E+02 0.66692E+01 0.12391E+01 0.41480E+00 0.12840E+00
0.44692E-01 0.19613E-01 0.79747E-02 0.17644E-04 0.24538E-06
0.00000E+00
0STAGE 2 ZZ = 0.83619E-04 0.12638E+00 0.72512E-01 0.10258E+00 0.12123E+00
0.80834E-01 0.84040E-01 0.31211E+00 0.70482E-01 0.28393E-01
0.13529E-02
ZY = 0.95527 YY = 0.45677E-03 0.62142E+00 0.19346E+00 0.11976E+00 0.45322E-01
0.97676E-02 0.41354E-02 0.56789E-02 0.14143E-05 0.41884E-08
0.13203E-16
ZX = 0.04693 XX = 0.65148E-05 0.24095E-01 0.47520E-01 0.99033E-01 0.13691E+00
0.95518E-01 0.10055E+00 0.37543E+00 0.85046E-01 0.34259E-01
0.16325E-02
KV = 0.70112E+02 0.25791E+02 0.40710E+01 0.12093E+01 0.33103E+00
0.10226E+00 0.41128E-01 0.15127E-01 0.16629E-04 0.12225E-06
0.80878E-14
0STAGE 3 ZZ = 0.65148E-05 0.24095E-01 0.47520E-01 0.99033E-01 0.13691E+00
0.95518E-01 0.10055E+00 0.37543E+00 0.85046E-01 0.34259E-01
0.16325E-02
ZY = 0.98095 YY = 0.29399E-04 0.10755E+00 0.19298E+00 0.31794E+00 0.23992E+00
0.68073E-01 0.30899E-01 0.42602E-01 0.85528E-05 0.20228E-07
0.37789E-16
ZX = 0.00671 XX = 0.52571E-07 0.52784E-03 0.64459E-02 0.37217E-01 0.10782E+00
0.10327E+00 0.12022E+00 0.46941E+00 0.10906E+00 0.43934E-01
0.20935E-02
KV = 0.55923E+03 0.20376E+03 0.29938E+02 0.85429E+01 0.22251E+01
0.65918E+00 0.25702E+00 0.90757E-01 0.78423E-04 0.46042E-06
0.18051E-13
---------------------

--------- -------------
N2 0.00125
C1 0.75596
C2 0.08780
C3 0.05102
NC4 0.03035
NC5 0.01418
C6 0.01245
C8 0.04086
C14 0.00486
C20 0.00125
C34 0.00001





------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 8318. 13774. 10839. 0.0000 1.3030 0.0000 0.6846
100.0 75.0 0. 212. 290. 251. 0.0000 1.1844 0.0000 0.8887
0.0 75.0 0. 286. 333. 286. 0.0000 1.0000 0.0000 1.6893

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1174 0.0000 0.1605 0.0000 0.6250
100.0 75.0 0.0000 0.0969 0.0000 0.0436 0.0000 0.6476
0.0 75.0 0.0000 0.0736 0.0000 0.0062 0.0000 0.6646
------------
0STAGE 1 ZZ = 0.12464E-02 0.75596E+00 0.87803E-01 0.51024E-01 0.30346E-01
0.14185E-01 0.12448E-01 0.40862E-01 0.48630E-02 0.12523E-02
0.10406E-04
ZY = 0.89252 YY = 0.14007E-02 0.83970E+00 0.89755E-01 0.43718E-01 0.16903E-01
0.40582E-02 0.18263E-02 0.26405E-02 0.56448E-06 0.00000E+00
0.00000E+00
ZX = 0.16048 XX = 0.85843E-04 0.12614E+00 0.73124E-01 0.10598E+00 0.13145E+00
0.90349E-01 0.92339E-01 0.32834E+00 0.41435E-01 0.10672E-01
0.88672E-04
KV = 0.16316E+02 0.66568E+01 0.12274E+01 0.41252E+00 0.12859E+00
0.44918E-01 0.19779E-01 0.80421E-02 0.13623E-04 0.00000E+00
0.00000E+00
0STAGE 2 ZZ = 0.85843E-04 0.12614E+00 0.73124E-01 0.10598E+00 0.13145E+00
0.90349E-01 0.92339E-01 0.32834E+00 0.41435E-01 0.10672E-01
0.88672E-04
ZY = 0.95393 YY = 0.46117E-03 0.61236E+00 0.19316E+00 0.12318E+00 0.49259E-01
0.10981E-01 0.45825E-02 0.60158E-02 0.85239E-06 0.16061E-08
0.93165E-18
ZX = 0.04360 XX = 0.67033E-05 0.23618E-01 0.47814E-01 0.10235E+00 0.14878E+00
0.10708E+00 0.11084E+00 0.39630E+00 0.50171E-01 0.12922E-01
0.10737E-03
KV = 0.68797E+02 0.25928E+02 0.40398E+01 0.12035E+01 0.33109E+00
0.10255E+00 0.41342E-01 0.15180E-01 0.16990E-04 0.12429E-06
0.86770E-14
0STAGE 3 ZZ = 0.67033E-05 0.23618E-01 0.47814E-01 0.10235E+00 0.14878E+00
0.10708E+00 0.11084E+00 0.39630E+00 0.50171E-01 0.12922E-01
0.10737E-03
ZY = 0.97993 YY = 0.27715E-04 0.96730E-01 0.17973E+00 0.31034E+00 0.25549E+00
0.76921E-01 0.34760E-01 0.46004E-01 0.52531E-05 0.78878E-08
0.26800E-17
ZX = 0.00621 XX = 0.50423E-07 0.46785E-03 0.60464E-02 0.36496E-01 0.11499E+00
0.11663E+00 0.13493E+00 0.50722E+00 0.66055E-01 0.17014E-01
0.14137E-03
KV = 0.54964E+03 0.20676E+03 0.29724E+02 0.85033E+01 0.22218E+01
0.65950E+00 0.25761E+00 0.90699E-01 0.79526E-04 0.46361E-06
0.18958E-13
---------------------

--------- -------------
N2 0.00126
C1 0.76923
C2 0.08946
C3 0.05119
NC4 0.02947
NC5 0.01310
C6 0.01083
C8 0.03324
C14 0.00193
C20 0.00028
C34 0.00000





------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 11201. 19863. 15137. 0.0000 1.3514 0.0000 0.6894
100.0 75.0 0. 228. 305. 277. 0.0000 1.2181 0.0000 0.9014
0.0 75.0 0. 333. 396. 333. 0.0000 1.0000 0.0000 1.7231

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.0932 0.0000 0.1541 0.0000 0.6164
100.0 75.0 0.0000 0.0766 0.0000 0.0417 0.0000 0.6404
0.0 75.0 0.0000 0.0567 0.0000 0.0059 0.0000 0.6583
------------
0STAGE 1 ZZ = 0.12591E-02 0.76923E+00 0.89462E-01 0.51187E-01 0.29474E-01
0.13101E-01 0.10831E-01 0.33243E-01 0.19316E-02 0.28130E-03
0.45219E-06
ZY = 0.89090 YY = 0.13797E-02 0.83534E+00 0.90991E-01 0.45161E-01 0.18087E-01
0.44119E-02 0.19422E-02 0.26854E-02 0.36809E-06 0.00000E+00
0.00000E+00
ZX = 0.15409 XX = 0.86187E-04 0.12631E+00 0.74596E-01 0.10978E+00 0.14022E+00
0.97597E-01 0.97269E-01 0.33041E+00 0.20713E-01 0.30170E-02
0.48497E-05
KV = 0.16009E+02 0.66136E+01 0.12198E+01 0.41137E+00 0.12900E+00
0.45206E-01 0.19967E-01 0.81273E-02 0.17771E-04 0.00000E+00
0.00000E+00
0STAGE 2 ZZ = 0.86187E-04 0.12631E+00 0.74596E-01 0.10978E+00 0.14022E+00
0.97597E-01 0.97269E-01 0.33041E+00 0.20713E-01 0.30170E-02
0.48497E-05
ZY = 0.95260 YY = 0.45294E-03 0.60174E+00 0.19492E+00 0.12720E+00 0.52756E-01
0.11951E-01 0.48747E-02 0.61075E-02 0.43630E-06 0.46354E-09
0.54337E-19
ZX = 0.04171 XX = 0.66792E-05 0.23241E-01 0.48512E-01 0.10601E+00 0.15918E+00
0.11616E+00 0.11730E+00 0.40072E+00 0.25203E-01 0.36710E-02
0.59010E-05
KV = 0.67814E+02 0.25892E+02 0.40180E+01 0.11999E+01 0.33143E+00
0.10288E+00 0.41558E-01 0.15242E-01 0.17312E-04 0.12627E-06
0.92080E-14
0STAGE 3 ZZ = 0.66792E-05 0.23241E-01 0.48512E-01 0.10601E+00 0.15918E+00
0.11616E+00 0.11730E+00 0.40072E+00 0.25203E-01 0.36710E-02
0.59010E-05
ZY = 0.97916 YY = 0.25493E-04 0.87968E-01 0.16983E+00 0.30474E+00 0.26813E+00
0.84132E-01 0.37547E-01 0.47622E-01 0.27421E-05 0.23134E-08
0.15735E-18
ZX = 0.00594 XX = 0.47015E-07 0.42280E-03 0.57433E-02 0.35951E-01 0.12077E+00
0.12746E+00 0.14541E+00 0.52519E+00 0.34086E-01 0.49651E-02
0.79813E-05
KV = 0.54223E+03 0.20806E+03 0.29571E+02 0.84765E+01 0.22203E+01
0.66009E+00 0.25821E+00 0.90675E-01 0.80446E-04 0.46593E-06
0.19715E-13
---------------------

--------- -------------

N2 0.00122
C1 0.76619
C2 0.09302
C3 0.05402
NC4 0.03108
NC5 0.01332
C6 0.01044
C8 0.02989
C14 0.00076
C20 0.00005
C34 0.00000




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 12425. 22121. 17557. 0.0000 1.4130 0.0000 0.6965
100.0 75.0 0. 246. 370. 311. 0.0000 1.2613 0.0000 0.9193
0.0 75.0 0. 395. 482. 395. 0.0000 1.0000 0.0000 1.7545

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.0871 0.0000 0.1497 0.0000 0.6097
100.0 75.0 0.0000 0.0710 0.0000 0.0405 0.0000 0.6351
0.0 75.0 0.0000 0.0504 0.0000 0.0058 0.0000 0.6543
------------
0STAGE 1 ZZ = 0.12246E-02 0.76619E+00 0.93017E-01 0.54018E-01 0.31076E-01
0.13323E-01 0.10437E-01 0.29893E-01 0.76430E-03 0.54545E-04
0.14629E-07
ZY = 0.88834 YY = 0.13334E-02 0.82721E+00 0.94477E-01 0.48030E-01 0.19616E-01
0.47215E-02 0.19990E-02 0.26079E-02 0.17035E-06 0.16900E-09
0.15890E-19
ZX = 0.14969 XX = 0.84456E-04 0.12673E+00 0.77721E-01 0.11676E+00 0.15116E+00
0.10346E+00 0.98863E-01 0.31582E+00 0.87718E-02 0.62614E-03
0.16794E-06
KV = 0.15788E+02 0.65275E+01 0.12156E+01 0.41135E+00 0.12977E+00
0.45636E-01 0.20220E-01 0.82577E-02 0.19420E-04 0.26991E-06
0.94622E-13
0STAGE 2 ZZ = 0.84456E-04 0.12673E+00 0.77721E-01 0.11676E+00 0.15116E+00
0.10346E+00 0.98863E-01 0.31582E+00 0.87718E-02 0.62614E-03
0.16794E-06
ZY = 0.95064 YY = 0.42762E-03 0.58366E+00 0.19990E+00 0.13494E+00 0.57304E-01
0.12820E-01 0.50253E-02 0.59274E-02 0.18994E-06 0.99191E-10
0.20080E-20
ZX = 0.04048 XX = 0.63651E-05 0.22748E-01 0.49919E-01 0.11263E+00 0.17252E+00
0.12409E+00 0.12022E+00 0.38634E+00 0.10768E-01 0.76862E-03
0.20615E-06
KV = 0.67182E+02 0.25658E+02 0.40044E+01 0.11981E+01 0.33215E+00
0.10331E+00 0.41802E-01 0.15342E-01 0.17640E-04 0.12905E-06
0.97404E-14
0STAGE 3 ZZ = 0.63651E-05 0.22748E-01 0.49919E-01 0.11263E+00 0.17252E+00
0.12409E+00 0.12022E+00 0.38634E+00 0.10768E-01 0.76862E-03
0.20615E-06
ZY = 0.97841 YY = 0.21911E-04 0.77744E-01 0.15934E+00 0.30179E+00 0.28309E+00

0.90889E-01 0.39575E-01 0.47546E-01 0.12278E-05 0.50618E-09

0.58638E-20
ZX = 0.00579 XX = 0.40729E-07 0.37413E-03 0.54047E-02 0.35667E-01 0.12754E+00
0.13759E+00 0.15302E+00 0.52417E+00 0.15148E-01 0.10813E-02
0.29002E-06
KV = 0.53796E+03 0.20780E+03 0.29481E+02 0.84614E+01 0.22196E+01
0.66056E+00 0.25862E+00 0.90707E-01 0.81055E-04 0.46812E-06
0.20219E-13
---------------------

--------- -------------
N2 0.00116
C1 0.74495
C2 0.09677
C3 0.05910
NC4 0.03575
NC5 0.01559
C6 0.01216
C8 0.03395
C14 0.00055
C20 0.00002
C34 0.00000




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 10141. 19475. 14918. 0.0000 1.4711 0.0000 0.7035
100.0 75.0 0. 263. 367. 342. 0.0000 1.3020 0.0000 0.9364
0.0 75.0 0. 453. 558. 453. 0.0000 1.0000 0.0000 1.7751

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1063 0.0000 0.1471 0.0000 0.6059
100.0 75.0 0.0000 0.0858 0.0000 0.0398 0.0000 0.6324
0.0 75.0 0.0000 0.0587 0.0000 0.0057 0.0000 0.6530
------------
0STAGE 1 ZZ = 0.11587E-02 0.74495E+00 0.96767E-01 0.59100E-01 0.35748E-01
0.15594E-01 0.12158E-01 0.33947E-01 0.54904E-03 0.24940E-04
0.23308E-08
ZY = 0.88576 YY = 0.12868E-02 0.81849E+00 0.98618E-01 0.51311E-01 0.20930E-01
0.48687E-02 0.19950E-02 0.25001E-02 0.86227E-07 0.00000E+00
0.00000E+00
ZX = 0.14710 XX = 0.82106E-04 0.12690E+00 0.81212E-01 0.12456E+00 0.16029E+00
0.10574E+00 0.97570E-01 0.29825E+00 0.51628E-02 0.23456E-03
0.21921E-07
KV = 0.15673E+02 0.64499E+01 0.12143E+01 0.41195E+00 0.13057E+00
0.46044E-01 0.20447E-01 0.83828E-02 0.16702E-04 0.00000E+00
0.00000E+00
0STAGE 2 ZZ = 0.82106E-04 0.12690E+00 0.81212E-01 0.12456E+00 0.16029E+00
0.10574E+00 0.97570E-01 0.29825E+00 0.51628E-02 0.23456E-03

0.21921E-07
ZY = 0.94870 YY = 0.40065E-03 0.56494E+00 0.20575E+00 0.14370E+00 0.61239E-01
0.13255E-01 0.50264E-02 0.56854E-02 0.11442E-06 0.38273E-10
0.27535E-21
ZX = 0.03981 XX = 0.59865E-05 0.22225E-01 0.51453E-01 0.11998E+00 0.18396E+00
0.12784E+00 0.11968E+00 0.36816E+00 0.63965E-02 0.29061E-03
0.27159E-07
KV = 0.66925E+02 0.25420E+02 0.39987E+01 0.11977E+01 0.33288E+00
0.10368E+00 0.41997E-01 0.15443E-01 0.17887E-04 0.13170E-06
0.10139E-13
0STAGE 3 ZZ = 0.59865E-05 0.22225E-01 0.51453E-01 0.11998E+00 0.18396E+00
0.12784E+00 0.11968E+00 0.36816E+00 0.63965E-02 0.29061E-03
0.27159E-07
ZY = 0.97790 YY = 0.18858E-04 0.69564E-01 0.15160E+00 0.30219E+00 0.29467E+00
0.94613E-01 0.40447E-01 0.46895E-01 0.76006E-06 0.19958E-09
0.80964E-21
ZX = 0.00573 XX = 0.35118E-07 0.33569E-03 0.51468E-02 0.35732E-01 0.13277E+00
0.14320E+00 0.15632E+00 0.51670E+00 0.93538E-02 0.42498E-03
0.39716E-07
KV = 0.53698E+03 0.20723E+03 0.29456E+02 0.84569E+01 0.22193E+01
0.66069E+00 0.25874E+00 0.90757E-01 0.81257E-04 0.46962E-06
0.20386E-13

---------------------------
----- ----------- ----------- ----------- -----------
1 1.00000000 0.45723549 0.00000000 0.00000000
2 1.00000000 0.07779610 0.00000000 0.00000000
3 1.00000000 0.45723549 0.00000000 0.00000000
4 1.00000000 0.07779610 0.00000000 0.00000000
5 1.00000000 0.40470231 0.00000000 0.00000000
6 1.00000000 0.08167780 0.00000000 0.00000000
7 1.00000000 0.45542160 0.00000000 0.00000000
8 1.00000000 0.07596840 0.00000000 0.00000000
9 1.00000000 0.43563280 0.00000000 0.00000000
10 1.00000000 0.07992980 0.00000000 0.00000000
11 1.00000000 0.46355090 0.00000000 0.00000000
12 1.00000000 0.07354740 0.00000000 0.00000000

---------------------------
----- ----------- ----------- ----------- -----------
1 1.05807516 0.48378951 0.05807516 0.02655403
2 1.00578144 0.07824588 0.00578144 0.00044977
3 1.03854436 0.47485934 0.03854436 0.01762385
4 0.96320736 0.07493378 -0.03679264 -0.00286232
5 0.98036518 0.39675605 -0.01963482 -0.00794626
6 0.91240908 0.07452357 -0.08759092 -0.00715423
7 0.92536204 0.42142986 -0.07463796 -0.03399174
8 0.86941433 0.06604802 -0.13058567 -0.00992038
9 0.88389513 0.38505370 -0.11610487 -0.05057909
10 0.96139524 0.07684413 -0.03860476 -0.00308567
11 1.01929798 0.47249649 0.01929798 0.00894560
12 1.00219008 0.07370847 0.00219008 0.00016107

---------------------------
----- ----------- ----------- ----------- -----------
1 1.00831572 0.46103773 -0.04975944 -0.02275178
2 0.95194119 0.07405731 -0.05384025 -0.00418856
3 1.01731469 0.46515238 -0.02122967 -0.00970696
4 0.94602114 0.07359676 -0.01718622 -0.00133702
5 0.96725544 0.39145050 -0.01310975 -0.00530554
6 0.88771670 0.07250675 -0.02469238 -0.00201682
7 0.76052873 0.34636121 -0.16483332 -0.07506865
8 0.79531472 0.06041879 -0.07409960 -0.00562923
9 0.79762999 0.34747378 -0.08626514 -0.03757992
10 0.87585282 0.07000674 -0.08554242 -0.00683739

11 0.92818115 0.43025921 -0.09111683 -0.04223729

12 0.93485284 0.06875600 -0.06733724 -0.00495248

---------------------------
----- ----------- ----------- ----------- -----------
1 0.88572667 0.40498566 -0.12258905 -0.05605207
2 0.83975833 0.06532992 -0.11218287 -0.00872739
3 0.96162778 0.43969034 -0.05568691 -0.02546203
4 0.89331498 0.06949642 -0.05270616 -0.00410033
5 0.97830964 0.39592417 0.01105421 0.00447366
6 0.90262912 0.07372476 0.01491242 0.00121801
7 0.68898795 0.31377999 -0.07154077 -0.03258121
8 0.73874626 0.05612137 -0.05656847 -0.00429742
9 0.81462195 0.35487604 0.01699196 0.00740226
10 0.90117960 0.07203110 0.02532679 0.00202436
11 0.82399837 0.38196518 -0.10418278 -0.04829402
12 0.85023717 0.06253273 -0.08461567 -0.00622326

---------------------------
----- ----------- ----------- ----------- -----------
1 0.89961195 0.41133451 0.01388529 0.00634885
2 0.85107701 0.06621047 0.01131869 0.00088055
3 0.94547576 0.43230507 -0.01615202 -0.00738528
4 0.87211691 0.06784730 -0.02119807 -0.00164913
5 0.98407055 0.39825562 0.00576091 0.00233145
6 0.90729010 0.07410546 0.00466098 0.00038070
7 0.64885019 0.29550039 -0.04013776 -0.01827960
8 0.69119770 0.05250918 -0.04754856 -0.00361219
9 0.86678491 0.37759993 0.05216296 0.02272390
10 0.94697215 0.07569129 0.04579254 0.00366019
11 0.82480039 0.38233696 0.00080202 0.00037178
12 0.85193643 0.06265771 0.00169926 0.00012498

---------------------------
----- ----------- ----------- ----------- -----------
1 0.90630162 0.41439326 0.00668966 0.00305875
2 0.85618720 0.06660803 0.00511018 0.00039755
3 0.93154384 0.42593490 -0.01393192 -0.00637017
4 0.85376455 0.06641955 -0.01835236 -0.00142774
5 0.99064943 0.40091811 0.00657888 0.00266249
6 0.91212830 0.07450063 0.00483820 0.00039517
7 0.61727793 0.28112170 -0.03157226 -0.01437869
8 0.66037347 0.05016752 -0.03082423 -0.00234167
9 0.90299119 0.39337258 0.03620628 0.01577264
10 0.97210443 0.07770011 0.02513229 0.00200882
11 0.82696906 0.38334225 0.00216867 0.00100529
12 0.85380072 0.06279482 0.00186429 0.00013711
THE RELATIVE CHANGE IN THE OBJECTIVE FUNCTION WAS LESS THAN TOL3 = 0.01000
--------------------

-- ------ ------- -------- -------- -------- -------- -------- -------- -------
1 N2 28.01 -232.40 493.00 0.2910 0.03720 0.45724 0.07780 35.0
2 C1 16.04 -116.60 667.80 0.2890 0.01260 0.41439 0.06661 71.0
3 C2 30.07 90.10 707.80 0.2850 0.09780 0.42593 0.06642 111.0

4 C3 44.10 206.00 616.30 0.2810 0.15410 0.45724 0.07780 151.0

5 NC4 58.12 305.70 550.70 0.2740 0.20150 0.45724 0.07780 191.0
6 NC5 72.15 385.70 488.60 0.2620 0.25240 0.45724 0.07780 231.0
7 C6 84.00 463.00 468.30 0.2698 0.23130 0.45724 0.07780 271.0
8 C8 109.30 602.85 415.02 0.2618 0.32270 0.40092 0.07450 351.0
9 C14 183.86 807.42 282.76 0.2350 0.49960 0.28112 0.05017 591.9
10 C20 279.75 1000.71 207.54 0.2156 0.70450 0.39337 0.07770 833.7
11 C34 438.36 1238.40 150.02 0.1979 1.04930 0.38334 0.06279 1397.9

-------------------------------
1 2 3 4 5 6 7 8 9 10
11
1
2 0.1200
3 0.1200 0.0000
4 0.1200 0.0000 0.0000
5 0.1200 0.0200 0.0100 0.0100
6 0.1200 0.0200 0.0100 0.0100 0.0000
7 0.1200 0.0298 0.0100 0.0100 0.0000 0.0000
8 0.1200 0.1347 0.0100 0.0100 0.0000 0.0000 0.0000
9 0.1200 0.0358 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000
10 0.1200 0.0165 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000
11 0.1200 0.0848 0.0100 0.0100 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

----------------------------------------------------------
NO. K-COEFFICIENT
----- ---------------
k(1) 0.9746020E+01
k(2) 0.1808340E+02
k(3) 0.4126660E+04
k(4) 0.4460550E+02
k(5) 0.9765440E+00
k(6) 0.8181340E+02
k(7) 0.1564990E+05

---------------------------------------
1 2 3 4 5 6 7 8 9 10
11
1
2 0.0000
3 0.0000 0.0000
4 0.0000 0.0000 0.0000
5 0.0000 0.0000 0.0000 0.0000
6 0.0000 0.0000 0.0000 0.0000 0.0000
7 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
9 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
10 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
11 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

-----------------------------------------
A = A0 + A1*T + A2*T**2 + A3*T**3 + A4*T**4
B = B0 + B1*T + B2*T**2 + B3*T**3 + B4*T**4
C = A0 + C1*T + C2*T**2 + C3*T**3 + C4*T**4

P in psia
T in degree F
A0 A1 A2 A3 A4
1.1630599 -16.6303997 111.0730515 -376.8592529 524.8891602
B0 B1 B2 B3 B4
0.9650900 -0.2725500 0.0923400 -0.1008300 0.0997900
C0 C1 C2 C3 C4

1.2803000 -10.7566004 52.6962204 -222.3948822 462.6725464

S0 S1
-0.0280370 -0.1203900

----------------------------------------------
D1 = 5.80000

-------------------------------------
H* = A + B*T + C*(T**2) + D*(T**3) + E*(T**4) + F*(T**5)

WHERE THE UNITS ARE
H* - BTU / LB-MOLE
T - DEGREES RANKIN
COMPONENT
NO NAME A B C D E F
-- ------ ---------- ---------- ---------- ---------- ---------- ----------
1 N2 -0.262E+02 0.715E+01 -0.498E-03 0.445E-06 -0.902E-10 0.445E-14
2 C1 -0.112E+03 0.917E+01 -0.472E-02 0.679E-05 -0.245E-08 0.312E-12
3 C2 -0.631E+00 0.796E+01 -0.752E-03 0.879E-05 -0.387E-08 0.548E-12
4 C3 -0.325E+02 0.761E+01 0.415E-02 0.951E-05 -0.472E-08 0.702E-12
5 NC4 0.432E+03 0.573E+01 0.156E-01 0.301E-05 -0.244E-08 0.381E-12
6 NC5 0.196E+04 -0.202E+00 0.318E-01 -0.623E-05 0.590E-09 -0.142E-13
7 C6 0.000E+00 0.242E+01 0.343E-01 -0.477E-05 0.000E+00 0.000E+00
8 C8 0.000E+00 0.656E+01 0.463E-01 -0.683E-05 0.000E+00 0.000E+00
9 C14 0.000E+00 0.462E+02 0.557E-01 -0.936E-05 0.000E+00 0.000E+00
10 C20 0.000E+00 0.541E+02 0.143E+00 -0.225E-04 0.000E+00 0.000E+00
11 C34 0.000E+00 0.165E+02 0.174E+00 -0.237E-04 0.000E+00 0.000E+00
-------------------------

--------- -------------
N2 0.00110
C1 0.68930
C2 0.08640
C3 0.05340
NC4 0.03480
NC5 0.01780
C6 0.01730
C8 0.06445
C14 0.02047
C20 0.01003
C34 0.00495


------- --------------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------ ------ ------
6010.0 0.00 158.00 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
5000.0 0.00 147.90 0.0000 0.0807 0.0000 0.1025 0.0000 0.0776
4000.0 0.00 136.62 0.0000 0.1946 0.0000 0.2491 0.0000 0.1866
3000.0 0.00 124.28 0.0000 0.3533 0.0000 0.2997 0.0000 0.2035
2100.0 0.00 117.31 0.0000 0.5189 0.0000 0.2797 0.0000 0.1680
1200.0 0.00 113.64 0.0000 0.6938 0.0000 0.2463 0.0000 0.1274
700.0 0.00 112.50 0.0000 0.7910 0.0000 0.2242 0.0000 0.1047


------- --------------- --------------- ---------------
------- ------ ------ ------ ------ ------ ------
6010.0 0.0000 0.0000 0.0000 1.0361 0.0000 0.0000
5000.0 0.0000 1.1383 0.0000 0.9196 0.0000 0.6265
4000.0 0.0000 0.9219 0.0000 0.8378 0.0000 0.5893
3000.0 0.0000 0.7636 0.0000 0.8192 0.0000 0.6065
2100.0 0.0000 0.6056 0.0000 0.8367 0.0000 0.6432
1200.0 0.0000 0.4041 0.0000 0.8802 0.0000 0.6862
700.0 0.0000 0.2634 0.0000 0.9141 0.0000 0.7133

------- --------------- --------------- -----------
------- ------ ------ ------ ------ -----------
6010.0 0.0000 0.0000 0.0000 0.0693 0.0000E+00
5000.0 0.0000 0.1943 0.0000 0.0523 0.2388E+00
4000.0 0.0000 0.1472 0.0000 0.0364 0.5777E+00
3000.0 0.0000 0.1605 0.0000 0.0245 0.2443E+01
2100.0 0.0000 0.2020 0.0000 0.0182 0.6613E+01
1200.0 0.0000 0.2693 0.0000 0.0148 0.1418E+02
700.0 0.0000 0.3241 0.0000 0.0136 0.2030E+02
---------------------------
PRESSURE - PSIG
---------------
OIL COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C20 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C34 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000

------------------------
PRESSURE - PSIG
---------------
OIL COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0000 0.0007 0.0007 0.0005 0.0003 0.0002 0.0001
C1 0.0000 0.5283 0.5089 0.4277 0.3204 0.1922 0.1127
C2 0.0000 0.0850 0.0860 0.0849 0.0785 0.0617 0.0445
C3 0.0000 0.0557 0.0586 0.0624 0.0640 0.0585 0.0480
NC4 0.0000 0.0418 0.0451 0.0520 0.0591 0.0628 0.0595
NC5 0.0000 0.0234 0.0260 0.0317 0.0386 0.0456 0.0478
C6 0.0000 0.0252 0.0284 0.0358 0.0455 0.0573 0.0639
C8 0.0000 0.1189 0.1320 0.1687 0.2199 0.2899 0.3413
C14 0.0000 0.0551 0.0596 0.0740 0.0957 0.1282 0.1560
C20 0.0000 0.0223 0.0296 0.0387 0.0495 0.0660 0.0803
C34 0.0000 0.0436 0.0251 0.0235 0.0285 0.0376 0.0458
---------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C1 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C3 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC4 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
NC5 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C6 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C8 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C14 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C20 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
C34 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000


------------------------
PRESSURE - PSIG
PRODUCED ---------------
GAS COMP 6010. 5000. 4000. 3000. 2100. 1200. 700.
-------- ------ ------ ------ ------ ------ ------ ------
N2 0.0011 0.0011 0.0012 0.0013 0.0013 0.0012 0.0012
C1 0.6893 0.7028 0.7337 0.7675 0.7800 0.7734 0.7491
C2 0.0864 0.0865 0.0865 0.0869 0.0890 0.0938 0.0992
C3 0.0534 0.0532 0.0521 0.0506 0.0509 0.0544 0.0603
NC4 0.0348 0.0342 0.0322 0.0296 0.0287 0.0309 0.0362
NC5 0.0178 0.0173 0.0158 0.0136 0.0125 0.0129 0.0155
C6 0.0173 0.0166 0.0146 0.0117 0.0100 0.0099 0.0118
C8 0.0644 0.0599 0.0477 0.0330 0.0251 0.0223 0.0257
C14 0.0205 0.0176 0.0108 0.0046 0.0021 0.0012 0.0010
C20 0.0100 0.0090 0.0051 0.0014 0.0004 0.0001 0.0000
C34 0.0050 0.0017 0.0002 0.0000 0.0000 0.0000 0.0000
------------------------
0 P = 5000.0 ZZ = 0.10972E-02 0.68811E+00 0.86390E-01 0.53417E-01 0.34851E-01
0.17841E-01 0.17358E-01 0.64849E-01 0.20729E-01 0.10119E-01
0.52363E-02
ZY = 0.91963 YY = 0.11316E-02 0.70285E+00 0.86520E-01 0.53206E-01 0.34215E-01
0.17329E-01 0.16636E-01 0.59863E-01 0.17555E-01 0.89987E-02
0.16985E-02
ZX = 1.13827 XX = 0.72412E-03 0.52833E+00 0.84978E-01 0.55707E-01 0.41754E-01
0.23400E-01 0.25189E-01 0.11891E+00 0.55141E-01 0.22271E-01
0.43596E-01
KV = 0.15628E+01 0.13303E+01 0.10181E+01 0.95509E+00 0.81944E+00
0.74055E+00 0.66044E+00 0.50343E+00 0.31837E+00 0.40405E+00
0.38961E-01
0 P = 4000.0 ZZ = 0.10817E-02 0.68165E+00 0.86376E-01 0.53602E-01 0.35222E-01
0.18135E-01 0.17755E-01 0.67270E-01 0.22129E-01 0.10823E-01
0.59512E-02
ZY = 0.83782 YY = 0.12070E-02 0.73374E+00 0.86485E-01 0.52107E-01 0.32231E-01
0.15768E-01 0.14554E-01 0.47741E-01 0.10835E-01 0.51466E-02
0.18504E-03
ZX = 0.92190 XX = 0.66609E-03 0.50892E+00 0.86013E-01 0.58561E-01 0.45144E-01
0.25985E-01 0.28371E-01 0.13204E+00 0.59586E-01 0.29649E-01
0.25074E-01
KV = 0.18121E+01 0.14418E+01 0.10055E+01 0.88979E+00 0.71396E+00
0.60679E+00 0.51299E+00 0.36158E+00 0.18184E+00 0.17358E+00
0.73797E-02
0 P = 3000.0 ZZ = 0.10333E-02 0.66059E+00 0.86254E-01 0.54336E-01 0.36614E-01
0.19257E-01 0.19252E-01 0.75686E-01 0.26434E-01 0.13134E-01
0.74098E-02
ZY = 0.81925 YY = 0.12788E-02 0.76750E+00 0.86871E-01 0.50613E-01 0.29550E-01
0.13563E-01 0.11655E-01 0.32974E-01 0.45857E-02 0.14069E-02
0.67563E-05
ZX = 0.76358 XX = 0.49854E-03 0.42771E+00 0.84912E-01 0.62447E-01 0.52001E-01
0.31660E-01 0.35800E-01 0.16873E+00 0.74028E-01 0.38679E-01
0.23537E-01
KV = 0.25651E+01 0.17944E+01 0.10231E+01 0.81049E+00 0.56826E+00
0.42840E+00 0.32556E+00 0.19543E+00 0.61945E-01 0.36375E-01
0.28706E-03
0 P = 2100.0 ZZ = 0.94777E-03 0.61949E+00 0.85319E-01 0.55503E-01 0.39325E-01
0.21591E-01 0.22425E-01 0.93107E-01 0.34798E-01 0.17533E-01
0.99611E-02
ZY = 0.83674 YY = 0.12818E-02 0.77995E+00 0.88973E-01 0.50948E-01 0.28740E-01
0.12477E-01 0.10036E-01 0.25091E-01 0.21441E-02 0.35851E-03
0.31500E-06
ZX = 0.60560 XX = 0.32527E-03 0.32042E+00 0.78508E-01 0.63993E-01 0.59056E-01
0.38579E-01 0.45517E-01 0.21988E+00 0.95659E-01 0.49542E-01
0.28526E-01
KV = 0.39406E+01 0.24342E+01 0.11333E+01 0.79614E+00 0.48665E+00
0.32341E+00 0.22048E+00 0.11411E+00 0.22414E-01 0.72365E-02
0.11042E-04
0 P = 1200.0 ZZ = 0.78722E-03 0.53166E+00 0.80471E-01 0.56116E-01 0.44160E-01
0.26527E-01 0.29593E-01 0.13356E+00 0.53998E-01 0.27490E-01
0.15648E-01
ZY = 0.88017 YY = 0.12290E-02 0.77336E+00 0.93811E-01 0.54429E-01 0.30857E-01
0.12945E-01 0.98698E-02 0.22251E-01 0.11631E-02 0.89250E-04
0.14524E-07
ZX = 0.40407 XX = 0.16664E-03 0.19216E+00 0.61734E-01 0.58486E-01 0.62844E-01
0.45603E-01 0.57295E-01 0.28989E+00 0.12821E+00 0.65978E-01
0.37626E-01
KV = 0.73752E+01 0.40244E+01 0.15196E+01 0.93064E+00 0.49101E+00
0.28387E+00 0.17226E+00 0.76757E-01 0.90719E-02 0.13527E-02
0.38602E-06

0 P = 700.0 ZZ = 0.61832E-03 0.43043E+00 0.71773E-01 0.54153E-01 0.47860E-01

0.31663E-01 0.37894E-01 0.18377E+00 0.78649E-01 0.40263E-01
0.22931E-01
ZY = 0.91407 YY = 0.11501E-02 0.74913E+00 0.99157E-01 0.60333E-01 0.36209E-01
0.15491E-01 0.11758E-01 0.25682E-01 0.10384E-02 0.48430E-04
0.30733E-08
ZX = 0.26337 XX = 0.88272E-04 0.11274E+00 0.44477E-01 0.47994E-01 0.59475E-01
0.47784E-01 0.63946E-01 0.34134E+00 0.15601E+00 0.80350E-01
0.45788E-01
KV = 0.13029E+02 0.66447E+01 0.22294E+01 0.12571E+01 0.60880E+00
0.32419E+00 0.18388E+00 0.75239E-01 0.66557E-02 0.60274E-03
0.67119E-07
---------------------

--------- -------------
N2 0.00110
C1 0.68930
C2 0.08640
C3 0.05340
NC4 0.03480
NC5 0.01780
C6 0.01730
C8 0.06445
C14 0.02047
C20 0.01003
C34 0.00495




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 3677. 4276. 4410. 0.0000 1.1991 0.0000 0.6686
100.0 75.0 0. 181. 212. 202. 0.0000 1.1187 0.0000 0.8577
0.0 75.0 0. 210. 212. 210. 0.0000 1.0000 0.0000 1.5410

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.2203 0.0000 0.1708 0.0000 0.7397
100.0 75.0 0.0000 0.1845 0.0000 0.0470 0.0000 0.7601
0.0 75.0 0.0000 0.1475 0.0000 0.0067 0.0000 0.7817
------------
0STAGE 1 ZZ = 0.11000E-02 0.68930E+00 0.86400E-01 0.53400E-01 0.34800E-01
0.17800E-01 0.17300E-01 0.64447E-01 0.20473E-01 0.10029E-01
0.49510E-02
ZY = 0.90200 YY = 0.13921E-02 0.85010E+00 0.88272E-01 0.41045E-01 0.13704E-01
0.29832E-02 0.13410E-02 0.11549E-02 0.51466E-05 0.47522E-07
0.30446E-10
ZX = 0.17082 XX = 0.66049E-04 0.12016E+00 0.79776E-01 0.97128E-01 0.10947E+00
0.70242E-01 0.73785E-01 0.28846E+00 0.92916E-01 0.45525E-01
0.22474E-01
KV = 0.21077E+02 0.70746E+01 0.11065E+01 0.42259E+00 0.12519E+00

0.42471E-01 0.18174E-01 0.40036E-02 0.55390E-04 0.10439E-05

0.13547E-08
0STAGE 2 ZZ = 0.66049E-04 0.12016E+00 0.79776E-01 0.97128E-01 0.10947E+00
0.70242E-01 0.73785E-01 0.28846E+00 0.92916E-01 0.45525E-01
0.22474E-01
ZY = 0.95871 YY = 0.38432E-03 0.62271E+00 0.20444E+00 0.11713E+00 0.40815E-01
0.83108E-02 0.34893E-02 0.27090E-02 0.83136E-05 0.36914E-07
0.62559E-15
ZX = 0.04695 XX = 0.43982E-05 0.22817E-01 0.55627E-01 0.93253E-01 0.12276E+00
0.82238E-01 0.87401E-01 0.34381E+00 0.11091E+00 0.54343E-01
0.26828E-01
KV = 0.87381E+02 0.27292E+02 0.36753E+01 0.12561E+01 0.33247E+00
0.10106E+00 0.39922E-01 0.78794E-02 0.74956E-04 0.67928E-06
0.23319E-13
0STAGE 3 ZZ = 0.43982E-05 0.22817E-01 0.55627E-01 0.93253E-01 0.12276E+00
0.82238E-01 0.87401E-01 0.34381E+00 0.11091E+00 0.54343E-01
0.26828E-01
ZY = 0.98324 YY = 0.21760E-04 0.11148E+00 0.24142E+00 0.32122E+00 0.22123E+00
0.58242E-01 0.26030E-01 0.20308E-01 0.54877E-04 0.19423E-06
0.20457E-14
ZX = 0.00673 XX = 0.31013E-07 0.51580E-03 0.88941E-02 0.35912E-01 0.97997E-01
0.88274E-01 0.10284E+00 0.42518E+00 0.13880E+00 0.68013E-01
0.33576E-01
KV = 0.70165E+03 0.21613E+03 0.27144E+02 0.89445E+01 0.22575E+01
0.65978E+00 0.25312E+00 0.47763E-01 0.39537E-03 0.28558E-05
0.60928E-13
---------------------

--------- -------------
N2 0.00113
C1 0.70285
C2 0.08652
C3 0.05321
NC4 0.03421
NC5 0.01733
C6 0.01664
C8 0.05986
C14 0.01756
C20 0.00900
C34 0.00170




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 4310. 5277. 5267. 0.0000 1.2219 0.0000 0.6704
100.0 75.0 0. 195. 223. 221. 0.0000 1.1324 0.0000 0.8624
0.0 75.0 0. 231. 227. 231. 0.0000 1.0000 0.0000 1.5571

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.2012 0.0000 0.1635 0.0000 0.7251

100.0 75.0 0.0000 0.1676 0.0000 0.0449 0.0000 0.7467

0.0 75.0 0.0000 0.1326 0.0000 0.0064 0.0000 0.7693
------------
0STAGE 1 ZZ = 0.11316E-02 0.70285E+00 0.86520E-01 0.53206E-01 0.34215E-01
0.17329E-01 0.16636E-01 0.59863E-01 0.17555E-01 0.89987E-02
0.16985E-02
ZY = 0.90147 YY = 0.13994E-02 0.84895E+00 0.88121E-01 0.41608E-01 0.14202E-01
0.31306E-02 0.14054E-02 0.11830E-02 0.50285E-05 0.45003E-07
0.00000E+00
ZX = 0.16350 XX = 0.68525E-04 0.12278E+00 0.80162E-01 0.99254E-01 0.11368E+00
0.73701E-01 0.77108E-01 0.29285E+00 0.87237E-01 0.44727E-01
0.84425E-02
KV = 0.20422E+02 0.69145E+01 0.10993E+01 0.41921E+00 0.12493E+00
0.42478E-01 0.18227E-01 0.40397E-02 0.57642E-04 0.10062E-05
0.00000E+00
0STAGE 2 ZZ = 0.68525E-04 0.12278E+00 0.80162E-01 0.99254E-01 0.11368E+00
0.73701E-01 0.77108E-01 0.29285E+00 0.87237E-01 0.44727E-01
0.84425E-02
ZY = 0.95826 YY = 0.38801E-03 0.62024E+00 0.20298E+00 0.11881E+00 0.42393E-01
0.87464E-02 0.36659E-02 0.27719E-02 0.80991E-05 0.35221E-07
0.25159E-15
ZX = 0.04489 XX = 0.45682E-05 0.23193E-01 0.55575E-01 0.95339E-01 0.12795E+00
0.86704E-01 0.91810E-01 0.35092E+00 0.10470E+00 0.53681E-01
0.10133E-01
KV = 0.84939E+02 0.26742E+02 0.36523E+01 0.12462E+01 0.33134E+00
0.10088E+00 0.39930E-01 0.78990E-02 0.77356E-04 0.65612E-06
0.24830E-13
0STAGE 3 ZZ = 0.45682E-05 0.23193E-01 0.55575E-01 0.95339E-01 0.12795E+00
0.86704E-01 0.91810E-01 0.35092E+00 0.10470E+00 0.53681E-01
0.10133E-01
ZY = 0.98291 YY = 0.21738E-04 0.10903E+00 0.23321E+00 0.31979E+00 0.22808E+00
0.61409E-01 0.27492E-01 0.20912E-01 0.53763E-04 0.18616E-06
0.81977E-15
ZX = 0.00642 XX = 0.31837E-07 0.51367E-03 0.86439E-02 0.36037E-01 0.10149E+00
0.93387E-01 0.10880E+00 0.43811E+00 0.13235E+00 0.67863E-01
0.12810E-01
KV = 0.68279E+03 0.21227E+03 0.26979E+02 0.88741E+01 0.22473E+01
0.65758E+00 0.25268E+00 0.47732E-01 0.40623E-03 0.27432E-05
0.63997E-13
---------------------

--------- -------------
N2 0.00121
C1 0.73374
C2 0.08649
C3 0.05211
NC4 0.03223
NC5 0.01577
C6 0.01455
C8 0.04774
C14 0.01083
C20 0.00515
C34 0.00019





------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 6205. 7828. 7816. 0.0000 1.2595 0.0000 0.6742
100.0 75.0 0. 213. 248. 246. 0.0000 1.1579 0.0000 0.8733
0.0 75.0 0. 270. 263. 270. 0.0000 1.0000 0.0000 1.5940

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1560 0.0000 0.1547 0.0000 0.7072
100.0 75.0 0.0000 0.1294 0.0000 0.0423 0.0000 0.7299
0.0 75.0 0.0000 0.1003 0.0000 0.0060 0.0000 0.7541
------------
0STAGE 1 ZZ = 0.12070E-02 0.73374E+00 0.86485E-01 0.52107E-01 0.32231E-01
0.15768E-01 0.14554E-01 0.47741E-01 0.10835E-01 0.51466E-02
0.18504E-03
ZY = 0.90029 YY = 0.14170E-02 0.84649E+00 0.87647E-01 0.42765E-01 0.15397E-01
0.34967E-02 0.15544E-02 0.12235E-02 0.41383E-05 0.33090E-07
0.00000E+00
ZX = 0.15474 XX = 0.71057E-04 0.12375E+00 0.80203E-01 0.10265E+00 0.12330E+00
0.82152E-01 0.84881E-01 0.29940E+00 0.69428E-01 0.32989E-01
0.11861E-02
KV = 0.19942E+02 0.68405E+01 0.10928E+01 0.41663E+00 0.12488E+00
0.42564E-01 0.18312E-01 0.40864E-02 0.59606E-04 0.10030E-05
0.00000E+00
0STAGE 2 ZZ = 0.71057E-04 0.12375E+00 0.80203E-01 0.10265E+00 0.12330E+00
0.82152E-01 0.84881E-01 0.29940E+00 0.69428E-01 0.32989E-01
0.11861E-02
ZY = 0.95720 YY = 0.39382E-03 0.61353E+00 0.20110E+00 0.12222E+00 0.46043E-01
0.97900E-02 0.40608E-02 0.28603E-02 0.66299E-05 0.25880E-07
0.37628E-16
ZX = 0.04233 XX = 0.47267E-05 0.23095E-01 0.55358E-01 0.98624E-01 0.13917E+00
0.97023E-01 0.10149E+00 0.36034E+00 0.83694E-01 0.39768E-01
0.14298E-02
KV = 0.83319E+02 0.26565E+02 0.36328E+01 0.12392E+01 0.33083E+00
0.10090E+00 0.40012E-01 0.79379E-02 0.79215E-04 0.65076E-06
0.26316E-13
0STAGE 3 ZZ = 0.47267E-05 0.23095E-01 0.55358E-01 0.98624E-01 0.13917E+00
0.97023E-01 0.10149E+00 0.36034E+00 0.83694E-01 0.39768E-01
0.14298E-02
ZY = 0.98211 YY = 0.20899E-04 0.10100E+00 0.21805E+00 0.31531E+00 0.24382E+00
0.69033E-01 0.30815E-01 0.21909E-01 0.44549E-04 0.13905E-06
0.12240E-15
ZX = 0.00605 XX = 0.31089E-07 0.47573E-03 0.81197E-02 0.35708E-01 0.10879E+00
0.10515E+00 0.12201E+00 0.45860E+00 0.10798E+00 0.51315E-01
0.18450E-02
KV = 0.67223E+03 0.21231E+03 0.26854E+02 0.88301E+01 0.22412E+01
0.65652E+00 0.25256E+00 0.47773E-01 0.41256E-03 0.27097E-05
0.66343E-13
---------------------

--------- -------------
N2 0.00128
C1 0.76750
C2 0.08687
C3 0.05061
NC4 0.02955
NC5 0.01356
C6 0.01166
C8 0.03297
C14 0.00459
C20 0.00141
C34 0.00001





------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 10453. 13774. 13745. 0.0000 1.3150 0.0000 0.6796
100.0 75.0 0. 232. 290. 278. 0.0000 1.1980 0.0000 0.8889
0.0 75.0 0. 330. 333. 330. 0.0000 1.0000 0.0000 1.6444

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.1045 0.0000 0.1455 0.0000 0.6875
100.0 75.0 0.0000 0.0864 0.0000 0.0396 0.0000 0.7109
0.0 75.0 0.0000 0.0649 0.0000 0.0056 0.0000 0.7368
------------
0STAGE 1 ZZ = 0.12788E-02 0.76750E+00 0.86871E-01 0.50613E-01 0.29550E-01
0.13563E-01 0.11655E-01 0.32974E-01 0.45857E-02 0.14069E-02
0.67563E-05
ZY = 0.89859 YY = 0.14196E-02 0.84271E+00 0.87606E-01 0.44111E-01 0.17064E-01
0.40568E-02 0.17733E-02 0.12602E-02 0.26451E-05 0.45370E-08
0.00000E+00
ZX = 0.14549 XX = 0.72199E-04 0.12309E+00 0.80568E-01 0.10632E+00 0.13653E+00
0.95012E-01 0.96324E-01 0.30470E+00 0.43854E-01 0.13462E-01
0.64645E-04
KV = 0.19663E+02 0.68462E+01 0.10874E+01 0.41491E+00 0.12498E+00
0.42697E-01 0.18410E-01 0.41359E-02 0.60316E-04 0.33703E-06
0.00000E+00
0STAGE 2 ZZ = 0.72199E-04 0.12309E+00 0.80568E-01 0.10632E+00 0.13653E+00
0.95012E-01 0.96324E-01 0.30470E+00 0.43854E-01 0.13462E-01
0.64645E-04
ZY = 0.95564 YY = 0.39392E-03 0.60281E+00 0.20053E+00 0.12620E+00 0.51105E-01
0.11378E-01 0.46383E-02 0.29391E-02 0.42560E-05 0.10781E-07
0.21526E-17
ZX = 0.03957 XX = 0.47669E-05 0.22542E-01 0.55424E-01 0.10215E+00 0.15444E+00
0.11254E+00 0.11554E+00 0.36795E+00 0.53044E-01 0.16283E-01
0.78195E-04
KV = 0.82636E+02 0.26742E+02 0.36180E+01 0.12355E+01 0.33091E+00
0.10110E+00 0.40144E-01 0.79878E-02 0.80236E-04 0.66209E-06
0.27529E-13
0STAGE 3 ZZ = 0.47669E-05 0.22542E-01 0.55424E-01 0.10215E+00 0.15444E+00
0.11254E+00 0.11554E+00 0.36795E+00 0.53044E-01 0.16283E-01
0.78195E-04
ZY = 0.98100 YY = 0.19095E-04 0.89453E-01 0.20039E+00 0.30605E+00 0.26438E+00
0.80771E-01 0.35849E-01 0.23062E-01 0.29126E-04 0.59710E-07
0.70064E-17
ZX = 0.00563 XX = 0.28447E-07 0.41335E-03 0.74832E-02 0.34716E-01 0.11808E+00
0.12305E+00 0.14190E+00 0.48201E+00 0.70577E-01 0.21668E-01
0.10405E-03
KV = 0.67124E+03 0.21641E+03 0.26778E+02 0.88157E+01 0.22390E+01
0.65642E+00 0.25265E+00 0.47846E-01 0.41268E-03 0.27556E-05
0.67334E-13
---------------------

--------- -------------
N2 0.00128
C1 0.77995
C2 0.08897
C3 0.05095
NC4 0.02874
NC5 0.01248
C6 0.01004

C8 0.02509
C14 0.00214
C20 0.00036
C34 0.00000




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 14472. 19863. 19808. 0.0000 1.3687 0.0000 0.6851
100.0 75.0 0. 250. 305. 309. 0.0000 1.2366 0.0000 0.9038
0.0 75.0 0. 387. 396. 387. 0.0000 1.0000 0.0000 1.6805

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.0803 0.0000 0.1404 0.0000 0.6722
100.0 75.0 0.0000 0.0660 0.0000 0.0381 0.0000 0.6962
0.0 75.0 0.0000 0.0480 0.0000 0.0054 0.0000 0.7232
------------
0STAGE 1 ZZ = 0.12818E-02 0.77995E+00 0.88973E-01 0.50948E-01 0.28740E-01
0.12477E-01 0.10036E-01 0.25091E-01 0.21441E-02 0.35851E-03
0.31500E-06
ZY = 0.89676 YY = 0.13874E-02 0.83730E+00 0.89527E-01 0.45741E-01 0.18414E-01
0.44699E-02 0.19117E-02 0.12497E-02 0.16139E-05 0.00000E+00
0.00000E+00
ZX = 0.14041 XX = 0.71757E-04 0.12338E+00 0.82628E-01 0.11055E+00 0.14696E+00
0.10415E+00 0.10305E+00 0.29806E+00 0.26675E-01 0.44633E-02
0.39216E-05
KV = 0.19335E+02 0.67863E+01 0.10835E+01 0.41375E+00 0.12530E+00
0.42917E-01 0.18551E-01 0.41927E-02 0.60503E-04 0.00000E+00
0.00000E+00
0STAGE 2 ZZ = 0.71757E-04 0.12338E+00 0.82628E-01 0.11055E+00 0.14696E+00
0.10415E+00 0.10305E+00 0.29806E+00 0.26675E-01 0.44633E-02
0.39216E-05
ZY = 0.95409 YY = 0.38086E-03 0.58973E+00 0.20339E+00 0.13076E+00 0.55243E-01
0.12566E-01 0.50099E-02 0.29115E-02 0.26554E-05 0.36174E-08
0.13844E-18
ZX = 0.03811 XX = 0.46672E-05 0.22162E-01 0.56416E-01 0.10617E+00 0.16687E+00
0.12403E+00 0.12433E+00 0.36212E+00 0.32464E-01 0.54320E-02
0.47728E-05
KV = 0.81603E+02 0.26610E+02 0.36053E+01 0.12316E+01 0.33106E+00
0.10132E+00 0.40295E-01 0.80401E-02 0.81795E-04 0.66594E-06
0.29006E-13
0STAGE 3 ZZ = 0.46672E-05 0.22162E-01 0.56416E-01 0.10617E+00 0.16687E+00
0.12403E+00 0.12433E+00 0.36212E+00 0.32464E-01 0.54320E-02
0.47728E-05
ZY = 0.98018 YY = 0.17084E-04 0.80460E-01 0.18846E+00 0.29918E+00 0.27924E+00
0.89778E-01 0.39438E-01 0.23412E-01 0.18545E-04 0.20559E-07
0.45127E-18
ZX = 0.00543 XX = 0.25642E-07 0.36984E-03 0.70567E-02 0.34020E-01 0.12487E+00
0.13683E+00 0.15606E+00 0.48873E+00 0.44592E-01 0.74625E-02
0.65569E-05
KV = 0.66626E+03 0.21755E+03 0.26707E+02 0.87942E+01 0.22363E+01
0.65612E+00 0.25271E+00 0.47904E-01 0.41589E-03 0.27550E-05

0.68824E-13
---------------------

--------- -------------
N2 0.00123
C1 0.77336
C2 0.09381
C3 0.05443
NC4 0.03086
NC5 0.01295
C6 0.00987
C8 0.02225
C14 0.00116
C20 0.00009
C34 0.00000




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 15687. 22121. 22698. 0.0000 1.4469 0.0000 0.6939
100.0 75.0 0. 274. 370. 354. 0.0000 1.2920 0.0000 0.9260
0.0 75.0 0. 469. 482. 469. 0.0000 1.0000 0.0000 1.7162

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.0765 0.0000 0.1367 0.0000 0.6583
100.0 75.0 0.0000 0.0620 0.0000 0.0371 0.0000 0.6834
0.0 75.0 0.0000 0.0430 0.0000 0.0053 0.0000 0.7124
------------
0STAGE 1 ZZ = 0.12290E-02 0.77336E+00 0.93811E-01 0.54429E-01 0.30857E-01
0.12945E-01 0.98698E-02 0.22251E-01 0.11631E-02 0.89250E-04
0.14524E-07
ZY = 0.89373 YY = 0.13250E-02 0.82707E+00 0.94347E-01 0.49097E-01 0.20170E-01
0.48187E-02 0.19792E-02 0.11871E-02 0.97211E-06 0.00000E+00
0.00000E+00
ZX = 0.13667 XX = 0.70068E-04 0.12447E+00 0.87329E-01 0.11883E+00 0.15995E+00
0.11111E+00 0.10518E+00 0.27669E+00 0.15201E-01 0.11673E-02
0.18997E-06
KV = 0.18910E+02 0.66446E+01 0.10804E+01 0.41318E+00 0.12610E+00
0.43369E-01 0.18818E-01 0.42903E-02 0.63952E-04 0.00000E+00
0.00000E+00
0STAGE 2 ZZ = 0.70068E-04 0.12447E+00 0.87329E-01 0.11883E+00 0.15995E+00
0.11111E+00 0.10518E+00 0.27669E+00 0.15201E-01 0.11673E-02
0.18997E-06
ZY = 0.95168 YY = 0.35266E-03 0.56682E+00 0.21069E+00 0.13987E+00 0.60688E-01
0.13608E-01 0.52068E-02 0.27638E-02 0.15780E-05 0.96346E-09
0.73215E-20
ZX = 0.03712 XX = 0.43990E-05 0.21682E-01 0.58662E-01 0.11394E+00 0.18302E+00
0.13377E+00 0.12841E+00 0.34034E+00 0.18733E-01 0.14386E-02
0.23412E-06

KV = 0.80169E+02 0.26143E+02 0.35916E+01 0.12275E+01 0.33159E+00

0.10173E+00 0.40548E-01 0.81207E-02 0.84240E-04 0.66973E-06
0.31273E-13
0STAGE 3 ZZ = 0.43990E-05 0.21682E-01 0.58662E-01 0.11394E+00 0.18302E+00
0.13377E+00 0.12841E+00 0.34034E+00 0.18733E-01 0.14386E-02
0.23412E-06
ZY = 0.97933 YY = 0.14251E-04 0.69757E-01 0.17584E+00 0.29473E+00 0.29631E+00
0.98106E-01 0.42149E-01 0.23086E-01 0.11396E-04 0.56672E-08
0.23942E-19
ZX = 0.00532 XX = 0.21639E-07 0.32269E-03 0.66021E-02 0.33616E-01 0.13269E+00
0.14961E+00 0.16674E+00 0.48130E+00 0.27050E-01 0.20777E-02
0.33813E-06
KV = 0.65861E+03 0.21617E+03 0.26634E+02 0.87675E+01 0.22331E+01
0.65574E+00 0.25279E+00 0.47966E-01 0.42131E-03 0.27276E-05
0.70806E-13
---------------------

--------- -------------
N2 0.00115
C1 0.74913
C2 0.09916
C3 0.06033
NC4 0.03621
NC5 0.01549
C6 0.01176
C8 0.02568
C14 0.00104
C20 0.00005
C34 0.00000




------ ------ --------------- --------------- --------------- --------------
------ ------ ------ ------ ------ ------ ------ ------ ------ -----
450.0 75.0 0. 12336. 19475. 18865. 0.0000 1.5292 0.0000 0.7027
100.0 75.0 0. 299. 367. 404. 0.0000 1.3495 0.0000 0.9478
0.0 75.0 0. 555. 558. 555. 0.0000 1.0000 0.0000 1.7409

------ ------ ------------------ ------------------ ------------------
------ ------ -------- -------- -------- -------- -------- --------
450.0 75.0 0.0000 0.0968 0.0000 0.1342 0.0000 0.6495
100.0 75.0 0.0000 0.0775 0.0000 0.0365 0.0000 0.6759
0.0 75.0 0.0000 0.0509 0.0000 0.0053 0.0000 0.7075
------------
0STAGE 1 ZZ = 0.11501E-02 0.74913E+00 0.99157E-01 0.60333E-01 0.36209E-01
0.15491E-01 0.11758E-01 0.25682E-01 0.10384E-02 0.48430E-04
0.30733E-08
ZY = 0.89059 YY = 0.12661E-02 0.81602E+00 0.99862E-01 0.53040E-01 0.21741E-01
0.49794E-02 0.19684E-02 0.11185E-02 0.73892E-06 0.54602E-09
0.67778E-20
ZX = 0.13418 XX = 0.68106E-04 0.12529E+00 0.92582E-01 0.12834E+00 0.17114E+00

0.11353E+00 0.10306E+00 0.25477E+00 0.10716E-01 0.50010E-03

0.31736E-07
KV = 0.18590E+02 0.65133E+01 0.10786E+01 0.41328E+00 0.12703E+00
0.43861E-01 0.19098E-01 0.43902E-02 0.68957E-04 0.10918E-05
0.21357E-12
0STAGE 2 ZZ = 0.68106E-04 0.12529E+00 0.92582E-01 0.12834E+00 0.17114E+00
0.11353E+00 0.10306E+00 0.25477E+00 0.10716E-01 0.50010E-03
0.31736E-07
ZY = 0.94922 YY = 0.32467E-03 0.54283E+00 0.21882E+00 0.15046E+00 0.65626E-01
0.14133E-01 0.52015E-02 0.26045E-02 0.11557E-05 0.42304E-09
0.13227E-20
ZX = 0.03652 XX = 0.41030E-05 0.21126E-01 0.61090E-01 0.12282E+00 0.19746E+00
0.13832E+00 0.12748E+00 0.31768E+00 0.13388E-01 0.62485E-03
0.39652E-07
KV = 0.79131E+02 0.25695E+02 0.35819E+01 0.12250E+01 0.33234E+00
0.10217E+00 0.40803E-01 0.81986E-02 0.86317E-04 0.67702E-06
0.33358E-13
0STAGE 3 ZZ = 0.41030E-05 0.21126E-01 0.61090E-01 0.12282E+00 0.19746E+00
0.13832E+00 0.12748E+00 0.31768E+00 0.13388E-01 0.62485E-03
0.39652E-07
ZY = 0.97873 YY = 0.11937E-04 0.61097E-01 0.16626E+00 0.29397E+00 0.30987E+00
0.10282E+00 0.43329E-01 0.22637E-01 0.86458E-05 0.25786E-08
0.43436E-20
ZX = 0.00528 XX = 0.18244E-07 0.28457E-03 0.62519E-02 0.33585E-01 0.13885E+00
0.15683E+00 0.17135E+00 0.47152E+00 0.20365E-01 0.95066E-03
0.60328E-07
KV = 0.65427E+03 0.21470E+03 0.26594E+02 0.87530E+01 0.22316E+01
0.65561E+00 0.25287E+00 0.48008E-01 0.42454E-03 0.27124E-05
0.72000E-13


Appendix
E
References
1. Katz, D.L., and Firoozabadi, A.: "Predicting Phase Behavior of
Condensate / Crude-Oil Systems Using Methane Interaction
Coefficients," J. Pet Tech, (Nov. 1978), 1649-1655; Trans., AIME, 228.
2. Lohrenz, J., Bray, B.G. , and Clark, C. R.: "Calculating Viscosities of

Reservoir Fluids From Their Compositions, " J. Pet Tech. (Oct. 1964),
1171-1176.
3. Whitson, C. H.: "Characterizing Hydrocarbon Plus Fractions," Soc. Pet.

Eng. J. (Aug. 1983), 683-694.
4. Nghiem, L.X., and Li, Y.K.: "Effects of Phase Behavior on CO2

Displacement Efficiency at Low Temperatures: Model Studies with an
Equation of State," SPE Res.Eng. (July, 1986) Vol. 1 , No. 4, 414-422.
5. Reid, R.C., Prausnitz, J.M., and Sherwood, T.K.: The Properties of

Gases and Liquids. McGraw-Hill Book Company, Third Edition, 1977.
6. Passut, C.A. and Danner, R. P.: I & EC Process Design and

Development, 11, 543 (1972).
7. Hwang, P.K. and Daubert, T.E.: I & EC Process Design and

Development, 13, 193 (1974).
8. Edminster, W.C. and Lee, B.I.: Applied Hydrocarbon

Thermodynamics, Vol. 1, Second Edition, Gulf Publishing Co., 1984.
9. Kesler, M.G. and Lee, B. I.: " Hydrocarbon Processing", 55(3), 153,
(1976).
10. Pedersen, K. S., Fredenslund, A., and Christensen, P.L.: "Viscosity of

Crude Oils," Chem. Eng. Sci., 39, pp. 1011-1016 (1984).
11. Pedersen, K.S. and Fredenslund, A.: "An Improved Corresponding

States Model for the Prediction of Oil and Gas Viscosities and Thermal
Conductivities," Chem. Eng. Sci., pp. 182-187 (1987).
12. Twu, C.H.: "Internally Consistent Correlation for Predicting Liquid

Viscosities of Petroleum Fractions," Ind. Eng. Chem. Process Des. Dev.,
(1985) 24, 1287-1293.
R2003.4 - Landmark E-269

References DESKTOP-PVT Keyword Reference Manual
13. Twu, C.H.: "Generalized Method for Predicting Viscosities of

Petroleum Fractions," AICHE J., (Dec. 1986) 32, 2091-2094.
14. Malinin, S.D. and Savelyeva, N.I.: "The Solubility of CO2 in NaCl
and CaCl2 Solutions at 25, 50, and 75 Under Elevated CO2
Pressures," Geochemistry International, (1972) 410-418.
15. Malinin, S.D. and Kurovskaya, N.A.: "Solubility of CO2 in Chloride

Solutions at Elevated Temperatures and CO2 Pressures," Geochemistry
International, (1975) 199-201.
16. McRee, B.C.: "CO2 : How It Works, Where It Works," Petroleum

Engineers, (Nov. 1977) 52-63.
17. Rowe, A.M. and Chou, J.C.: "Pressure-Volume-Temperature-

Concentration Relation of Aqueous NaCl Solutions," J. of Chemical and
Engineering Data, Vol. 15, No. 1 (1970) 61-66.
18. Parkinson, W.J. and De Nevers, N.: "Partial Model Volume of Carbon
Dioxide in Water Solutions," I & EC Fundamentals, Vol. 8, No. 4 (Nov.
1969) 709-713.
19. Sayegh, S.G. and Najman, J.: "Phase Behavior Measurements of CO2 -
SO2 -Brine Mixtures," The Canadian Journal of Chemical Engineering, Vol.
65 (April 1987)314-320.
20. Osif, T.L.: "The Effects of Salt, Gas, Temperature, and Pressure on the
Compressibility of Water," SPE Reservoir Engineering, Vol. 3, No. 1 (Feb.
1988) 175-181.
21. Kestin, J., Khalifa, H.E., Abe, Y, Grimes, C.E., Sookiazian, H. and
Wakeham, W.A.: "Effect of Pressure on the Viscosity of Aqueous NaCl
Solutions in the Temperature Range 20-150 C", J. of Chemical and
Engineering Data, Vol. 23, No. 4 (1978) 328-336.
22. Wiebe, R: "The Binary System Carbon Dioxide-Water Under Pressure,"

Chemical Reviews, 29 (1941) 475-481.
E-270 Landmark - R2003.4

000000Keyword E
Index ENDEOS 2-23
ENDREG 5-111
ENTHL 3-64
ENTHV 3-64
ENVELOPE 3-62
C ENVPT 3-77
EOS 2-6
CCEXP 3-44 EOS Data Card 2-6
CCEXPX 9-133
CCEXPY 9-133
CCEXPZ 9-133
CO2COR 2-20
G
CO2TAB 3-84
GIBBS 8-125
COMP 5-107
COMPONENTS 2-8
CVDEP 3-48
CVDEPX 9-133 H
CVDEPY 9-133
CVDEPZ 9-133 HIDEAL 2-22
D I
DBUGF 8-130 IMAX 5-106
DBUGS 8-130
DIFF 3-56
DIFFX 9-133
DIFFY 9-133 K
DIFFZ 9-133
DISTIL 3-69 KNTMXF 8-128
DJK 2-12 KNTMXS 8-126
DJKCOR 2-13 KVCOR 2-17
DPFAC 8-129 KVFILE 2-25
DPMAX 8-129
DPMIN 8-129
DPMXS 8-126
DRIFT 8-128
L
DXMXF 8-128 LBC 8-131
DXMXS 8-126 LIQDEN 3-36
R2003.4 - Landmark Keyword Index-271

Keyword Index DESKTOP-PVT KEYWORD REFERENCE MANUAL
TOLKS 8-126
M TOLPS 8-126
TOLS 8-126
MCSVAP 3-87 TOLXF 8-128
MCVAP 3-59 TOLXS 8-126
N V
NEWTON 8-125 VARIABLE 5-105
VISC 3-42
VISK 2-14, 2-15
VISKJ 2-15
O VISOIL PEDERSON 2-14
VISPE 8-131
Output 2-25 VP 3-38
P W
PROPERTIES 2-9 WATPRP 3-66
PSAT 3-40 WINOIL 2-25
PSATW 3-67
PVTFILE 2-24
Z
R ZFACTOR 3-34
ZGRAD 3-80
REGRESS 5-105 ZGRADX 9-133
RPS 8-131 ZGRADY 9-133
ZGRADZ 9-133
S
SEP 4-98
SEPARATOR 4-95
SPLIT 7-118
SS 8-125
SWELL 3-54
SWELLLY 9-133
SWELLX 9-133
SWELLZ 9-133
T
THERMAL 2-26
TOLF 8-128
TOLKF 8-128
Keyword Index-272 Landmark - R2003.4

000000Subject Index hydrocarbon 3-79

constant composition
in multiple contact vaporization 3-59
constant composition expansion procedure 3-
43
constant volume depletion
B how specified 3-48
binary interaction coefficients corresponding states principle 2-15
how specified 2-12
input in thermal option 2-26
bounded variables D
how established B-149
bubble point data
how calculated 3-40 how input 1-2
use in phase envelope calculation 3-62 overview for DESKTOP-PVT 1-1
bubble point pressure data sets
of oil in the presence of water 3-67 how handled 3-33
density
of liquid 3-36
of water 3-66
C depth
carbon dioxide effect on composition 3-79
water saturation 3-84 DESKTOP-PVT
carbon dioxide saturated water purpose of 1-1
specifying properties for 2-18 dew point
carbon dioxide solubility 2-18 how calculated 3-40
complete phase envelope use in phase envelope calculation 3-62
calculation of 3-77 differential expansion
component characteristics how specified 3-55
how specified 2-9 distillation test 2-17
component identification codes 2-5 how specified 3-69
component names
how specified 2-8
components E
pseudo 6-113
composition eigenvalues A-141
alternative specification 9-133 enthalpy
expansion of 3-43 of ideal gas state 2-22
R2003.4 - Landmark Subject-273

Subject DESKTOP-PVT KEYWORD REFERENCE MANUAL
of water 3-66
equation of state H
end of property data 2-23
how specified 2-6 heavy component composition
properties variations 3-79
how adjusted 5-103 heavy fractions
types defined 2-5 characterization of 7-117
use to predict PVT properties 2-5 example 7-123
expansion how grouped 2-5
differential 3-55 hydrocarbon composition
expansion test variation with depth 3-79
setting tolerances 8-129
I
F ideal gas state enthalpy 2-22
flash calculation input data
pressure intervals 8-129 how formatted 1-2
selection of alternative methods 8-125
specifying output 8-130
tolerances 8-128 K
fluid properties
how defined 2-5 Kestin et al. correlation 2-20
fluid samples K-values
variation in composition 3-33 specifying for components 2-17
fluid viscosity writing output for 2-25
calculation methods 8-131
fluids
type allowed 1-1 L
formation volume factor 2-18
FORTRAN file assignments 1-3 laboratory procedures
free field input 1-2 how simulated 3-33
fugacity coefficient least-squares function
of water 3-66 unconstrained minimum of A-137
least-squares method A-142
liquid
G water properties 3-66
liquid density 3-36
gas liquid viscosity
z-factor 3-33 how to specify 3-42
Gauss-Newton minimization A-139 Lohrenz, Bray, and Clark correlation 3-42
advantages of A-140 alternatives to 2-15
disadvantages of A-141 Lohrenz, Bray, and Clark viscosity correlation
Gibbs energy minimization 8-125 8-131
Subject-274 Landmark - R2003.4

DESKTOP-PVT KEYWORD REFERENCE MANUAL Subject
pressure
M bubble point of oil 3-67
saturation 3-40
mathematical models vapor 3-38
how to develop 1-1 production
minimization variables how to analyze 1-1
bounds of B-149 properties
mixing rules 2-12 carbon dioxide saturated water 3-84
multiple contact steam vaporization test 3-86 equation of state 5-103
multiple contact vaporization test of water 3-66
how specified 3-59 writing output for 2-24
multistage surface separation facilities properties data 2-9
how modeled 4-95 properties table 2-9
PSAT 3-40
pseudo components
N as composition output 3-59
pseudoization
near-critical reservoirs 3-79 how specified 6-113
Newton- Raphson method 8-125 PVT properties
nonlinear regression how generated 1-1
control parameters 5-106 how predicted 2-5
how used 5-103
nonlinear regression package 1-1
R
O real gas law 3-33
Redlich-Kwong equation of state 2-5, 2-6
oil-cycling process 3-59 regression
output files use in separator test 4-97
how to write for PVT properties 2-24 regression variables
writing for K-values 2-25 how assigned 5-107
initial value 5-105
Reid, Prausnitz and Sherwood 8-131
P rotational discrimination
algorithm used A-144
Passut-Danner 2-22 method used A-142
Pedersen et al. viscosity correlation 8-131
how specified 2-15
Peng-Robinson equation of state 2-5, 2-6 S
phase behavior calculation
default values 8-125 salinity 2-18
phase envelope saturation pressure
calculation of 3-62 calculation defaults 8-125
complete 3-77 how specified 3-40
predictive mode in composition expansion procedure 3-43
how used 1-1 saturation pressure calculation
R2003.4 - Landmark Subject-275

Subject DESKTOP-PVT KEYWORD REFERENCE MANUAL
tolerances 8-126 VIP-ENCORE

saturation pressure test using DESKTOP-PVT to generate data for
specifying output for 8-130 1-1
separator battery viscosity
how specified 4-95 fluid, calculation of 8-131
separator test of CO2 saturated water 2-20
how calculated 4-97 of liquid or vapor 3-42
Soave-Redlich-Kwong equation of state 2-5, 2- of water 3-66
6 viscosity correlation 8-131
steam vaporization test how specified 2-15
multiple contact 3-86 volume
sum-of-squares objective function A-139 constant volume depletion 3-48
surface separation facilities
how modeled 4-95
swelling test 3-54 W
water
T how properties specified 3-66
water properties
ternary diagrams warning 3-67
how constructed 3-59 water viscosity 2-20
thermal option 2-26 water-in-oil option
Twu viscosity correlation 8-131 selection of 2-25
Whitsons method 7-117
U
Z
units
default 3-33 z-factor
specifying for pressure and temp 3-33 of gas 3-33
Zudkevitch-Joffe-Redlich-Kwong equation of
state 2-5, 2-6
V
vapor pressure
of a pure component 3-38
vapor viscosity
how to specify 3-42
vaporization
multiple contact 3-59
vaporization test
multiple contact steam 3-86
variable boundaries
how established B-149
VIP-COMP
using DESKTOP-PVT data in 1-1
Subject-276 Landmark - R2003.4

PVT Keyword

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Part No. 159678 R2003.4

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About This Manual

R2003.4 - Landmark iii

2.15 Thermal Option (THERMAL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-26

5.2 EOS Property Adjustment (REGRESS) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-105

About This Manual

Simulating Laboratory Measurement.

Simulating Multistage Separators.

Automatic Parameter Adjustment.

Heavy Fraction Characterization.

R2003.4 - Landmark vii

DESKTOP-PVT Users Manual. Characterizing equations of state for

viii Landmark - R2003.4

DESKTOP-PVT is used to simulate the behavior of fluid mixtures when

The program can be used in a purely predictive mode to generate PVT

To aid in development of a fluid model that matches experimental data, a

1.1 Overview of the Data

4. Automatic parameter adjustment

6. Heavy fraction characterization

R2003.4 - Landmark 1-1

1.2 Free Field Input

1-2 Landmark - R2003.4

1.3 FORTRAN File Assignments

Figure 1-1: DESKTOP-PVT I/O Structure

R2003.4 - Landmark 1-3

1-4 Landmark - R2003.4

In order to completely define fluid properties it is necessary only to define

Heavy fractions are normally grouped together over a reasonably wide

The properties of a large number of components have been internally

R2003.4 - Landmark 2-5

2.2 Equation of State (EOS)

To specify the Peng-Robinson equation-of-state, the following data card is

NOTE: 1. The original Peng-Robinson equation of state uses the same

2-6 Landmark - R2003.4

if VSHFT is also included on the PROPERTIES card.

R2003.4 - Landmark 2-7

2.3 Component Names (Components)

cmpn Component name. An alphameric label contain-

Define the components in a fluid system that contains carbon dioxide,

In both components definitions, all components except C7+ will have

2-8 Landmark - R2003.4

2.4 Component Characteristics (PROPERTIES)

Default properties for internally defined components are given in Table 2-

For non-internally defined components, a minimum of molecular weight

All properties for internally-defined components and all except molecular

cmpi mwi tci pci zci wi o

F, C, K, R Alpha label indicating that the units of all temperature

F Degrees Fahrenheit, F. This is the

R2003.4 - Landmark 2-9

PSIA Psia. This the default.

cmpi Component name for component i. Must be identical

mwi The molecular weight of component i.

si Dimensionless volume shift parameter. (This property

nbpi Normal boiling point temperature for component i.

grvli Specific gravity of component i at temperature trefi

2-10 Landmark - R2003.4

trefi Reference temperature for component i specific grav-

d, e Parameters d and e for computing volume shift

where M is the molecular weight of a component.

The default value for d is 1.74 and is 0.133 for e.

NOTE: l. If either of the temperature or pressure unit flags is specified,