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Buffers
A. Solutions that resist changes in pH when an Acid or Base is added to them
B. Consist of a weak acid and its conjugate base in aqueous solution
1. When an acid is added, it is neutralized by the conjugate base
2. When a base is added, it is neutralized by the conjugate acid
C. Making A Buffer at a Certain pH
1. Choose an acid/base conjugate pair with an acid pKa that us +1/-1 unit
away from the desired pH
2. Add the acid and base at a proper ration to satisfy the Henderson-
Hasselbalch Equation
3. Buffers Work Best When the [A-]/[HA] Ratio is Between 10/1 and 1/10
VIII. Thermochemistry
A. Energy has the capacity to do work
1. Thermal Energy Associated With Temperature
2. Kinetic Energy Due to Motion
3. Potential Energy Due to Position or Composition
4. Chemical Energy Associated with Positions of Electrons
B. The System
1. The material or process within which we are studying energy changes
C. The Surroundings
1. Everything else with which the system can change energy
D. Energy Exchange
1. Energy is exchanged between the system and surroundings through heat
and work.
E. Standard Conditions
1. Usually 25C
2. Exactly 1 atm
3. Substance in solution with 1M concentration
F. Standard Enthalpy Change (H)
1. The Enthalpy change when all reactants and product are in their standard
states
G. Standard Enthalpy of Formation (Hf)
1. The enthalpy changes for the reaction that forms 1 mole of a pure
compound from its elements
2. The elements must be in their standard states
3. The Hf for a pure element in its standard state = 0 kJ/mol