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Abstract
Environmentally friendly, gas turbine driven co-generation plants can be located close to energy con-
sumption sites, which can produce their own fuel such as waste process gas or biomass derived fuels. Since
gas turbines are available in a large power range, they are well suited for this application. Current gas
turbine systems that are capable of burning such fuels are normally developed for a single specic fuel (such
as natural gas or domestic fuel oil) and use conventional diusion ame technology with relatively high
levels of NOx and partially unburned species emissions. Recently, great progress has been made in the clean
combustion of natural gas and other fossil fuels through the use of dry low emission technologies based on
lean premixed combustion, particularly with respect of NOx emissions. The objective of the AFTUR
project is to extend this capability to a wider range of potentially commercial fuel types, including those of
lower caloric value produced by gasication of biomass (LHV < 25% natural gas in line with the European
Union targets) and hydrogen enriched fuels. The paper reports preliminary progress in the selection and
characterisation of potential, liquid and gas, alternative fuels for industrial gas turbines. The combustion
and emission characteristics of the selected fuels will be assessed, in the later phases of the project, both in
laboratory and industrial combustion chambers.
European Communities, 2004. Published by Elsevier Ltd. All rights reserved.
Keywords: Gas turbines; Alternative fuels; Biofuels; Hydrogenated fuels; DLE technologies
*
Corresponding author. Fax: +33-238-25-78-75.
E-mail address: gokalp@cnrs-orleans.fr (I. G
okalp).
1359-4311/$ - see front matter European Communities, 2004. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2003.10.035
1656 I. Gokalp, E. Lebas / Applied Thermal Engineering 24 (2004) 16551663
Nomenclature
1. Introduction
Table 1
Partners of the AFTUR project
Partner no. Organisation name Short name Country code
1 CNRS-LCSR CNRS.LCSR FR
2 Turbomeca sa Turbomeca.de FR
3 Nuovo Pignone S.p.A. NP IT
4 Alstom Power UK ABAL UK
5 INSA de Rouen INSARO.Coria FR
6 Universite de Rouen Urouen.Coria FR
7 CNRS-Coria CNRS.Coria FR
8 Institut Francais du Petrole IFP.PE FR
9 QINETIQ Limited QINETIQ.CAT.FST UK
10 AEA Technology Engineering Software Ltd AEA.CFX UK
11 Consorzio Perlarea di Ricera Scientica e AREA.CAR.PS IT
Technologica di Trieste
12 Instituto di Ricerche Sulla CombustioneCNR CNR.IRC IT
13 TPS Termiska Processer AB TPS SW
14 Agricultural University of Athens AUATH.NRMAE GR
15 University Twente THT.TE NL
16 Instituto Superior Tecnico IST.DEM PT
17 Universita Degli Studi Roma Tre UROM3.DIMI IT
18 Universad de Zaragoza UZAZ.SII.AMF ES
19 Lunds Universitet ULUND.LIT.DP.DCP SW
20 Craneld University CIT.SE UK
21 University of Manchester Institute of Science UUMIST.DME UK
and Technology
22 Universidade da Beira Interior UBEI.AST.AS PT
23 Auxitrol sa AUXI.RD FR
As already introduced, the scientic and technical objective of the AFTUR project is to extend
the gas turbine sphere of application to a wider range of potentially commercial fuel types,
including biofuels and waste process gases. These fuels have typically low to medium caloric
values and a wide range of other properties. The AFTUR project aims to establish the appro-
priate selection procedure of the liquid and gaseous fuels with the development of a Multicriteria
Decision Support System, the atomisation and spray characteristics of liquid fuels, the combus-
tion and emission characteristics of the selected alternative fuel ames, the sooting tendency and
NOx emission properties of the fuels under various operation conditions, and the adaptability of
existing conventionally fuelled combustors for use with the selected alternative fuels.
The rst objective of the AFTUR project is to select a spectrum of alternative fuels for
industrial gas turbines. The selection will be done according to availability, composition, physical
properties, and costs of the fuel. As a rst step to this aim, a list of potential alternative gaseous
and liquid fuels for gas turbines is established:
vegetable oils
esters
1658 I. Gokalp, E. Lebas / Applied Thermal Engineering 24 (2004) 16551663
For each fuel, a detailed and representative manufacturing process is explained with the mass
balances, the energy requirements, and the capital and eventually the operational expenditures.
The present and future production capacities as well as the thermodynamic, physical and chemical
characteristics of the fuel are presented to complete the study. Some of this information is
summarized below.
Fatty acid methyl esters (FAME) are made from renewable resources such as plant oils and
animal fats. In the European Union, FAMEs are mostly vegetable oil methyl esters from rapeseed
and sunower oils. Because they have similar properties to Diesel fuel, FAMEs are alternative
fuels capable of being directly used in a turbine and can be blended in various proportions with
Diesel fuel (generally 5% or 30% FAME in Diesel fuel). Properties of FAME may dier slightly
from Diesel fuel in terms of energy content or physical properties. Two types of processes exist to
produce methylester-biodiesel: the homogeneous catalysis process and the heterogeneous catalysis
process.
Pyrolysis consists in heating solid biomass (generally waste or wood) in the absence of air to
produce solid, liquid or gaseous fuels. Depending on the conditions, the solid, liquid or gaseous
products are maximised (slow pyrolysis produces a high yield of gas and solids). For our study,
biomass used in the slow pyrolysis unit is wood and the reactor is a rotary kiln with indirect
heating.
Anaerobic digestion occurs naturally when high concentrations of wet organic matter accu-
mulate in the absence of dissolved oxygen. Anaerobic micro-organisms digest the organic material
producing carbon dioxide and methane that can be collected and used as fuel (biogas). The
stabilised solid residue, which averages 4060% by weight of the feedstock, can be used as soil
conditioner material (compost). Anaerobic digester systems, also called fermentation or meth-
anisation, use closed reactors to control the anaerobic process and to collect all of the biogas fuel
produced. The yield of biogas depends on the composition of the waste feedstock and the con-
I. Gokalp, E. Lebas / Applied Thermal Engineering 24 (2004) 16551663 1659
ditions within the reactor. For example, the rate of anaerobic digestion can be increased by
operating in certain temperature ranges. The modern anaerobic digestion treatment processes are
engineered to control the reaction conditions to optimise digestion rate and fuel production.
The industrial gases are rejections from reneries or chemical industries. Instead of burning o
these gases in are stacks or in steam boilers, those gases rich in hydrogen could be used as fuels in
industrial gas turbines. Examples of such gases are: renery are gases, steam reforming fuel gas,
FisherTropsh fuel gas.
The following gures present some physico-chemical characteristics of liquid and gas fuels
envisaged as alternative fuels for gas turbines. They are taken from the literature [114] listed in
the References section.
50000
45000
40000
LHV (kJ/kg)
35000
30000
25000
20000
15000
10000
5000
0
D
ER
S
l
l
el
0R
l
E
R
ES
oi
oi
0S
no
no
FO
E5
M
fu
E5
s
E3
d
M
ha
ha
E3
si
M
ee
FT
Et
ly
M
et
M
es
ro
M
ap
py
R
h
as
Fl
Liquid fuels
Viscosity at 20 C (mPa.s)
120
100
80
60
40
20
0
l
D
R
ES
l
ER
oi
S
l
l
no
oi
no
oi
FO
E5
E5
er
M
ha
s
M
ha
d
M
si
M
ee
Et
et
ly
lo
es
ro
M
nf
py
ap
Su
ash
Fl
Liquid fuels
problem to spray the oils in the combustion chamber of gas turbines; however, these fuels may be
heated up to decrease their viscosity, as was shown for rapeseed pure oil in the ACREVO project
of the FAIR program (FAIR-CT-95-0627).
1400
Density at 20 C (kg/m3)
1200
1000
800
600
400
200
0
l
l
l
0S
oi
no
oi
E
S
el
ER
ES
0R
R
l
no
oi
M
E5
fu
E5
s
D
d
ha
E3
si
ha
E3
M
D
er
ee
FO
M
FT
ly
Et
w
et
es
ro
lo
M
py
ap
nf
Su
R
h
as
Fl
Liquid fuels
1000
900
800
MW (g/mol)
700
600
500
400
300
200
100
0
l
ES
ER
l
l
D
l
oi
E
no
oi
no
oi
FO
s
M
er
ha
M
ha
d
D
si
ee
w
ly
Et
et
lo
es
ro
M
nf
py
ap
Su
R
h
as
Fl
Liquid fuels
8.0
7.0
C/H (% w. / % w.)
6.0
5.0
4.0
3.0
2.0
1.0
0.0
D
l
l
l
l
ER
l
no
no
oi
oi
oi
FO
ha
ha
d
s
er
M
D
ee
si
w
Et
et
ly
es
lo
M
ro
nf
ap
py
Su
R
h
as
Fl
Liquid fuels
Fig. 6 shows that the LHVs of industrial gases (steam reforming gas, renery gas and FT-
process o-gas, of O2 -blown gasication, and of wood slow pyrolysis gas) are higher than the
LHV of natural gas. The reason for this is the high hydrogen content of these fuels (between 19
and 45% vol.). On the contrary, the LHVs of waste methanisation gas and especially of air-blown
gasication gas are very low; also they are both generated at atmospheric pressure and need to be
compressed before their use in gas turbines.
1662 I. Gokalp, E. Lebas / Applied Thermal Engineering 24 (2004) 16551663
60000
50000
LHV (kJ/m3)
40000
30000
20000
10000
as
as
s
s
as
as
as
ga
ga
ga
f-g
og
og
og
og
g
al
of
y
bi
bi
bi
in
er
bi
ur
ss
n
rm
n
in
s
n
at
tio
tio
si
ce
tio
ef
fo
N
ly
ca
R
ro
ca
re
is
ro
ifi
-p
n
ifi
py
m
ha
as
FT
as
ea
ow
et
rg
2 g
St
m
Sl
ai
O
te
d
d
as
oo
oo
W
W
Gaseous fuels
12.0
C/H (% w. / % w.)
10.0
8.0
6.0
4.0
2.0
0.0
as
...
...
...
s
s
s
as
ga
ga
ga
bi
bi
og
bi
f-g
n
n
bi
n
al
y
g
tio
tio
of
tio
er
in
ur
s
rm
sa
ca
in
si
ss
ca
at
ly
ef
ni
ifi
N
ce
fo
ifi
ro
R
as
ha
as
re
ro
py
rg
et
2 g
-p
m
ow
m
FT
ea
ai
O
te
Sl
d
St
d
oo
as
oo
W
W
Gaseous fuels
Fig. 7 shows that, except the steam reforming gas, all the gaseous fuels have a higher C/H ratio
than the natural gas.
This paper briey presented the global objectives of the AFTUR project on the identication,
selection and characterisation of various alternative fuels for industrial gas turbines. Liquid and
gaseous alternative fuels have been identied and they are partly characterized by using existing
data on their physico-chemical properties.
In the next phase of the project, the atomisation, combustion and emission properties of these
fuels will be characterized under laboratory ame conditions by using advanced laser diagnostics
and computational techniques.
I. Gokalp, E. Lebas / Applied Thermal Engineering 24 (2004) 16551663 1663
Acknowledgements
The nancial support of the European Commission to the AFTUR project through the con-
tract ENK5-CT-2002-00662 is greatly acknowledged. The authors also thank Dr. Petros Pilavachi
for his ecient support and scientic monitoring of the AFTUR project.
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