Section A

Bahagian A

[60 marks]
[60 markah]

Answer all questions in this section.

Jawab semua soalan dalam bahagian ini.

1 The freezing point of acetamide was determined by using the cooling method. The graph of
. temperature against time was plotted as shown in Diagram B.
Takat beku asetamida ditentukan dengan kaedah penyejukan. Graf suhu lawan masa diplot seperti
pada Rajah B.

Diagram A/Rajah A

(a i. From the graph, state the freezing point of the acetamide.

) Daripada graf, nyatakan takat beku asetamida.

____________________________________________________________________________
______
[1 mark/1 markah]
ii What is the physical state of the acetamide at the section of the curve from :
. Apakah sifat fizikal asetamida pada lengkung graf diantara :
R to S :
R ke S : _________________________________________________________________________
T to U :
T ke U : _________________________________________________________________________
[2 marks/2 markah]
(b It was observed from the graph that there was no change in temperature from S to T. Explain the
) observation.
Diperhatikan dari graf didapati tidak ada perubahan suhu dari S ke T. Terangkan pemerhatian.

______________________________________________________________________________
 _______

______________________________________________________________________________
_______
[2 marks/2 markah]
(c What is the physical state of the acetamide at P?
) Apakah sifat fizikal asetamida?

______________________________________________________________________________
_______

______________________________________________________________________________
_______
[1 mark/1 markah]
(d
)

Diagram B/Rajah B

Diagram B shows the changes of state of matter.

Rajah B menunjukkan perubahan fizikal bagi jirim.
i. Name the following changes of state:
Namakan perubahan fizikal yang berikut :

X : ______________________________________Y : _____________________________________
[2 marks/2 markah]
ii State the heat change for the process in (b) (i):
. Nyatakan perubahan haba bagi proses yang berlaku di (b) (i):

X : ______________________________________Y : _____________________________________
[2 marks/2 markah]

2 Diagram below shows the position of some elements in the Periodic Table of Element.
. Rajah di bawah menunjukkan kedudukan beberapa unsur dalam Jadual Berkala Unsur.

Diagram/Rajah
(a) Write the letter of the alphabet that represent
Nyatakan huruf yang mewakili
(i) an alkali metal,
satu logam alkali,

___________________________________________________________________________
_______
[1 mark/markah]
(ii) an inert gas,
satu gas nadir,

___________________________________________________________________________
_______
[1 mark/markah]
(iii the elements in the halogen group.
) unsur-unsur dalam kumpulan halogen.

___________________________________________________________________________
_______
[1 mark/markah]
(b)(i) Name the elements that have bleaching ability.
Nyatakan unsur-unsur yang mempunyai kebolehan meluntur.

___________________________________________________________________________
_______
[1 mark/markah]
(ii) Arrange them according to bleaching power in ascending order.
Susunkan kuasa kelunturan mereka secara menaik.

___________________________________________________________________________
_______
[1 mark/markah]
(iii Why is L not used as a bleach for clothes?
) Mengapakah L tidak digunakan untuk meluntur pakaian?

___________________________________________________________________________
_______
[1 mark/markah]
(c) Consider element O.
Pertimbangkan unsur O.
(i) Write the electronic configuration of atom O.
 Tuliskan konfigurasi elektron bagi atom O.

___________________________________________________________________________
_______
[1 mark/markah]
(ii Explain why atom O is stable.
) Terangkan mengapa atom O adalah stabil.

___________________________________________________________________________
_______
[1 mark/markah]
(d)Write a possible formula for the compound formed between
Tuliskan formula yang mungkin bagi sebatian yang dibentuk antara unsur...
(i) G and L,
G dan L,
___________________________________________________________________________
_______
[1 mark/markah]
(ii) J and M,
J dan M,

___________________________________________________________________________
_______
[1 mark/markah]
(iii F and M,
) F dan M,

___________________________________________________________________________
_______
[1 mark/markah]
(e) Draw a diagram to show the electronic structure of the compound formed between I and oxygen.
Lukiskan rajah untuk menunjukkan struktur elektron bagi sebatian antara I dan oksigen.

[1 mark/markah]

3. Diagram below shows the set-up of an electrolytic cell. Beaker I contains a components of a simple
. chemical cell whereas electrolysis takes place in Beaker II.
Rajah di bawah menunjukkan susunan radas bagi satu sel elektrokimia. Bikar I mengandungi
komponen sel kimia ringkas sementara proses elektrolisis berlaku di dalam Bikar II.
 DIAGRAM/RAJAH

(a State the changes in energy in Beaker I and Beaker II.

) Nyatakan perubahan tenaga di dalam Bikar I dan Bikar II.
Beaker I /Bikar I
______________________________________________________________________________
__________

Beaker II/Bikar II
_____________________________________________________________________________
___________
[2 marks/2 markah]

(b Which metal is the negative terminal in Beaker I?

) Logam yang manakah ialah terminal negatif di dalam Bikar I?
_____________________________________________________________________________
___________
[1 mark/1 markah]

(c (i) State the process occurred in the copper electrode in Beaker I.

) Nyatakan proses yang berlaku di dalam elektrod kuprum di dalam Bikar I.
___________________________________________________________________________
__________
[1 mark/1 markah]

(ii What would you observe at the silver electrode in Beaker I?

) Apakah yang kamu dapat perhatikan pada elektrod argentum di dalam bikar I?
___________________________________________________________________________
__________
[1 mark/1 markah]

(d Write equations for reactions which occurred at anode and cathode in Beaker II.
) Tuliskan persamaan bagi tindak balas yang berlaku di anod dan katod di dalam Bikar II.
Anode/Anod:
_____________________________________________________________________________
___________
 [1 mark/1 markah]
Cathode/Katod:
_____________________________________________________________________________
___________
[1 mark/1 markah]

(e (i)What happens to the voltmeter reading when the magnesium electrode in Beaker I is replace
) with zinc electrode?
Apakah yang berlaku pada bacaan voltmeter apabila elektrod magnesium di dalam bikar I
digantikan dengan elektrod zink?
___________________________________________________________________________
__________
[1 mark/1 markah]

(ii Explain your reasons in (e) (i).

) Terangkan alasan kamu di (e) (i).
___________________________________________________________________________
__________
[2 marks/2 markah]

4. An experiment is carried out to investigate the rate of reaction of zinc with hydrochloric acid.
Excess zinc powder is added to 20 cm3 of 0.2 mol dm-3 hydrochloric acid. The volume of gas
collected at regular intervals is shown in Diagram below.
Satu eksperimen dijalankan untuk mengkaji kadar tindak balas antara zink dengan asid hidroklorik.
Serbuk zink berlebihan ditambah kepada 20 cm3 asid hidroklorik 0.2 mol dm-3. Isi padu gas yang
terkumpul pada sela masa yang sama ditunjukkan dalam di bawah.
 Diagram
Rajah

(a State the meaning of the rate of reaction.

) Nyatakan maksud kadar tindak balas.

________________________________________________________________________________
_____
[1 mark]
[1 markah]
( From the graph in Diagram above, determine:
b Daripada graf dalam Rajah di atas, tentukan:
)
(i) The rate of reaction at 120 s.
Kadar tindak balas pada 120 s.

_____________________________________________________________________________
_____
[2 marks]
[2 markah]
(ii The average rate of reaction between 60 s and 120 s.
) Kadar tindak balas purata antara 60 s dan 120 s.

_____________________________________________________________________________
_____
 [1 mark]
[1 markah]

(c Explain why the rate of reaction decreases with time.

) Terangkan mengapa kadar tindak balas berkurangan dengan masa.

________________________________________________________________________________
_____
[1 mark]
[1 markah]
( Another experiment is carried out to study the factors that affect the rate of this reaction. The result
d of this experiment is shown in Diagram below. Curve I represents the result of this experiment
) using excess zinc powder and 50 cm3 of 1.0 mol dm-3 dilute hydrochloric acid.
Satu eksperimen lain dijalankan untuk mengkaji faktor-faktor yang mempengaruhi kadar tindak
balas ini. Keputusan eksperimen ini ditunjukkan dalam Rajah di
bawah. Lengkung I mewakili keputusan eksperimen yang menggunakan serbuk zink berlebihan
dan 50 cm3asid hidroklorik cair 1.0 mol dm-3.

Diagram
Rajah

(i) Suggest the factors that influence the rate of reaction to obtain the curves labelled II and III.
Cadangkan faktor yang mempengaruhi kadar tindak balas untuk mendapatkan
lengkunglengkung berlabel II dan III.

Curve II/LengkungII : _______________________________________________________________________

Curve
_______________________________________________________________________
III/LengkungIII:
[2 marks]
[2 markah]
(ii Describe briefly how to carry out the experiment to obtain the curve labelled III.
) Huraikan dengan ringkas bagaimana eksperimen itu dijalankan untuk mendapatkan lengkung
berlabel III.

______________________________________________________________________________
 ____

______________________________________________________________________________
____

______________________________________________________________________________
____
[3 marks]
[3 markah]
(ii Give one reason why the final volume of gas obtained in curve III is half the final volume of gas
i) in curve I.
Beri satu sebab mengapa isi padu akhir gas yang terhasil dalam lengkung III adalah separuh
daripada isi padu akhir gas dalam lengkung I.

______________________________________________________________________________
____

______________________________________________________________________________
____
[1 mark]
[1 markah]

5. Diagram below shows the structural formulae of compound M and compound N.

Both compound M and compound N are isomers of a carbon compound.
Rajah di bawah menunjukkan formula struktur bagi sebatian M dan sebatian N.
Kedua-dua sebatian M dan sebatian N adalah isomer satu sebatian karbon.

Diagram
 Rajah

(a) (i) State the meaning of isomer.

Nyatakan maksud isomer.

___________________________________________________________________________
[1 marks]
[1 markah]
(ii) Write the molecular formula for the carbon compound in diagram above.
Tulis formula molekul bagi sebatian karbon dalam rajah di atas.

___________________________________________________________________________
[1 mark]
[1 markah]
(iii State the names of compound M and compound N using IUPAC nomenclature.
) Nyatakan nama sebatian M dan sebatian N dengan menggunakan penamaan IUPAC.

Compound
M: ________________________________________________________________
Sebatian M:

Compound
N: ________________________________________________________________
Sebatian N:
[2 marks]
[2 markah]
(iv)Draw the structural formula for another isomer of the carbon compound.
Lukis formula struktur untuk satu lagi isomer bagi sebatian karbon itu.

[1 mark]
[1 markah]
(b) An alcohol can be prepared from compound M.
Satu alkohol boleh disediakan daripada sebatian M.
(i) What is the general formula of alcohols?
Apakah formula am bagi alkohol?

___________________________________________________________________________
[1 mark]
[1 markah]
(ii) State the name of the process for the conversion of compound M to the alcohol.
Nyatakan nama proses penukaran bagi sebatian M kepada alkohol itu.
 ___________________________________________________________________________
[1 mark]
[1 markah]
(iii State two of the conditions used in the conversion.
) Nyatakan dua keadaan yang digunakan dalam penukaran itu.

1. _______________________________________________________________________

2. _______________________________________________________________________
[2 marks]
[2 markah]

6. Diagram shows the apparatus set-up for an experiment to investigate electron transfer at a distance
in redox reactions.
Rajah menunjukkan susunan radas bagi satu eksperimen untuk mengkaji pemindahan elektron pada
suatu jarak dalam tindak balas redoks.

Diagram
Rajah

(a State the colour of iron(Il) sulphate solution.

) Nyatakan warna larutan ferum(II) sulfat.

_______________________________________________________________________________
_________
[1 mark]
[1 markah]
(b When the circuit is completed, the galvanometer shows a deflection.
) Apabila litar dilengkapkan, galvanometer menunjukkan satu pesongan.
(i) Write the half-equation for the reaction at X.
Tulis setengah persamaan bagi tindak balas di X.

____________________________________________________________________________
_________
[1 mark]
 [1 markah]
(ii) State the type of reaction in (b)(i)/Nyatakan jenis tindak balas di (b)(i).

____________________________________________________________________________
_________
[1 mark]
[1 markah]
(iii Describe briefly a chemical test to identify the cation formed in (b)(i).
) Huraikan secara ringkas ujian kimia untuk mengenal pasti kation yang terbentuk di (b)(i).

____________________________________________________________________________
_________
[2 marks]
[2 markah]
(c (i) The half-equation below shows the reaction that occurs in acidified potassium dichromate(VI)
) solution.
Complete the half-equation.
Setengah persamaan di bawah menunjukkan tindak balas yang berlaku dalam larutan kalium
dikromat(VI) berasid.
Lengkapkan setengah persamaan itu.
Cr2O72 + ___H+ + ___e ___Cr3+ + ___H2O
[2 marks]
[2 markah]
(ii) Based on the answers in (b)(i) and (c)(i), on Diagram, draw the arrows to show the direction of
electron flow.
Berdasarkan jawapan di (b)(i) dan (c)(i), pada Rajah, lukiskan anak panah untuk menunjukkan
arah aliran elektron.
[1 mark]
[1 markah]
(d Table shows a list of apparatus and materials.
) Jadual menunjukkan senarai radas dan bahan.

Table
Jadual

Draw one labelled diagram to show the apparatus set-up to investigate electron transfer at a
distance. The diagram must include the apparatus and materials given in Table.
Mark in the diagram the positive and negative terminals of the cell.
Lukis satu rajah berlabel untuk menunjukkan susunan radas bagi mengkaji pemindahan eIektron
pada suatu jarak. Rajah itu hendaklah menggunakan radas dan bahan yang diberi dalam Jadual.
 Tandakan terminal positif dan negatif bagi sel pada rajah itu.
[3 marks]
[3 markah]

Section B
Bahagian B

[20 marks]
[20 markah]

Answer any one questions from this section.

Jawab mana-mana satu soalan daripada bahagian ini.

7. Food stored in a refigerator lasts longer than food stored in a kitchen cabinet.
(a) Explain why. [4 marks]
Makanan yang disimpan dalam peti sejuk tahan lebih lama daripada makanan yang disimpan
dalam almari dapur.
Terangkan mengapa. [4 markah]

(b) A group of pupils carried out three experiments to investigate the factors affecting the rate of a
reaction. Table below shows information about the reactants and the temperature used in each
experiment.
Sekumpulan murid telah menjalankan tiga eksperimen untuk mengkaji kesan faktor-faktor yang
mempengaruhi kadar tindak balas.
Jadual di bawah menunjukkan maklumat tentang bahan tindak balas dan suhu yang digunakan
dalam setiap eksperimen.

Temperature/
Experiment Reactants
C
Eksperimen Bahan tindak balas
Suhu/ C
I Excess calcium carbonate chips and 30 cm3 of 0.5 30
mol dm-3 hydrochloric acid
Ketelan kalsium karbonat berlebihan dan 30 cm3
hidroklorik 0.5 mol dm-3
II Excess calcium carbonate chips and 30 cm3 of 0.5 40
mol dm-3 hydrochloric acid
Ketelan kalsium karbonat berlebihan dan 30 cm3
hidroklorik 0.5 mol dm-3
III Excess calcium carbonate powder and 30 cm3 of 40
0.5 mol dm-3 hydrochloric acid
Ketelan kalsium karbonat berlebihan dan 30 cm3
asid sulfurik 0.5 mol dm-3
 Table
Jadual

Graph below shows the results of these experiments.

Graf di bawah menunjukkan keputusan eksperimen-eksperimen ini.

Gra
ph
Graf

(i) Calculate the average rate of reaction for Experiment I. [2 marks]

Hitungkan kadar tindak balas purata bagi Eksperimen I. [2 markah]

(ii) Based on Table and Graph above, compare the rate of reaction between:
Berdasarkan Jadual dan Graf di atas, bandingkan kadar tindak balas antara:

Experiment I and Experiment II

Eksperimen I dengan Eksperimen II

Experiment II and Experiment III

Eksperimen II dengan Eksperimen III

 In each case explain the different in rate of reaction with reference to the collision theory.

[10 marks]

Bagi setiap kes terangkan perbezaan dalam kadar tindak balas dengan merujuk kepada teori
perlanggaran.

[10 markah]

(iii The chemical equation below shows the reaction between calcium carbonate and hydrochloric
) acid.
Persamaan kimia di bawah menunjukkan tindak balas antara kalsium karbonat dengan asid
hidroklorik.

Given that the relative atomic mass of C = 12, O = 16, Ca = 40 and the molar volume of any
gas is 24 dm3 mol-1 at room temperature and pressure.
Diberi, jisim atom relatif bagi C = 12, O = 16, Ca = 40 dan isi padu molar sebarang gas
adalah 24 dm3 mol-1pada suhu dan tekanan bilik.

Calculate the maximum volume of carbon dioxide gas produced in Experiment II.
[4 marks]
Hitungkan isi padu maksimum gas karbon dioksida yang terhasil dalam Eksperimen II.
[4 markah]

8.
(a Diagram below shows the apparatus and observations for a redox reaction between iron(III)
) chloride solution and a metal.
Rajah di bawah menunjukkan radas dan pemerhatian bagi satu tindak balas redoks antara larutan
ferum(III)klorida dan sekeping logam.
 Diagram
Rajah

Based on the observation shown in Diagram above, suggest a suitable metal to be used in this
experiment.
Predict the ion present in the green solution and explain the answer based on the following aspects:
Berdasarkan pemerhatian yang ditunjukkan dalam Rajah di atas, cadangkan logam yang sesuai
untuk digunakan dalam eksperimen ini.
Ramalkan ion yang hadir dalam larutan hijau itu dan jelaskan jawapan berdasarkan aspek-aspek
berikut:
The change in oxidation number for both the reactants

Perubahan dalam nombor pengoksidaan bagi kedua-dua bahan tindak balas

The type of reaction that has occurred to each reactant

Jenis tindak balas yang berlaku pada setiap bahan tindak balas

The role of each reactant in the redox reaction

Peranan setiap bahan tindak balas dalam tindak balas redoks tersebut

The half-equations involved in the redox reaction

Setengah persamaan yang terlibat dalam tindak balas redoks tersebut
[10 marks]
[10 markah]
(b
)

You are given the following apparatus:

U-tube, galvanometer, connecting wires, stopper, dropper, carbon electrodes and retort stand with
clamps. Suggest a suitable chemical and describe an experiment to verify the above statement
using the given apparatus.
Anda diberi radas berikut:
Tiub-U, galvanometer, wayar penyambung, penutup,penitis, elektrod karbon dan kaki retort
dengan penyepit. Cadangkan bahan kimia yang sesuai dan huraikan satu eksperimen untuk
mengesahkan pernyataan di atas dengan menggunakan radas yang diberi.
 [10 marks]
[10 markah]

Section C
Bahagian C

[20 marks]
[20 markah]

Answer any one questions from this section.

Jawab mana-mana satu soalan daripada bahagian ini.

(a) Diagram below shows a beaker of latex, natural rubber. It is a natural polymer.
Rajah di bawah menunjukkan satu bikar mengandungi lateks, susu getah asli. Ia merupakan
polimer semula jadi.

Diagram/Rajah

(i) Name and draw the structural formula for its monomer.
Namakan dan lukiskan formula struktur bagi monomernya.
[2 marks/2 markah]
(ii) By naming a suitable substance, explain how it can be used to coagulate the latex.
Dengan menamakan bahan yang sesuai, terangkan bagaimana ia boleh digunakan untuk
membekukan lateks.
[7 marks/7 markah]
(b) The following shows natural rubber can be changed to vulcanised rubber.
Berikut menunjukkan getah asli boleh ditukarkan kepada getah tervulkan.
(i) Describe by using an experiment in laboratory to show the vulcanisation of natural rubber.
Huraikan dengan menggunakan eksperimen, untuk menunjukkan pemvulkanan getah asli.
(ii) State four advantages of vulcanised rubber over natural rubber.
Nyatakan empat kelebihan getah tervulkan berbanding getah asli.
[8 marks/8 markah]

10.
a) The following are the formulae of two compounds.
 Berikut adalah formula bagi dua sebatian.

A12 O3 Cu2 O

(i) Based on the two formulae, state the oxidation number for aluminium and copper.
Berdasarkan dua formula itu, nyatakan nombor pengoksidaan bagi aluminium dan kuprum.
[2 marks]
[2 markah]

(ii) Name both the compounds based on the IUPAC nomenclature system.
[2 marks]
Namakan kedua-dua sebatian itu mengikut sistem tatanama IUPAC.
[2 markah]
(iii Explain the difference between the names of the two compounds based on the IUPAC
) nomenclature system.
Jelaskan perbezaan antara nama kedua-dua sebatian itu mengikut sistem tatanama IUPAC.
[2 marks]
[2 markah]
(b) Diagram below shows the set up of the apparatus of an experiment to investigate electron transfer
through a solution.
Rajah di bawah menunjukkan susunan radas bagi satu eksperimen untuk mengkaji pemindahan
elektron melalui satu larutan.

Diagram
Rajah

(i) Name the oxidation agent in the experiment.

[1 mark]
Namakan agen pengoksidaan dalam eksperimen itu.
[1 markah]
(ii) Write the half equations for the reactions that occur at the negative and positive terminals.
Tulis setengah persamaan bagi tindak balas yang berlaku di terminal negatif dan terminal
positif.
[5 marks]
[5 markah]
(iii Based on your answer in (b)(ii), describe the oxidation and reduction processes in terms of the
) electron transfer that occurs at the negative and positive terminals.
Berdasarkan jawapan anda di (b)(ii), huraikan proses pengoksidaan dan penurunan dari segi
pemindahan elektron yang berlaku di terminal negatif dan terminal positif.
State also the changes that can be observed after 10 minutes.
Nyatakan juga perubahan yang dapat diperhatikan selepas 10 minit.
[8 marks]
[8 markah]