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Choose the appropriate answer for each from the given options:
( )+ ( ) ( ) = 393.5
( )+ ( ) ( ) = 395.4
Use the examples of the given atoms to explain the following rules of electronic configurations:
* N (z=7) for rule of maximum multiplicity * K (z=19) for (n+l) rule
14. Differentiate between the following:
* Orbit and Orbital * Continuous and Line Spectra
15. Lassaigne test shows that a compound contains Nitrogen. Complete combustion of 5.0 grams of that
compound yielded 14.375 grams of NO2 and 5.625 grams of H2O. Using this information, find the empirical
formula of the compound.
16. Explain the following terms using the example of ion:
* Coordinate covalent bond * sp3 hybridization
17. Give reasons for the following:
* Ionization Potential of Nitrogen is greater than Oxygen.
* P and Cl atoms form PCl5 but P and I atoms form PI3.
* Mercury forms convex meniscus while water forms concave meniscus.
* CO2 molecule is non-polar while CO bond is polar.
* Electronegativity of elements decreases from left to right along a period.
18. Kc for the following reaction is 4. Calculate the equilibrium concentration of CH 3 COOC 2 H 5 when
1.66moles of CH 3 COOH and 2.17 moles of C 2 H 5 OH are allowed to come to equilibrium:
+ +
19. What is chemical equilibrium? Illustrate it with the help of graph. What is the effect of increase in
temperature on a chemical equilibrium?
20. For the redox cell ( ) (1 ) 2 ( ) ( ):
* Write the half cell equations
* Suggest the sign of the reduction potential of ( )
* identify the reaction at cathode.
21. Balance any one of the equations by ion-electron method:
* + + + (basic medium)
* + + (acidic medium)
22. Determine the order of the following reaction using the initial rate data:
A B2
AB2
Experiment [A] [B] ( )
1. 0.1 M 0.1 M 2 x 10-4
2. 0.2 M 0.1 M 4 x 10-4
3. 0.1 M 0.2 M 8 x 10-4
23. The mass of a substance is 20.0865 gram and its volume is 8.9 cm3.Find its density, rounding off
your answer considering rules of significant figures.
24. A 600 cm3 cylinder contains 2g of hydrogen H2 and 8g of CH4.Calculate the total pressure of the
mixture of gas at 30oC.
25. Discuss the relationship between Kc and Kpof the following equilibrium:
* N2 + 3H2 2NH3 * 2SO3 2SO2 + O2
26. Define Activation energy. Find the activation energy of a reaction if the threshold energy is 125
calories per mole and the average energy of reactant molecules is 1000 joules per mole.
27. Differentiate intensive properties and extensive properties.
28. Discuss the types of Reactions based on reaction velocity.
29. Give scientific reason:
* Rate of reaction is increased by an increase in temperature.
* Powered marble gives more effervescence with HCl than a piece of marble.
* NaF and MgO are isomorpheous solids.
* Surface tension of diethylether is less than water.
30. Explain any two of the following gas laws with the help of Kinetic theory of gases.
* Boyles Law * Charless Law * Daltons Law of Partial pressure
31. Calculate the volume of Oxygen at 39oC and 1200 torr pressure, formed by complete decomposition
of 170g of KClO3 according to following reaction:
2 KClO 3
2 KCl 3O2
32. A sample of an organic compound consisted of 2.0g Carbon, 0.34g Hydrogen and 2.67g Oxygen.
The molecular mass of the compound is 60. Calculate its molecular formula.
33. Gas A diffuses 4 times faster than gas B. if the molecular mass of gas B is 64, what is the molecular
mass of gas A.
34. Define the following: * Error and deviation * Molar volume * Significant figure * Avogadros
number.
35. Derive the equation of state for an ideal gas and calculate the value of the gas constant in two
different units.
36. What is chemical equilibrium? Illustrate it with the help of graph.
37. Kc for the following reaction is 4. Calculate the equilibrium concentration of CH 3 COOC 2 H 5 when
1.66 moles of CH 3COOH and 2.17 moles of C 2 H 5 OH are allowed to come to equilibrium.
CH 3COOH C 2 H 5 OH CH 3COOC 2 H 5 H 2 O
38. Different between (any two).
* Empirical and Molecular formula * Isomorphism and Polymorphism
* Continuous spectrum and line spectrum
39. How cathode rays are produced? Prove that these rays:
a) Travel in straight line b) are material in nature c) are electrons
40. Differentiate between Hydration and Hydrolysis? Explain why is the aqueous solution of NH4Cl is
acidic while that of Na2CO3 is basic.
41. State and explain Hesss law of constant heat summation. Give its applications.
42. What is oxidation number? Determine the oxidation number of the following:
a) Cr in K2Cr2O7 (b) O in OF2 (c) Mn in MnO4- (d) N in NCl3
43. Differentiate between a Molal and Molar solution.
44. 1.2 gm of CH3COOH is dissolved in H2O to make 200cm3 of solution. Find concentration of this
solution in moles/dm3.
45. Discuss the effect of light on the rate of a reaction.
46. For the given reaction A + B products, determine the order of reaction from the following data:
A(mol./dm3) B(mol./dm3) Rate(mol. s-1)
0.1 0.1 1 x 10-3
0.2 0.1 4 x 10-3
0.1 0.3 3 x 10-3
47. For the reaction, NH3 + H2O NH4+ + OH- , point out acid, conjugate base and conjugate acids,
according to Brnsted-Lowry and give reason.
48. The Kc for the reaction 2HI H2 + I2 is 1.310-2 . If there are 0.5M H2, 1.5M I2 and 5M HI, predict
the direction in which the reaction will proceed in order to achieve the equilibrium.
49. How was the presence of proton detected? What are the characteristics of protons?
50. Predict the shapes of the following molecules on the basis of electron repulsion (any two).
i) NH3 ii) C2H4 iii) BeCl2 iv) H2O
51. Define a unit cell. Name the crystal system which has the following cell dimensions.
* a = b = c, = = = 90o * a b c, = = = 90o
52. Name the physical methods along with the observed physical properties for determining the rate of a
reaction.
53. Write the electronic configuration and give the number of protons in each of the following atoms/
ions: * Ne (Z=10) * Cu (Z = 29) * Mg2+ ( Z =12) * Cl-1 ( Z = 17)
54. Give the reasons of any four of the following.
a. Glycerin is distilled at reduced pressure
b. A liquid rises in a capillary tube.
c. Graphite is a good conductor of electricity where diamond is not.
d. NaF and MgO are isomorphic compounds.
e. Evaporation is a cooling process.
f. The density of ice is less than that of water.
g. Boiling point of H2O is higher than B.P. of H2S.
h. A positive catalyst increases the rate of reaction.
55. 3600Jof heat enters a gas cylinder. Calculate value of E
a) If the volume is kept constant.
b) If the volume is not constant, work of 800J was performed by the gas.
56. Describe the relationship between Kc and Kp.
57. 60g of acetic acid and 46g of ethyl alcohol are mixed with each other at a constant temperature and
are allowed to attain equilibrium. At equilibrium, 58.2g of ethyl acetate and 12g of water were
present, find the equilibrium constant (Kc).
CH3COOH+ C2H5OH CH3COOC2H5 + H2O
58. Balance the following equations;
(i) MnO4-1 + SO3-2 + OH-1 Mn+2 + SO4-2
(ii) MnO4-1 + Cl-1 + H+1 Mn+2 + Cl2
59. What is neutralization? Give the examples of normal, acidic acid and basis salts.
60. Define the term viscosity? Explain with examples that why some liquids have higher viscosity than the
others? Describe the effect of temperature change on viscosity of a liquid.
61. Energy of an electron in nth orbit of an atom with atomic number z by Bohrs model is calculated as:
2
=
62. Use that equation to derive an expression for the wave number of radiation emitted by an excited atom.
Discuss the shape of Ethylene (C2H4), Acetylene (C2H2) molecules and ammonia (NH3)on the basis of:
* Hybridization model * Electron pair repulsion model
63. What are Thermochemical reactions? State and explain Hesss law of constant heat summation with its
applications.
64. Differentiate between the following pairs:* Sigma and pi bond * Electrovalent and Covalent bonding
65. The value of the dissociation constant of water ( = [ ][ ]) is 10 at 25oC. Use this
information to define pH and pOH and to describe their relation. Also find the pH of a solution containing
0.005 moles of NaOH per dm3.
66. AgCl (mol. mass=143.5) is a sparingly soluble salt. Its Ksp is 9.610-11 .
* Write an equation showing dissociation of AgCl in water.
* Give an expression for the solubility product of AgCl.
* Find the solubility of AgCl in .
67. Will a precipitate of Mg(OH)2 be formed if the pH of 0.001M aq. Mg(NO3)2 solution becomes 10?
(Ksp of Mg(OH)2 = 4 10 )
68. Write salient points of Bohrs atomic model.
69. What is a limiting reactant? Calulate the minimum mass of Al(OH)3 that can be obtained by the
reaction of 13.4 g of AlCl3 with 10g of NaOH according to the following equation:
AlCl 3 3 NaOH Al OH 3 3 NaCl
70. Describe the effect of temperature change on viscosity of a liquid.
71. In a thermodynamic process, the internal energy of a gas increases by 200J, and the volume of the
gas increases by 4.95 x 10-3 dm3 at constant pressure of 800 torr. Calculate the work done by the gas
and the heat energy supplied to it.
72. What is rate of reaction? Describe how the rate of following reaction is determined by chemical
method:
CH 3 COOC 2 H 5 H 2 O CH 3 COOH C 2 H 5 OH
73. Differentiate between amorphous and crystalline solids.
74. Define Thermochemistry. State and explain Hesss law of constant heat summation with its
applications.
75. State the law of Mass action.Write the expression of Kc for a general reversible gaseous reaction:
n1 A( g ) n2 B( g ) n3C ( g ) n4 D( g )