Documente Academic
Documente Profesional
Documente Cultură
Gerard McKeogh
Global Sales Leader Analyzers
1
Moisture and Humidity overview
Condensation RH TDLAS
Trace moisture
Hygrometers
moisture.IQ
Optica Multi channel MMR31 Aurora
Top of the line Trace moisture RH, polymer relative Process solution
condensation analyzers in dew humidity transmitter
hygrometers point or ppm range
PM880, MMY245
Trace moisture
handhelds in dewpoint
or ppm range
2
Oxygen and Gas analyzers
overview
Paramagnetic
Thermal-
Zirconium Electro-
Conductivity
Oxide chemical
XMO2 XMTC CGA 351 Oxy.IQ
%O2 in gases %Gas Analyzer in other Clean Gas Oxygen Galvanic Fuel Cell oxygen
Transmitter w/optional gases based on Analyzer for non- sensor for PPM or % O2
displays with relatively measuring differences in combustion in other gases
constant background thermal-conductivity applications
gas (Typically H2 analysis)
APX Delta F
Non-depleting
%O2 in gases Analyzer
electrochemical oxygen
with widely varying or
sensors for PPM O2 in
unknown background
other gases; used in
gases
conjunction with MIS1
and MMS3
3
Why Measure Moisture in
your Processes?
A Critical Parameter in Natural Gas
Refining Process Overview
Where we measure
Hydrotreating/
Cracker Unit
Catalytic Reformer
Isomerization Unit
Alkylation Unit
Refinery Products
Flare Lines
Utilities
Refinery Catalytic Reforming Process
(CCR) CCR
Moisture
H2 Converts low octane heavy
Dryer Oxygen Napthas (HC liquid) to high
octane reformate (gasoline
Liquid Naptha blend component)
feed Produces H2
Typical range 0-50ppm
Nominal moisture: 20ppm
Licensor: UOP & Axens
9
GE Title or job number
10/21/2015
Ethylene Process Diagram
Cracker type
Steam
Catalytic
FEEDSTOCK
Naptha/Gas Oil
(Refinery product)
OR
Ethane (Natural Gas by
product)
Measurement locations
Moisture in cracked gas feed after drying
Moisture in condensate from Fractionator Bottoms
Moisture in H2 (Acetylene (removal) Hydrogenation Unit)
H2 purity measurement (Acetylene (removal) Hydrogenation Unit)
Moisture & Oxygen in Ethylene Product
Oxygen measurement in flare and vent lines for leak detection
Moisture in utilities (Air/Nitrogen)
Polyethylene Process Diagram
A. Moisture in feed gas C D
(Ethylene + co-
monomers+H2)
B. Oxygen in feed gas
(Ethylene + co-
monomers+H2)
C. Moisture in recycle gas
stream
D. H2 measurement in recycle
gas stream
E. Oxygen in Extruder
Oxygen measurement in flare
and vent lines for leak detection
Moisture in utilities
(Air/Hydrogen/Nitrogen) B E
A
POWER APPLICATIONS
1. H2 Cooled Generator
2. Gas Turbine
3. Compressed Air
4. Distribution
5. Nuclear Power
6. Renewables
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GE /
October 21, 2015
H2 Cooled Generator
Hydrogen: High thermal
conductivity & low viscosity
(resistance to flow)
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GE /
October 21, 2015
Gas Turbine
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GE /
October 21, 2015
Dew point control of compressed air
Compressed air use in Power
Industry
Instrument Air
Sprinkler installations
Cleans boiler tubes
Pumps
Conductor isolation
Presence of Moisture
Causes
Corrosion
Failure of Critical Components
Loss of Instrument Sensitivity
Condensation/Freezing of Air
Lines
Inefficient Regeneration Cycle 15 /
GE /
October 21, 2015
Distribution
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GE /
October 21, 2015
Nuclear Power
H2 & O2 Detection in Reactor %RH for leak detection
in Containment Zone
Biogas> CH4/CO2
Measure CH4, O2 RH control of steam
and H2O in clean & injection
dry Biogas
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GE /
October 21, 2015
Moisture Measurement Technology
19
Moisture
..is the amount of water
vapor present in a given
sample
Pressure (mbar)
Sample system
24
Aluminum Oxide Sensor
Construction
Temperature Sensor
Pressure Sensor
Viton O Ring Seal
Straight Thread
Aluminum Oxide Sensor Theory
GE Sensing is the global leader in automated humidity & moisture instrument calibration
Global service centers NIST and other NMI traceable calibrations
Web based archive enables customers to access calibration data and plan instrument cal cycles
Onsite training and start up assistance as well as classroom training
Calibration Profile
Global Calibrations Centers
Shannon
Boston Ireland
Saudi Shanghai
Arabia China Tokyo, Japan
Abu
Dhabi Bangalore
Brazil India
moisture.IQ
GE Measurement & Control introduces
moisture.IQ as the newest addition to the
Panametrics family of aluminum oxide
moisture analyzers.
33
moisture.IQ new Features
Industrial touch-screen display with intuitive
graphical user interface
Calibration reminders
USB port for in-field firmware upgrades
Modbus over Ethernet
Remote programming and display over
Ethernet using any internet browser
Alarm contacts are Division 2 standard
All channels have Delta F standard
1 and 3 channel
module options Temp compensation for Delta F cell O2 sensor
Following in coming months:
Henrys Law database imbedded in firmware
for liquid applications
Each available output assignable to any
parameter on any channel
Computer Enhanced Response
XPF & WPF options
dew.IQ moisture analyzer
Single-Channel
Moisture Analyzer
Aurora TDLAS
Hygrometer
for Natural
Gas
40
TDLAS H2O Sensor Block Diagram
Sample Pressure
Inlet Sensor Temperature Sample
Sensor Outlet
Desiccant
Signal
Photodiode
Driving Circuit
Optical
Mirror Window Hermetic
chamber Microprocessor
Reference
Collimator Photodiode
TEC for
Temperature
Laser Diode
control
N = ln(I/Io)
SxL
Response Time of Aurora
0C
Td
Other Trace
Aurora Moisture Sensors
TDLAS
-60C Td
6 Hours
Test of Process Upset
3 min
Sample System Aurora H2O
Temperature
Sensor
Inlet Isolation
Absorption
Valve
Cell
Pressure
Sensor
Fast
Loop
Bypass
Needle Valve
Aurora Calibration System
7 7
4 1 7
6
1 Dew Point Generator
2 Pressure Reference
3 Reference Chilled Mirror
4 NI Data Acquisition &
Control
5 User Interface (PC
Based)
6 CPU
7 Units under test (up to 6)
45
Presenter and Event
10/21/2015
Pressure Dew Point
4-20mA
GE Druck RTX 1000H Series
Pressure Transmitter
Hasteloy C Diaphram
NACE MR-0175 compliant
FM, CSA & ATEX (XP)
Known for long term stability
Simple push button setup
Maintenance Kit
Part Number: AURORA
H2O MAINTENANCE
Description: Aurora
H2O maintenance kit
to include magnetic
stylus, hex wrench to
remove mirror flange,
mirror cleaning
accessories, and
replacement filter
cartridges
Example of Custom Sampling System
High sensitivity
DP range -30+30
APX Delta F
Non-depleting
%O2 in gases Analyzer
electrochemical oxygen
with widely varying or
sensors for PPM O2 in
unknown background
other gases; used in
gases
conjunction with MIS1
and MMS3
55
Gas Purity Analyzer
XMTC Thermal Conductivity
Analyzer
Air/N2
SO2 CO2 Ne He H2
CH4
Technical Strengths
No Moving Parts
Stability
Minimal maintenance
Easy field calibration
Small package size
XMTC Thermal Conductivity
Analyzer
Specifications
Range: 0 to 100% and any portion of
range in between (eg 0-2%, 98-100%)
Output: 0/4 to 20 mA
Accuracy: +/- 2% of span
Response Time: 20 sec for 90% step
change
Stability: 0.5% of span per week
Applications
H2 Recycle Gas Monitoring Refineries
H2 cooled Generators H2 Purity-Power Plants
Compressor leakage Monitoring (for CH4
leakage)
Gas Manufacturers-Nitrogen, Argon, Helium
Purity
Thermal Conductivity Gas Analyzer Applications H2
Recycle
Make Up Hydrogen
Reformer
Hydrogen
Analyzer Recycle
XMTC
Point Stream
Gas
Gas-Liquid Separator Cooler
Liquid
Product
Hydrogen cooled generator - overview
Generato Turbin
r e
Brushes
Electricity
Coils
Low-Pressure High-
H2 Make Up Steam outlet Pressure
Steam inlet
Pump Dryer
Compressor Leakage 0-100% CH4 in AIR
Nuovo Pignone builds centrifugal compressors for O&G customers to help those customers harvest oil and gas from
wellheads as well as push gas in the pipeline. The compressors have a primary seal and a secondary seal that
prevents the process gas from mixing with the sealing gas. During operation, the primary seal is monitored for reliability
by checking the outlet pressure and flow of the sealing gas. If there is a break in the seal, the pressure rises and flow is
increased downstream of the seal. Once this occurrence happens, the operators understand that they will have a
certain amount of time to shut down the compressor to replace the primary seals.
During the time between primary seal failure and shutdown, the secondary seal will prevent the mixing of process gas
and escape of process gas. The pressure has increased on the secondary seal and the secondary seal is being
purged by nitrogen ( or Air). After failure of the primary seal, there will be a mixing of process gas and nitrogen. With a
small leak in the primary seal the concentration of gas/nitrogen will be mostly nitrogen (95%), but as time goes by and
the failure increases, the concentration will change until it is 100% process gas. This happens because the pressure of
the process gas is greater than the nitrogen purge.
This time between seal failures will allow the customer to switch to different power train, purge contained gas and
safely shutdown the system. If this time is not permitted, the plant will shut down immediately. This type of shutdown
causes tax issues for released gases as well as millions of dollars for a shutdown unit.
GEOG's request is to measure the percentage of process gas after the secondary seal. They want the sensor to be
calibrated from 0-100%. They understand that levels of concentration of 30% will alert them to major problems, but they
want the sensor for 0-100%.
1)Reliability
2)Accuracy
3)Current status in Safety Applications
4)ATEX/UL/CSA approvals
Process gas could be methane or propanein case of mixture of HC we need to check if thermal conductivity of the
sample could be detected by our XMTC with reasonable reliability and accuracy
Paramagnetic Oxygen
Analyzer
XMO2 Paramagnetic Oxygen Analyzer
Relative Magnetic Susceptibility of Common Gases
N2 O2
HCl, CH4 ,CO2 H2 , CO
NO2 NO
0 50 100
Upper Measuring Thermistors @160degC
measurement
chamber
@45degC Magnetic Field
Lower flow-
through Wheatstone Bridge V =raw O2 Signal
O2
chamber
@45degC W2
W1
VO2 RZ
R2
R1
Technical Strengths
0.01 to 100% O2
Atmospheric pressure compensation
No Moving Parts Compact & Rugged
Most Stable Paramagnetic Sensor
Long-Term Reliability
Dual-Chamber Design for Resistance
to Contamination
XMO2 Paramagnetic Oxygen
Analyzer
Specifications
Range: 0 to 100% and any portion of range in
between (eg 0-1%, 90-100%)
Output: 0/4 to 20 mA
Accuracy: +/- 1% of span
+/-0.2%O2 for 90-100% range
Response Time: 15 sec for 90% step change
(Fast Response option, 70 sec standard
response)
Stability: 0.4% of span per month
Applications
Oxygen Purity Monitoring
Inerting applications LEL
Catalyst regeneration in refinery
Oxygen Monitoring in Flare Line
(APX)
Blanketing
Vapor
Recovery /
Vent
All tanks with Hydrocarbon
liquids are potentially
explosive and hazardous O2
Monitoring
The oxygen concentration
need to be controlled below N2 Blanket
Gas
LEL (app. below 4%)
The best technology for this
application is Paramagnetic N2 Blanket
Oxygen
ZrOx would burn the HC
Electrochemical fail low Tank with
causing a sense of false HC Liquid
safety
Electrochemical
Oxygen Analyzers
oxy.IQ Electrochemical Oxygen
Loop Powered transmitter
Intrinsically safe option
User Interface
User selectable and
programmable ranges
Sensor diagnostics
Sensor lifetime feature
Sensor raw signal Thin Electrolyte Layer %O2
Error indication choice Sensing Membrane Cathode
+ v -
Cathode: O2 + 2H2O + 4e- => 4OH-
Anode: 2Pb => 2 Pb+2 + 4e-
Overall: 2Pb + O2 => 2PbO
O2X1 Electrochemical Oxygen
Analyzer
Specifications
Range: Field programmable 0-10, 0-100, 0-
1000, 0-10000ppm & 0-1, 0-10, 0-25%
Output: 4 to 20 mA Display
Accuracy: +/- 1% of span @ cal point (+/-2%
for 0-10ppm range)
Response Time: 10 22 sec ** for 90% step
change, (** range dependent)
Stability: 0.4% of span per month
Applications
Gas purity monitoring, feed gases to
petrochemical processes, O2 in
Natural gas, O2 in utility N2
Ambient Air Monitor
DF Electrochemical sensors & analyzers
DF Electrochemical sensors & analyzers
Specifications
Range: PPM & % range cells available (up to max 25%)
Output: MIS1/MMS3 outputs (Digital & analog 0/4-20mA)
Accuracy: +/- 1% of full scale (+/-5% of full scale for ranges
<2.5ppm)
Response Time: Instantaneously to O2 change
Stability: 0.4% of span per month
Intrinsically safe for hazardous area use
Technical Benefits
Ultra stable, drift free
Long lifetime with unique 5 year sensor warranty
Fast response and fast recovery after transient oxygen shock.
Applications
Gas purity monitoring
Petrochemical feed gases
DF Electrochemical sensors &
analyzers
Secondary Electrodes
Reservoir
4e
1.3V KOH Sample
1.3 PPM O2 Sample
4OH O2
Chamber
When oxygen is present in the sample, a current is produced in the measurement circuit which is
proportional to the oxygen concentration. Unlike the galvanic cell, the measurement reaction is
driven by an applied voltage across the measurement electrodes supplied from the instrument
electronics.
Zirconia Oxygen
Analyzer
CGA351 Zirconium Oxide O2
Analyzer
Specifications
Range: Field Programmable between
0.1 ppm to 100% O2, typical range 0
to 10ppm O2
Output: 0/4 to 20 mA
Dual Alarm contacts, fail safe
Accuracy: +/- 0.2ppm from 0 to
10ppm or +/- 2% of reading
Response Time: less than 2 sec for
90% step change
Stability: less than 3% of reading per
year
CGA351 Zirconium Oxide O2
Analyzer
Technical Strengths
Fastest Responding Oxygen Sensor
Provides Oxygen Measurement over the widest
range
Maintenance free
Applications
Air Separation Plants Gas Purity
Measurement
Cylinder Filling
GE Aurora Global Installations + Customization + Local Support
77
GE
Measurement & Control