JEE(Advanced)2017Paper1Code0ChemistrySolutions(Date:2152017)

19. (B,C) (C) AreaunderirreversiblePv/sVgraphin

Thecoloursarisefromtheabsorptionoflight compressionismorethanthatunder
on promoting an electron from the ground PVgraphofreversiblecompression.
state to higher state. On descending the
group,theenergylevelsbecomecloserand
gapbetweenHOMOLUMOdecreases.
HOMOis p *
LUMOis s *
20. (A,B,C)
(X)=CoCl2.6H2O,or[Co(H2O)6]Cl2(Pink)
Co2+ =[Ar]
22. (A,D)
H2Oisweakfieldligand,thereforeNopairing
ofelectron.
Numberofunpairedelectron,n=3
ms = n(n + 2)B.M.

= 15 B.M.
=3.87B.M.

[Co(H2O)6]2++6NH3(aq) [Co(NH3)6]2+
+6H2O
O2 willoxidise[Co(NH3)6]2+ to[Co(NH3)6]3+,
thereforeshiftinforward
Y=[Co(NH3)6]3+Cl3 [1:3complex]
Co(III)=[Ar] PointZrepresentsv.p.ofpureliquidL
3d AtxL 1,solutionisverydilute,Lbecomes
NH3 isstrongfieldligand solvent.VerydilutesolutionofMinLisnearly
Forceselectronstopairup
idealandobeyRaoultslaw (pL = xLpL
n=0
Also,thereispositivedeviationindicatedby
m =0B.M.
graphabovedottedline(expectedforideal
[Co(NH3]3+=[Ar] solution.
LMinteraction<LL&MMInteractions.

23. (A,B)
3d 4s 4p
IUPACname

Also,
[Co(H2O)6 ]2 + 4Cl [CoCl4 ](aq)
2
+ 6H2O DH = + ve
(X) (Z)
Pink Blue

At, 0 C, equilibrium shifts in backward,

therforePinkcolour.
21. (A,B,C)
(A)Infreeexpansion,Pex =0 w=0
Forisothermalfreeexpansionofanideal
gas, DU =0 q=0 \ adiabaticalso.

(B) WIsothermal >WAdiabatic

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24. (B,D) 27. (6)

CisantiRacemic
MandNmeso(identical)
OandParepairofenantiomers
(B) Brominationproceedsthroughantiadition.
(D) (MandO)and(NandP)aretwopairsof
diastereomer.
25. (A,B,D)
28. (5)
(A) HClO4 >H2OAcidiccharacter
ClO-4 <OH Conjugatebase
(B) BothHClO4 andHClOcentralatomissp3
hybridised
(D) HClO4 >HClOAcidicstrength

HClO 4 H+ + ClO-4 29. (2)

a=4108 cm(a=edgelength
HClO H+ + ClO-
d=8gcm3 (density)
ZM
d=
NAa3
M=molecularmass(g/mol)
Z numberofatomin1unitcell
In ClO-4,nagativechargeisdispersedonfour
oxygen,sobetterresonancestabilised. dNAa3 8 6 1023 64 1024
M= =
Z 4
26. (6)
=76.8g/mol
l Moleofsolidin256g=3.33moles
k = C
A No.ofatom
=3.33NA =201023 =21024
120
=5107 30. (6)
1
2
=6105 Scm1 H2 s1s Diamagnetic
k 1000 2
He2+ s1s *1
s1s Paramagnetic
lM =
M
2 *2
Li2 s1s s1s s2
2s Diamagnetic
6 10 -5 1000
= 2 *2 2 *2
15 104 Be2 s1s s1s s2s s2s Diamagnetic
lM =40Scm2 mol1. 2
Be2 s1s *2 2 *2 1
s1s s2s s2s p2p = p1 Paramagnetic
2p x y
+ 4
[H ]= Ca =10
2 *2 s
C2s1s s1s s2s s*2 2 2
2s p2p = p2p Diamagnetic
104 1 x y

a= =
15 10-4 15 2 *2 2 *2 2
N2s1s s1s s2s s2s p2p = p22p s2
2p Diamagnetic
x y z

lM 2 *2 2 *2 2
a=
lM =4015=600 O2s1s s1s s2s s2s s2p p22p = p22p p*1 = p*1
2py Paramagnetic
z x y 2px
lM
2 *2 2 *2 2
=6102 Scm1 mol1 F2s1s s1s s2s s2s s2p p22p = p22p p*2 = p*1
2py Diamagnetic
z x y 2px

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31. (D) 35. (C)
1s orbital is nondirectional so y will not
dependupon cosq .
32. (D)
ForHlikespeciesonlyDiscorrectbecause
In(A)1sorbitalhasnoradialnode
In(B)for 3dz2 ,xyplaneisnotnodalplane.
In(C)2pz orbitalhasnoradialnode
33. (D)
ForHatom
Itishaloformreaction
3 Zr
-
Z 2 a0 36. (C)
1sorbital y e
a0

3
Also,E4E2 =
16
2
E6 E2 =
9
27
(E6 E2) =E4 E2
32

34. (D)

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