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CHEMISTRY 11 – TEST 2
SECTION A
[10 Marks]
Section A contains TEN (10) objective questions. Each question carries equal
mark. Answer ALL questions. All symbols carry their usual meanings unless
indicated otherwise.
a) 2-ethyl-3-methylpentane
b) 3,4-dimethylhexane
c) 2,3-diethylbutane
d) 3-methyl-4-ethylpentane
O O Cl
HO C C OH Cl CH2Cl H2C F Br Cl
C C C C C C C C
H H H CH3 H3C Cl H3C I
I II III IV
a) I, II
b) II, III
c) III, IV
d) II, IV
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a)
b)
c)
d)
e)
a) b) c) d)
Answer d
a) I, II
b) III, IV
c) I, III
d) II, IV
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a. -1.34 volt
b. +1.34 volt
c. -4.18 volt
d. +4.18 volt
S−Na+ S
I Na+ + I−
a) Na+
b) CH3CH2I
c) C6H5SCH2CH3
d) I-
Assuming no other changes, what effect on the rate would result from
simultaneously doubling the concentrations of both butyl bromide and OH-
ion?
a) No effect.
b) It would double the rate.
c) It would triple the rate.
d) It would increase the rate four times.
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a) O
C
H3C CH3
b) O
S
H3C CH3
c) O
C CH3
H N
CH3
d) CH3
CH
H3C OH
10. A galvanic cell is composed of these two half cells, with the standard reduction
potentials shown
a. +0.06 volt
b. +0.09 volt
c. +0.15 volt
d. +0.18 volt
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SECTION B
[15 Marks]
Answer ALL questions. All symbols carry their usual meanings unless indicated
otherwise.
1/2
..
: Br : H ..
1/2 slow 1/4 :OCH
.. 3
..
[ - Br: fast
.. ] 1/4 H
1/2 1/2
1/2
[3 Marks]
1 1
The second alkene is the major product. The alkene that is more substituted
is
more stable.
[2 Marks]
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2. a. Use reaction (curved) arrows to show the major product for the flowing
reaction.
1/2
1/4
+ H Br +
1/2
1/4
Br H
Br
1/2
b. For the compound listed below, draw its mirror image and label
them
the enantiomers as R or S isomers.
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CHO
CHO 1
C
CH3O CH3 C
CH3 CH3O
H H
R
S 1/2
1/2
[2 Marks]
a.
Br
tBuO K
[3 marks]
b.
Br2 Br
CCl4
Br
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[3 marks]