ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE: 2015 CRASH COURSE (C-18) DATE:

TOPIC:PERIODIC TABLE, CHEMICAL BONDING

SECTIONI (Multiple Choice Questions)

This section contains 05 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONLY ONE is correct.

1. Choose the incorrect order for acidic strength

(a) CO 2 > CO (b) SO 2 < SO3 (c) HClO 2 > HOCl (d) SiO 2 > CO 2

2. For an element the successive ionization energy values (in eV/atom) are given below 12.32, 26.84,
44.56, 65.73, 203.9, 251.12, 308.4
The element that satisfies the above values is
(a) Si (b) Ca (c) Al (d) S

3. Find the pair of species having the same shape but different hybridization of the central atom
(a) SO3 , CO32 (b) NO 2 , ClO 2 (c) BeCl2 , HCN (d) XeF2 ,SnCl2

4. Which of the following species has the same number of X O X linkages, where X = S or P?
(I) S4 O62 (II) S3O9 (III) S2 O52 (IV) P3O39
(a) II & IV (b) II & III (c) I & III (d) I & IV

5. Which is the correct order of the bond angle?

(a) NH 3 < NF3 (b) H 2 O > Cl2 O (c) PH 3 < SbH3 (d) H 2 Te < H 2S

SECTION-II (Multiple Choice Questions)

This section contains 3 multiple choice questions. Each question has 4 choices (A),
(B), (C) and (D) for its answer, out which ONE OR MORE is/are correct.

6. Choose the correct ionization energy order for the given species:
(a) O > S > S > O (b) F > F > Cl > Cl (c) O > O > S > S (d) F > Cl > Cl > F

7. In which of the following statements is the correct order with respect to the given property?
(a) Fe +3 ( aq ) > Fe 2+ ( aq ) : Ionic mobility order
(b) Br ( aq ) < Cl ( aq ) < F ( aq ) : Hydrated radius order
(c) SbH3 > AsH 3 > PH 3 : M H bond polarity order
(d) S > C > H > B : Electronegativity order
CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1
8. Consider the following four monoatomic ions M + , N + , X an dY
If lattice energy order is MX > NX and hydration energy order is NY > NX , which of the following
must be true?
(a) Covalent character order is MX > MY
(b) Thermal stability order is MY > NY
(c) Hydration energy order is MX > NX
(d) Hydration energy order is MX < NX

SECTION III (Integer Answer Type)

This section contains 5 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The correct digit below the question number in
the ORS is be bubbled.

9. The sum of oxidation states of N atom in the following compounds of nitrogen is _________
NH 3 , N 2 H 4 , NH 2 OH, N 2 , N 2 O, NO, N 2 O3 , NO 2 , N 2 O5

The maximum number of atoms lying in the same plane in [ AlCl4 ] and the number of such planes

10.
are respectively _________ and _________

11. The maximum number of atoms that may lie in the same plane in P ( CH 3 )( CF3 )2 is ______ and the
number of such planes is ___________

12. The maximum number of atoms that may lie in the same plane in ( CH 3 )2 C = SF2 ( CH 3 )2 is _______

13. The number of nodal planes when two d xy orbitals from two atoms produce antibonding bonds is
_____

SECTION IV (Paragraph Type)

This section contains 2 multiple choice questions relating to 1 paragraph. Each
question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Passage For (Que. No.14 to 15)

The structures of P ( CH 3 )2 F3 and P ( CH 3 ) F4 are shown below:
F F
F CH3
H3C P and F P
H3C F F F
14. Which of the following are correct values for x and y in the above figure?
(a) x > 1200 , y > 1200 (b) x > 1200 , y < 1200
(c) x= y= 1200 (d) x < 1200 , y < 1200

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3
15. For molecules P ( CH 3 )n F5 n , when the value of n increases from 1 to 4, which of the following
statements is incorrect regarding the change observed?
(a) d P C (equatorial) increases
(b) d P F (axial) increases
(c) d P F (axial) decreases
(d) d P F (axial) > d P F (equatorial) wherever it is applicable

SECTION - V (Matrix Match Type)

This section 1 Question. Each question has four statements Given in Column - I and
four statements in Column II. Any given statement in Column I can have correct
matching with one or more statement (s) given in column II.
16. Match the ionic species with their characteristics.

Column I Column II
(A) Mn 2+ (P) Has the highest ionization energy
(B) Mn 4+ (Q) Has the highest ionic radius
(C) Mn 3+ (R) Has the highest magnetic moment
(D) Mn 7 + (S) Paramagnetic
(T) Diamagnetic

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
TOPIC: PERIODIC TABLE, CHEMICAL BONDING
(ANSWER KEY) (C-18)

1 [d] 2 [a] 3 [b] 4 [a] 5 [d] 6 [ad] 7 [bcd]

8 [abc] 9 [9] 10 [3,10] 11 [7,4] 12 [8] 13 [3]

14 [b] 15 [c] 16 [ ( A ) q, r,s; ( B ) s; ( C ) s; ( D ) p, t ]

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5