Chem1BPracticeproblemsforExam2

Onceagain,thisisnotapracticetest.Theseproblemsareprovidedtoseeifyouhavemasteredthe
conceptsofthechapterscovered.Donotuseyourbookornotesonyourfirstattemptattheseproblems.

17.917.10

1.Inagasphasereaction,dimethylamine,(CH3)2NH,reactswithHCltoform[(CH3)2NH2]Cl.Intheisreaction
dimethylamineisactingasa
a)Lewisacid
b)Lewisbase
c)Lewisacid,BronstedLowryacid
d)Lewisbase,BronstedLowrybase

Answerd
2. IdentifyfromthefollowinglistofmoleculesandionswhichtwobehaveasLewisbases:H2O,F,BH3,Fe3+.
a)H2OanF b)FandBH3 c)BH3andFe3+ d)H2OandFe3+ e)FandFe3+

Answer:a
3.Allofthefollowingcompoundsareacidscontainingchlorine.Whichcompoundistheweakestacid?
a)HCl b)HClO c)HClO2 d)HClO3 e)HClO4

Answer:b
4.ThechemicalequationsbelowshowthereactionofAl(OH)3asaLewisacidandasaLewisbase,respectively.
Al(OH)3(s)+OH(aq)Al(OH)4(aq)
Al(OH)3(s)+3H3O+(aq)Al3+(aq)+3H2O()
SubstancesthatcanbehaveaseitherLewisacidsorbasesarecalled:
a) Answer:amphoteric
b) BronstedLowryacidbasepairs
c) Conjugateacidbasepairs
d) Adducts

6. WhenaLewisacidandaLewisbasecombine,theproductmaybereferredtoas:
a)anode b)BronstedAcid c)BronstedBase d)Adduct e)Noneoftheabove

Answer:adduct(orcomplex)
59. WhichisthestrongerBrnstedLowryacid,Fe(H2O)62+orFe(H2O)63+?Notmultiplechoicebutcanyou
explainbasedonthereadingsfromyourtext?Explain.
Answer:Fe(H2O)63+.Whenaprotondissociatesfromtheoxygenatom,theoxygenisleftwithanextra
electron.Thisnegativechargeisstabilizedbytheinteractionoftheoxygenwiththeironcation.Sincethe
Fe3+ismorepositivelychargedthantheFe2+,itcanmoreeffectivelystabilizethenegativecharge.


18.418.7
16.IfametalcomplexhasaKfthatissignificantlygreaterthan1,onecanconcludethatforthereactionin
water

Metal+BaseComplex

a) Thecomplexiskineticallystable
b) TheconcentrationofLewisbaseisrelativelysmall(Answer)

Page1of5
 c) Theconcentrationofthecomplexislow
d) Kwislessthanone

17.InwhichaqueoussolutionshouldAgBrhavethehighestsolubility?
a)0.1MLiBr
b)Purewater(answer)
c)0.2MAgNO3
d)0.3MKBr
18.SaltscontainingbasicanionshaveagreatersolubilityinwaterthanpredictedfromcalculationsusingKsp
values(ieCaCO3,PbF2,Ca3(PO4)2).Why?

a) Answer:Basicanionsreactwithwatertoformtheirconjugateacids
b) Thesereactionsincreasetheconcentrationofthebasicanion.
c) Basicanionsdonotreactatall
d) Noneoftheabove

19. Whichofthefollowingequationsisthesolubilityproductforlead(II)iodate,Pb(IO3)2?
[Pb IO3 2 ]
a) K sp =
[Pb 2+ ][IO3- ]2
[Pb 2+ ][IO3- ]2
b) K sp =
[Pb IO3 2 ]
c) K sp = [Pb 2+ ][IO3- ]
d) K sp = [Pb 2+ ]2 [IO3- ]
e) K sp = [Pb 2+ ][IO3- ]2

Answer:e
20. TheKspofPbCl2is1.7105at25C.WhatistheconcentrationofCl(aq)inasaturatedsolutionof
PbCl2(aq)?
a)4.1103M b)1.6102M c)2.6102M d)3.2102M e)5.1102M

Answer:d
21. TheKspofCaSO4is4.9105at25C.WhatmassofCaSO4(molarmass=136.1g/mol)willdissolvein1.0L
ofwaterat25C?
a)0.0067g b)0.0070g c)0.081g d)0.67g e)0.95g

Answer:e

43. WhatisthemolarsolubilityofCaF2in0.010MNaF(aq)at25C?ThevalueofKspforCaF2is5.31011at25
C.
a)5.3109mol/L
b)5.3107mol/L
c)7.3106mol/L
d)7.2104mol/L
e)0.010mol/L

Answer:b

Page2of5
23. TheconcentrationofMg2+inanaqueoussolutionis1.5103M.WhatconcentrationofCO32isrequired
tobeginprecipitatingMgCO3?TheKspofMgCO3is6.8106.
a)6.8106M b)1.3103M c)1.5103M d)2.6103M e)4.5103M

Answer:e

25. Considerthereaction
Zn2+(aq)+4OH(aq)Zn(OH)42(aq) Kf=2.91015
IfKspforZn(OH)2is3.01017,whatisthevalueoftheequilibriumconstant,K,forthereactionbelow?
Zn(OH)2(s)+2OH(aq)Zn(OH)42(aq)
a)1.01032 b)1.6109 c)8.7102 d)11 e)9.71031

Answer:c

Ch 19
1. Which substance is likely to have the largest standard molar entropy at T = 25oC.
a) CH4 (g) b) C2H6 (g) c) C3H8 (g) d) C4H10 (g)

2.AsdefinedbyLudwigBoltzmann,thethirdlawofthermodynamicsstatesthat
a)thereisnodisorderinaperfectcrystalat0K.
b)inaspontaneousprocess,theentropyoftheuniverseincreases.
c)thetotalentropyoftheuniverseisalwaysincreasing.
d)thetotalmassoftheuniverseisconstant.
e)massandenergyareconservedinallchemicalreactions.

Answer:a

3. Whichoneofthefollowingprocessesinvolvesadecreaseinentropy?
a)thedecompositionofNH3(g)toH2(g)andN2(g)
b)thecondensationofsteamtoliquidwater
c)thesublimationofCO2fromasolidtoagas
d)theevaporationofethanol
e)thedissolutionofNH4NO3(s)inwater

Answer:b

5. Calculatethestandardentropychangeforthecombustionofpropaneat25C.
C3H8(g)+5O2(g)3CO2(g)+4H2O(g)

Species S(J/Kmol)
C3H8(g) 270.3
O2(g) 205.1
CO2(g) 213.7
H2O(g) 188.8

a)72.9J/K b)+72.9J/K c)+100.5J/K d)+877.9J/K e)+2692J/K

Answer:c

6 Forthefollowingreactionat298.2K,
2CO(g)+O2(g)2CO2(g)
Page3of5
 calculateS(universe)givenS(system)=173.1J/KandH(system)=566.0kJ.
a)2071.3J/K b)739.0J/K c)175.0J/K d)171.3J/K e)+1725.0J/K

Answer:e

7. IfrG<0forareactionatalltemperatures,thenrHis________andrSis________.
a)negative,positive
b)positive,negative
c)negative,negative
d)positive,positive
e)positive,eitherpositiveornegative

Answer:a

8. Dilutingconcentratedsulfuricacidwithwatercanbedangerous.Thetemperatureofthesolutioncan
increaserapidly.WhatarethesignsofrH,rS,andrGforthisprocess?
a)rH<0,rS>0,rG<0
b)rH<0,rS<0,rG<0
c)rH<0,rS>0,rG>0
d)rH>0,rS>0,rG<0
e)rH>0,rS<0,rG>0

Answer:a

9. AtwhattemperatureswillareactionbespontaneousifrH=+45kJandrS=+312J/K?
a)Alltemperaturesbelow144K.
b)Alltemperaturesabove144K.
c)Temperaturesbetween45Kand312K.
d)Thereactionwillbespontaneousatanytemperature.
e)Thereactionwillneverbespontaneous.

Answer:b

10. CalculaterGforthereactionbelowat25.0C.
Fe3O4(s)3Fe(s)+2O2(g)

Species fH(kJ/molrxn) S(J/Kmolrxn)
Fe3O4(s) 1118.4 146.4
Fe(s) 0 27.8
O2(g) 0 205.1

a)1221.9kJ b)1014.9kJ c)771.2kJ d)+771.2kJ e)+1014.9kJ

Answer:e

Page4of5
11. Forachemicalreaction,ifrG=0,then________.
a)K>1 b)K=0 c)K=1 d)K<0 e)K=1

Answer:e

12. Whatistheequilibriumconstantforreactionbelowat25C?(R=8.314J/Kmol)
MgCO3(s)MgO(s)+CO2(g)
givenfG[MgCO3(s)]=1028.2kJ/mol,fG[MgO(s)]=568.8kJ/mol,andfG[CO2(g)]=394.4kJ/mol.
a)4.01012 b)0.97 c)1.0 d)1.0104 e)2.51011

Answer:a

28. CalculaterGforthereactionbelowat25.0C
2CaO(s)2Ca(s)+O2(g)
givenrH=+1270.2kJandrS=+211.9J/K.
a)1058.3kJ b)+5.994kJ c)+1058.3kJ d)+1207.0kJ e)+1482.1kJ

Answer:d

Page5of5