Aplicaii ale Spectroscopiei IR i Raman n Criminalistic

Video Raman (fenomen)

Fire i fibre (sintetice sau naturale)

Ex: Un fir de bumbac se obine prin mpletirea mai multor fibre de bumbac.
Metode de analiz IR
1. Motoda clasic a pastilrii n
KBr poate fi aplicat ns
mojararea trebuie realizat cu
atenie deosebit. Proba este
distrus n urma analizei FTIR.

2. Motoda modern ATR este

aplicabil cu succes, firele nu
sunt distruse n urma analizei,
durata msurtorilor este scurt
ns baza de date ATR nu este
foarte bogat.

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 Aplicaii ale Spectroscopiei IR i Raman n Criminalistic

Pentru fire i fibre de dimensiuni mici, se impune o metot suplimentar de

investigare i cea mai la ndemn este analiza prin microscopie optic.

Cu scopul de a obine informaii despre compoziia

chimic sau despre natura fibrelor s-au construit
spectrometre FTIR cuplate cu un microscop optic:
micro FT-IR, noua tehnic spectral numindu-se
Infrared Microspectroscopy.

Bibliografie

Infrared Microspectroscopy in Forensic Science, Hair Fiber Analysis

http://www.thermo.com/eThermo/CMA/PDFs/Articles/articlesFile_2278.pdf

Video Micro-FTIR
http://www.youtube.com/watch?v=xYvIHtSIyqY 2
 Aplicaii ale Spectroscopiei IR i Raman n Criminalistic

n mod similar ideii de funcionare a sistemului micro FT-IR, s-a construit un spectrometru
Raman cuplat cu un microscop optic: Confocal Raman Microscope, noua tehnic spectral
numindu-se Raman Microspectroscopy sau micro-Raman.
Bibliografie
Li-Ling Cho
Identification of textile fiber by Raman microspectroscopy
Forensic Science Journal 2007;6 (1):55-62
http://fsjournal.cpu.edu.tw/content/vol6.no.1/6(1)-4.pdf

JASON V. MILLER and EDWARD G. BARTICK

Forensic Analysis of Single Fibers by Raman
Spectroscopy
APPLIED SPECTROSCOPY 55, Number 12, 2001
http://bartick.net/ed/42.pdf

Video Raman Microscope 1

http://www.youtube.com/watch?v=v4lHUPwkEs0

Video Raman Microscope 2

http://www.youtube.com/watch?v=YM2aEXZNfMw

Video Raman Microscope 3

http://www.youtube.com/watch?v=DjHO7xaTrzc
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 Aplicaii ale Spectroscopiei IR i Raman n Criminalistic

Tehnicile micro FT-IR i micro Raman pot fi aplicate aproape n orice situaie de identificare sau
comparare de probe materiale de dimensiuni mici. n acelai timp ele ofer posibilitatea unei
analizei locale a unor probe de dimeniuni mari. Exemplu: analiza unei semnturi pe un document
fr a deteriora documentul.

Bibliografie

T. Gal, J. Sandor, A. Karoly

Micro-Raman study of the sequence of non-intersecting lines for forged document investigation
http://www.horiba.com/fileadmin/uploads/Scientific/Documents/Raman/forensic04.pdf

Video Raman Pixuri 4

http://www.youtube.com/watch?v=I34tz5nIPCs
 Raman and Fraud

5
Lewis, I. R.; Edwards, H. G. M., Handbook of Raman Spectroscopy: From the Research Laboratory to the
Process Line, Marcel Dekker, New York: 2001.0
 Ivory or Plastic?

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Lewis, I. R.; Edwards, H. G. M., Handbook of Raman Spectroscopy: From the Research Laboratory
to the Process Line, Marcel Dekker, New York: 2001.
The Vinland Map: Genuine or
Forged?

Brown, K. L.; Clark, J. H. R., Anal. Chem. 2002, 74,3658. 7