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Abstract
In small solid biomass power and heat plants, the ORC is used for cogeneration. This application shows constraints dierent from
other ORC. These constraints are described and an adapted power plant design is presented. The new design inuences the selection
criteria of working uids. A software has been developed to nd thermodynamic suitable uids for ORC in biomass power and heat
plants. Highest eciencies are found within the family of alkylbenzenes.
2006 Elsevier Ltd. All rights reserved.
Keywords: Organic Rankine Cycle; Working uid; Plant design; Biomass; Cogeneration
1359-4311/$ - see front matter 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2006.04.024
224 U. Drescher, D. Bruggemann / Applied Thermal Engineering 27 (2007) 223228
Nomenclature
Fig. 2. T ; H_ diagram for the standard (a) and an improved (b) plant design for an ORC without superheating (state 5 and 6 are equal). PP = pinch point.
The small dierence between states 1 and 2 is neglected in the diagrams.
3. Methods
molecular weight,
critical temperature,
critical pressure, Fig. 3. Typical T, S-diagram for ORC with superheating.
acentric factor,
melting point,
autoignition temperature, as well as state 6 are obtained from an isothermal change of
vapor pressure of the liquid, state starting from the 0.1 MPa isobar using PengRob-
heat of vaporization, insonEOS [10,11].
heat capacity of the liquid, The thermal eciency g is dened by
heat capacity of ideal gas.
h6 h7 jwpump j
g 1
These thermodynamic properties have been extracted h6 h 3
from the database of the Design Institute for Physical with the feed pump work
Properties (DIPPR) [8,9] which includes nearly 1800 sub- Z pmax
1
stances. The calculation method has to cover the range wpump v dp 2
from liquid phase to superheated gas (Fig. 3). Specic gpump pmin
enthalpy dierence h3 h2 is the recovered heat provided Feed pump work is calculated neglecting the uid com-
by the recuperator using h7 h8. The dierence h6 h1 pressibility which inuences enthalpy only marginally.
is input enthalpy, h7 h6 gained work wturbine and The eciency of the internal heat exchanger is
h8 h1 waste heat which may be used for space heating.
State 6 can be in the gas phase or on the dew line (then h3 h2
gihe 3
state 5 equals state 6). The maximum temperature Tmax is h7 h8
the turbine inlet temperature (state 6) and the minimum and turbine eciency is given by
temperature Tmin is the condenser temperature (state 1
h6 h7
and 9). gturbine 4
h6 h7s
The states 1, 2, 3, 4, 5 and 9 are calculated directly from
the DIPPR database. In the case of minimum process pres- In order to validate the calculation procedure, a compari-
sure below 0.1 MPa, states 7s, 7 and 8 are calculated from son with the software Fluidcal [12] which is based on an
state 9 using ideal gas heat capacity. Otherwise, these states analysis by Lemmon et al. [13] was carried out for toluene
226 U. Drescher, D. Bruggemann / Applied Thermal Engineering 27 (2007) 223228
Table 2
Input and constraints of the screening
Parameter Value or constraint
Melting temperature <275 K
Maximum process temperature <Autoignition temperature
Condenser pressure P5000 Pa or vapor pressure
Condenser temperature P363 K
Dryness at turbine outlet >0.9
Eciency of internal 0.95
heat exchanger
Minimum DT of internal 10 K
heat exchanger (T8T9)
Turbine eciency 0.8
Feed pump eciency 0.8
Maximum process pressure 62 MPa or vapor pressure
and isopentane. Aside from the critical point, relative dis- Fig. 4. Schematic T, S-diagram illustrating the decision pattern for the
crepancies were found to be less than 3% for calculated interaction between vapor pressure and process parameters. The lled
rhomb marks the turbine inlet state without superheating and the triangle
gas and liquid heat capacity and below 1.5% for cycle
with superheating, each at 2 MPa. VP = vapor pressure, con =
eciency. condensation.
4. Screening of uids
Fig. 5 shows the number of substances which reach
Many parameters have to be considered for uid selec- given eciency values with or without internal heat
tion and ORC thermal eciency calculation (Table 2). exchanger. The implementation of a recuperator increases
The two main parameters are maximum and minimum eciency considerably. The eciency of the 100 best-suited
process temperature. The upper limit of the maximum pro- uids ranges from 25.4% to 24.3%. Thus, many uids with
cess temperature is the uid stability and material compat- similar thermal eciencies are available for considering
ibility. These are dicult to evaluate. Typical maximum further criterions.
temperature for existing biomass ORC is about 573 K. As expected, there is a strong relation between eciency
Thus, we analyzed this temperature in detail. In addition, and vaporization temperature (Fig. 6(a)). The highest e-
maximum process temperature was varied from 523 to ciencies were obtained when superheating was avoided
623 K, aware that some uids might not be adequate for and the uid was expanded directly from dew line.
this temperature range. The minimum temperature was According to Fig. 6(b), the eciency rises to approxi-
set to 363 K. If necessary, the condenser temperature was mately 25% at 1 MPa with a slight decrease for higher
raised to make the vapor pressure equal 5000 Pa, the lowest pressures.
pressure accepted for the condenser (Fig. 4). In accordance with the law of corresponding states, u-
The melting temperature should be below ambient tem- ids with low maximum process pressure at maximum
perature. Otherwise the uid may solidify during shutdown
time. For this study, the turbine eciency was xed at 80%,
which is in the typical range from 75% [14] up to 85% [15].
The maximum process pressure was limited to 2 MPa to
reduce safety measures and material expenses [16]. If the
vapor pressure at maximum process temperature was lower
than 2 MPa, the uid was expanded directly from dew line.
Otherwise, the uid was superheated (Fig. 4). In the rare case
of maximum process temperature and pressure being in the
supercritical region of a uid, the maximum process pressure
was reduced by 0.1 MPa below critical pressure and the uid
was superheated. If the adjusted process pressure was below
0.3 MPa, the uid was excluded, because the pressure ratio
in the turbine was too low for ecient power generation.
5. Results
. .
. .
. .
. .
. .
. .
. . . . . .
Fig. 6. Relation between eciency and vaporization temperature (a) and maximum process pressure (b) with Tmax = 573 K and Tmin = 363 K. Triangles
symbolize uids with lower vaporization temperature and maximum process pressure of 2 MPa. Filled rhombs stand for uids with vaporization at
maximum process temperature and corresponding vapor pressure as maximum process pressure.
Table 3
Thermodynamic properties and results of selected uids
h5 h4
Working uid CASN Tc (K) pc (MPa) pmax (MPa) Tvap (K) h6 h3 (%) pmin (kPa) Tcon (K) g (%)
OMTS 107-51-7 564 1.44 1.34 560 15 13.8 363 22.5
Toluene 108-88-3 592 4.11 2.00 536 42 54.1 363 23.2
Ethylbenzene 100-41-4 617 3.61 2.00 570 36 24.3 363 24.3
Propylbenzene 103-65-1 638 3.20 1.41 573 40 11.4 363 24.9
Butylbenzene 104-51-8 661 2.89 0.92 573 43 5.0 364 25.3
228 U. Drescher, D. Bruggemann / Applied Thermal Engineering 27 (2007) 223228