Documente Academic
Documente Profesional
Documente Cultură
AND MICROELECTRONICS
3
1.
INTRODUCTION TO MATERIAL
In this section, we will study the general material concept ;
definition of material, classification, and its simple overview.
4
DEFINITION OF MATERIAL, MATERIAL SCIENCE AND MATERIAL ENGINEERING
Material
Material Science
Material Engineering
5
MATERIAL TYPES [1]
Material can be classified into two types : Engineering material and advanced material. The
classifications can be seen as below :
TYPE OF MATERIAL
ENGINEERING ADVANCED
MATERIAL MATERIAL
Semiconductor
Metal Ceramic
Biomaterial
Composite
Polymer
We will see the explanation of each type of material on the next slide.
6
[2] Source from / Photo credits to http://www.slideshare.net/adhiprimartomo/mme-323-materials-science-week-1-intro-to-materials-science-engineering
MATERIAL TYPES : 1. Metal
Most Utilized Engineering Materials
General properties :
* strength & stiffness high
* toughness & formability high
* electrical & thermal conductivity
high
Usually used in Alloy ( mixed of 2 @ more metals )
Examples : steel, aluminium, magnesium, zinc, copper and nickel
7
MATERIAL TYPES : 2. Ceramic
A compound containing metallic & non-metallic element formed by the action of heat
General properties :
* hard & brittle
* compressive strength high
* resistance to chemical action
and weathering
* thermal insulator high
( thermal conductivity low )
Examples : sand, brick, glass, graphite and tile
8
MATERIAL TYPES : 3. Polymer
Organic compounds, formed by repeating structural unit (Mers), where the atoms
share electron to form very large molecules
General properties :
* light weight
* low thermal & electrical
conductivity
* moderate resistance on Inorganic
Acids, Bases & Salts
Examples : PVC, polyethylene, rubber, and
nylon
9
MATERIAL TYPES : 4. Composite
10
MATERIAL TYPES : 5. Semiconductor
Semiconductors are a special case of electronic material that combines two differently
electrically conductive materials, usually ceramics
A semiconductor is also known as a P-N junction, where one material allows loose electrons to
move through an ordered structure, and the other allows holes (where an electron could be, but
is not) to move in the same way.
This behavior and the interactions between charge carriers and photons and phonons allows
semiconductors to store binary information, form logic gates, and convert between voltage, light,
heat, and force as sensors and emitters
Examples : DVD player, telephone
11
MATERIAL TYPES : 6. Biomaterial
A natural or synthetic material (as a metal or polymer) that is suitable for
introduction into living tissue especially as part of a medical device (as an artificial
joint)
Biomaterials are used in:
* Joint replacements.
* Bone plates & Bone cement.
* Artificial ligaments and tendons.
* Dental implants for tooth fixation.
* Blood vessel prostheses.
* Heart valves.
* Skin repair devices (artificial tissue)
15
WHAT IS SEMICONDUCTOR??
16
WHAT IS SEMICONDUCTOR??
Semiconductor devices can display a range of useful properties such as passing current
more easily in one direction than the other, showing variable resistance, and sensitivity to
light or heat. Because the electrical properties of a semiconductor material can be modified
by doping, or by the application of electrical fields or light, devices made from
semiconductors can be used for amplification, switching, and energy conversion.
Doping greatly increases the number of charge carriers within the crystal. When a doped
semiconductor contains mostly free holes it is called "p-type", and when it contains mostly
free electrons it is known as "n-type". The semiconductor materials used in electronic
devices are doped under precise conditions to control the concentration and regions of p-
and n-type dopants. A single semiconductor crystal can have many p- and n-type regions;
the pn junctions between these regions are responsible for the useful electronic behavior.
17
SEMICONDUCTOR PROPERTIES
-Variable conductivity
-Heterojunction
-Excited Electron
-Light Emission
-Thermal Energy Conversion
18
SEMICONDUCTOR PROPERTIES : Variable Conductivity
19
SEMICONDUCTOR PROPERTIES : Heterojunction
This introduces electrons and holes to the system, which interact via a
process called ambipolar diffusion. Whenever thermal equilibrium is
disturbed in a semiconducting material, the amount of holes and
electrons changes.
The process that creates and annihilates electrons and holes are
called generation and recombination.
.
21
SEMICONDUCTOR PROPERTIES : Light Emission
22
SEMICONDUCTOR PROPERTIES : Thermal Energy Conversion
Semiconductors have large thermoelectric power factors making them useful in thermoelectric
generators, as well as high thermoelectric figures of merit making them useful in thermoelectric
coolers.
Figure 10 : Energy Bandgap in Materials [6] Figure 11 : Properties of semiconductor types [7]
Intrinsic
Semiconductor
and
Extrinsic
Semiconductor
24
SEMICONDUCTOR TYPE : Intrinsic Semiconductor
25
SEMICONDUCTOR TYPE : Intrinsic Semiconductor
In an intrinsic semiconductor such as silicon at temperatures above absolute
zero, there will be some electrons which are excited across the band gap into
the conduction band and which can support charge flowing.
When the electron in pure silicon crosses the gap, it leaves behind an electron
vacancy or "hole" in the regular silicon lattice. Under the influence of an
external voltage, both the electron and the hole can move across the material.
26
SEMICONDUCTOR TYPE : Intrinsic Semiconductor
27
SEMICONDUCTOR TYPE : Extrinsic Semiconductor
An extrinsic semiconductor is one that has been doped, giving it different electrical properties than
the intrinsic (pure) semiconductor. This doping involves adding dopant atoms to an intrinsic
semiconductor, which changes the electron and hole carrier concentrations of the semiconductor
at thermal equilibrium, the temperature at which two adjacent substances exchange no heat energy.
Donor impurity atoms have more valence electrons than the atoms they replace in the intrinsic
semiconductor lattice. Donor impurities "donate" their extra valence electrons to a semiconductor's
conduction band, providing excess electrons to the intrinsic semiconductor. Excess electrons
increase the electron carrier concentration (n0) of the semiconductor, making it n-type.
Acceptor impurity atoms have fewer valence electrons than the atoms they replace in the intrinsic
semiconductor lattice. They "accept" electrons from the semiconductor's valence band. This provides
excess holes to the intrinsic semiconductor. Excess holes increase the hole carrier concentration (p0)
of the semiconductor, creating a p-type semiconductor.
28
SEMICONDUCTOR TYPE : Extrinsic Semiconductor
EXTRINSIC SEMICONDUCTOR
N-type P-type
p-type semiconductors have a larger hole concentration than
N-type semiconductors have a larger electron concentration
electron concentration.
than hole concentration.
The term p-type refers to the positive charge of the hole. In p-
The term n-type comes from the negative charge of the
type semiconductors, holes are the majority carriers and
electron. In n-type semiconductors, electrons are the majority
electrons are the minority carriers.
carriers and holes are the minority carriers.
P-type semiconductors are created by doping an intrinsic
N-type semiconductors are created by doping an intrinsic
semiconductor with acceptor impurities (or doping an n-type
semiconductor with donor impurities (or doping a p-type
semiconductor).
semiconductor as done in the making of CMOS chips).
A common p-type dopant for silicon is boron. For p-type
A common dopant for n-type silicon is phosphorus. In an n-
semiconductors the Fermi level is below the intrinsic Fermi
type semiconductor, the Fermi level is greater than that of the
level and lies closer to the valence band than the conduction
intrinsic semiconductor and lies closer to the conduction band
band.
than the valence band
29
SEMICONDUCTOR TYPE : Extrinsic Semiconductor
Figure 13 :
30
SEMICONDUCTOR TYPE : Extrinsic Semiconductor
USES OF EXTRINSIC SEMICONDUCTOR
1. A semiconductor diode (devices that allow current in only one direction) consists of p-type and n-
type semiconductors placed in junction with one another. Currently, most semiconductor diodes use
doped silicon or germanium.
33
3.
SEMICONDUCTOR MATERIAL
In this section, we will learn about the general semiconductor
material concepts .
34
WHAT IS SEMICONDUCTOR MATERIAL??
Because of their application in the computer and photovoltaic industry, in devices such as
transistors, lasers and solar cells, the search for new semiconductor materials and the
upgrading of existing materials is an important field of study in materials science.
Most commonly used semiconductor materials are crystalline inorganic solids. These
materials are classified according to the periodic table groups of their basic atoms.
35
SEMICONDUCTOR MATERIAL CLASSIFICATION
Semiconductor Material
36
SEMICONDUCTOR MATERIAL: Single Semiconductor
A semiconductor is a substance whose electrical conductivity lies between that of a conductor like
copper or aluminum and an insulator like rubber or glass.
It can conduct electricity under some conditions but insulate electricity under other conditions. Of the
92 elements existing on the earth, only several elements, including silicon (Si), germanium (Ge) and
selenium (Se), can behave as semiconductors.
Si Ge Se
37
SEMICONDUCTOR MATERIAL: Single Semiconductor ; Si
Silicon is the most widely used type of semiconductor material.
One of the prominent German scientists wrote in an article about silicon that this
era is the silicon era since silicon impacted and still affecting the modern
civilization development very much.
Each has four valence electrons, but germanium will at a given temperature have
more free electrons and a higher conductivity.
Silicon is by far the more widely used semiconductor for electronics, partly
because it can be used at much higher temperatures than germanium.
38
SEMICONDUCTOR MATERIAL: Single Semiconductor ; Si
Advantages and Disadvantages of Si are :
Advantages Disadvantages
Easy to fabricate Performance degrades badly at high
temperatures
Forms high quality silicon oxide that is Electron hole mobility in silicon is very
used for insulation layers between poor, and this is a barrier to higher
different active elements of the IC performance
Abundantly available in earth's crust so
its easily available resulting in low cost
39
SEMICONDUCTOR MATERIAL: Single Semiconductor ; Ge
In solid state electronics, either pure silicon or
germanium may be used as the intrinsic semiconductor
which forms the starting point for fabrication.
Advantages Disadvantages
Requires lower purity Low stable temperature
40
SEMICONDUCTOR MATERIAL: Compound Semiconductor
In contrast to a semiconductor composed of a single element, one composed of two or more elements is
called a compound semiconductor.
Typical examples of compound semiconductors include gallium arsenide (GaAs), gallium nitride (GaN),
indium phosphide (InP), zinc selenide (ZnSe), and silicon carbide (SiC).
41
SEMICONDUCTOR MATERIAL: Compound Semiconductor
42
SEMICONDUCTOR MATERIAL: Compound Semiconductor ; GaAs
Gallium arsenide is the second most widely used type of semiconductor after silicon.
It is widely used in high performance RF devices where its high electron mobility is utilized.
It is also used as substrate for other III-V semiconductors, for example InGaAs and GaInNAs.
Advantages Disadvantages
Six times higher electron mobility than Brittle and expensive
silicon which allows faster operation
Wider band gap, which allows operation of Insulation layers can not be created by just
power devices at higher temperatures growing an oxide layer
Gives lower thermal noise to low power Has a lower hole mobility than Silicon
devices at room temperature
Its direct band gap gives it more favorable Has high leakage current
optoelectronic properties
Can be alloyed to ternary and quaternary
compositions
43
SEMICONDUCTOR MATERIAL: Compound Semiconductor ; SiC
Also known as carborundum is a compound of silicon and carbon with chemical formula SiC.
It occurs in nature as the extremely rare mineral moissanite.
Silicon carbide powder has been mass-produced since 1893 for use as an abrasive
SiC is used in semiconductor electronics devices that operate at high temperatures or high voltages, or both
Advantages Disadvantages
SiC can carry much higher currents High cost
(almost 5 times) compared to silicon
SiC has a much higher thermal
conductivity (roughly 3 times) compared to
silicon.
Has a higher energy band gap
44
SEMICONDUCTOR MATERIAL: Compound Semiconductor ; InAs
Indium arsenide, InAs, or indium
monoarsenide, is a semiconductor
composed of indium and arsenic.
Advantages
Narrow energy bandgap
45
Figure 16 : A list of all common semiconductor materials
46
SEMICONDUCTOR MATERIAL: Comparisons of common material used
The silicon (Si) is most widely used material in semiconductor devices. Its
having lower raw material cost and relatively simple process. Its useful temperature
range makes it currently the best compromise among the various competing materials.
Silicon used in semiconductor device manufacturing is presently fabricated into bowls
that are large enough in diameter to allow the manufacture of 300 mm (12 in.) wafers.
Germanium (Ge) was a widely used in early semiconductor material, but its
thermal sensitivity makes less useful than silicon. Nowadays, germanium is often
alloyed with (Si) silicon for use in very-high-speed SiGe devices; IBM is a main
producer of such devices.
47
4.
TECHNOLOGY FROM
SEMICONDUCTOR MATERIAL
Let us see few examples of the devices formed by the
semiconductor material, and the relationship between it with
microeletronics.
48
SEMICONDUCTOR TECHNOLOGY: Application Devices
Semiconductor materials and devices have become ubiquitous in our daily lives, enabling modern home
appliances, toys, computing and communication devices, transportation systems, and medical equipment.
There are various application devices formed by the semiconductor, but in our discussions, we will show
some examples of them. The list of common semiconductor devices mainly includes two terminals, three
terminals and four terminal devices.
The two-terminal devices are Three-terminal devices are Four-terminal devices are
Diode (rectifier diode) Bipolar transistor Photo couple (Optocoupler)
Gunn diode Field-effect transistor Hall effect sensor (magnetic field
IMPATT diode Darlington transistor sensor)
Laser diode Insulated-gate bipolar transistor
Zener diode (IGBT)
Schottky diode Unijunction transistor
PIN diode Silicon-controlled rectifier
Tunnel diode Thyristor
Light-emitting diode (LED) TRIAC
Photo transistor
Photocell
Solar cell
Transient-voltage-suppression diode
VCSEL
50
SEMICONDUCTOR TECHNOLOGY: Application Devices
SCHOTTKY DIODE [11] LIGHT EMITTING DIODE (LED) [12] QUANTUM DOT [13]
it is a semiconductor diode with a The LED is a light source which uses Quantum dots (QD) are very
very fast switching action, but a low semiconductors&electroluminescence small semiconductor particles,
forward voltage drop. to create light. There are two major only several nanometres in size,
Schottky diodes are used for the kinds of light emitting diodes: LED so small that their optical and
voltage clamping applications and and OLED. electronic properties differ from
prevention of transistor saturation LED lamp is popular due to it's those of larger particles.
due to the high current density in efficiency and many believe it is a They are a central theme
that diodes. They are also used as 'new' technology. It is commonly used in nanotechnology.
rectifiers in power supplies. as indication lights on devices, small Many types of quantum dot will
Schottky diodes are used in many and large lamps, traffic lights, large emit light of specific frequencies
applications compare to other types video screens, signs, street if electricity or light is applied to
of diodes that do not perform well. lighting(although this is still not them, and these frequencies can
The features of Schottky diode widespread) be precisely tuned by changing
mainly include the following The Organic LED is made of a layer of the dots' size, shape and
Higher efficiency organic electroluminescent material material, giving rise to many
Low forward voltage drop with p/n junction sandwiched between applications.
Low capacitance to electrodes. It is commonly used as
Low profile surface-mount Lamps - short distance indoor lamps
package, ultra-small (produces a diffused light)
Integrated guard ring for stress Displays - small: phones and media
protection devices and large: televisions,
computer monitors
semiconductor packages
And
Below are some abbreviated definitions, meant to gain some common understanding before diving in further:
SMT (Surface Mount Technology) examples include a Hybrid Microelectronics multiple ICs/packages
motherboard in a PC, or an FR4 board with ICs, resistors, incorporated into a space-saving package. This can
and capacitors reflow soldered making a completed include SMT and semiconductor technologies and
electronic product. The number of products built with this can be very complexmixed technologies that allow
technology is staggeringly large. for powerful and/or small final products. The number
of products built with this technology is small
compared to SMT and semiconductor packaging,
Semiconductor consider lead frame packages but it is a growing market.
with a single IC that is die-attached, wire-bonded,
and over-molded. These packages are made by the
millions, can be surface mounted, and soldered into
through hole substrates/FR4 boards. The number
of products built with the technology is staggeringly
large.
53
RELATIONSHIP BETWEEN SEMICONDUCTOR AND
MICROELECTRONICS
While SMT technology generally incorporates semiconductor products, semiconductor
products do not typically include SMT components.
Microelectronics can incorporate both, and the result is smaller and usually
faster final products.
Just as SMT technologies incorporate semiconductor packages but rarely the other way
around, microelectronics can incorporate both semiconductor and SMT technologies
to create complex packages and products.
WELL, can you see the relationship between semiconductor and microelectronics now?
54
CREDITS
Special thanks to all the people who made and released these
awesome references and sources:
https://en.wikipedia.org/wiki/List_of_semiconductor_materials
http://www.radio-electronics.com/info/data/semicond/semiconductor/semiconductor-
materials-types-list.php
http://phys.org/news/2015-08-silicon-limits-power-electronics-revolution.html
http://www.testandmeasurementtips.com/why-silicon-and-germanium-are-
semiconductors/
http://www.anvil-semi.co.uk/advantages-of-silicon-carbide-in-power-electronics/
http://ieeexplore.ieee.org/document/1021562/
55