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DISAMBIGUOUS OUTLINE
Please note the differences between the British English (UK, European
countries) and American English (North America, Thailand) usages of some
terms
INTRODUCTION
Component of Asphalt Oils Resins Asphaltenes
Carbon
Sources of Asphalt 0.6 0.8
Hydrogen
5 6
S OU R C E S O F A S P H A L T S OU R C E S O F A S P H A L T
1. Native Asphalt or Natural Asphalt they are asphalt materials found in 2. Tar it is a liquid by-product from the distillation of coal to make coke
natural states. Only few native sources in the world can produce enough (which is used as smokeless fuel in stove or blast furnace). The use of
asphalt to have economical importance. tar (mostly in the UK) has been declined dramatically because its vapor
Asphalt Lake The area may be the bottom of a lake in prehistoric times. was found to cause cancer
Asphalt may be separated or mixed with water.
Tar Pit (e.g. Rancho La Brea Tar Pit in Los Angeles)
Rock Asphalt Asphalt impregnated within sedimentary rocks (limestone,
shale, or sandstone). Usually used by crushing the rock and asphalt
together.
Source: Wikipedia
Higher Temperature
Source: Wikipedia
11 12
TYPES OF ASPHALT PRODUCTS
13 14
15 16
GRADES OF ASPHALT CEMENT GRADES OF ASPHALT CEMENT
Asphalt cement can be manufactured to have different consistency or fluidity A different consistency can be achieved by 2 means
from hard to soft Lower the temperature during the distillation to get more oils in the residue
Why do we need different consistencies of asphalt? softer asphalt
Softer asphalt is suitable to colder climate to avoid excessive brittleness during Diluting (fluxing) some lighter oils with asphalt cement (not good)
winter
Harder asphalt is suitable to hot climate as to avoid softening in summer
Asphalt that is too soft will not provide uniform film to bind all the aggregates Asphalt cement is primarily graded by its consistency using one of these
Asphalt that is too hard is difficult to mix and the resulting mixture will be systems:
nonuniform Penetration (in unit of 0.1 mm) this is the oldest and most popular grading of
asphalt cement
Absolute Viscosity (in poise)
Kinematic Viscosity (in stoke)
Too hard asphalt may crack Too soft asphalt may deform
17 18
Penetration (ASTM D 5) is an measure of hardness/softness of asphalt cement by Viscosity is a more direct measurement of the fluidity of asphalt cement
dropping a standard needle to an asphalt surface for 5 sec at temperature of 25 C Measured by counting the time it takes for a standard amount of hot asphalt (in liquid
state at standard temperature) to flow through a standard orifice
Absolute viscosity has the unit of poise (g /cm /sec)
Kinematic viscosity has the unit of stoke (cm2/sec) or centistoke (0.01 cm2/sec = 1
mm2/sec)
Absolute viscosity (ASTM D 2171) and kinematic viscosity (ASTM D 2170) differ by
the type of viscometer used but can be related (for the same test temperature).
Absolute Viscosity
Kinematic Viscosity =
Density of Asphalt Cement
Penetration Distance Drop (in mm) 10
The density of AC is about 1 g/cm3. Therefore, absolute viscosity in poise is
Higher value indicates softer asphalt Source: http://www.soiltest.com
approximately numerically equal to kinematic viscosity in stoke
Common penetration grades are AC 40-50, AC 60-70, AC 70-80, AC 80-100,
AC 120-150 (example: AC 60-70 has the penetration between 60 and 70) Higher viscosity value means that the asphalt does not flow well (i.e. harder
asphalt)
This grading has been used for a very long time
There is a trend to substitute the penetration with viscosity grading system
19 20
PROPERTIES & TESTS AC SPECIFICATIONS
Standard Specifications:
. . 401/2531
. 851-2542
ASTM D 946 Standard Specifications for Penetration-Graded Asphalt Cement
for Use in Pavement Construction
21 22
Temperature we need to make it sufficiently Softening Point Test (ASTM D 36, E 28)
soft In ductility test, we pull the sample of AC
Maximum temperature that we can heat it Flash Point Test (Cleveland Open-Cup or apart in a temperature-controlled bath and see
without catching fire Pensky-Marten Closed Tester) (ASTM D how much it can stretch without breaking, the
92, 93) higher the better.
How much impurities there are Solubility Test (ASTM D 4, D 2042)
In softening point test, we use ring and ball apparatus. The
How much volatile constituents are Loss on Heating (ASTM D 6), Thin-Film
softening point is defined as the temperature at which the asphalt
presented Oven Test (ASTM D 1754)
sample in the ring becomes soft enough that the asphalt stretches
Specific Gravity and Density Specific Gravity Test (ASTM D 70) to the reference plate under the weight of the metal ball
23 24
PROPERTIES & TESTS
Cutback asphalt is a liquid asphalt product. It is obtained by diluting asphalt Since cutback asphalt is obtained by mixing asphalt cement with solvents, it is
cement in volatile oils. therefore classified based on the solvent used
It is liquid at room temperature so it can be sprayed and mixed easily Rapid Curing (RC) use gasoline as solvent + low-penetration AC
The solvent (oils) will eventually evaporated, leaving the asphalt cement on Medium Curing (MC) use kerosene as solvent + higher-penetration AC
the road Slow Curing (SC) use heavy oils as solvent + very high-penetration AC
Due to the pollution and health risk of the evaporation solvent, cutback or obtained directly from the distillation by cutting off early to get
asphalt is no longer permitted in the USA, but it is still in use in many parts residue + heavy oils
of the world, including Thailand.
The choice of curing rate depends on:
Solvent The time desired for curing
Room The penetration grade of the finished pavement (after solvent has
Temperature Evaporation evaporated); for example, MC will result in softer finished pavement
Cutback Mixer or Asphalt compared with RC due to the higher-penetration AC used, which is good
Compact
Asphalt Sprayer Cement for colder climates)
on Road
27 28
GRADES OF CUTBACK ASPHALT GRADES OF CUTBACK ASPHALT
For each type, the cutback asphalt is graded by kinematic viscosity (in
centistoke = 0.01 stoke) or Saybolt-Furol viscosity (ASTM D 88) (in
seconds; 1 SSF = 0.02 stoke)
Different viscosity is obtained by changing the amount of solvent
Common grades are RC-70, RC-250, RC-800, RC-3000, MC-30, MC-70
(example: RC-70 has kinematic viscosity between 70 and 140, MC-30 has
kinematic viscosity between 30 and 60 etc)
The choice of viscosity depends on
Application (spraying requires lower viscosity)
Aggregate used (smaller aggregates requires lower viscosity)
Cost (lower viscosity requires more solvent and cost more but it
requires less heat which saves the fuel cost)
Saybolt Furol Viscosity Test
29 30
EMULSIFIED ASPHALT
Emulsified Asphalt
The distillation test is used to see Emulsifier
how much asphalt cement there is. Grades of Emulsified Asphalt
After the test, we can perform tests,
Properties & Tests
such as penetration and ductility, on The flash point test using
the asphalt residue as well the tag open cup is similar
to the cleveland open cup.
35 36
EMULSIFIED ASPHALT EMULSIFIER
Emulsified Asphalt or Asphalt Emulsion is a liquid asphalt product. It is a The emulsifier is a long
colloidal mixture obtained by mixing asphalt cement in water, with the help hydrocarbon chain with ionic
of the emulsifier. part at the end
It is liquid at room temperature so it can be sprayed and mixed easily The hydrocarbon end attached
The water will eventually evaporated, leaving the asphalt cement on the road to the asphalt particle
It is an alternative to cutback asphalt The ionic end has an affinity for
water
The same ions repel each other,
allowing the asphalt particle to
Water
suspend in water without
Room sticking to each other
Temperature Evaporation
Emulsified Mixer or Compact Asphalt
Asphalt Sprayer Cement
on Road
Since Emulsified Asphalt is obtained by mixing the asphalt cement with For each type, the emulsified asphalt is graded by kinematic viscosity (in
water and emulsifier, they are graded by the types of emulsifier. centistoke = 0.01 stoke) or Saybolt-Furol viscosity (ASTM D 88)
Anionic Emulsions the asphalt cement particle has negative (-) charge Common grades are: CRS-1, CRS-2, CMS-2, CSS-1
(good for limestone aggregate, which has positive charges)
Rapid Setting (RS)
Medium Setting (MS)
Flow
Slow Setting (SS) Easily
Saybolt-Furol Second Grade
Cationic Emulsions the asphalt cement particle has positive (+) charge
15-30 0
(good for silica aggregate, which has negative charges)
Rapid Setting (CRS) 40-80 1
Other relevant tests for Emulsified Asphalt In the water content test, the emulsified is heated in a
Property to be Measured Test Method
closed container. The water will evaporate, condense in a
condenser, and be collected in the trap. The water content
Fluidity (or consistency) Viscosity Tests (ASTM D 88, 2170, 2171)
is the percentage of the total water collected to the
Amount of water presented Water Content Test (ASTM D 244)
original weight of sample.
Amount of asphalt cement Distillation (ASTM D 6997), Residue by
Evaporation (ASTM D 6394)
Fluidity (or consistency) of residue Penetration Test (ASTM D 5),Viscosity Tests
How much impurities there are in the residue Solubility Test (ASTM D 4, D 2042) In particle charge test,
How well it can coat aggregate and withstand Coating Ability and Water Resistance (ASTM D electrodes are inserted into
washing of water 244) the liquid asphalt. If it is a
How well asphalt residue can bind aggregate Ductility Test (ASTM D 113) cationic emulsified asphalt
How fast the emulsified asphalt will set Demulsibility Test (ASTM D 6936), Cement-Mixing (positive charge), the asphalt
Test (ASTM D 6935), Silica Sand Coating Test particles will adhere to the
(ASTM D 244) cathode (negative side).
How well it withstand the addition of water Miscibility in Water Test (ASTM D 6999) There will be nothing on the
Stability during storage Sieve Test (ASTM D 6933), Settlement Test (ASTM anode side.
D 244), Freezing Test (ASTM D 244)
41 42
43 44
PROPERTIES & TESTS SUMMARY PROPERTIES & TESTS SUMMARY
45 46
Advantages Disadvantages
Asphalt Strong and durable Require high heat to mix
Cement Must use with dry aggregates ASPHALT MIXTURES
Cut-Back Does not require high heat to use Highly flammable Types of Asphalt Pavement
Asphalt Evaporated fume is toxic Applications in Pavement
Solvent can be expensive
Must use with dry aggregates Required Properties of Pavement
Emulsified Does not require high heat to use Can be washed off by rain quite Asphalt Concrete Mixture
Asphalt easily
Use with wet or dry aggregates Marshall Method
Less toxic
Non-flammable Manufacturing
47 48
TYPES OF ASPHALT PAVEMENTS TYPES OF ASPHALT PAVEMENTS
There are many types of asphalt pavement construction, ranging from low- Hot Mix Asphalt Concrete
cost, lightly traveled roads to heavily traveled highways. We first consider 2
extremes of asphalt construction, hot-mix asphalt concrete (or just
asphalt) and macadam.
Macadam
Source: Illston and Domone (2001) 49 Source: Illston and Domone (2001) 50
Macadam uses asphalt just enough to coat aggregates and provide adhesion.
Dense-graded aggregate is needed for strength. It is porous and not very
durable, but cheaper because it needs only little asphalt. It is generally used
for lightly traveled roads.
In typical asphalt pavement, the road structure has several layers, each Asphalt Cement (Hot-Mixed or Liquid Asphalt (Cutback or
having a specific function. Different asphalt products and different Hot-Rolled Asphalt) Emulsified)
mixtures are used for different layers. Wearing surface of new road Patching of minor surface
construction damages
Wearing Course Resurfacing or overlaying of Surface Dressing
Surfacing existing road Tack Coat - to provide adhesion
Basecourse Surface Dressing hot asphalt is between old and new layers
Asphalt Materials sprayed over compacted base, Prime Coat to prepare (base)
Roadbase followed by a layer of graded surface for new asphalt layer
crush stone, and then rolled Slurry Seal
together. Another layer may be
put on top. Soil Stabilization
Sub-Base
Foundation Granular Materials Patching of surface damages
Capping
Subgrade Soil
Typical Pavements
53 54
Generally, hot-mix asphalt concrete mixture consists of asphalt cement (AC Required properties of the pavement are:
60/70 or AC 80/100 are most common), fine aggregate (sand), and coarse
aggregate (crushed limestone) Stability is the strength of the pavement to resist deformation under
The quality and proportion of each of these components plays an important traffic load. It comes from aggregate interlocking and asphalt cohesions
role in the property and durability of the finished asphalt pavement Durability is the resistance of the pavement against disintegration either
by weathering of asphalt or mechanical breakdown of aggregate.
Flexibility is the ability to withstand deformations without cracking
Skid Resistance is the ability of the pavement to provide long-lasting
nonskid surface. Pavement bleeding and aggregate polishing is the two main
sources of slippery surface
Source: Wikipedia
55 56
ASPHALT CONCRETE MIXTURE MIXTURE PROPORTIONING
Compromise is needed for the property of asphalt, aggregate, and the Factors affecting asphalt concrete pavement are:
amount of air voids in the asphalt mixture Quality of Asphalt Binder
Quality of Aggregates (gradation, strength, texture, shapes, etc)
Construction Processes
Property Asphalt Aggregate Air Void Mixture Proportions
Stability Just enough to coat Angular shapes
the aggregate Rough texture We want to know the optimum content of asphalt for a given type and
Dense graded gradation of aggregate, and the asphalt cement used to provide the best
Durability Need a lot of asphalt Need minimal air void stability, durability, flexibility, and skid resistance
to coat the aggregate to prevent oxidation
and completely fill and entrance of water
There are several methods developed. Some of the more popular mix-
out the voids
design methods are:
Flexibility Open graded
Hubbard-Field (Asphalt Institute)
Skid Resistance Just enough to coat Aggregate containing Need some void Marshall (U.S. Army Corps of Engineer)
the aggregate many minerals in it space to prevent
bleeding Stabilometer or Hveem (California Highway Department)
57 58
Source: http://www.soiltest.com
Mold
Source: http://www.soiltest.com
Hammer Source: http://www.soiltest.com
Source: http://www.soiltest.com
Breaking Head
Marshall Stability Testing Machine
59 60
MARSHALL METHOD MARSHALL METHOD
61 62
It can be seen that the optimum asphalt content for density and stability are
NOT the same so we generally average them to get the design asphalt
content. We read the flow from the flow curve.
Source: Illston and Domone (2001) 65 Source: Illston and Domone (2001) 66
Flow
increases as
asphalt
content
increases
MANUFACTURING MANUFACTURING
Continuous Plant produce asphalt mixture continuously
The choice of mixing process depends on:
The hot asphalt is mixed Production Capacity (Continuous plant is good for large production of
with the heated aggregate
one material specification whereas Batch plant is good for small
in the final portion of the
productions of different mix proportions)
drum
DETERIORATION OF ASPHALT
Design Life of Pavement
Failure Modes
Deterioration of Surface
Deterioration of Structure
Preventions
Remedies
Source: Illston and Domone (2001)
73 74
The failure of asphalt pavement is a little tricky to define because when the The asphalt may fail in one of the two main forms
pavement fails it does not collapse Deterioration of Road Surface the damages occur at the top of the
So we define failure in terms of serviceablity (ability to service) or wearing course (top layer) of the pavement
repairability (ability to repair vs. rebuilt) Bleeding of asphalt
Examples of criteria Breakdown of surface materials
Riding Comfort (surface too rough, uneven surface, excessive noise) Polishing of surface
Safety of Drivers on the road (slippery road, potholes) Fuel spillage
Crack widths Deterioration of Road Structure the damages occurs on the pavement as
Permanent deformations a whole
Permanent Deformation
Fatigue Cracking
75 76
DETERIORATION OF SURFACE DETERIORATION OF SURFACE
Low Temperature Crack this occurs Structure failures consists of two main types
in cold climates when the asphalt is too Permanent Deformation
hard. When the asphalt shrinks under Fatigue Failure
low temperature, it cannot deform
enough, so it cracks.
Source: www.asphaltwa.com
PREVENTIONS REMEDIES
To prevent or delay the failure, the followings must be done: When the pavement has deteriorated, we need to do some maintenances.
Use of strong and durable aggregates The maintenance of roads may fall into one of these categories:
Use asphalt binder with grade suitable for the geographical area to
prevent cracking Patching
Control maximum temperature during mixing to prevent excessive It is the repairs of potholes and minor damages
evaporation of lighter constituents, which may result in premature
hardening Surface Treatments
Control maximum air voids in the mix to prevent water permeation and It is the application of liquid asphalt onto small sized stone on the
oxidation existing surface
Control minimum air voids to prevent bleeding and slippery surface To improve skid resistance or prevent further deterioration of the
Control the amount of asphalt in the mix (not too low and not too existing pavement
high) We do this when the structure of the pavement is still OK
Also known as Surface Dressing, Chip Seal, Slurry Seal, etc
83 84
REMEDIES MODIFIED ASPHALT
Pavement Resurfacing / Overlay In recent years, modified asphalt material has becoming more popular.
This involves the laying of the new surface layer (usually hot rolled Additives are added to the asphalt binder for the purpose of:
asphalt) either after removal of the existing surface or on top (overlay) Improve durability (reduce oxidation)
May be laid on top of existing asphalt surface or concrete surface Increase stability/ stiffness / fatigue resistance
Restore ride quality, skid resistance, and road profile Improve aggregate adhesion
Improve workability/ viscosity/ ductility
To prevent further deterioration of the existing pavement
Improve elasticity/ reduce permanent deformation
Also increase the strength of the pavement due to increase thickness
Reduce bleeding
Usually the most cost-effective method Reduce fuel and oil damage
Dosage varies from less than 1% of the total mix to more than 20%,
Reconstruction depending on the additive
This involves the removal of the construction depth and construct a Examples: tar, gilsonite, carbon black, sulfur, ethylene vinyl acetate,
newly designed pavement polyethylene, polypropylene, natural rubber, styrene-butadiene rubber-
Only used at the end of service-life or when overlay is not possible synthetic latex, styrene-butadiene-styrene, manganese catalyst, epoxy-resin,
etc
85 86
RECAP REFERENCES
Introduction Properties & Tests ASTM (1996), Annual Book of ASTM Standards, West Conshohocken, PA.
Components of Asphalt Ductility, Solubility, Softening Point, Atkinson, K. (1990), Highway Maintenance Handbook, Thomas Telford, London,
Flash Point, Loss on Heating, 460 pp.
Sources of Asphalt
Distillation, Solubility, Miscibility, Hunter, R. N. (2000), Asphalt in Road Construction, Thomas Telford, London, 563
Natural, Tar, Petroleum
etc pp.
Applications Asphalt Mixture
Types Illston, J. M., and Domone, P. L. J. (2001), Construction Materials Their Nature and
Properties Required Behavior, 3rd Edition, Spon Press, London.
Asphalt Cement Design Methods
Cutback Asphalt Marshall Design Method Krebs, R. D. and Walker, R. D. (1971), Highway Materials, McGraw Hill, New York
Emulsified Asphalt Applications http://www.asphaltwa.com
Grading of Asphalt Deterioration of Asphalt & http://www.doh.go.th
Prevention
Penetration
Causes of Failure
Kinematic, Absolute, and Saybolt-
Prevention
Furol Viscosity
Remedies
Curing Rate (Cutback), Setting
Rate (Emulsified) Modified Asphalt Products
87 88