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ORGANIC CHEMISTRY

TARGET : JEE (MAIN) 2017


Course : ABHINAV (EA) Date : 04-05-2015 NO. 01

TEST INFORMATION

DATE : 31.05.2015 PART TEST-1 (PT-1) (MAIN)

Syllabus : IUPAC nomencalture of non-chain terminating Functional group.

This DPP is to be discussed in the week (04-05-2015 to 09-05-2015)


DPP No. # 01
Total Marks : 60 Max. Time : 42 min.
Single choice Objective ('1' negative marking) Q.1 to Q.18 (3 marks, 2 min.) [54, 36]
Fill in the Blanks ('1' negative marking) Q.19 to 20 (3 marks, 3 min.) [06, 06]

1. Common valency of carbon is :


dkcZu dh lkekU; la;kstdrk gS %
(1) 1 (2) 2 (3) 3 (4*) 4

2. A double bond consists of :


,d f}cak esa gksrs gS %
(1) 1 and rFkk 2 (2) 2 (3*) 1 and rFkk1 (4) 2

3. C C bond length is minimum in :


fuEu esa ls fdl esa C C cak yEckbZ lcls de gS \

(1*) CH3 CH3 (2) CH2= CH2 (3) CH CH (4)

4. How many and bond are present in (cyclobutadiene) ?


(1*) 8 , 2 (2) 3 , 3 (3) 2 ,4 (4) 4 , 2
lkbDyksC;wVkMkbZu esa fdrus rFkk cU/k mifLFkr gSa \
(1*) 8 , 2 (2) 3 , 3 (3) 2 ,4 (4) 4 , 2

5._ How many and bonds are present in CH3COOH :


(1) 1, 7 (2) 5, 2 (3*) 7, 1 (4) 3, 2
CH3COOH esa fdrus rFkk cU/k mifLFkr gSaA
(1) 1, 7 (2) 5, 2 (3*) 7, 1 (4) 3, 2

6. How many and -bonds are there in tetracynoethylene (CN)2C = C(CN)2 molecule.
VsVk lk;uks,Fkhyhu (CN2)C = C(CN)2 v.kq esa fdrus rFkk -cU/k gSA
(1*) 9, 9 (2) 9, 7 (3) 5, 9 (4) 5, 7

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7. Arrange the following molecules in increasing order of to bond ratio :
fuEu v.kqvksa dks rFkk ca/k vuqikr ds c<+rs gq, e esa O;oLFkhr dhft,A

(i) (ii) (iii) (iv)

(1) ii < iii < iv < i (2) ii < iv < iii < i (3*) iii < ii < i < iv (4) ii < iii < i < iv

4 19
Hint : 12 , 3, = =4 ; 19, 5, = = 3.8
1 5

26 25
26 , 7, = = 3.7 ; 25, 6, = = 4.166
7 6

8. Number of hydrogen atoms in the given compound is :


fn;s x;s ;kSfxd esa gkbMkstu ijek.kqvksa dh la[;k gSA

(1) 8 (2) 10 (3*) 12 (4) 14


9. Ketene CH2 = C = O has
(1) Only sp2 carbon atom (2) Only sp carbon atom
(3*) sp2 and sp carbon atoms (4) sp3, sp2 and sp carbon atoms
dhVhu CH2 = C = O esa gS %
(1) dsoy sp2 dkcZu ijek.kq (2) dsoy sp dkcZu ijek.kq
(3*) sp2 rFkk sp dkcZu ijek.kq (4) sp3, sp2 rFkk sp dkcZu ijek.kq
10. Which of the following is not an unsatrurated compound.
fuEu esa ls dkSulk ;kSfxd vlar`Ir ugha gSA
(1) CH3 CH = CH CH3 (2) HC C C CH

(3*) CH3 CH2 CH2 (4) CH2 = CH CH = CH2

11. Which of the following is homocyclic compound.


fuEu esa ls dkSulk ;kSfxd lepf; gSA

(1) (2) (3) (4*)

12. The incorrect options for a homologous series


(1) All members have same general formula (2) All members have same chemical properties
(3*) All members have same physical properties (4) All members have same functional groups
ltkrh; Js.kh ds fy, dkSulk fodYi vlR; gS\
(1) lHkh lnL; dk lkekU; lw=k leku gksrk gSA (2) lHkh lnL;ksa ds jklk;fud xq.k leku gksrs gSaA
(3*) lHkh lnL;ksa ds HkkSfrd xq.k leku gksrs gSaA (4) lHkh lnL;ksa ds f;kRed lewg leku gksrs gSaA

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13. Total number of 1 hydrogen atom in following compound :
fuEu ;kSfxd esa 1 gkbMkstu ijek.kqvksa dh dqy la[;k gksxh %

(1) 6 (2) 9 (3) 12 (4*) 18

14. Which of the following alkanes contains primary, secondary, tertiary and quaternary carbon atoms together?
fuEu esa ls fdl ,Ydsu esa izkFkfed] f}fr;d r`rh;d vkSj prq"d dkcZu ijek.kq mifLFkr gS \
(1) (CH3)3CH (2) (C2H5)3CH (3*) (CH3)3CCH2CH(CH3)2 (4) (CH3)4C

15. Number of secondary carbon atom are present in the compound ?


;kSfxd esa fdrus f}rh;d dkcZu ijek.kq mifLFkr gS \

(1) 7 (2) 8 (3*) 9 (4) 10

16. Number of 3 and 2 carbon atoms in the following compound are.


fuEu ;kSfxd esa 3 vkSj 2 dkcZu ijek.kqvksa dh la[;k gSaA

(1) 7, 8 (2) 6, 9 (3) 6, 8 (4*) 8, 9

Sol.

* = 3carbon, = 2carbon

17. Which of the following is saturated hydrocarbon?


fuEu esa ls dkSulk lar`Ir gkbMksdkcZu gSA

(1) (2) (3) (4*)

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18. An organic compound has molecular formula C9H18. Its all carbon atoms are sp3 hybridised and its all
hydrogen atoms are identical. Its structural formula can be :
,d dkcZfud ;kSfxd ftldk v.kqlw=k C9H18 gS lHkh dkcZu sp3 ladfjr gS vkSj lHkh gkbMkstu leku gSA bldh lajpuk gks
ldrh gS %

(1) (2*)

(3) (4)

Sol.

This structures has 1 H-atoms and all are identical.


mijksDr lajpuk esa lHkh 1 H-ijek.kq gS rFkk lHkh le:i gSA

19. Mark ( ) or (x) in appropriate boxes


mi;qDr [kkuksa esa ( ) vFkok (x) HkjsaA
Compound Saturated Unsaturated Hetrocyclic Alicyclic Aromatic
;kS f xd lar`Ir vlar`Ir fo"ke ph; ,yhlkbDyhd ,jkseSfVd

(i)

(ii)

(iii)

(iv)
N

O
(v)
O

(vi)

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(vii)

(viii)
S

(ix)

20. Fill in the blanks :


Bondline Formula Condensed Formula Expanded Formula
fjDr LFkkuksa dh iwfrZ dhft, %
cak js[kk lw=k la?kfur lw=k foLr`r lw=k

(A)

(B)

(C)

(D)

(E)

(F)

(G)

(H)

Sol. Bondline Formula Condensed Formula Expanded Formula


cak js[kk lw=k la?kfur lw=k foLr`r lw=k
CH2
(A)
CH3 CH3

(B)

(C)

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(D)

(E)

(F)

(G)

(H)

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