Documente Academic
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Science
Department of Mechanical and Materials
Department: Engineering
Title
Objectives
Where p = pressure;
V = volume;
m = mass;
T = temperature.
Equipment and Materials
Air compressor E 1
Item Category:
SP Sample or specimen
C Consumable
CH Chemical
W Labware, glassware, tool and components
E Equipment
S Software
Experimental setup
#Interconnected vessel #Recorder #Valve
Procedure
2.) The location of all the valves and how they are connected to the compressed air
3.) Vessel A was filled with air until the pressure reached 0.40 bar.
4.) The air in vessel B was evacuated until the pressure reached -0.95 bar.
6.) The interconnected valve was opened to allow the air expand to fill both
containers.
7.) The pressures and temperatures in vessel A and B were recorded.
8.) The steps above were repeated for pressure 0.2 bar, 0 bar, -0.2 bar, -0.4 bar, -0.6
Results
0.025
0.020
m2 = m2A + m2B
0.015
Series1
0.010
0.005
0.000
0.000 0.005 0.010 0.015 0.020 0.025
m1 = m1A + m1B
Sample calculations
= 301.1 K
= 0.4 + 1.0
= 1.4 bar
P1 AV1 A
Mass of air in vessel A ( m1A ) =
RT1 A
=
1.4 x10 0.012
5
287 x301.1
= 0.019441 kg
= 310.9 K
Pressure in vessel B ( P1B ) = P1g + Patm
= -0.95 + 1.0
= 0.05 bar
P1BV1B
Mass of air in vessel B ( m1B ) =
RT1B
=
0.05x10 0.007
5
287 x310.9
= 0.00039 kg
= 300 K
= -0.122 + 1.0
= 0.878 bar
P2 AV2 A
Mass of air in vessel A ( m2A ) =
RT2 A
=
0.878x10 0.012
5
287 x300
= 0.012237 kg
= 313.2 K
= -0.117 + 1.0
= 0.883 bar
P2 BV2 B
Mass of air in vessel B ( m2B ) =
RT2 B
=
0.883x10 0.007
5
287 x313.2
= 0.00688 kg
= 0.019831 kg = 0.019117 kg
M1 = M2 = 0.019831 kg
Discussion
An ideal gas is defined as one in which all collisions between atoms or molecules
are perfectly elastic and in which there are no inter-molecular attractive forces. One
can visualize it as a collection of perfectly hard spheres which collide but which
otherwise do not interact with each other. In such a gas, all the internal energy is in
the form of kinetic energy and any change in internal energy is accompanied by a
absolute pressure (P), volume (V), and absolute temperature (T). The relationship
between them may be deduced from kinetic theory and is called the ideal gas law :
PV =mRT.
The ideal gas law can be derived from the kinetic theory of gases and relies on
the assumptions that the gas consists of a large number of molecules, which are in
random motion and obey Newton's laws of motion. Next, the volume of the molecules
is negligibly small compared to the volume occupied by the gas and there have no
forces act on the molecules except during elastic collisions of negligible duration.
Besides, its assume that all collisions between gas molecules are elastic and all motion
It states that if the volume of a container is held constant as the pressure of a gas
increases, the temperature inside the container will also increase. As with the other
P1 P2
gas laws, this one can be represented in the form of an equation: . From this
T1 T2
experiment, it found out that as the pressure of the gas increases in vessel A and B, the
temperatures will also increases in most case. Besides, the volume in vessel B is
smaller compare to vessel A, in this experiment we could analyze that when volume is
smaller the temperature is higher. First, temperature is a measure of the speed and
frequency of the collisions of the gas molecules with their surroundings. As the vessel
gets smaller, they have a smaller distance to travel before they collide with the walls,
and thus the time between collisions gets increasingly smaller. In a given amount of
time the particles hit the walls more, which results in a greater amount of pressure and
Bases on ideal gas law, the total masses of air before mixing and after mixing is
the same. However in this experiment there have a slightly different between the
value of M1 and M2. The total masses of air after mixing (M2) following a trend that it
is always lower then the total masses before mixing (M1). This may due to some
leakage of gases when the two connecting valve were opened. Besides, the mass of air
in vessel B is always lower than vessel A. Based on ideal gas law equation: PV=MRT,
when the volume of vessel is lower and temperature is higher, this will causes a
decrease in the masses of air and this is the main reason why the mass of air in vessel
In this experiment, there were many possible causes of error. First of all, a faulty
vacuum pump couldve let the air escape and so the pressure sensor would read a
smaller value. Next, error increases as volume decreases because when compressing
the gas with higher pressure, the density increases and the gas behave less like an
ideal gas. As the volume decreases, the movement of gas restricted and become less
randomly move, thus its break the assumption of ideal gas law which state that gases
are made up of molecules which are in constant random motion in straight lines.
Another sources of error was reading the pressure and temperature which due to
uncertainties of the equipment, it take times and difficult to make the values of
A few precaution steps should be taken in order to get a better result. Firstly,
adjust the control valve slowly to prevent any over leakage of gases. Next, record
down the values of pressure and temperature after it stabilize. Furthermore, a
high-tech equipment should be use to replace the faulty equipment like vacuum pump
There are some improvement can be make to the equipment. This experiment can
be done with or without a computer connected, however, for quicker tests with easier
recording of results, TecQuipment can supply the optional Versatile Data Acquisition
System (VDAS). This gives accurate real-time data capture, monitoring and display,
calculation and charting of all the important readings on a computer. To improve the
accuracy of data, few equipment can be connected inside the apparatus. For example,
a thermocouple use to measure the temperature of the heater surface for the controller.
While, two thermocouples measure the temperature of the air in the vessel. A pressure
transducer measures the pressure of the heated air in the vessel. A digital display
shows the absolute pressure, both temperatures and their average value.
Conclusion
In conclusion, the ideal gas law was the main equation used in the calculations for this
experiment. Since both trials came out with almost identical calculations, it is
believed that the experiment went as planned and no errors were made. Under the
present experimental conditions, air behaves like an ideal gas. At fixed volume and
consistent with the equation of state for an ideal gas. However, as the pressure
increases, the gas behave less like an ideal gas because the movement of gas restricted
and become less randomly move. Lastly, the largest source of uncertainty came from a
2.) Barnett, Martin K. (Aug 1941), "A brief history of thermometry", Journal of
Chemical Education, 18
4.) Cooper, Crystal (Feb. 11, 2010). "Gay-Lussac's Law". Bright Hub Engineering.