PPSC CHEMISTRY PAPER LECTURER 2015 MCQS 11.

NMR use ------------------source of radiation

1. Enzymes belong to which class of compound----------- a)UV

Proteins--------------- right answer)
B)Radio waves right answer)
2. The helical structure of protein is stabilized by --------
Hydrogen----------bond. right answer) c)micro waves

3. Enzymes havePolypeptide..unit d)visible rays

A)Polypeptide right answer) 12. Existence of nucleus is confirmed by..

B)HYDROCARBON Millikian method or

4. Function of enzymes in biological system is. Alpha scattering by thin metal foil right answer)

Catalyze biochemical action right answer) 13. What is fase about electron

5. Night blindness is produce due to deficiency of (Not conform but it should be d)

a) Electron is a particle
..VITAMIN A right answer)

6. Zwitter ion exist in which of the following b) Wave is associated with electron

a)Alanine right answer) c) When electron jump from orbital its energy c..

b)Glycine HCL d) oriented by magnetic field

14. Which one is occur in whole number always

c) Both a and b

d)None a) Atomic number right answer)

b) Molecular weight
7. IR determine --------------------bond
c) Equivalent weight
a)kind of bond nature of bond right answer)
15. A metal has an electronic configuration is M+2 has
c)hydrocarbon
2,8,14 and its atomic weight is 56.the
8. Marsh gas is
number of neutron is
CH4 right answer)
30) right answer)
9. Solvent used in IR Spectroscopy is..
16. Least soluble in Water Is
a)CCL4 right answer)
a. Ethano
B)CH30H
b. l b. Phenol
C)WATER
c. c. Carboxylic acid
D)CH3CH2OH
d. d. benzene right answer)
10. 1700------1760 PEAK In IR Spectroscopy is
17. The EAN Value of Ni(CO)4 is
Carbonyl group right answer)
a)36 right answer)
b)54 c. low ionization energy

18. The ration of C:Si in their neutron ration with atoic 25. the order of oxidizing agent is
weight having 12 and 28 respectively
I<Br<Cl<F
(3:7) right answer)
26. inversion of cane sugar into glucose and fructose is
19. Phenolphthalein is colourless in acidic medium due ?(not conform)
to __
a)slow process
__Benzenoid form right answer)
fast process
20. The weakest base is
b)spontaneous process
a) Hb)
instaneous process
Cl- right answer)
27. rate of chemical reaction is-----------when it proceed
c) HCO3-
a. decrease right answer)
d) OH-
b. increase
21. Which compound declourize KMnO4 solution but
not give test with AgNO3 solution 28. when reactants are added then rate of reaction is

a) Ethylene right answer) (not conform)

b) Acetylene decrease

c) Ethane increase right answer)

22. Which one of the following does not give Lassaignes 29. which one of the following metal has highest
test for nitrogen electrical conductivity

A. Phenylhydrazine A. gold

B. Glycine B. silver right answer)

C. Urea C. aluminium

D. Azobenzene right answer) D. copper

23. which one the following compound does not 30. preparation of ice cream is
explode: a) colloids
a) trinitro toluene b) excesive cooling right answer)
b) b)2-amine toluene (I think this is not conform) c) coagulation
24. Strongest oxidizing agent is supported by---------- d) peptization
a. Low dissociation energy 31. colloids are example of ---------------equilibria
b. hIgh electron affinity right answer) a. homogenous equilibria
A. hetrogenous equilibria ( right answer) c) neutral (my answer is neutral not confirm)

b. suspension d) may be positive or negative

c. none of these 39. who classify element first

32. pure water is nonconductor of electricity a) lother meyer

A. water is neutral b) doberiener

B. water is almost unionized ( right answer) c) newlands

B. water is completely ionized d) mendleevs

33. which one of the following aqueous solution 40. molecularity of reaction is always in whole
conductor of electricity number ( right answer)

C. Glucose 41. the chemical which destroy ozone layer is CFCl3 (

right answer)
D. HCl( right answer)
42. Physisorption occur at ---------------temperature low (
34. Which is correct statement (not confirm my answer
right answer)
is c)
43. if dispersion medium is gas its example is
A. Catalyst increase the rate of forward reaction
Aerosol( right answer)
B. Catalyst increase the rate of backward reaction
44. pressure vs temperature equation is called (not
C. Catalyst influence on the rate of forward reaction and
conform answer)
backward reaction equally right answer)
A. Langmuir equation
D. Catalyst decrease the rate of forward reaction
B. Fredluck equation
35. Pick a right statement:
C. Bet equation
Order of reaction is in fraction ( right answer)
D. None of these
36. The unit for formation of ammonia from
N2+3H..>2NH3 45. Resonationg structure caanot be seprated ( right
answer)
Mol-2.lit2( right answer)
46. Nickel is use in the hydrogenation of vegetable ghee
37. The unit of active mass is----------- ( right answer)
A. Gram atom per litre ( right answer) 47. Colloids shows Brownian movement( right answer)
B. Gram molecule per litre 48. Methyl group is 0rtho and p-directiong bcz..
C. Gram litre (Not conform my answer is all ob above)
38. colloidal particles are a) E donating effect of methyl group inductively
a) negative b) E donating effect of methyl group resonatingly
b) positive
c) E donating effect of methyl group hyperconjugation ( A. Decrease the concentration of solid
right answer)
B. increase the concentration of solid
d) All of above
C. Decrease the concentration of liquid
49. Chloro group is ortho and para but electron
withdrawing ( right answer) D. Decrease the concentration of liquid

50. To avoid maximum yield For a Reversible reaction to 55. The fastest reaction occur in which of the following:
occur A. Rusting of iron
A. Glass vessel B. Burning of coal
B. Closed vessel( right answer) C. The AgCl formation by the reaction of AgNo3 and
C. Open vessel Nacl ( right answer)

51. In benzene, there are ---------------type of carbon 56. The amount of energy required to separate
nucleons is called
atom

A. One type ( right answer) A. Ionization energy

B. Two type B. Binding energy ( right answer)

C. Three type 57. The enthalphy of heat of formation of sodium ion

from its atom is known as
D. Four type
A. Enthalphy of atomization
52. In benzene, the number of pi electron is
B. First ionization energy (not conform )
A. 3 e
C. Enthalphy of combustion
B. 4e
58. The brown vapour is formed of which element when
C. 6e ( right answer) MnO2 and conc. H2SO4 is added in them

D. 4e A. NO2 ( right answer)

53. In benzene , all carbon atoms are------------- B. CL2

hybridization
C. Br2
A. Sp3
D. I2
B. Sp2 ( right answer)
59. Stability of nucleus is due to
C. Sp
A. Proton and neutron ( right answer)
D. None
B. Proton and electron
54. According to lechatlier principle in a reversible
reaction between solid and liquid, the amount of C. Neutron and electron

60. Difference between particle mass and real mass is

heat added
called
(Not conform answer)
Mass defect ( right answer) 66. Which one of the following equation is not affected
by change in pressure
61. A gas has a volume of 2 litre at S.T.P at constant
pressure, the new volume is 4 litre at which A. 1/2N2+1/2O2..>NO ( right answer)

temperature: B. P2O5..>P2O+O2

A. 50c C. N2+3H2.>2NH3

B. 100c 67. A Reaction approaches go farthest completions

62. The difference between the crystalloids and colloids A. K=102

A. Particle size ( right answer) B. K=101

B. Colloidal size C. K=10

C. Diffusion D. K=10-2

D. True solution 68. Isothermal thermal system is one in which

63. The gas which shows deviation from ideal behavior DELTA T=0 ( right answer)
is:
DELTA E=W
A. Helium
V=0
B. Hydrogen
E=0
C. Ammonia ( right answer)
69. Temperature of the system decreases in
D. Trichloro methane
adiabatic expansion ( right answer)
64. Some substance shows scattering of light but they
can pass through ordinary filter paper adiabatic compression

is. 70. System in which no change in temperature is

A. Colloids ( right answer) Isochoric

B. Suspension isobaric

C. True solution isothermic ( right answer)

D. None 71. Cyclic structure of benzene is given by

65. In the lime kiln , CaCO3>CaO+CO2 Kekule( right answer)

proceed to complete because.. Doberiener
A. CO2 ESCAPPE 72. Which is least soluble in water
B. CaO remove A. Ethanol
C. Low Temperature B. Benzene ( right answer)
D. High Pressure C. Benzoic acid
D. Phenol +5

73. Heterogenous catalysis is based on +2

a. Adsorption ( right answer) 80. Molten KCl conduct electricity because of

A. Absorption Free ions ( right answer)

B. Sorption Free electron

C. Desorption 81. which individual units loose identity

74. Entropy of the unive rse is a. Complex salts right answer)

Always increasing ( right answer) b. Simple salts

Decreasing c. Compound salts

Constant d. Double Salt

75. Which indicator is not used in conical flask
A. Self indicator
B. External indicator ( right answer)
C. Internal indicator
D. Mixed indicator
76. Toluene is prepared from benzene
A. Fridel craft reaction( right answer)
B. Perkin reaction
C. Wurtz reaction
77. Catalyst used in fridel craft alkylation is
82. When a multidentate ligand is surrounded it is
known as
Coordination sphere
Coorination complex
83. Group no. represents
Same electronic configuration
same number of electron in valance shell( right
answer)Chelates ( right answer)
84. Entropy decreases in melting of ice rusting of iron
85. In this reaction
6NaOH+3Cl25NaCl+NaClO3+3H2O

A. AlCl3 ( right answer) A. Chlorine is reduced

B. BFCl3 B. Chlorine is oxidized

78. Order of reaction is C. Disproportionation reaction

Can be determined from equation 86. Aqueous solution is electrical conductor MgCl2

Can be determined from experiment ( right answer) .

79. Oxidation number of P in KH2PO2 IS 87. According to lewis concept ,

+1 ( right answer) bases are electron pair donor

+3 88. Aacording to lowry-bronsted concept

bases are proton acceptor

89. Which one of the following aquesous solution of

oxide and chloride give same test with litmus

solution.

A. Phosphorous

B. Sodium

C. Magnesium

90. The element of group 1B is known as coinage metal.

91. oxidation of which gives positive DNP but not

Fehling's test

A. CH3CH2CH2CH2OH

B. CH3CH(OH)CH2CH3

C. CH3CH(CH3)CH2CH2OH

D. (CH3)3COH

92. Product of hydrolysis of CH3CO2C3H7 with NaOH

gives

A. CH3COONa +C3H7OH

93. Flourescene, rhodamine, are example of---------------

indicators.

A. Acid base indicator

B. Adsorption indicator

C. Absorption indicator

94. Evaporation causes a change in entropy