Documente Academic
Documente Profesional
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380385
School of Materials Science and Engineering, Chongqing University, Chongqing, 400044 P.R. China.
E-mail: lvxuewei@163.com, bguang@cqu.edu
(Received on July 6, 2009; accepted on November 26, 2009 )
Mineral changes of Philippine and Indonesia nickel lateritic ores during the sintering and the mineralogy of
their sinter were studied in present work. A laboratory scale sintering pot was used to prepare the sinter
samples. Thermo-gravimetric (TG) tests, differential thermal analysis (DTA), and X-ray diffraction (XRD) ex-
periments were carried out to understand the mineral change of laterites. These measurements indicate
that chlorite (Fe,Mg,Al)3(Si,Al)2O5(OH)4 and serpentine Mg21Si2O28(OH)34H2O are the primary phases, while
FeO(OH) and (Fe,Mg,)3Si4O10(OH)2 are the minor phases in both Philippine and Indonesia nickel laterite. The
XRD, scanning electron microscope (SEM), and energy dispersive spectrometer (EDS) were used to analyze
the sinter samples; the results demonstrate that olivine (Mg,Fe)2SiO4 is the main bonding phase in both
Philippine and Indonesia laterite sinters, and spinel MgFe2O4 is also found as the solid bonding phase in the
Philippine laterite sinter.
KEY WORDS: sinter mineralogy; nickel laterite; thermal analysis; mineral change.
Fig. 2. XRD patterns for nickel literates from Philippine and In-
donesia.
from Philippine has more FeO and MgO and less SiO2 than
that from Indonesia. Fig. 3. TG pattern for nickel literates from Philippine and In-
donesia.
3.1.2. XRD Analysis
The XRD patterns shown in Fig. 2 reveals that both the
two nickel laterites are typical saprolitic ore, containing
dominant amounts of Mg silicate and MgFe silicate miner-
als.6) In saprolitic ores, Ni occurs mainly in Mg silicates,
and Cr occurs mainly in Fe silicates or goethite.1) The min-
eral species contains much crystal water and hydroxyl
group. In addition, some aluminates are present.
900C.
(3) Olivine (Mg,Fe)2SiO4 is the main bonding phases in
both Philippine and Indonesia laterite sinter, and spinel
MgFe2O4 is also found as the solid bonding phase in the
Philippine laterite sinter.
Acknowledgments
The authors are especially grateful to Jingguang Corp.
Ltd., Sichuan, China for the financial support, and the
Chongqing University Postgraduates Science and Innova-
tion Fund (200911B1A0120328).
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