1.

Preparacin de la disolucin del acetato de sodio (NaOAC- CH3COONa)

Datos
0.05 L NaOAC
0.1 M NaOAC
CH3COONa= 82 g
CH3COONa . 3 H2 O= 136 g
Pureza de CH3COONa . 3 H2 O = 99.5101.5 % (se lo considera puro)
Frmula

M= .
Donde M = concentracin molar; g=gramos; L= litros

Clculo
g NaOAC= M . Mol . L

g NaOAC= 0.1 . 82
. 0.05 L

g NaOAC=0.41 g
Considerando la sal trihidratada
82 g NaOAC 136 g CH3COONa . 3 H2 O
0.41 g NaOAC 0.68 g CH3COONa . 3 H2 O

2. Preparacin de la disolucin del cido actico (HOAc -CH3COOH )

Datos
0.05 L HOAc
0.1 M
Pureza HOAc= 99.7 % (p/p)
Densidad= 1.06 g/ml
CH3COOH= 64 g
Frmula

M= .
Donde M = concentracin molar; g=gramos; L= litros

Clculo
g HOAc = M . Mol . L

g HOAc 0.1 . 64
. 0.05 L

g HOAC=0.32 g
Pureza
0.32 g HOAC 99.7%
0.32 g HOAC 100%
Clculo del volumen
Frmula

d.=

v=
0.32
v= 1.06 /

v= 0.30 ml
3. Realizar los clculos de ph para: la disolucin tampn, cido actico y acetato de
sodio
Calculo del ph de NaOAC ( acetato de sodio)
Datos
Ka CH3COOH =1.8 X 10-5
Pka CH3COOH= 4.74
M CH3COOH =0.1
Pkw=14
Frmula
Ph= pkw + pka + log M
Clculo
Ph= 7 + 4.74 + log 0.1
Ph=8.87

Clculo del ph de HOAc (cido actico)

Datos
Ka CH3COOH =1.8 X 10-5
Ca= 0.1
Formula

[H] = Ka x ca
Clculo

[H] = 1.8 X 10 5 X 0.1

[H] = 1.34 x 10-3
pH= - log [H]
pH= -log [1.34x10-3]
pH= 2.87
Calculo de pH de disolucin tampn
Datos
Ka CH3COOH =1.8 X 10-5
Pka CH3COOH= 4.74
Acetato de sodio (NaOAc) Acido actico (H0Ac)
50 ml 50 ml
0.1M 0.1M
Formula
[ ]
pH= pka + log [ ]

Clculo
[ 0.1]
pH= 4.74 + log [0.1]

pH= 4.74
RESULTADOS DE pH DE LAS SOLUCIONES
Tabla 1
NaOAC HOAC pH disolucin
Buffer
+ Heliantina naranja rojo naranja
pH Mayor a 4 Menor a 4 Mayor a 4
8.87 2.87 4.74

COMPARACIN DE DISOLUCIN BUFFER Y HOAC

Tabla 2
NaOAC + HOAC= HOAC
disolucin buffer
+ Heliantina naranja rojo
pH Mayor a 4 Menor a 4
+ 2 gotas ------ Rojo ph= menor a 4
+ 50 gotas Rojo ph= menor a 4 ----------