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propylene production
RFCC units are being commissioned and operated to convert hydrotreated and
straight-run resid to high levels of propylene
W
orldwide demand for propylene contin- Relative to VGO, resid contains larger quantities
ues to rise at a rapid pace. of polycyclic aromatics and smaller quantities of
Consequently, propylene continues to paraffins. Relative to VGO, resid has a lower API
command a substantial price premium over most gravity and lower hydrogen content. Conradson
other refined products. Refiners have long carbon and heterocyclics of sulphur, nitrogen
exploited this price structure by designing and and oxygen, as well as organometallics of nickel
operating their conventional fluid catalytic crack- and vanadium tend to concentrate in the heavi-
ing (FCC) units to produce higher levels of est fraction. See Figure 1 for a description of
propylene. In recent years, refiners have these phenomena.1
extended this practice to converting residual Aromatic rings cannot be opened in an FCC
feedstocks to propylene. This article explores the unit due to the low hydrogen partial pressure.
technical challenges and opportunities presented Consequently, the potential conversion of resid
when targeting high propylene
production from a residual fluid
catalytic cracking (RFCC) unit. Kero, jet, diesel, No.2 FO Vacuum gas oil Vacuum resid.
The discussion will focus on the Gas C1-C4 Naphtha/gasoline Light gas oil Heavy gas oil Lube fraction
operation of propylene-targeted Boiling points, F
grassroots RFCC units designed 100 200 300 400 500 600 700 800 900 1000
by UOP and commissioned in 100 Tri
Dinu nu
Mon clea cle Residue
the past few years. The discus- o nucle
ar ar
r arom
atic
ar
aro
oma s ma
sion will also include a summary 80
t ic s t i cs
Composition, vol%
ycl ins
op Di
Resins
ara cy
clo
Unique features of resid FCC ffin
s pa
ra
ffin
operations 40 iso-
par s
affi
Resid FCC operations differ ns
Impact of hydrotreating
Table 3 shows a comparison of the feed proper-
ties and corresponding catalyst properties
operating in two RFCC units. One of the units
processes hydrotreated resid feedstock, while the
other processes straight-run resid feedstock.
Note the high 50% boiling point temperature
Figure 6 Propylene production in a catalytic cracking and corresponding high concentration of hetero-
unit cyclics and organometallics consistent with
Hydrogen yield,
wt% fresh feed
Early generations of quench
5000 0.25
systems consisted of a single
nozzle with no internals, which 4000 0.20
08
08
08
08
8
fouling.
/0
/0
/0
/0
/0
/0
/0
3/
3/
3/
3/
/3
/3
/3
/3
/3
/3
/3
6/
7/
8/
9/
10
11
12
13
14
15
16
Exchanger fouling can be
effectively mitigated by using Figure 8 Impact of antimony on H2 production
proper equipment design and
procedures, and by implementing a rigorous occur during restart. This scenario has occurred
monitoring program. A key equipment design throughout the industry since refiners first began
element is a quench distributor, which evenly processing resid. Consequently, UOP now recom-
distributes cool slurry throughout the fractiona- mends installing coke anchors (similar to
tor bottoms pool, thereby minimising localised refractory anchors) around the gas tube for
hot spots. The quench rate is adjusted to main- RFCC units. The coke anchors serve to capture
tain the target pool temperature. The normal coke deposits that might otherwise dislodge
operating liquid level is maintained on the low during a thermal cycle. Coke anchors have been
side to minimise the residence time in the pool. practised occasionally since 19999 and are gain-
Also, the circulating slurry flow rate is set to ing wider acceptance as a way to mitigate this
maximum at all times. This results in a high tube problem.
side velocity and maximises the amount of In addition to coke anchors, UOP recommends
cooled slurry available for quench. Also, a rigor- 45-degree flapper valves for the reactor cyclone
ous monitoring program is required whereby the diplegs in RFCC units. In the event a piece of
slurry viscosity, tube side velocity and exchanger coke dislodges from a gas tube, a 45-degree flap-
overall heat transfer coefficient are tracked as a per valve has an advantage because the dipleg is
function of the LCO draw rate. With these design completely free draining when the flapper valve
and procedure features, the time between clean- is wide open.
ing can be extended substantially.
Dry gas production
Reactor dipleg coke fouling Given the high nickel levels associated with
Coke deposits inside the reactor and associated processing resid, dry gas production, and specifi-
equipment are more common in resid FCC units cally molecular H2 production, can be quite
due to the coke precursors in the feedstock. Coke substantial. This is problematic because H2
deposits are most commonly found in stagnant cannot be economically recovered from dry gas
or cooled regions where precursors might plate and is thus valued as fuel gas, thereby down-
out on a surface. Perhaps the most problematic grading its value. Since H2 has a low molecular
coke deposits attach to the interior of the cyclone weight, small quantities (on a wt% basis) can
near the stagnant region on the back side of the substantially increase the flow rate of dry gas,
gas tubes. Coke deposits at this location can be which might hydraulically bottleneck the wet gas
on the same scale as the dipleg diameter. These compressor and downstream gas plant.
deposits can be dislodged as the gas tube Furthermore, since resid feedstocks are generally
contracts and expands during a thermal cycle hydrogen-deficient (less than 12.5 wt% hydro-
caused by an emergency shutdown and restart. gen), diverting just 0.1 wt% to molecular H2
If the deposits then fall into the dipleg, blocking diminishes the ability to produce propylene.
catalyst flow, high reactor side catalyst losses can Previously discussed well-proven methods for