AMENDMENT NO.1 JUNE 2008 TO 1S 228 (PART 1): 1987 METHODS FOR CHEMICAL ANALYSIS OF STEELS PART 1 DETERMINATION OF CARBON BY VOLUMETRIC METHOD (FOR CARBON 0.0570 2.50 PERCENT) (Page 3, clause 5.7, Table 1)~ columns (2) to "29 (Third Revision) Insert the following atthe appropriate place and renumber the existing ‘Table | Correction Factors (elause 5.7) rmaig’s | 10 | v2 | r08 ] rae | 208 J rio J ruz | nus J rue | ous J rao | 222 | rae | a6 | 228 Tempra wwe0C L o leleleleleta FN oR A 15] 521 [oom [oso [oom | ore Loos7 oo [oss [ooss [n94s [ost |noer [woes [ooss Looe 16 [0320 0922 fos2s [oss [o30 [0930] ov Posse] oon Loses [oss [nae Loos Lasse [oss 17 fasts oss [0921 [0928 0926] 0929 [oon | oss [oss [nsw [osu fosus four Loose] o9ss 15 fas [ost Losi6Looi9| 0922] 0524 Lo27 052 Loo Loos Loo [now Loss Looss | o9a5 19 [osos 09 fosi2 [oss] ovr] 0920 [os [0925 [092 [now [oss Pow Poors Loon [ose zo fas02} 0901} 0907} o0i0] e912 Paois |osre [oso basa Posas fosas [oss [oor | ose [esse 21 —[ose7[os00 | os [000s [ose fosie [oss fois | ovis | o921 {0921 | 0235] 09 [oom [ons 22 [sss osesf oxox} oonr [090s foos| oss Poo foots ose osi0 | 0322 | osza | osm [oss 23 [oss 0301 s9s os96| os [os [oss fasns| os o912 0912 | 0917 | 0912 [osx | 092s 24 | oses [osse} 0899] 0x01 | 0804 0195) os [ose] ons a907 [0910 0912 0915 [asi7| oom 2s] os [ose | 0581 oss] asso] 09 [ ove [a7 | a0 | o02| 000s] osm | os10 foste [oots 2 [esr Posie osio 0582 | oxss[ 0881 | oss [oso Loses 0807 [a0 os02| ass [osns| ao 22 [oss [osz2 037 os71 osm [osso| oxse oss | o690[ osv2[ os 0807] oo | ose | a00s 2s | osss oser | oss | os72 | 0874 0877[ 0x7 [oss [oss [oss [ oso oa] 0195 [0505 | 0900 22 —[ oss) [onal ossal 0267 | ox Los [owe | osm [ossol osse [asss| oss | oso | osv2l oss 30 [assaf oas6 | 082 | osez| ose1| asc7] osco| x72] osva] osr7] ost] ossa] oss] oss7| oso a fos fossr | oss | ont [oss -o [ones | owe| oso] oxre| osrs| 0x77 om | om | om so] oass [ossel osse| oxsr [oats Lossef 0189] oncr[ onsal once! oxsol oxns| om [owrel osm 33 [oxse] asso] ose] osel onss| ost [oass] onss| ose] osc | o5ns one) nse] osm [oxrs st foss) oass| oxss| osi0 | oss Loss) osss| oaso] oxss[ osss[ oss] oxo] osss| once] oss 35__foszrf osso) oss2[ oss] oss7] oso! one [osss] asi7] ossol ossal oass [oss7| oxco| ano 36 [om [ns0s Losze oso nant] onss[ 0536 0830] ons] osss| asso) ono [095 [ons | once 37 ose} oss] oso} os2s| 0826] om [oxo oa) asso) oss} ossol osss onse| esas | oss 3 [oso a2} osis | oar] os20) 0x2] aszs | oso7) asso) oss | ual oxx7[ ons] ose Posse 22 [sash osnaf os Loans| onts[ omiel osis {os [ oszil oxzel oss [oan Doss [ oss | on 20 forse) oso | oaiz | onns| osn7[ osiol osi2l oars | osi7] oszo o822] om2s| ox7[ oso) ose 11 fami [ores 0706 07 oso [os0: [osos} oss | osi1 | 0813 -osi6) osteo [os2s] oss fans) wa | oo) one [ores or7| oslo: | vavel var vaus| vate] use| ostr| oss «6 [onsf om 07 | ome] ors 071 [ors] 0795] 0798) 0800 ox0+! ows] osos| osi0] os zsforrah orsf ore] o7m | o7mi[ ore os] 099] 0701) 0704) 9706078 [osm | o80s] os és—Lonsl ora [ oxol ore ozrsl orl one] ora! oze1" 077 oreo] one bores o736[ 019 (MTD4) “RESSHRAY Ln, Bh, New DASMO<2_2265)) Ret: Doc Motods of Chemica Aneiysis of Ferrous Metels Soctiona Commi te, SMoC 2 (oe 69'14 : 549'24 [ 549°842 | (Fifth Reprint OCTOBER 2007) IS : 228 (Part 1)- 1987 {Reathemed 2097) Indian Standard METHODS FOR CHEMICAL ANALYSIS OF STEELS PART 1 DETERMINATION OF CARBON BY VOLUMETRIC METHOD ( FOR CARBON 0:08 TO 2'50 PERCENT) ( Third Revision) 1, Scope- This standard (Part 1) covers volumetric method for determination of carbon in the range 0°05 to 2'50 percent in plain carbon, low alloy and high alloys steels, 2. Determination of Carbon 2.1 Outline of the Method- The sample is burnt in a current of pure oxygen in presence of a suitable flux. “Combustion of the sample in a stream of oxygen, thus converts all the carbon present to carbon dioxide. After removal of sulphurous gases by suitable absorbents, the carbon dioxide gas is collected in a specially jacketed burette along with excess of oxygen. The carbon dioxide is then absorbed in alkali. On passing the excess oxygen back to the burrette, the contraction in volume is read against a scale, calibrated directly to the percentage of carbon 3. Sampling - The sarnple shall be drawn as. prescribed in the relevant Indian Standard, (The Sample is cleaned with organic solvent like ether or acetone, dried in an air oven at 100° + 5c before use. } 4, Apparatus - The apparatus recommended in \S: 6226 (Part 1)-1971 ‘Recommendations for apparatus for chemical analysis of metals: Part | Determination of carbon by direct combustion method may be used 5. Procedure 5.1 Before use the apparatus should be tested for satisfactory working against standard steel of appropriate values of carbor 5.2 For Plain Carbon Steel-Take one gram of an accurately weighed and clean sample free from ‘extraneous carbon in the form of small dnilings or shavings in a porcelain boat which can withstand atemperature of 1 150°Cwithout breaking or cracking. 5.2.1 Introduce the boat into the hot combustion tube in the furnace kept at 1000” 1 1 100°C, 5.3 For Low Alloy and High Alloy Steels - Take one gram of an accurately weighed and clean sample free from extraneous carbon in the form of small drillings or shavings in a porcelain boat, which can stand a temperature of 1 250°C without breaking and cracking. Spread 0'S g of pure tin granules over the sample. In case of high alloy steel mix the sample with 0°5 9 of pure iron (99°99 percent) filings also. Introduce the boat into the hot combustion tube in the furnace, kept between 1 150’ to 1 260°C, 6.4 Close the furnace inlet with a rubber stopper, allow the sample to heat for one to one and a half minute. Regulate the flow of oxygen to 300-400 ml per minute into the furnace and establish connection with the burette, which has been previously filled with acidulated water/brine water coloured with methyl red, so that the liquid level in the bulbed portion of the gas bureite does not fall rapidly. After a minute or so the level of water in the burette begins to fall more rapidly. though the same rate of oxygen is maintained, indicating completion of combustion. 5.6 Take readings, when the level reaches near the zero graduation mark after closing the bend way stopcock and equalizing the levels of the burette and the connected levelling bottle. Pass the iaaopied # Obcémiber isi da BUREAU OF INDIAN) STANDARDS: MANAK GHAVAN, 9. BAIADUR SHAH ZAFAR MAKGIS : 228 ( Part 1 )- 1987 collected and measured gas twice into the absorbing bulb, till constant reading is obtained, Record the burette reading. On the basis of one gram of sample taken for analysis, the burette is graduated fo measure directly the peresntrqa of carbon. 6.5.1 Examine the combustion boat for complete fusion of the sample, if not thoroughly fused, repeat the determination with a fresh sample. 5.6 Blank- Run a blank experiment on the same quantity of accelerators used, without any sample land make the appropriate corrections. &7 Calculation Carbon, percent = (A- B) xX F where A= burette reading after absorption of carbon dioxide in caustic potash with one gram of sample, 8 = burette reading for the blank experiment, and F = Correction teeter for temperature and pressure (see Table 1 ). 5.8 Reproducibility- :1:0-01 percent up to 150 percent carbon, and. 40-02 percent above 1°60 percent carbon. APPENDIX A INDIAN STANDARDS ON METHODS FOR CHEMICAL ANALYSIS OF STEELS IS : 228 Methods for chemical analysis of steels: (Part 2)-1987 Determination of manganese in plain carbon and low alloy steels by arsenite method (third revision) (Part 3)-1987 Determination of phosphorus by alkalimetric method (third revision) (Part 4)-1987 Determination of carbon by gravimetric method (for carbon > 0" percent) (third revision) (Part 5)-1987 Determination of nickel by dimethviqlvoxirne (gravimetric) method (for nickel": 01 percent) (third revision) (Part 6)-1987 Determination of chromium by persulphate oxidation method ( for chromium > 01 percent) (third revision) (Part 7)-1974 Determination of molybdenum by e-benzoinoxime method (for molybdenum > 1 percent) (second revision) (Part 8)-1975 Determination of silicon by the gravimetric method (for silicon 0° percent) (second revision) (Part 9)-1975 Determination of sulphur in plain carbon steels by evolution method (second revision) (Part 10).1976 Determination of molybdenum by thiocyanate (photometric) method (for molybdenum up to 1 percent) in’ low and high alloy steels (second revision) (Part 11 }-1976 | Determination of silicon by photometric method in carbon steels and low alloy steels ( for silicon 001 %0 0-05 percent) (second revision) (Part 12)-1988 Determination of manganese by pertodate (spectrophotometric) method in low and high alloy steels (for manganese up to 0-01 to 2-00 per- cent) (second revision) (Part 13 )-1982 Determination of arsenic (Part 14 )-1987 Determination of carbon by thermal conductivity method (for carbon 1005 to, 2-000 percent)1S 228( Part 1) +1987 0980 9780 S¥e-0 YEO 0¥9-0 SEE SELO FFE OC #0 GRO FTRO 1200 H190 9100 1130 600 908-0 08.0 109-0 ea 496-0 9580 2990 0980 L480 S¥B0 Z4R0 oreo aeRO SEBO EERO OES ERO ETO cZEO airs 9180 © yee0 20-0 690-0 (S80 seo zo00 fre0 Zee OF|O ZeE0 GEO TAO fA8O see 2780 o (ue0 sero g9n0 ree lend osRo Tse gpA0 oreo pred Ineo ceo ORO ite eze-0 = Si80 $780 e280 6¢8.0 9980 Soro 996-0 S600 EeO OSSO ere Meso Fred reo BRD ScRO i Foon 290) 6280 S100 200 2200 000 2900 S500 LsBo FIEO T5809 Ose $60 2>00 oF 68.0 020-0 eso az8.0 isa 990.0 9980 €980 1970 $58.9 9990 Isto 99.0 6 feo rea deo reno eo F400 2100 GORD Leo sve 290 seed yano & too 6 600 0500 Gene Oee0 gia S260 tien WSO FORO feo Gono bs 606-2 9060 660-0 9680 S080 G22 yABO eeu0 Ged MPO feo iZed G9RO 990 rs Steo z60 $060 2060 See0 2680 ooeo i900 saad Bro ONO Lao sLe0 2190 se zea e180 liso 906.0 tos-0 9699 966-0 eoe-0 1620 seo.0 veGo ono ex0-0 * 6-0 $260 9160 r80 9060 Foe-0 ‘1080 g5e.0 20. 9880 vee & 206-0 oreo 226-0 26-0 Bie 606-0 L062 $089 2ee0 6280 te feo see 8260 S200 “160 S160 2160 o160 tee 580-0 ie oreo Ineo £60 066.0 G60 O20 G60 Stee aed coe 0 2960 seo r900 460 960 95-0 926.0 sz6-0 e260 0280 e060 S060 @ foe 2800 Gree seed rE 96-0 ¥e60 esd ezee S260 aiso o1e-o & faeo Js80 yoeo fe0 GrG0 gree. 6b60 Grd peo tO Sie az 960 2940 Ga6-0 186-0 4960 266-0 Pre-o ‘1P60 8060 9ta.C eso 026-0 82 O16 1980 #960 260 6550 2260 S260 oreo ved Ihed eo S200 s 246-0 1980 :96.0 #960 Z96-0 6560 9560 HHO I5e0 oH0-0 HBO srEO FEO F289 oto Zee seo weo eae-o 2960 $960 i960 aewo G58e raed Is60 Fred SMO EiRO Stoo. Jeo leo i260 feo e160 Gor0 oO HED IME BOD OO ood HED Erin oreo. Zoo vend eo e160 S160 P60 1220 BLED 9960 e960 1900 HAO S60 iro Shao Zee eed sooo fond Ise0 8260 9760 f4E-9 1260 B90 960 SOSO oped Heo ose0 (890-0 2960 G9E0 195-0 G15 S160 CLE-D 016-0 19 S960 Z960 H56-0 LS6D ¥90o 906.0 100. fee0 ised wpe0 Ge60 Reo Gao Luso S160 ee $86-0 1960. Us6- 200.1 06-0 seaa fon G69 Yee see0 2060 6160 G96n beeo EoeO ne, £00.81 800. zse0 se6-0 Ze-0 e0e-0 Les 86-0 fle oz60 S560 sto 206. $00.1 Zoo! 6860 9660 tooo 1EO $8 eue-0 see 2260 @ ©) & a @ G &) G GW Oo ® @) see HL TEL one ole 99L OL OL TL: COML:CRL:CMEL SL: CSLCORL:=COMLOOHL:mL THLE a us omseoid Ces em) SuOISv4 NOLOaHUOS | aevLIS : 228 ( Part 1 ) - 1987 EXPLANATORY NOTE 15: 228 was issued £8 a tentative stardard in 1952 and revised in_ 1959,covering the chemical analysis of pig iron, cast iron and plain carbon end low allcy steels. For the convenience, it was decided to publish ccmprehersive series on che mir at analysis of steels including high alloy steels, and another series en ct emical analvsis. of pig iren and erst lion. Acccrdingly, chemical analysis of steele was published in various parts, This standard is series of parts on Chemical analysis of stools. The other parts published are given in Appendix A. The chemical analysis of pig iron and cast iron Js being published in separate standard. In this revision the major modifications are as follows: 1a) The limit of determination of carbon in steel have been medified as 0'05 to 2°50 percent in place of greater than or equal to 0'T percent. b) The rarge of pressure for the correction factors in .Table 1 have been incorporated from 730 10 770 instead of 700 to 770. raked aT aimed (OTR EST eA