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Documente Cultură
D. E. Soper2
University of Oregon
4 April 2011
1 Introduction
Non-relativistic classical mechanics is invariant under a change of reference
frame to one that is moving with a fixed velocity with respect to the reference
frame originally considered. To be more precise, suppose that we describe a
system in the lab frame using coordinates (t, x, y, z). Then we switch to a
moving frame using coordinates (t0 , x0 , y 0 , z 0 ). The transformation is t0 = t,
~x 0 = ~x + ~v t. Note that if we were doing relativistic physics, we would have
t0 6= t, but life is simpler with non-relativistic physics. For understanding
quantum mechanics, it is simpler to think of leaving the coordinates alone
but giving the system a boost by velocity ~v : we simply add ~v to the velocity
of every particle.
2 Boost operator
We are thus led to consider the unitary operator U (~v ) that boosts the sys-
tem. The operator U (~v ) does nothing to spins. For this reason, we consider
particles without spins. We consider a system made of particles 1 through N
with masses m1 through mN . We begin with a momentum space description,
in which the basis vectors are p~1 , p~2 , . . . , p~N .
The operator U (~v ) adds ~v to the velocity of every particle. Thus for a
particle i with mass mi , U (~v ) adds mi~v to the momentum of the particle:
U (~v )p~1 , p~2 , . . . , p~N = p~1 + m1~v , p~2 + m2~v , . . . , p~N + mN ~v . (1)
1
Copyright, 2011, D. E. Soper
2
soper@uoregon.edu
1
Now lets see what this does in a position space description. We have
Z !
X
U (~v )~x1 , ~x2 , . . . , ~xN = (2)3N/2 d~p1 d~pN exp i
p~i ~xi
i
U (~v )p~1 , p~2 , . . . , p~N
Z !
X
= (2)3N/2 d~p1 d~pN exp i p~i ~xi
i
p~1 + m1~v , p~2 + m2~v , . . . , p~N + mN ~v
Z
= (2) 3N/2
d~k1 d~kN
(2)
!
X
(~ki mi~v ) ~xi ~k1 , ~k2 , . . . , ~kN
exp i
i
! Z
X
= exp i mi~v ~xi (2) 3N/2
d~k1 d~kN
i
!
X
~ki ~xi ~k1 , ~k2 , . . . , ~kN
exp i
i
!
X
= exp i mi~v ~xi ~x1 , ~x2 , . . . , ~xN .
i
That is
~ ~x1 , ~x2 , . . . , ~xN
U (~v )~x1 , ~x2 , . . . , ~xN = exp iM~v R (3)
and R~ is the operator that gives the position of the center of mass of the
system
~ = 1
X
R mi~xi . (5)
M i
We learn two things from this. First, the boost operator is very simple in
the position representation. Second, the generator of boosts is M R. ~ That
is rather similar to the generator of space translations being P~ .
2
3 Transformation of operators
These results tell us how the operators ~xi and p~i transform under boosts.
(We could call these ~xi,op and p~i,op , but we dont do that here because we are
not in danger of confusing the operators with their eigenvalues.) We have
U (~v )1~xi U (~v ) = ~xi ,
(6)
U (~v )1 p~i U (~v ) = p~i + mi~v .
One operator of some importance in quantum mechanics is the total mo-
mentum, X
P~ = pi . (7)
i
It transforms according to
X
U (~v )1 P~ U (~v ) = U (~v )1 p~i U (~v )
i
X (8)
= (~pi + mi~v ) .
i
Thus
U (~v )1 P~ U (~v ) = P~ + M~v . (9)
Let us take the hamiltonian to be
X p~ 2
i
H= + V (~x1 , . . . , ~xN ) . (10)
i
2m i
3
4 The internal hamiltonian
Define
1 ~2
Hint. = H P . (13)
2M
Here int. denotes internal, M is the total mass of the system and P~ is
the total momentum of the system. The internal hamiltonian represents
the energy in a reference frame in which the total momentum of the system
vanishes. That is, if the system is in an eigenstate of P~ , then we can boost
it with velocity ~v = P~ /M and thus make the eigenvalue of P~ vanish. Then
Hint. is the hamiltonian for the suitably boosted system. Of course, the
system in general will not be in an eigenstate of P~ and ~v is a numerical
vector while P~ is an operator, so in general we cannot boost to make P~ = 0.
However, Eq. (13) is a relation among operators that can define what we
mean by Hint. .
How does Hint. transform under boosts? We note that
1 ~2 1 ~2 ~ 1
U (~v )1 P U (~v ) = P + P ~v + M~v 2 . (14)
2M 2M 2
Thus Hint. is boost invariant
5
with X
~ki = 0 . (25)
i
Then the complete system can be described using the ~ki and the total mo-
mentum P~ .
Similarly, we can define internal coordinates
~ .
~ri = ~xi R (26)
with X mi
~ri = 0 . (27)
i
M
Then the complete system can be described using the ~ri and the position of
~
the center of mass, R.
A simple calculation shows that R~ and P~ are conjugate operators in the
sense that their commutation relation is
(Indeed, M R~ is the generator of boosts, so this says that ~ki is boost invari-
ant.) A simple calculation also shows that ~ri commutes with P~ ,
[rik , P l ] = 0 . (30)
6
Then the hamiltonian Hint. depends only on the internal operators.
Unfortunately, the commutation relations between the ~ri and the ~ki are
a little complicated since the operators ~ki are not independent because of
Eq. (25) and neither are the operators ~ri , because of Eq. (27). We have
mj
[rik , kjl ] = ikl (ij ) . (32)
M
Suppose that you want to solve for the internal motion of three particles.
Then you need to reduce the three position vectors to just two, with two
conjugate momentum vectors. There are more than one ways to do this,
but we will not pursue them here. What we want to notice is that for any
number of particles the internal motion factors from motion of the center of
mass. Taking P~ to be diagonal, we can use a wave function
~ 0 R
~
e iP (~r1 , , ~rN ) , (33)
7
Then
~k 2
Hint. = + V (|~x1 ~x2 |) . (38)
2
~ and ~r = ~r1 ~r2 :
For space coordinates, we can use R
~ = 1 (m1~x1 + m2~x2 ) .
R
M (39)
~r = ~x1 ~x2 .
Then
~k 2
Hint. = + V (|~r|) . (40)
2
We know already that
[Rk , P l ] = ikl ,
[Rk , k l ] = 0 , (41)
[rk , P l ] = 0 .
8
8 Angular momentum
The angular momentum operator for our particles is
X
J~ = ~xi p~i . (45)
i
That is,
~ ~ iP ~ ~a
eiP ~a Je = J~ + ~a P~ ,
(47)
~ (~v ) = J~ + R
U (~v )1 JU ~ M~v .
Since both ~ri and ~ki are invariant under translations and boosts, so is S.
~
Let us see how S ~ is related to J.
~ We have
~ p~i mi P~
X
S~= (~xi R)
i
M
X X mi X X mi
= ~xi p~i ~xi P~ ~ p~i +
R ~ P~
R
M M (49)
i i i i
= J~ R
~ P~ R
~ P~ + R
~ P~
= J~ R
~ P~ .
That is
J~ = L
~ +S
~ , (50)
where
~ =R
L ~ P~ . (51)
9
Thus the total angular momentum J~ is composed of the orbital angular
momentum L ~ associated with the motion of the center of mass plus the
internal angular momentum S.~ The orbital angular momentum transforms
under translations and boosts as an ordinary angular momentum,
~ ~ iP ~ ~a ~ + ~a P~ ,
eiP ~a Le =L
(52)
~ (~v ) = L
U (~v )1 LU ~ +R ~ M~v .
but
[J k , J l ] = ikln J n , (57)
so
[S k , S l ] = ikln (J n Ln ) . (58)
That is, the internal angular momentum has the usual angular momentum
commutation relations with itself,
[S k , S l ] = ikln S n . (59)
10
~ here would be made of the internal orbital angular
operator we are calling S
ri ~ki , plus the sum of their spin
P
momenta of the constituent
P particles, i~
angular momenta, i ~si . For example, a simple model for a proton is that
it is made of three spin 1/2 quarks combined, with some orbital angular
momentum, to make a system with total angular momentum 1/2.
for each pair of particles. The analysis that we have applied works for any
state, but it is most useful for bound states. Thus, lets consider a bound
state here.
We can make the system more complicated by supposing that there is an
additional force that acts on our system. The simplest case is that we have a
bound state, an atom, say, and we place it in an external electric field. Then
we have an additional potential
X
V = ei (~xi ) . (60)
i
11
Then the full (time independent) Schrodinger equation is
1 ~2 ~
P + Q (R) = (E Eint. ) . (64)
2M
~
Our atom moves in the potential (R).
A more exact approximation to the interaction of the atom with the
external field is X
V Q (R) ~ ~ R)
ei~ri E( ~ , (65)
i
where
~ =
E ~ . (66)
This next approximation is especially important if the lowest order approxi-
mation is zero because the atom is electrically neutral, Q = 0. Now we have
an interaction between the external field and the electric dipole moment of
the atom. This couples the internal and external motions. Perhaps we can
come back to this when we deal with approximation methods in the next
quarter.
~x ~x + ~v t a boost
~x + ~v t + ~a a translation
(68)
~x + ~a an inverse boost
~x an inverse translation .
That is, the product of these transformations leaves the coordinates alone. If
our quantum operators obeyed the group multiplication laws, we would have
U = 1. However, we know how P~ transforms under boosts, so
~ ~
U (~v )1 eiP ~a U (~v ) = ei(P +M~v)~a . (69)
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Thus
U = eiM~v~a . (70)
We do not get the unit operator. But what we get is a number with absolute
value 1, a phase factor. This phase factor is applied to every vector in the
space of quantum
mechanical
2 states. It then cancels whenever we calculate
a probability | | .
We see that the quantum theory provides a representation of the Galilei
group up to a phase. This phase doesnt matter. When we dealt with rota-
tions and translations by themselves, we could have had something similar,
but there we got a true representation with no phase. At least thats what
we got if you didnt have spin 1/2 particles. With a spin 1/2 particle, a
rotation through 2, which is the same as not rotating at all, gives a phase
factor 1.
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