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1 ABSTRACT / SUMMARY
This experiment determines the molarity of a solution and the percent by mass of
acetic acid in vinegar by the method of titration with a standardized sodium hydroxide
solution. Besides, preparing a stock solution of standardized solution of sodium
hydroxide. The NaOH solution is standardized by titrating potassium hydrogen
phthalate, KHP solution with NaOH solution. The KHP stock solution is prepared by
dissolving KHP in distilled water.
Basically, this experiment is divided into two parts which are the first part is
standardizing the NaOH solution and the second part is proceeded with the determining
the molarity of a solution and the percent by mass of acetic acid in vinegar. In
standardizing the NaOH solution, 250 mL of distilled water is used to dilute
approximately 6 g of NaOH solid in order to prepare 0.6 M NaOH solution. This NaOH
solution is then titrated with potassium hydrogen phthalate, KHC 8H4O4 or KHP solution
which has been prepared by diluting 1.5 g of KHP granules in 30mL of distilled water.
The experiment is then preceded to the second part of the experiment which
standardized NaOH solution is titrated the with 10 mL vinegar that has been diluted with
100 mL of distilled water. Both titration for part 1 and 2 are repeated twice to get more
accurate results.
Overall, it can be conclude that the greater the mass of solute in the acid solution,
the more concentrated the solution becomes. Thus, the higher the molarity and more
volume of NaOH needed to neutralize the acid. The experiment is completed and
successfully conducted.
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2 INTRODUCTION
Molarity(M) =
Percent by mass is the mass in grams of solute per 100 grams of solution
Percent solute =
Vinegar is a dilute solution of acetic acid. The molecular formula for acetic acid is
CH3COOH. Both molarity and percent by mass of acetic acid in a vinegar solution can
be determine by performing a titration. A titration is a process in which small increments
of a solution of known concentration are added to a specific volume of a solution of
unknown concentration until the stoichiometry for that reaction is attained. Knowing the
quantity of the known solution required to complete the titration, calculation of the
unknown solution can be done. The purpose of titration is to determine the equivalence
point of the reaction. The equivalence point is reach when the added quantity of one
reactant is the exact amount necessary for stoichiometric reaction with another reactant.
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3 AIMS
a) To determine the molarity of a solution and the percent by mass of acetic acid in
vinegar by the method of titration with a standardized sodium hydroxide solution.
b) To determine the concentration of acetic acid in vinegar.
c) To standardize the sodium hydroxide solution by using KHP acid.
4 THEORY
In the titration process, burette is used due to dispense a small, quantifiable of
solution of the known concentration. A typical burette which has the smallest calibration
unit of 0.1 mL always been used and the volume dispensed by the burette will be
estimated to the nearest 0.01 mL.
When the moles of acid in the solution equals to the moles of base added in the
titration, the equivalence point is occur. For example, the stoichiometric amount of 1
mole of the strong base, sodium hydroxide (NaOH), is necessary to neutralize 1 mole of
the weak acid, acetic acid (CH3CO2H).
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As the titration has reached the equivalence point, there will be a sudden change
in the pH of the solution. In an aqueous solution, pH is related to its hydrogen ion
concentration. Symbolically, the hydrogen ion concentration is written as [H 3O+]. pH is
defined as the negative of the logarithm of the hydrogen ion concentration.
pH = -log [H3O+]
Figure 1.2 Acid-base titration curve of weak acid titrated with NaOH
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Titration of a vinegar with a standardized sodium hydroxide solution will be done
in this experiment. Initially, a primary standard acid solution is prepared in order to
standardize the sodium hydroxide solution. In general, dissolving a weighed quantity of
pure acid or base in a known volume of solution will produce the primary standard
solutions. In this experiment, sodium hydroxide solution will be titrated with sodium
potassium phthalate, KHP.
When the sodium hydroxide already standardized, it will be used to titrate 10.00
mL vinegar.
Then, the molarity and the percent by mass of acetic acid in vinegar can be
calculated after standardized the sodium hydroxide solution and titration of acetic acid in
vinegar.
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5 APPARATUS
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5.2 Molarity of acetic acid and percent of vinegar
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6 METHODOLOGY/PROCEDURE
1) 250 mL of approximately 0.6 M sodium hydroxide solution from NaOH solid was
prepared. The solution was prepared in a beaker and the calculation was checked
by the laboratory instructor prior to prepare the solution. The calculation was
recorded.
2) A beaker was placed on the balance and it was tared. 1.5 grams of KHP was added
into the beaker and the mass of KHP was recorded to the nearest 0.001 g. Then, 30
mL of distilled water was added to the beaker, and the solution was stirred until the
KHP had dissolved completely.
3) This solution was titrated with NaOH and the pH was recorded with 1 mL additions
of NaOH solution.
4) Steps 1 to 3 was repeated and two more solutions was prepared for NaOH
standardization.
5) The graph of pH versus NaOH was plotted. From the plots, the volume of NaOH
required to neutralize the KHP solution in each solution was determined.
6) The molarity of sodium hydroxide for titrations 1,2 and 3 was calculated.
7) The average molarity of the sodium hydroxide solution was calculated. The resulting
sodium hydroxide concentration would be used in part B of the experiment.
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6.2 Molarity Of Acetic Acid And Mass Percent In Vinegar
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7 RESULTS
7.1 Experiment 1
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Figure 1.4 pH against volume of NaOH required to neutralized KHP
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7.2 Experiment 2
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32 7.91 11.92
33 11.64 12.09
34 11.93 12.20
35 12.09 12.29
36 12.21 12.35
37 12.31 12.42
38 12.31 12.42
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8 CALCULATIONS
8.1.1 Calculation for the preparation of 150 mL of approximately 0.6M sodium hydroxide
solution,
Titration 1 Titration 2
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8.1.2 Calculation of molarity of sodium hydroxide for each titration
Titration 1
Moles of KHP,
1.50g KHC8H4O4 (1mol KHC8H4O4 / 204.2g KHC8H4O4)(1mol NaOH/1mol KHP)
= 0.00735 mol of NaOH
Experiment 1
Average molarity of NaOH = (Molarity 1 + Molarity 2) / 2
= (0.5654 M + 0.5762 M) / 2
=0.5708 M of NaOH
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8.2 Calculation Of Acetic Acid And Mass Percent In Vinegar
Titration 1 Titration 2
Volume of NaOH to
32 31
neutralize vinegar (mL)
For titration 1:
Number of moles of acetic acid that neutralized by the number of moles of NaOH,
= 1.827 M of CH3COOH
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For titration 2:
Number of moles of acetic acid that neutralized by the number of moles of NaOH,
= 1.769 M of CH3COOH
= 1.798 M of CH3COOH
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8.2.3 CALCULATION OF THE PERCENT BY MASS OF ACETIC ACID IN VINEGAR
FOR EACH TITRATION
Titration 1 :
= 1.0973 g of CH3COOH
= 10 g of CH3COOH
= 10.97% of CH3COOH
Titration 2 :
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Mass of acetic acid in the vinegar,
= 1.0625 g of CH3COOH
= 10.63% of CH3COOH
= (Titration 1 + Titration 2) / 2
= 10.8% of CH3COOH
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8.3 CALCULATION FOR EQUIVALENCE POINT FROM THE GRAPH
Experiment 1,
Titration 1 Titration 2
= 9.00 = 9.09
pH = (9.00 + 9.09) / 2
= 9.05
Experiment 2,
Titration 1 Titration 2
= 9.78 = 10.75
pH = (9.78 +10.75 ) / 2
= 10.27
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9 DISCUSSION
This first experiment is repeated twice to achieve the required precision reading.
The calculated molarity of sodium hydroxide for the first and second titration in the first
experiment are 0.5654 M and 0.5762 M respectively. The average molarity of sodium
hydroxide is 0.5708 M.
The next experiment is carried out after the standardization of sodium hydroxide
solution, which is to calculate the molarity and mass percent in vinegar. The calculated
molarity of acetic acid in vinegar for the first and second titration are 1.827 M and 1.769
M respectively. The average molarity of acetic acid is 1.798 M. The average percent by
mass of acetic acid in vinegar that we got through this experiment is 10.8%.
One possible source of error for the difference in first and others trials would be
recording an incorrect initial volume of NaOH solution, such as recording the initial
volume as 0.00 mL even though the level of solution was actually higher than the 0.00
mL on the burette. The excess NaOH solution above the 0.00 mL mark would be the
result in more NaOH solution delivered than is actually recorded based on the endpoint.
The resulting calculated molar concentration of acetic acid will be incorrectly low as well
as the incorrectly low volume of NaOH delivered. Thus, correct technique is essential for
obtaining good data and accurate and precise results in this experiment.
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Another reasons could be the vigorous swirling of the conical flask which will
allow atmospheric carbon dioxide to enter the beaker, thus increasing the acidity of the
vinegar solution. Although this error may be small, it affects the final result of the
experiment significantly. To avoid this from happening, the beaker should be swirled
gently using the right reading of the magnetic stirrer motor.
Besides, some beakers are not rinsed with distilled water before used and some
of them are not completely dry and clean. This might give some effect on the solution.
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10 CONCLUSION
Through the experiment, the equivalence point for the experiment 1 at volume of
sodium hydroxide neutralized KHP is at 13 mL and the pH at equivalence point is 9.05,
while in experiment 2 is at 31 mL and the pH is 10.27. The molarity of sodium hydroxide
is 0.5708 M while the molarity of acetic acid in vinegar is 1.798 M. Then, for the percent
mass of acetic acid in vinegar is 10.8%.
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11 RECOMMENDATION
To get the accurate value of result in the experiment, there are a few
recommendations and precaution that need to be considered through the experiments.
First, look at the lower meniscus in the light coloured solution and upper
meniscus in the dark coloured solution because of visibility. Besides, look at the
meniscus of solution at eye level to avoid parallax error. Then, do not forget to add
distilled water to the vinegar.
Usually an air bubble is present in the nozzle of the burette, it must be removed
before taking the initial reading. When chemicals are spilled on skin, wash for at least 15
minutes with running water.
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12 REFERENCES/APPENDIX
1) Arun Syamal (2008), Living Science Chemistry, 10 th Edition, Ratna Sagar P. Ltd,
India, p.p 37-66
2) http://projects.icbse.com/chemistry-327
3) https://www.scribd.com/doc/86725525/Determination-of-the-Concentration-of-
Acetic-Acid-in-Vinegar
4) Albert R. Leeds, Journal Of The American Chemical Society, 1895, Acetic Acid In
Vinegar, ACS Publications, p.p 741.
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