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Temperature:
Increase the temperature Increase solubility of precipitate Precipitate will
dissolved or coagulated & Difficult to filter
STEP 2: PRECIPITATION
Precipitation method is a process of weighing an element in form of precipitates which is separated by filtration from solution.
Factors affecting on precipitation method:
Precipitates must be free from soluble impurities
Precipitates must be insoluble in solution
Precipitates must be readily separated from the solution by filtration
Precipitates must be convertible into a pure compound by ignition or by simple evaporation
Example: Gravimetric analysis of a sulphate or halides
Na2SO4 + BaCl2 BaSO4 + NaCl
NaCl + AgNO3 AgCl + NaNO3
STEP 3: FILTRATION
Filtration is a process of separating precipitates from the mother liquor. The media employed for filtration are:
Filter paper
Gooch crucible
Porous fritted plates of resistance glace (Pyrex sintered crucible)
Vitreosil filtering crucibles (Silica)
Porcelain filtering crucibles (Porcelain)
The choice of filtering medium depends on nature of the precipitates and by cost factor.
Properties of filter paper:
It should be Ash-less
Size and diameter of filter paper should be according to the bulk of the precipitates
Pores of filter must be smaller than the size of the particle of the precipitates.
Example: Bulky precipitates like aluminium hydroxide need a larger filter paper than dense precipitates like barium sulphate.
Washing:
Precipitates must be washed with liquid to remove all soluble impurities sticking with the precipitates.
Properties of Ideal washing liquids:
Having no solvent action on precipitates but must removes all foreign impurities
Should not form any volatile product with precipitates
Should easily volatile on ignition
Should have no dispersive action on the precipitates
Should not interfere with precipitates
- If precipitates get colloid during filtration the solution used for washing must contain electrolytes e. g.
ammonium nitrate
solution is used for washing iron (III) hydroxide.
- If precipitates tends to oxidize during filtration, then solution used for washing must reconvert the oxidise form to its
original one e. g. acidified hydrogen sulphide water for copper sulphide.
- If precipitates settles rapidly or is gelatinous by nature, then washing is done by decantation. Gelatinous precipitates require
more washing than crystalline ones e. g. aluminium hydroxide requires more washing than calcium oxalate.