Documente Academic
Documente Profesional
Documente Cultură
Hybridisation
1 2
Metallic bonding
3 4
Metallic bonding Hexagonal close packed lattice
Most metals exist in close packed lattices of cations Sequence: ab, ab, ab
surrounded by delocalised outer electrons. The close Examples: Mg and Zn
packed layers can be stacked together where either
every other or every third layer is vertically aligned.
5 6
7 8
Metallic bonding Properties of Metals
Conduction: A metal lattice contains a very large number of
Lattice energy is used and defined as energy required free, delocalised outer electrons. When a potential gradient
to break up one mole of atoms in a lattice into (voltage) is applied, these electrons can move to the positive
separate atoms. i.e. M (s) M (g) end of the potential gradient carrying charge. Metals conduct
electricity.
Lattice energy decreases as the size of cations
increase (going from Li to Na, Group 1) Ductility and Malleability: Metals can be bent and reshaped
BUT increases as the charge on the ion increases without snapping. Bending and reshaping can occur because
close packed layers can slide over each other without breaking
going across a period (e.g. Na<Mg<Al) more bonds than are formed.
High lattice energies result from small highly charged
cations. Impurities in metals disturb the lattice and make metals less
ductile. Alloys are harder than pure metals from which they are
made.
9 10
13 14
Brittleness: When a force is applied to an ionic lattice, it A covalent bond is the electrostatic force of attraction that two
makes the layers slid past each other. When ions of the same neighbouring nuclei have for a localised pair of electrons
charge are next to each other, the layers repel causing the shared between them.
lattice to break.
Two types of covalent bond exist. E.g. Sigma () and pi
()bonds.
15 16
Covalent bonding (sigma bond) Covalent bonding ( bond)
When the orbitals from two atoms overlap along a line drawn Sometimes, after a sigma bond has formed, the p orbitals of
between the two nuclei. A sigma () bond is formed and is end- the two atoms also overlap above and below the line drawn
to-end overlap. between the two nuclei (overlapping sideway).
This can be between two s orbitals, an s and a p orbital and two This second bond that forms is called bond and consists of
p orbitals. two regions of electron density.
17 18
21 22
23 24
VSEPR (Examples) VSEPR
One central atom with all its valence electrons used to form Pairs of Valence Bond angle Shape
single bonds. Electrons
25 26
AB2 AB5
B------A------B PCl5
Valence electron at P = 5
Valence electron at Be =2 Five P-Cl bonds =5
Two Be-Cl bonds =2 Total valence electrons =10
Total valence electrons at Be = 4
Five pairs of valence electrons so Trigonal bipyramid
27 28
Shapes of Ions Molecules and Ions containing Lone Pairs
29 30
Molecules and Ions containing Lone Pairs Molecules and Ions containing Lone Pairs
NH3 H2O
Valence electrons at N = 5 Valence electrons at O = 6
Three N-H bonds =3 Two O-H bonds =2
Total valence electrons =8 Total valence electrons = 8
Four pairs so shape based on tetrahedron but only three bonds Four pairs of valence electrons but only two bonds so
so AB3L. tetrahedral based with two lone pairs
Lone pair repulsion is greater than bond angle H-N-H will be less Lone pair repulsion greatest so 10928 reduced to 1045
than 10928. Its 107. Order of repulsion lp/lp > lp/bp > bp/bp
31 32
Molecules with more than one central atom Molecules with more than one central atom
Ethane C2H6
33 34
Molecules with more than one central atom Molecules with more than one central atom
CH3NH2 H
H
C N
Valence electrons at C =4 Valence electrons at N =5 H
Four bonds =4 Three bonds =3
C N
(3C-H,1C-C) (2 N-H,1N-C)
4 pairs electrons 4 bonds 4 pairs electrons, 3 bonds,
1 lone pair
H H
Tetrahedral (10928 ) 107
CH3NH2
35 36
Carbonate ion CO32- Carbonate ion CO32-
Central C atom - -
O
Valence electrons at C = 4 -
O - O
O C O C O C
Three C-O single bonds = 3
O O O
One C=O = -1 - -
37 38
Hybridisation
Delocalisation
These resonance structures lead to the concept of Principles involved in the covalent bonding:
delocalisation:
2-
1. Promotion of electrons
O
O
C 2. Hybridisation - A process in which the electrons
O rearrange themselves.
3. Formation of molecular orbitals
Delocalisation occurs in most oxo-anions (e.g. nitrate sulphate,
manganate) and in some organic molecules, notably bezene
which will be considered in the next section.
39 40
Hybridisation Hybridisation
C 1s22s22px12py12pz (ground state configuration of C)
an electron is promoted from the 2s orbital to the vacant 2p orbital to allow 4
equivalent orbitals to be formed which are sp3 hybrids.
C 1s22s12px12py12pz1
These are sp3 hybrids that form a regular tetrahedron and the shape of the
new hybrid orbitals is intermediate between those of s and p orbitals.
The 4 electrons in the sp3 hybrids can each form a covalent bond (sigma
bond).
Energetically, sp3 hybridisation is favoured since although the energy required
for promoting the electron, much more energy is gained by the formation of
two extra bonds.
41 42
Hybridisation Hybridisation
If one electron is promoted from a 2s orbital to a 2p orbital but one of
the p orbitals remains unchanged, then sp2 hybridisation has
occurred.
Electron configuration of C:
This enables 3 equivalent sigma bonds to be formed with a bond angle
of 120.
The electron density in the p orbital can form a second C-C bond, but
this is a pi bond.
Thus the C=C bond in alkenes comprises one sigma bond and one pi
bond with the pi bond being the weaker one.
43 44
Hybridisation Hybridisation
Consider benzene where sp2 hybridisation occurs. The 6 p electrons for the 6 ring
carbons are equivalent to 3 pi bonds in the ring.
For ethyne, one electron is again promoted from a 2s orbital to a 2p
orbital but two of the p orbitals remains unchanged, then sp1
Thus for each of the 6 carbons, there are 3 sigma bonds and 1 pi bond. hybridisation has occurred.
The bond length of 0.139 nm for benzene is between those of 0.154 and 0.134 nm for Electron configuration of C:
C-C and C=C bonds.
The hybrid orbitals are arranged as far apart in space as possible: 180
Benzene is stabilised considerably compared to 3 normal C=C bonds to the apart.
delocalisation of the p electron clouds above and below the ring.
The bonds between H and C and the first C-C bond are formed by the
The process of delocalisation of electron density in cyclic carbon structures is known end-on overlap of these sp1 hybrid orbitals to form sigma bonds.
as aromatisation. The second and third bonds of the triple bond between C atoms are
formed by the side-on overlap of the 2 original atomic unhybridised
orbitals. These are pi bonds.
Thus for each of the carbon in ethyne, there are 2 sigma bonds and 2
pi bonds.
45 46
Hybridisation
47