Soalan Pengiraan

1. The rate of the reactants A + 2B C has been observed at 25C. From the
following data, determine the rate law for the reaction and calculate the rate constant

Experiment Initial A (M) Initial B (M) Initial rate (M/s)

1 0.100 0.100 5.50 x 10 -6
2 0.200 0.100 2.20 x 10 -5
3 0.400 0.100 8.80 x 10 -5
4 0.100 0.300 1.65 x 10 -5
5 0.100 0.600 3.30 x 10 -5

2. The reactions of peroxydisulfate ion (S2O8 2-) with iodide ion (I-) is

S2O8 2- (aq) + 3I- 2SO4 2- (aq) + I3- (aq)

From the following data collected at a certain temperature, determine the rate law
abnd calculate the rate constant.

Experiment S2O8 2- I- Initial rate (M/s)

1 0.080 0.034 2.2 x 10 -4
2 0.080 0.017 1.1 x 10 -4
3 0.16 0.017 2.2 x 10 -4