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C0 E_ CRE the —<—<—— Date Olek. 2614 Mid sym oy uo, Peredie table Aiid-eose =v.v.9. Peale gutifrotin types apertont emsne vey vey lop Teen 4, te, up, matt, Oleetam sffntty, chataemepatiotty, jam ag tiem wea PR iy pct Cy me oats) Meld ee - Matty . Redox iS - nesetyom balsmeiacy . Sm onbetts. pnbitels potembal emeng t ag divalion sees A Delamination ae ot ide Bem menarten - * aE ARR eel “hk Lig eleoteor dst ganechnt- Bug -7 fs gers finan) “Me 8CES ed 7 fa tice as aed vee 1e plain Limitations of Arrhenius concept (a) For the acidic or basic properties, the presence of water is absolutely necessary. Dry jzcy shall not act as an acid. gycg is regarded as an acid only when dissolved in water and not in any other solvent, (b) The concept does not explain acidic and basic character of substances in non-aqueous solvents (€) The neutralisation process is limited to those reactions which can occur in aqueous solutions only, although reactions involving salt formation do occur in absence of solvent. (@) It cannot explain the acidic character of certain salts such as ict, in aqueous solution. ow friends: & Rizvee Hasan and Afra Binte Mim ar 11 mins 4, Add Friend vy Like = Comment id any three from the following: Answer briefly (any five): ‘Draw the shapes of d-orbitals which are along the axis. Explain whether the following set of quantum numbers is permissible for orbital or not. n=2,1=1, mi=+1, m= +1/2 ¢. For a first order reaction, rate constant is 0.0276. Calculate the time required to complete one fourth of the reaction, Write down the electronic configuration of i) Na” and ii) Ar. ‘©. What will be the frequency of light (in s") if the energy of radiation is 325 Kj? f. Show that half-life of a first order reaction is constant. g, What isa line spectrum? What is the condition for generation of Paschen series for line spectrum of the hydrogen atom? LEX. For the following reaction CaCO; ———» CaO + CO2, AH = -58.75 kJ i. Define exothermic reaction. Sketch and explain the potential energy diagram forthe reaction given above. If the reaction given above is a first order reaction, derive the integrated form ii. of rate equation for this reaction. Also, sketch the plot from which you can determine the rate constant for this reaction. Write down the observations of Rutherford’s atomic theory. . Using the Rydberg equation find the wavelength (in nm) of the photon when a hydrogen atom undergoes a transition from n = 4 to generate Lyman series (Rydberg constant = 1.097 x 107m!) c. According to the concept of the quantum numbers which of the following orbitals is possible and which is not? Justify your answers giving reasons. i) 2p ii) 2d What are the factors that favour the formation of an ionic bond? Describe the hybridization and sketch the orbital diagram for PCls molecule. State Aufpau Principle. According to this Principle, arrange the following orbitals in increasing order of energies: 3s 4p 2p 3d 2s 3p What are the pre-conditions for a reaction to occur according to collision theory? For the third shell, calculate i) number of orbitals of different shapes ii) total number of orbitals in a subshell and iii) total number of electrons in each type of orbital. 9 Bee 10, cher oa + f o(24+!) z (3 plochen " : Summer Semester, 2017 Course No: CHEL10 Course Title: Principles of Chemistry Section:02 Fall Marks: 40 Time: 1 hour Date: 21 June, 2017 Answer question 1 and any three from the following: $x2=10 1. Answer briefly (any five): ‘a. What isa line spectrum? What is the condition for generation of Balmer series for ‘a line spectrum of hydrogen atom? Explain whether the following set of quantum numbers is permissible for an b. orbital or not, n=3, l= 1, m=+2,m=+12 ec. Fora first order reaction, rate constant is 0.0255. Calculate the time required to complete 60% of the reaction. 1s which have lobes in between the axes. Draw the shapes of all possible d-orbital . Why is density of ice less than that of water? What are the pre-conditions for a reaction to occur according to collision theory’? Prove that half-life of a second order reaction is inversely proportional to the R®moae initial concentration of the reactant. For the following reaction Os +O ——+ 20; A4H=96.5k) 2 a. Write down the rate law and rate expression with respect to the concentration of 03 for the given reaction. ii. Define endothermic reaction. Sketch and explain the potential energy diagram for the reaction given above. 'b, The decomposition of NrOs dissolved in CCl is a first order reaction. 2N:0; -+ 4NO2 + O: At 48°C, starting with a solution of concentration 1.00 moll" after 3 hrs the concentration decreases to 1.33 X 10? moll"!, Calculate the half-life in minutes for the decomposition of NOs at 45°C. Page Lo flaws of Hatherford!s atonnle theory 4a Writ Ling the Rystberg equation, find the wavelength cin nm) of the phokon when » i wen ator didergoes a (rannitlon from a 5 to yenerate Balmer serie hyvtny (Ryatberg constant” L007 x LOT!) 4. & Broflne coontinate covalent bond with exampley nolooular and intersmolec tDurmevntiate int lar hydrogen bonding: © Deworite the hybridization and sketoh the orbital diagram for HC®CH molecules. 4 & Didrwntiate sigmra and phbonds, Sketch the possible types of bonding for the RLOWwing eaves ws po-pe pred b State Hund's Rule, Write down the electron’ sloments aevonting to Hund’s Rute (box system): iNa i Ar iii, P \ 8 Iv configuration of the following yauvy nal) +h when he tie cons of [i € Pont Golfers Buller silstion chomae iy te yas Ye Wy aided to gontonheaNen of UH | = [eer] ov Contonttalon oF —Filohal toneentation cone oF LOH] coneortrcabion ie & Setukion. Oharrcterieed by dhe {ng whon Snited armounls oF add ep Yecblum ‘nn td fuskopation proj eek 1 OX tong, Prepac. topper plate. Chdking golutions 4 Sng treat eos Hie HN, - Colealale [Hap] 4, fg a ¢ OF te Afuue grlutions al amy Cott = a0 pit dog 2 #30 re pear !4 io von" \ = BKC Ny or 14.30 foe Wo, = «40M het tier Chon of Yeh sbeulakion of PH of \ ns nae ; — a comtiving +20. mabe n Md nN A 1 be ee Ko be agittel acide i Qrupanoie \ ch ’ om Us sal} “api ts Wax W3x\o > Od G4 hemibt weds a baller Solution of CAC) CONG toleulate | qeqpired 40 id ih pris gumoie. oid {he walt. of 4.30. 6¢—Fon.

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