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ceramic arts dail y.

org

making the switch from


cone 10 to cone 6
ceramic glaze recipes

a little knowledge of
ceramic glaze chemistry
and raw materials
goes a long way
www.ceramicartsdaily.org | Copyright © 2010, Ceramic Publications Company | Making the Switch from Cone 10 to Cone 6 Ceramic Glaze Recipes | i
Making the Switch from Cone 10
to Cone 6 Ceramic Glaze Recipes
A Little Knowledge of Ceramic Glaze Chemistry
and Raw Materials Goes a Long Way
If you want to convert cone 10 glaze recipes to cone 6, you’ll need to know something about glaze chemistry and the
materials that work best at those different temperatures. If you just want to start with established cone 6 recipes, which
is often a lot easier, there are now many people who have done the research and testing so you don't have to. But don’t
worry; there will still be plenty of glaze-testing fun for you to try in your own studio.

In Making the Switch from Cone 10 to Cone 6 Ceramic Glaze Recipes: A Little Knowledge of Ceramic Glaze Chemistry
and Raw Materials Goes a Long Way, we present several successful examples of cone 10 glazes reformulated to work at
mid range, and include explanations of the glaze chemistry behind these successes.

Mid-Range Reduction: It’s Not Just


Cooler, It’s Cool
by John Britt
There are a number of reasons why someone would want to fire at cone 6 rather
than cone 10, but John Britt was not one of those people—until he was asked to
present a workshop on the topic. His understanding of ceramic glaze materials and
glaze chemistry helped him to quickly find a path from cone 10 firing to cone 6.

Cone 6 Crystalline Glazes:


Developing Crystals at Mid Range
by William Schran
Historically, crystalline glazes have been the purview of the high-fire potter. But
like everything else, if enough people experiment and test, good results can be
obtained under all sorts of circumstances - in this case, crystals at cone 6.

Traditional Cone 10 Glazes Make the


Leap to Cone 6
by Rick Malmgren
There are a lot of traditional glaze recipes out there, but they are typically
formulated for firing at cone 10. Rick Malmgren has reformulated and adjusted
many traditional ceramic glazes to function well as cone 6 glazes, and he has
some compelling reasons to do so.

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Mid-Range Reduction:
It’s Not Just Cooler, It’s Cool
by John Britt

Thrown and altered platter, 12 in. (30 cm) in diameter, stoneware with Cherry
Blossom Shino and Woo Yellow glaze, fired in reduction to cone 6, by Bar-
bara Morgenbesser.

W
ith all the current discussion about global range, (cone 5–7), is about 2200°F (1204°C). Although this
warming and conservation, I thought I should is only about a 150°F (66°C) temperature difference, raising
relate a recent workshop I taught at MudFire the temperature 150°F at the peak of the firing takes quite a
Clayworks and Gallery, a community ceramic bit more energy and puts a lot of extra wear and tear on the
art center in Decatur, Georgia, just outside of Atlanta. They kiln. It could easily take two to four more hours of firing to
offer studio space, monthly workshops and a beautiful gallery go from cone 6 to cone 10 with the gas on high, so firing to
of contemporary ceramics artists. They also fire to cone 6 in mid-range reduction would save considerable fuel if compa-
reduction. Erik Haagensen and Luba Sharapan, the owners rable glazes could be found.
of MudFire, had started to fire cone 6 reduction because of a At that time, I didn’t have a lot of experience with mid-
defect in the kiln they’d purchased, but after seeing the results range reduction and I found it hard to believe that the results
they had no reason to change back, even after the kiln was were “almost indistinguishable.” I did have a good bit of
repaired. Firing to cone 6 was cheaper, faster, and the results experience firing mid-range oxidation in an electric kiln and
were almost indistinguishable from high fire. the results are far from the look of cone 10 reduction. But
the idea intrigued me, and the more I thought about it, the
The Project more I realized that the same principles of high fire reduc-
Although they fire to mid-range reduction, Erik and Luba tion should apply to mid-range reduction. The key question
had read my book, “The Complete Guide to High-Fire would be if the oxides and materials needed to melt the
Glazes,” and wanted me to give a workshop on the cost and glazes at a lower temperature would negatively affect the
time benefits of cone 6 reduction firing, as well as to explain glaze colors. So I took the challenge, reasoning that I could
the reasoning behind glaze recipes, firing cycles and to show use the same research methods I used for the high-fire glazes
them how to bring glazes from cone 10 down to cone 6. to explore these mid-range glazes.
I normally work with, and teach about, high-fire glazes Mid-range firing in both oxidation and reduction is a well
(cone 9–11), approximately 2350°F (1288°C), while mid- researched area dating back before the energy crisis of the

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Mugs, 4 in. (10 cm) in height, stoneware with Temmoku
Gold, gas fired in reduction to cone 6, by Luba Sharapan.

Handbuilt vase. 8 in. (20 cm) in height, porcelain with


Mint Julep Glaze, gas fired in reduction to cone 6, by
Noodle bowl, 4 in. (10 cm) in height, stoneware with Mal- Melissa Keen-Boggan.
colm Davis Shino Glaze, gas fired in reduction to cone 6, by
Erik Haagensen.
glaze recipes to test that would show a broad range of possi-
1970s. There are also several college clay programs that bilities within a type. Then I tested those recipes in a variety
use mid-range reduction and have published their glazes. of firing cycles, like heavy reduction, light reduction, early
One notable example is Diana Pancioli, at the University reduction, late reduction and oxidation. This way, I can
of Eastern Michigan, who started her “Glaze Forward” reveal a glaze’s full potential.
program. (For a small shipping fee, you could send for Iron glazes are a great type to start with because you can
a list of cone 6 reduction recipes and test tiles of those see a wide range of colors by incrementally adding one
glazes.) There are also organizations like the Clay Studio in colorant; iron oxide. For example, when firing in reduction
Philadelphia that fire cone 6 reduction and have developed using the same base glaze, adding 1% red iron creates a blue
a wonderful palette. celadon, adding 2–4% iron oxide will give green to amber
celadons, adding 5–10% iron oxide makes temmokus, and
The Research 10–20% iron oxide gives iron saturates. Teadust temmokus
My first step is always completing an exhaustive survey of result from additions of magnesium carbonate to temmokus
known glazes from books, internet and workshop handouts. fired with cooling soaks. Kakis, which are also part of the
Luba and Erik generously sent me all their recipes from iron glaze type, are obtained with additions of bone ash and
MudFire [see selected recipes on page 51], and I pulled out magnesium carbonate. Finally, oil spots result from stiff oxi-
my cone 6 glaze notebooks and began assembling recipe lists dized temmokus with magnesium oxide. So you can see how
and firing instructions. one glaze type can show you a world of glaze colors.
There is so much information available today that it is Copper red glazes are generally low alumina and high al-
almost paralyzing; you don’t know what to do with it all. So kaline bases with small amounts of copper carbonate (0.3%)
in order to make it usable, I organized the recipes into types, and tin oxide (1%). Oribe glazes use copper to get greens
like iron glazes (celadon, temmoku, kaki, iron saturate, etc.), while magnesium matt glazes yield satin whites and purples
shino, copper red, oribe (copper green), magnesium matt, with cobalt oxide. You can try to reproduce these “types”
etc. Then, after eliminating all the duplicates, I looked for at various cones and, as always, you may then have to make
similarities and differences, and from those, selected enough adjustments after you see the results.
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The final type I concentrated on
was shino glazes. Shinos are generally
made with varying amounts of feld-
Side By Side
spar and clay. For example, you may
have somewhere between 60–90%
feldspar and 10–40% clay. A typical
recipe would be 70% feldspar and
30% clay. This is the most difficult
glaze type to reproduce at mid-range
because most feldspars melt around
cone 9 and then with the added clay JEFF’S RED PANAMA RED
it is hard to melt much lower than Cone 10 Reduction Cone 6 Reduction
cone 10. I started by using nepheline Barium Carbonate. . . . . . . . . . . . . . 4.4 %. % Dolomite. . . . . . . . . . . . . . . . . . . . 7.76 %. %
Dolomite. . . . . . . . . . . . . . . . . . . . . 8.7 Gerstley Borate . . . . . . . . . . . . . . . 10.67
syenite, which is not a true feldspar Whiting. . . . . . . . . . . . . . . . . . . . . . 8.4 Strontium Carbonate. . . . . . . . . . . 4.17
but rather a feldspathoid (containing Zinc Oxide. . . . . . . . . . . . . . . . . . . . 1.7 Whiting. . . . . . . . . . . . . . . . . . . . . 2.60
less silica than a true feldspar). It melts Frit 3134 (Ferro). . . . . . . . . . . . . . . . 8.7 Zinc Oxide. . . . . . . . . . . . . . . . . . . 2.60
Custer Feldspar . . . . . . . . . . . . . . . . 41.9 Custer Feldspar . . . . . . . . . . . . . . . 44.10
around cone 6. Because it is high in
Silica (Flint). . . . . . . . . . . . . . . . . . . . 26.2 Ferro 3110 (Ferro) . . . . . . . . . . . . . . 9.70
sodium oxide and lower in silica, the 100.0 % EPK Kaolin. . . . . . . . . . . . . . . . . . . 2.60
effects are not identical, but it was a Add: Tin Oxide. . . . . . . . . . . . . . . . . 2.6 %. % Silica (Flint). . . . . . . . . . . . . . . . . . . 15.80
good starting point and worth a try. Copper Carbonate . . . . . . . . . 0.5 %. % 100.0 %
Bentonite. . . . . . . . . . . . . . . . . 1.0 %. % Add: Tin Oxide. . . . . . . . . . . . . . . . 2.62 %. %

Firing Copper Carbonate. . . . . . . . . 1.75 %. %

I loaded the kiln with these various


glaze types and then filled the re-
mainder with line blends within these
glaze types and a variety of other
recipes, like blues, greens, yellows,
blacks, etc., to see the overall effect of
varying firing cycles across the board Shaner Oribe SELSOR Oribe
of glaze colors. Cone 10 Cone 6
For the first firing, I started reduc- Bone Ash. . . . . . . . . . . . . . . . . . . . . 1.1 %. % Gerstley Borate . . . . . . . . . . . . . . . 12.50 %. %
Talc . . . . . . . . . . . . . . . . . . . . . . . . . 7.9 Whiting. . . . . . . . . . . . . . . . . . . . . 10.41
tion at cone 010 and kept it heavy Whiting. . . . . . . . . . . . . . . . . . . . . . 22.1 Nepheline Syenite . . . . . . . . . . . . . 56.25
(0.65–0.72 on the oxygen probe) to Custer Feldspar . . . . . . . . . . . . . . . . 31.0 Silica (Flint). . . . . . . . . . . . . . . . . . . 20.83
cone 6 at 3 o’clock (cone melting Kaolin . . . . . . . . . . . . . . . . . . . . . . . 12.6 100.00 %
Silica (Flint). . . . . . . . . . . . . . . . . . . . 25.3 Add: Copper Carbonate. . . . . . . . . 5.00 %. %
position, not time of day). I had pretty
100.0 %
good copper reds and iron glazes but Add: Copper Carbonate. . . . . . . . . . 5.2 %. %
This is a test I made with Selsor Copper Red
and I removed the colorants and added
the shinos were dull and washed out. copper carbonate, so I called it Selsor Oribe.
For the next firings, I increased the fir-
ing temperature to cone 7 at 3 o’clock,
which gave me about 25°F more and
brightened up the glazes. I ran five
more firings to this cone, including full
oxidation, light reduction, medium
reduction, heavy reduction and oxi-
dation with reduction at peak tem- Coleman Teadust Temmoku TEADUST Temmoku
perature. I also tested glazes with flux Cone 10 Cone 6
variations too numerous to mention, Talc . . . . . . . . . . . . . . . . . . . . . . . . . . 7 %. % Whiting. . . . . . . . . . . . . . . . . . . . . . 10.5 %. %
Whiting. . . . . . . . . . . . . . . . . . . . . . . 16 Frit P-25 (Pemco). . . . . . . . . . . . . . . 26.3
exploring mid-range fluxes like boron
Custer Feldspar . . . . . . . . . . . . . . . . . 40 Alberta Slip . . . . . . . . . . . . . . . . . . . 63.2
oxide, sodium oxide, lithium oxide, Ball Clay. . . . . . . . . . . . . . . . . . . . . . . 12 100.0 %
calcium oxide and zinc oxide [see side- Silica (Flint). . . . . . . . . . . . . . . . . . . . . 25 Add: Red Iron Oxide. . . . . . . . . . . . . 5.0 %. %
bar on page 50]. Adding fluxes and 100 %
Add: Red Iron Oxide. . . . . . . . . . . . . . 10 %. %
reducing alumina and silica affects the
response of coloring oxides in glazes,
so the trick was finding suitable colors
in properly melted glazes.

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Results
The results were great for copper reds and iron glazes, as well as
greens, blacks, blues and carbon-trap shinos, which were very nice in
heavy reduction. The carbon trap shinos worked because they contain
soda ash, which melts very early, and with early reduction the carbon
is already “trapped” below the soda layer so the peak temperature is
not a factor. The only glaze type I could not achieve was traditional
shinos, as I had expected. And I only had limited success with oil
spots in the gas oxidation trials. This was also to be expected as iron
oxide only starts to self reduce at 2250°F (1232°C) and that is about
the peak temperature we reached. Soaking at cone 7 helped, but they
were not as spectacular as a cone 13 oil-spot firing. Nevertheless, we
did get spotting and some promising oil-spot recipes.
From all this testing, I came to the inescapable conclusion that Erik
and Luba were correct. Ninety percent of the mid-range glazes were
indistinguishable from their high-fire twins. This leads us to ask, why
don’t more potters fire to cone 6/7 in reduction?

Making the Switch


There seem to be a few obstacles in getting potters to convert to the
idea of mid-range firing. First, there is the inertia of their current prac-
tice. Change is hard in spite of the obvious benefits, especially if you
have been doing the same thing for 20 years and it is working.
Also, there is an underlying belief, although it is completely incor-
Eggy Vase, 15 in. (38 cm) in height, John’s Shino rect, that cone 10 is superior to mid-range or low-fire, and chang-
with decoration using Amaco Velvet underglaze, gas
ing this mind set is an educational challenge. I think that this comes
fired in reduction to cone 6, by Erik Haagensen.
from the long historical European search to imitate Chinese high-fire
porcelain. The goal was always to achieve high fire, so it gained the
psychological high ground.
When you mention mid-range, potters immediately think, as I ini-
tially did, of mid-range electric oxidation. But this is not the only way

Note: Frits come in a wide range

Mid-Range lower in silica than other feldspars and of types. They are used by industry
as reliable and consistent sources of
melts around cone 6.), soda ash, wood

Fluxes ash, borax, frits and Gerstley borate or


its substitutes.
fluxing oxides in relatively insoluble
form. They are relatively low in
alumina and silica and are active
Glazes contain alumina and silica, which Lithium Oxide (Li2O) is the lightest melters, but they can settle rapidly.
both melt at very high temperatures, weight, smallest particle size and most
so getting them to melt at mid-range powerful of the alkaline fluxes with a
temperatures requires different fluxes strong color response similar to sodium and volatilize at 1742°F (950°C). It has a
than at high-fire temperatures: and potassium oxides. It has a melting low expansion/contraction rate, so it can
point of 1472°F (800°C) and has a low help to reduce crazing. Sources include
Sodium Oxide (Na20) is a strong expansion/contraction rate, which can zinc oxide and calcined zinc oxide.
alkaline flux and creates brightly colored cause shivering in glazes. Sources include Boron Oxide (B2O3) is a glass former
glazes. It has a melting point of 1652°F lithium feldspars and lithium carbonate. and a flux with a molecular structure
(900°C) and a high expansion/contraction Zinc Oxide (ZnO) is an auxiliary similar to alumina. It melts at 1292°F
rate, which will often cause crazing in flux in oxidizing atmospheres. It has a (700°C) but begins melting at 572°F
glazes. It is often found in association dramatic color response, both good and (300°C). It has a low expansion/contraction
with potassium oxide in feldspars. bad, depending on the colorant. It can rate and produces good color response in
Common mid-range sources include heighten colors with copper and cobalt glazes, with characteristic bluish, milky
sodium feldspars (nepheline syenite— oxides, but produces dull colors with streaks and cloudy effects. Sources include
actually a feldspathoid—is the lowest chrome oxide. It has a melting point Gerstley borate (or its substitutes like
melting feldspar and so it is often used of 3587°F (1975°C), but if it is fired in Gillespie Borate, Murray’s Borate, Laguna
at midrange. It is high in sodium and reduction it will change to the metal zinc Borate, etc.), borax and frits.
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to fire mid-range. Mid-range reduction has
a completely different look, as does mid-
range oxidation soda firing or mid-range
reduction soda firing.
recipes
And finally, when you mention firing to John’s Shino Mint Julep
(Cone 5–6) (Cone 6)
mid-range, potters immediately want to
Gerstley Borate . . . . . . . . . . . . . . . . 4.9 %. % Gerstley Borate . . . . . . . . . . . . . . . . 2.9 %. %
change or convert their cone 10 glazes to Soda Ash . . . . . . . . . . . . . . . . . . . . 2.9 Magnesium Carbonate. . . . . . . . . . . 2.9
this lower temperature. This is perceived as Nepheline Syenite . . . . . . . . . . . . . . 54.5 Whiting . . . . . . . . . . . . . . . . . . . . . . 22.4
a significant challenge because it means that Spodumene. . . . . . . . . . . . . . . . . . . 22.8 Frit 3124 (Ferro). . . . . . . . . . . . . . . . 8.8
they will have to learn a glaze calculation OM 4 Ball Clay. . . . . . . . . . . . . . . . . 14.9 Nepheline Syenite . . . . . . . . . . . . . . 22.7
100.0 % EPK Kaolin. . . . . . . . . . . . . . . . . . . . 20.3
software and unity molecular formulation.
Silica (Flint). . . . . . . . . . . . . . . . . . . . 20.0
Most just want recipes that work. They Malcolm Davis Shino
100.0 %
know it will take time and effort to learn to (Cone 10)
Soda Ash. . . . . . . . . . . . . . . . . . . . . . . 16 %. % Add: Red Iron Oxide. . . . . . . . . . . . . 1.0 %. %
convert all these recipes and they just don’t
Kona F-4 Feldspar . . . . . . . . . . . . . . . . 9
want to spend their time doing that. Nepheline Syenite . . . . . . . . . . . . . . . . 39 Woo Yellow
I don’t recommend converting glazes Cedar Heights Redart. . . . . . . . . . . . . . 6 (Cone 6)
to the lower temperature, because when EPK Kaolin. . . . . . . . . . . . . . . . . . . . . . 17 Dolomite . . . . . . . . . . . . . . . . . . . . 15.41 %. %
you lower the firing temperature of a glaze OM 4 Ball Clay. . . . . . . . . . . . . . . . . . . 13 Strontium Carbonate. . . . . . . . . . . 23.90
100 % Nepheline Syenite . . . . . . . . . . . . . 42.50
you are using different fluxing oxides that
Kaolin . . . . . . . . . . . . . . . . . . . . . . 9.04
have different color responses. So although Cherry Blossom Shino
Silica (Flint). . . . . . . . . . . . . . . . . . . 9.04
it is possible to convert your glaze to the (Cone 6)
100.0 %
lower temperature, you will end up with Soda Ash. . . . . . . . . . . . . . . . . . . . . . . 10 %. %
Nepheline Syenite . . . . . . . . . . . . . . . . 40 Add: Zircopax. . . . . . . . . . . . . . . . 19.23 %. %
a different glaze anyway. It is better to use Bentonite. . . . . . . . . . . . . . . . 4.76 %. %
Spodumene. . . . . . . . . . . . . . . . . . . . . 40
the many tried and true mid-range glazes EPK Kaolin. . . . . . . . . . . . . . . . . . . . . . 10 Epsom Salt. . . . . . . . . . . . . . . 1.19 %. %
already in use and test them in your cycle. 100 % Red Iron Oxide . . . . . . . . . . . 3.57 %. %
This is the same way potters find high-fire
Raw Sienna TEMMOKU GOLD
glazes; they get glaze recipes from books or (Cone 6) (Cone 6)
from friends and then vary the colorants Wollastonite. . . . . . . . . . . . . . . . . . . . . 28 %. % Cornish Stone . . . . . . . . . . . . . . . . 67.41 %. %
and opacifiers. Frit 3195 (Ferro). . . . . . . . . . . . . . . . . . 23 Dolomite . . . . . . . . . . . . . . . . . . . . 7.86
Although change is hard, potters should Nepheline Syenite . . . . . . . . . . . . . . . . 4 Gerstley Borate . . . . . . . . . . . . . . . 3.37
EPK Kaolin. . . . . . . . . . . . . . . . . . . . . . 28
focus on the benefits of firing mid-range Lithium Carbonate. . . . . . . . . . . . . 6.17
Silica (Flint). . . . . . . . . . . . . . . . . . . . . . 17 Whiting . . . . . . . . . . . . . . . . . . . . . 8.98
reduction. First, as stated above, it saves 100 % Silica (Flint). . . . . . . . . . . . . . . . . . . 6.17
fuel, reduces your carbon footprint and
Add: Red Iron Oxide. . . . . . . . . . . . . . . 6 %. % 100.00 %
costs less. Second, it saves time. It may take Add: Red Iron Oxide. . . . . . . . . . . 11.24 %. %
Rutile. . . . . . . . . . . . . . . . . . . . . . 6 %. %
2–4 hours to get the extra temperature of
cone 10 and maybe longer depending on
the size of the kiln. So rather than firing for
10–12 hours you will be out in 8–10 hours.
Firing to mid-range also reduces the wear
and tear on your kiln, which means that it
lasts longer. Finally, and most importantly,
you get great results!
After all this testing, we discovered that
the methods used to test high-fire glaze
types also apply to mid-range types and, as
a result, we found some very nice glazes.
Erik, Luba and the potters of MudFire
Clayworks are proof of that. Hopefully,
this will help other potters get started firing
to mid-range reduction.

the author John Britt lives in Bakersville, North


Carolina, and is the author of the book The Com-
plete Guide to High-Fire Glaze: Glazing & Firing Tumblers, 7 in. (18 cm) in height, stoneware with Gold Temmoku liner
at Cone 10. For more information and to see John’s and Raw Sienna exterior glaze, gas fired in reduction to cone 6, by
work, go to www.johnbrittpottery.com. Erik Haagensen.

www.ceramicartsdaily.org | Copyright © 2010, Ceramic Publications Company | Making the Switch from Cone 10 to Cone 6 Ceramic Glaze Recipes | 6
Cone 6 Crystals:
Developing Crystals at Mid Range
by William Schran

M
Four vessels, to y fascination with firing to cone 6 would also pro-
8 inches in height, macrocrystalline duce crystals. I had some limited
thrown B-Mix clay.
glazes began as a success with these glazes, but that
Glazes are as follows.
Left to right: Fa’s graduate student. comment stuck in my head.
Cone 6 Base (Revised) While visiting a local exhibition Fast forward to 1994. Discus-
glaze with 3% of an individual’s collection, I dis- sions of glazes with a group of my
manganese dioxide covered two small porcelain bottles students lead to a question about
and .5% cobalt by Herbert Sanders. The glazes ap- crystalline glazes. This one ques-
carbonate; MFE (Dan
Turnidge Revised)
peared to have blue colored snow- tion resulted in a semester-long
glaze with 3% flakes frozen on a transparent sky series of glaze tests that resulted in
manganese dioxide of orange. From that initial en- few successes. It was the problem I
and 1% cobalt counter, macrocrystalline glazing had encountered years before, our
carbonate; Fa’s Cone has become a process that I’ve re- electric kilns only reached cone
6 Base glaze revised
visited many times over the years. 9–10 with much difficulty. The
with 3% manganese
dioxide and .5% Sanders had published Glazes lack of success producing crystals
cobalt carbonate; and for Special Effects in 1974, which by my students only strengthened
MFE (Dan Turnidge contained recipes for crystalline my resolve to find a solution. It
Revised) glaze with glazes. In 1976, I began experi- was then, that I recalled the Snair
3% manganese menting with several recipes listed article and the comment about
dioxide and 1%
cobalt carbonate.
in the book, but since it was dif- cone 6.
ficult to fire our electric kilns to With additional information
the required cone 9–10 tempera- gathered through internet searches
ture range, I had little success. An and interlibrary loans, I discovered
article by David Snair in Ceramics some artists experimenting with
Monthly provided additional glaze crystalline glazes at lower tem-
recipes and techniques for prepar- peratures. Since we conducted our
ing the pots for firing. Though glaze firings to cone 6 at school,
all the recipes were for cone 9, a I decided to target this tempera-
comment in the article stated that ture for my testing. My initial
www.ceramicartsdaily.org | Copyright © 2010, Ceramic Publications Company | Making the Switch from Cone 10 to Cone 6 Ceramic Glaze Recipes | 7
experiments involved firing cone those that produced only limited
10 glaze recipes only to cone 6. success. Web searches and recent
These tests resulted in the discov- publications provide a variety of
ery that crystalline glazes could be approaches to this very involved
produced in this lower tempera- process, and each individual needs
ture range by simply introducing to conduct tests to find the process
additional fluxes. The flux that that makes the most sense for his
seemed to produce the best results or her particular circumstances.
was lithium carbonate. Other Crystalline glazes produce the
materials that would function as a best results when applied to a
powerful flux were either soluble smooth white clay body. Many
or contained additional silica and artisans work with a porcelain
alumina, which are not desirable clay body. Porcelain comes with its
in crystalline glazes. own set of issues and I have found
All of my experiments with a cone 10 porcelaneous stoneware
crystalline glaze firings, up until clay—B-Mix or Bee-Mix—that
fall 2006, have been done in a works very well with my glazes.
manually operated electric kiln. I chose to use a cone 10 clay to
The kiln has infinite controls, so reduce the amount of alumina that
with careful monitoring, I was might be picked up by the glaze.
able to control the firing sched- A normal glaze has a mix of
ule fairly accurately. A digital silica/flux/alumina in a ratio that
pyrometer is an essential tool to provides a glassy surface and
closely track temperature changes, remains in place when melted on
especially during long holding a vertical surface. A crystalline
cycles. Acquisition of my first kiln glaze contains little or no alu-
with a programmable controller mina, which would inhibit crystal
has allowed for more complicated, growth. The glaze is comprised of
repeatable firing schedules. The silica, flux and a saturation of zinc
ability to be able to alter tempera- oxide. This highly fluxed mix of
ture ramp speeds and specific tem- materials leads to a very fluid glaze
perature hold times has opened up and steps must be taken to avoid
new avenues of experimentation. destroying kiln shelves or the kiln.
I have also found that, for both
types of kilns, a direct vent system Catch Basins
is important for rapid cooling and Pedestals
cycles and maintaining an oxidiz- Every pot must have its own catch
ing atmosphere. plate/basin to contain the glaze
Crystalline that runs off the pot. The catch
plate need not be made from the
Technique same clay as the pot. The plate can
I’ve developed techniques through be wheel thrown or hand built.
years of experimentation, adopting Each pot must also have some type
processes that worked, eliminating of pedestal device to facilitate re

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1 2

Crystalline glazes run off the pot so you need to raise Apply three to four coats of glaze to achieve the
the piece on a pedestal that sits in a catch basin. It’s desired thickness, brushing each layer in a different
important to select a pedestal that closely matches the direction to ensure that brush strokes aren’t visible
diameter of the foot. Preparing several sizes allows and you have an even coating.
you to select one with the correct fit.

3 4

Pieces ready to load in the kiln. Each After the firing, the fluid glaze will
glazed pot is positioned on a pedes- have run down over the pedestal and
tal that is placed in a catch basin. into the catch basin.

moval of the pot after firing. Some a mix of white glue, which holds
potters use insulating firebrick the pedestal in place before firing,
to create the pedestal. The brick and kaolin, which acts as a sepa-
must be at least a 2600K-type and rating agent after firing. Striking
coated with kiln wash. Another with a sharp chisel or heating with
technique involves throwing the a small torch just below the joint
pedestal from the same clay body with the pot removes the pedestal.
as the pot. After bisque firing, the After encountering a number of
pedestal is attached to the pot with problems with each of these

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materials and form the mix into
5 ¾-inch thick “biscuits” cut to the
foot diameter of the bisque fired
WARNING
pot using round cookie cutters. Proper eye and respira-
I’ve found this material to stand tory protection must be
up well to the melting glaze and worn during this pro-
soft enough to be easily knocked cess. Do all grinding
off with a chisel. Any remaining outside the studio, if
pedestal is easily ground away possible.
from the pot.

Glaze Application
Crystalline glazes may be applied
The pedestal and catch basin are re-
moved by tapping with a small chisel like most other glaze, but since
along the line where the pedestal I don’t have spray equipment or
joins the pot. room in my studio to store large

6 7

Excess pedestal material and glaze I use a portable flat lap machine
are ground off the bottom using a fitted with diamond grinding and
bench grinder fitted with a silicon smoothing disks to even out and
carbide grinding wheel. smooth the bottom of the foot with
100 and 260 grit disks. Since water is
methods, such as pots falling over used in this process, I do this in the
or broken foot rings, I sought studio, but still wear eye protection.
another solution. Ellie Blair, a Self-adhesive diamond disks or silicon
carbide disks can be attached to plas-
fellow crystalline artist, provided tic bats and the potters wheel used
this process to me—the pedestals to grind and smooth the bottoms.
are a mix of equal parts by vol-
ume: alumina, kaolin and sawdust.
Add just enough water to bind the

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buckets of glaze, I apply crystal- time to heat and cool kiln furni-
line glazes by brush. Most of the ture than it does the pots. Always
time I mix a few hundred grams at use witness cones in every firing.
a time, which is sufficient to glaze Even if you fire with a program-
two or three small pots. Since the mable kiln and don’t look at the
crystalline glaze contains no added cones during the firing, they will
clay to keep the glaze in suspen- be the best record of the firing.
sion, you don’t want to add just Keep meticulous notes of every
water to wet the glaze. To wet the firing. Keep a logbook of your fir-
glaze, I use a CMC gum solution ings and cross-reference each glaze
by adding about two heaping to its firing. Fara Shimbo and Jon
tablespoons of CMC powder to Singer gave the best advice dur-
one quart of hot water. I let the ing a presentation at the Lattice
powder soak into the water for at Structures Crystalline Glaze Sym-
least 24 hours. The soaked gum posium in fall 2005: When you’re
is then stirred, resulting in a thin testing, change only one thing at a
honey consistency. I add this to the time. If you alter the glaze in any
dry glaze, stir and pass through way, change only one amount or
40 mesh, then 80 mesh sieves. material at a time. Do not change
The wetted glaze should have the anything else. If you alter the firing
consistency of thick honey.
schedule, do not change the glaze
Apply the glaze fairly thick. I ap-
until you see what change the fir-
ply one coat by brush horizontally
ing has made.
around the pot. When that dries,
Should the pot come out of the
I apply a second coat vertically,
firing with few or no crystals, take
then a third coat in a diagonal di-
heart and give it another chance.
rection to the upper ²/³ of the pot.
If the glaze has not filled the catch
Sometimes I’ll apply a fourth coat
plate, simply apply another coat of
to the top.
the same glaze or a different glaze
On the interior of vase/bottle
forms and on the exterior of and fire it again. Should the catch
bowls, I use a cone 6 stoneware plate be filled with glaze, it will
glaze. I selected a glaze that fits my be necessary to remove the pot
clay body to create a watertight from the pedestal, grind the foot
seal. With a crystalline glaze on even and create another pedestal
just the interiors of bowls, I don’t and catch plate. I have refired
have to be concerned with pedes- some pots up to five times before
tals or catch plates. I achieved results that were to my
satisfaction.
Firing
Pots, with their pedestals and Cleanup
catch plates, are loosely loaded in After the firing, knock the pedestal
the kiln. In my 4 cubic-foot-kiln, loose with a small chisel or screw-
I will have at the most a dozen driver. Strike the pedestal material,
pots. Avoid using too much kiln not the joint between the pots and
furniture. It takes more energy and pedestal. I use a bench grinder

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fitted with a silicon carbide grind-
ing wheel to remove any remain-
ing pedestal material and glaze.
I do all of my grinding outside
and I always wear proper eye and
respiratory protection. After coarse
grinding, I use a portable flat lap
fitted with diamond disks to even
out and smooth the foot. Silicon
carbide disks and diamond disks
with self adhesive backing can be
attached to plastic bats and used on
the wheel to grind and smooth pot
bottoms. Squirting or spraying with
water while grinding will help keep
down the dust.

Firing Schedule
Use one of the following firing
schedules for cone 6 crystalline
glazes. You will need to experi-
ment to determine the best firing
schedule for your kiln. The abil-
ity of the kiln to respond to rapid
heating and cooling ramps is a
critical factor in successful crystal-
line glazes. Kilns should be loaded
loose, using as little kiln furniture Bottle, 7 inches in height, thrown B-Mix clay,
with Fa’s #5 (Revised) glaze with additions of 4%
as possible. Older, well-used ele-
manganese dioxide and 1% cobalt carbonate.
ments may not be able to keep up
with programmed demands of the
kiln. I’ve found heavy duty ele-
ments begin to be unable to keep
up with the programmed firing
schedule after about forty crystal-
line firings.

For Manual Kilns with Infinite Control


n Low – ½ hour n Turn on kiln to a medium setting
n Medium – ½ hour and monitor closely.
n Try to maintain the holding
n High – cone 6 over
temperature for 3–4 hours.
n Turn off kiln, cool to holding

temperature (1850°F–1880°F)

Each section of the kiln may need to have a different setting to maintain a constant
temperature. For my kiln, a setting of #3 on the top and middle section, and “M” setting
on the bottom section provided a fairly consistent reading.

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For Programmable Kilns
Note: My kiln uses an “S” type platinum thermocouple with the thermocouple offset
turned off. Each kiln may indicate a different temperature when cone 6 bends over. Use
witness cones and closely monitor them until the correct peak temperature is determined.

n Increase temperature n Hold at 2210ºF for 10 minutes


350°F per hour to 700°F n Cool down 750°F per hour to
n Increase temperature 2000°F, hold for 1 hour
750°F per hour to 2000°F n Cool down 750°F per hour to
n Increase temperature 1900°F, hold for 3 hours
150°F per hour to 2210°F n Kiln off, vent off, total firing
(this puts cone 6 over, 9–9½ hours
cone 7 at 1 o’clock position)

Higher holding temperatures results in fewer but larger crystals with more ground (areas
without crystals) exposed.

Crystalline
Base Glazes
MFE Fa’s #5 (Revised)
(Dan Turnidge Revised) Cone 6
Cone 6 Zinc Oxide . . . . . . . . . . . . . . . . . . . . 27.0 %. %
Talc . . . . . . . . . . . . . . . . . . . . . . . . . . 5.0
Ferro Frit 3110. . . . . . . . . . . . . . . . . 50.0 %. %
Ferro Frit 3110. . . . . . . . . . . . . . . . . 50.0
Silica (325 mesh) . . . . . . . . . . . . . . . 22.5.
Spodumene. . . . . . . . . . . . . . . . . . . . 4.0
Zinc Oxide . . . . . . . . . . . . . . . . . . . . 22.5.
Silica (325 mesh) . . . . . . . . . . . . . . . 14.0
95.0 %
100.0 %
Add: . . . . . . . . Lithium Carbonate 1–5.0 %. %
Add: Titanium Dioxide. . . . . . . . . . . . 2.0 %. %

Fa’s Base (Revised)


Colorants
Cone 6 Add the following colorants individually or in
Zinc Oxide . . . . . . . . . . . . . . . . . . . . 25.0 %. % combination:
Dolomite . . . . . . . . . . . . . . . . . . . . . . 5.0
Cobalt Carbonate . . . . . . . . . . . 0.25–3.0 %
Ferro Frit 3110. . . . . . . . . . . . . . . . . 51.0
Copper Carbonate. . . . . . . . . . . . 0.5–6.0 %. %
Silica (325 mesh) . . . . . . . . . . . . . . . 19.0
Manganese Dioxide . . . . . . . . . . . 0.5–3.0 %. %
100.0 %
Iron Oxide . . . . . . . . . . . . . . . . . . 0.5–3.0 %. %
Add: Lithium Carbonate. . . . . . . . . 2–4.0 %. % Rutile. . . . . . . . . . . . . . . . . . . . . . 0.5–3.0 %. %
Nickel Oxide . . . . . . . . . . . . . . . . 0.25–3.0 %

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Traditional Cone 10
Glazes Make the
Leap to Cone 6
by Rick Malmgren

Undulating Rim Platter, 16 inches in diameter, wheel-


thrown and altered white stoneware, with Blue-Green/
Copper Red Glaze sprayed over scrap glaze, fired to Cone 6
in reduction.

I
have become a strong advocate of Cone 6 reduction used to take me is where the real savings comes in. At
firing in recent years. My reasons are as follows: Cone 6, I can fire during the day and teach at night,
• Lovely traditional glazes look as good as or better on a more normal work schedule.
fired at Cone 6 than they do at Cone 10. Copper reds, • Though I’ve fired my kiln more than 700 times, each
Shinos, temmokus and dolomite matts are virtually firing takes its toll. The hotter it is fired, the harder it
indistinguishable from their Cone 10 brethren. Some is on the arch, the walls and the shelves. There is that
Cone 10 glaze recipes don’t even need to be adjusted— much more expansion and that much more contrac-
a few look just great at Cone 6. tion, and that much more slumping. Cutting the tem-
• Fuel savings amount to about 30% over a Cone 10 perature saves all the way around.
firing. Granted, that isn’t much per firing (only the cost • Mountains of research have already been done for
of two coffee mugs per kiln load, as Pete Pinnell once Cone 6 oxidation, resulting in thousands of recipes.
said), but if you are burning $2000 worth of propane Oxidation potters have had to work hard with for-
per year, as I was a few years ago, it amounts to a nice mulation to bring vitality to their glazes; they can’t
$600 bonus at the end of the year. depend on the atmosphere to do the work for them.
• The savings in fuel costs is nothing, compared with Many of those same recipes fired in a reduction kiln
the savings of time and energy. Being able to fire off are simply dazzling.
a full kiln load in 7½ hours instead of the 10½ that it The following are my favorite recipes.
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Blue-Green/Copper SDSU Texture/Crawl Glaze Turquoise Glaze
Red Glaze Cone 6, oxidation or reduction Cone 6, oxidation or reduction
Cone 6, oxidation or reduction Magnesium Carbonate. . . . . . . . . . . . 25 %. % Talc . . . . . . . . . . . . . . . . . . . . . . . . . 11.7 %. %
Talc . . . . . . . . . . . . . . . . . . . . . . . . 3.30 %. % Nepheline Syenite . . . . . . . . . . . . . . . 70 Whiting . . . . . . . . . . . . . . . . . . . . . . 11.1
Whiting. . . . . . . . . . . . . . . . . . . . . 14.29 Kentucky Ball Clay (OM 4) . . . . . . . . . 5 Custer Feldspar . . . . . . . . . . . . . . . . 14.9
Frit 3134 (Ferro). . . . . . . . . . . . . . . 13.33 100 % Frit 3134 (Ferro). . . . . . . . . . . . . . . . 23.4
Kona F-4 Feldspar . . . . . . . . . . . . . 46.16 Edgar Plastic Kaolin . . . . . . . . . . . . . 19.1
Richard Burkett posted this glaze on Clayart
Edgar Plastic Kaolin . . . . . . . . . . . . 6.40 Flint. . . . . . . . . . . . . . . . . . . . . . . . . 19.8
several years ago. It is very sensitive to
Flint. . . . . . . . . . . . . . . . . . . . . . . . 16.52 100.0 %
thickness. Use by itself or over a contrasting
100.00 % glaze. Colorants can be added. Add: Cobalt Oxide. . . . . . . . . . . . . . 0.5 %. %
Add: Tin Oxide. . . . . . . . . . . . . . . . 2.24 %. % Chrome Oxide . . . . . . . . . . . . 0.5 %. %
Zinc Oxide. . . . . . . . . . . . . . . 4.37 %. %
Marilee’s Lava Glaze A lovely magnesium matt glaze that works
Black Copper Oxide. . . . . . . . 1.07 %. % Cone 6, oxidation or reduction well in oxidation or reduction; the base
A lovely celadon blue-green in oxidation. glaze also works well with other colorants.
Whiting . . . . . . . . . . . . . . . . . . . . . 23.91 %. %
In reduction, bright red; the color tends to Custer Feldspar . . . . . . . . . . . . . . . 49.73
burn off when near a heat source. Covering
Bronze Green Matt Glaze
Edgar Plastic Kaolin . . . . . . . . . . . . 13.18
with clear glaze helps reduce burning out Flint. . . . . . . . . . . . . . . . . . . . . . . . 13.18 Cone 6, oxidation or reduction
of the red. 100.00 % Whiting . . . . . . . . . . . . . . . . . . . . . 24.20 %. %
Custer Feldspar . . . . . . . . . . . . . . . 54.90
Shino Glaze Add: Titanium Dioxide. . . . . . . . . . 11.29 %. %
Edgar Plastic Kaolin . . . . . . . . . . . . 14.30
Silicon Carbide. . . . . . . . . . . 0.34 %. %
Cone 6, reduction Flint. . . . . . . . . . . . . . . . . . . . . . . . 6.60
A very rough glaze; not intended for food
Soda Ash. . . . . . . . . . . . . . . . . . . . . . 10 %. % 100.00 %
surfaces. Fine silicon carbide seems to work
Spodumene. . . . . . . . . . . . . . . . . . . . 40 best. For a gray-to-black variation, add 7% Add: Zinc Oxide. . . . . . . . . . . . . . . 9.90 %. %
Nepheline Syenite . . . . . . . . . . . . . . . 40 Mason stain 6600. Cobalt Oxide. . . . . . . . . . . . . 0.44 %. %
Edgar Plastic Kaolin . . . . . . . . . . . . . . 10 Copper Carbonate. . . . . . . . . 2.97 %. %
100 % SJC Turquoise/Red Glaze Rutile. . . . . . . . . . . . . . . . . . . 5.94 %. %
Apply very thinly to give an almost salt- Cone 6, oxidation or reduction
glazed look in reduction. Tends to be a bit
Rust Red Glaze
Gerstley Borate . . . . . . . . . . . . . . . . 5.1 %. %
bland in oxidation, but an addition of 4% Whiting . . . . . . . . . . . . . . . . . . . . . . 5.8 Cone 6, reduction
rutile seems to warm it up a bit. Custer Feldspar . . . . . . . . . . . . . . . . 34.9 Bone Ash. . . . . . . . . . . . . . . . . . . . . 4.0 %. %
Frit P-25 (Pemco) . . . . . . . . . . . . . . . 25.3 Talc . . . . . . . . . . . . . . . . . . . . . . . . . 4.0
Temmoku Glaze Kentucky Ball Clay (OM 4) . . . . . . . . 3.6 Whiting . . . . . . . . . . . . . . . . . . . . . . 20.0
Cone 6, reduction Flint. . . . . . . . . . . . . . . . . . . . . . . . . 25.3 Custer Feldspar . . . . . . . . . . . . . . . . 50.0
Whiting. . . . . . . . . . . . . . . . . . . . . . . 20 %. % 100.0 % Frit 3110 (Ferro). . . . . . . . . . . . . . . . 4.0
Custer Feldspar . . . . . . . . . . . . . . . . . 35 Edgar Plastic Kaolin . . . . . . . . . . . . . 18.0
Add: Copper Carbonate. . . . . . . . . . 3.0 %. %
Kentucky Ball Clay (OM 4) . . . . . . . . . 15 100.0 %
A glassy green in oxidation; in reduction,
Flint. . . . . . . . . . . . . . . . . . . . . . . . . . 30 a bright red. Good when used to overlap Add: Tin Oxide. . . . . . . . . . . . . . . . . 4.0 %. %
100 % other glazes. When sprayed over Annette’s Black Iron Oxide. . . . . . . . . . . . 5.0 %. %
Add: Red Iron Oxide. . . . . . . . . . . . . . 10 %. % Florida Tan, it gives a highly speckled look, A Cone 6 version of Shaner’s Red; it is very
A Cone 10 recipe that works equally well at particularly where it is thin. The two base sensitive to application thickness, reduction
Cone 6; yields yellow “tea dust” crystals in glazes can be colored with different color- and clay body. The best reds seem to come
reduction. Not as interesting in oxidation; ing oxides and still give the same speckled from relatively thin applications on high-iron
just lies there and looks brown. look when they overlap. clays, with a moderate reduction from Cone
010 to the end of the firing.
Straw Glaze Annette’s Florida Tan Glaze
Cone 6, oxidation or reduction Cone 6, oxidation or reduction
Dolomite. . . . . . . . . . . . . . . . . . . . . 13.1 %. % Dolomite . . . . . . . . . . . . . . . . . . . . 6.58 %. %
Lithium Carbonate. . . . . . . . . . . . . . 3.3 Gerstley Borate . . . . . . . . . . . . . . . 13.05
Whiting. . . . . . . . . . . . . . . . . . . . . . 3.9 Soda Ash. . . . . . . . . . . . . . . . . . . . 0.11
Frit 3134 (Ferro). . . . . . . . . . . . . . . . 27.5 Talc . . . . . . . . . . . . . . . . . . . . . . . . 13.05
Edgar Plastic Kaolin . . . . . . . . . . . . . 22.2 Custer Feldspar . . . . . . . . . . . . . . . 41.01 Angle Cut-Rim
Flint. . . . . . . . . . . . . . . . . . . . . . . . . 30.0 Edgar Plastic Kaolin . . . . . . . . . . . . 6.58 Vase, 11 inches
100.0 % Flint. . . . . . . . . . . . . . . . . . . . . . . . 19.62 in height, with
100.00 % SJC Turquoise
Add: Copper Carbonate. . . . . . . . . . 2.5 %. %
Add: Zircopax . . . . . . . . . . . . . . . . 9.65 %. % sprayed over
Red Iron Oxide. . . . . . . . . . . . . 2.0 %. %
Red Iron Oxide. . . . . . . . . . . . 1.97 %. % Annette’s Florida
A mossy green glaze (in oxidation or reduc-
Rutile. . . . . . . . . . . . . . . . . . . 5.48 %. % Tan Glaze,
tion) with matt crystals suspended within
Best as a background for other glazes, such $90, by Rick
glassy fields. Very promising when tested
as SJC Turquoise/Red. Yields similar results Malmgren, Lo-
with other colorants, including white (add-
in oxidation or reduction. thian, Maryland.
ing no colorants) and blue (adding 1.5%
cobalt carbonate).

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