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1 (2017) P a g e |1
National Institute of Geological Sciences, College of Science, University of the Philippines, Diliman, Quezon City 1101
2
ABSTRACT
THE EXPERIMENT WAS CONDUCTED TO DESCRIBE THE KINETICS OF THE REACTION OF I- AND S2O82- BY USING
DIFFERENT CONENTRATIONS OD THE REACTANTS WITH A CONSTANT CONCENTRATION OF S 2O82-, USE THE INITIAL
RATE METHOD TO DETERMINE THE RATE LAW OF THE REACTION, OBSERVE THE EFFECT OF TEMPERATURE ON THE
REACTION RATE BY HEATING THE REACTANTS AND COOLING AND TIME THE REACTION RATE OR THE TIME IN WHICH
THE SOLUTION HAS CHANGED COLOUR, SPECIFICALLY A BLUE-BLACK COLOUR. A STARCH WAS USED AS AN INDICATOR
OF THE END POINT OF THE REACTION AS IT FORMED A BLUE-BLACK COMPLEX IODINE-STARCH COMPLEX. THE
DIFFERENT RUNS WAS TIMED FOR AND THE TIME WAS USED TO CALCULATE THE REACTION RATE, DETERMINE THE
RATE OF THE REACTION AND THE RATE CONSTANT.
reactants, a rate law is used: Rate = k[A]m[B]n, where k is Results and Discussion (Cambria 10, Bold)
the rate constant, [A] and [B] are the concentrations of the
reactants, and m and n pertain to the order of the reaction Table 1. Effect of Reactant Concentration on Reaction
with respect to concentration of A and B respectively. Thus Rate
the rate law between the reaction of iodine and thiosulfate Runs [S2O8 ] [I ]
2- - [S2O32-] Time, s Rate, M/s
in figure 2 shows that the rate is directly proportional to 1 0.02 0.08 8x10-4 174.8 2.29x10-6
the concentrations of iodide ion and persulfate. 2 0.02 0.04 8x10-4 308 1.30x10-6
3 0.02 0.02 8x10 -4 745 5.37x10-7
The Arrhenius equation describes the effect of 4 0.03 0.04 8x10 -4 117.91 3.40x10-6
temperature on the reaction rate: 5 0.04 0.04 8x10 -4 34.7 1.15x10-5
Table 2. Effect of Temperature and Catalyst on Reaction the humans response time might differ in stopping the
Rate stop watch once solutions have turned blue. This could be
Run 2 Temp, K Time, s Rate, M/s k, M-1sec-1 remedied by doing more trials to make the data and the
Set 1 301 308.6 1.31x10-6 1.63x10-3 result more reliable to use.
Set 2 332 5.3 7.55x10-5 9.43x10-2
References (Cambria 10, Bold)
Set 3 279 2,233 1.79x10-7 2.24x10-4
Set 4 297 123 3.25x10-6 4.06x10-3 [1] Pauling, L. 1970 General Chemistry. US: Dover
Publications.
[2] Ebbing, D., Gammon, S., 2009, General Chemistry,
One factor affecting the rate is the temperature as shown Cengage Learning
in the equation below. As the activation of energy E a, gets [3] A2-Level Chemistry Exam Board: Edexcel Complete
bigger, k gets smaller. So a large activation energy will Revision and Practice 2009. CGP
mean a slow rate. The equation also shows that as the [4] Rate Laws from Graphs of Concentration Versus Time
(Integrated Rate Laws) nd, Integrated Rate Laws.
temperature rises, k increases. [5]
Retrieved June 19 2017. From
Ea
http://www.chem.purdue.edu/gchelp/howtosolveit/Kinet
k = Ae RT ics/IntegratedRateLaws.html
Ea [5] Clark Jim 2002 Retrieved June 19, 2017
ln k = + ln A
RT http://www.chemguide.co.uk/physical/basicrates/arrheni
us.html
Referring to Table 2, Set 1 was done at room temperature,
set 2 was heated using a hot plate and set 3 was cooled
using ice bath. Larger k or temperature means larger rate
of reaction. This can be explained by the collision theory
where particles get more excited at high temperature,
colliding more often and also more particles have a more
sufficient energy to collide and this causes a faster rate of
reaction.
ln
(1/T)
1/T
Figure 4. Effect of temperature on reaction rate by the
Arrhenius equation.