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Buffer 138 mV

EXTERNAL CALIBRATION METHOD

Standard (ppm) Trial 1 Trial 2 Trial 3 log[F-]


0.5 61.3 59 56.8 -0.3010299957
1 59.5 57.3 55.5 0
2 39.5 38 35.9 0.3010299957
3 25.1 24.7 23.8 0.4771212547

Trial 1 Trial 2 Trial 3 ave. mV


Sample -15.5 -14.7 -14.2 -14.8

slope -45.497460409
intercept 50.1269513492

-45.497460409 50.1269513492
stdev of slope 11.5124837545 3.6807681313 stdev of intercept
0.8864822466 6.8300339648
15.6183895532 2
728.5879387453 93.2987279214

STANDARD ADDITION METHOD

Sample 0: No addition (mV) 1st: 25L (mV) 2nd: 50L (mV) 3rd: 75L (mV)
1 10.4 -0.2 -8.1 -13.9
2 8.5 -2.9 -10.8 -16.1
3 5.8 -5.8 -12.9 -18.5
average mV 8.2333333333 -2.9666666667 -10.6 -16.1666666667
Vtotal 10 10.025 10.05 10.075
slope -45.497460409

y values 6.5923084357 11.649022549 17.1848639621 22.8336974875


x values 0 0.025 0.05 0.075

slope
Vtotal x 10^(E/m) vs. Vstd intercept
50
40 V'
Vtotal x 10^(E/m)

f(x) = 253.9510775714x + 5.3258947752 [F-]


30
R = 0.9884757483
20
10
0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14
Volume of Standard Added
f(x) = 253.9510775714x + 5.3258947752

Vtotal x 10^(E/
30
R = 0.9884757483
20
10
0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14
Volume of Standard Added
average mV per std
59.0333333333
mV vs. log[F-]
57.4333333333 70
37.8 60
f(x) = - 45.497460409x + 50.1269513492
24.5333333333 50
R = 0.8864822466

millivolts
40
30
calculated [F-] in ppm
20
26.7328717289
10
0
-0.4 -0.3 -0.2 -0.1 0 0.1 0.2 0.3 0.4 0.5 0.6
Concentration of Standard F- (in log[F-])

of intercept

4th: 100L (mV) 5th: 125L (mV)


-21.5 -28.9
-20.8 -24.6
-22.4 -26.2
-21.5666666667 -26.5666666667
10.1 10.125

30.0843411778 38.8427891283
0.1 0.125

253.9510775714
5.3258947752

0.0209721291
2.0972129066
]
13492

0.3 0.4 0.5 0.6


in log[F-])

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