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The data in this table are presented as values of pKa, defined as can be calculated from the equation
the negative logarithm of the acid dissociation constant Ka for the
reaction OH NH 4 +
K b = K water /K a =
[ NH 3 ]
BH B + H+
Thus pKa = log Ka , and the hydrogen ion concentration [H+] can where Kwater = 1.01 1014 at 25 C. Note that pKa + pKb = pKwater.
be calculated from All values refer to dilute aqueous solutions at zero ionic strength
at the temperature indicated. The table is arranged alphabetically
H+ B by compound name.
Ka =
[ BH ]
Reference
In the case of bases, the entry in the table is for the conjugate acid;
1. Perrin, D. D., Ionization Constants of Inorganic Acids and Bases in
e.g., ammonium ion for ammonia. The OH concentration in the Aqueous Solution, Second Edition, Pergamon, Oxford, 1982.
system
8-40