Basic Derivatives

V(T,P)

V V
dV = ( T )P dT + ( P )T dP

1 V
= V ( )P isobaric thermal expansivity, coefficient of thermal expansion
T
1 V
= = V ( )T isothermal compressibility
P
dV = V dT - V dP
do and give everything we need to know about mechanical behavior?
(P ) =?
T V
V V
0 = dV = ( ) dT + ( )T dP
T P P

(V)
P T
dP = (
V
) dT
T P
V
( ) dT
T P
dP =
(V )
P T
V
( )
(P ) =
T V
T P
(V)
P T
for small changes V doesn't change much: V Vo
cst. P dV = V dT
V2 T2
dV = V dT V = Vo T
V1 T1

cst. T dV = -V dP
V = -Vo P